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Maria Vittoria Mazziotti

Publications and source records attributed to Maria Vittoria Mazziotti.

5 recordsLinked to original sources

Spin-orbit coupling controlling the superconducting dome of artificial superlattices of quantum wells

While it is known that a resonant amplification of Tc in two-gap superconductors can be driven by using the Fano-Feshbach resonance tuning the chemical potential near a Lifshitz transition, little is known on tuning the Tc resonance by cooperative interplay of the Rashba spin-orbit coupling (RSOC) joint with phonon mediated (e-ph) pairing at selected k-space spots. Here we present first-principles quantum calculation of superconductivity in an artificial heterostructure of metallic quantum wells with 3 nm period where quantum size effects give two-gap superconductivity with RSOC controlled by the internal electric field at the interface between the nanoscale metallic layers intercalated by insulating spacer layers. The key results of this work show that fundamental quantum mechanics effects including RSCO at the nanoscale (Mazziotti et al Phys. Rev. B, 103, 024523, 2021) provide key tools in applied physics for quantitative material design of unconventional high temperature superconductors at ambient pressure. We discuss the superconducting domes where Tc is a function of either the Lifshitz parameter (?) measuring the distance from the topological Lifshitz transition for the appearing of a new small Fermi surface due to quantum size effects with finite spin-orbit coupling and the variable e-ph coupling g in the appearing second Fermi surface linked with the softening of the phonon energy cut off.

cond-mat.supr-con↗

Scale free distribution of oxygen interstitials wires in optimum doped HgBa$_2$CuO$_{4+y}$

Novel nanoscale probes are opening new venues for understanding unconventional electronic and magnetic functionalities driven by multiscale lattice complexity in doped high temperature superconducting perovskites. In this work we focus on the multiscale texture at supramolecular level of atomic oxygen interstitials (O-i) stripes in HgBa$_2$CuO$_{4+y}$ at optimal doping for the highest superconducting critical temperature $T_C$=94K. We report compelling evidence for the nematic phase of oxygen-interstitial O-i atomic wires with fractal-like spatial distribution over multiple scales by using scanning micro and nano X-ray-diffraction. The scale free distribution of O-i atomic wires at optimum doping extending from micron scale down to nanoscale has been associated with the intricate filamentary network of hole rich metallic wires in the CuO$_2$ plane. The observed critical opalescence provides evidence for the proximity to a critical point controlling the emergence of high temperature superconductivity at optimum doping

cond-mat.supr-con↗

Resonant multigap superconductivity at room temperature near a Lifshitz topological transition in sulfur hydrides

The maximum critical temperature for superconductivity in pressurized hydrides appears at the top of superconducting domes in Tc versus pressure curves at a particular pressure, which is not predicted by standard superconductivity theories. The a high-order anisotropic van Hove singularity near the Fermi level observed in band structure calculations of pressurized sulfur hydride, typical of a supermetal, has been associated with the array of metallic hydrogen wires modules forming a nanoscale heterostructure at atomic limit called superstripes phase. Here we propose that pressurized sulfur hydrides behave as a heterostructure made of a nanoscale superlattice of interacting quantum wires with a multicomponent electronic structure. We present first-principles quantum calculation of a universal superconducting dome where Tc amplification in multi-gap superconductivity is driven by the Fano-Feshbach resonance due to configuration interaction between open and closed pairing channels, i.e., between multiple gaps in the BCS regime, resonating with a single gap in the BCS-BEC crossover regime. In the proposed three dimensional (3D) phase diagram the critical temperature shows a superconducting dome where Tc is a function of two variables (i) the Lifshitz parameter ($η$) measuring the separation of the chemical potential from the Lifshitz transition normalized by the inter-wires coupling and (ii) the effective electron phonon coupling (g) in the appearing new Fermi surface including phonon softening. The results will be of help for material design of room temperature superconductors at ambient pressure.

cond-mat.supr-con↗

Metastable states in plateaus and multi-wave epidemic dynamics of Covid-19 spreading in Italy

The control of Covid 19 epidemics by public health policy in Italy during the first and the second epidemic waves has been driven by using reproductive number Rt(t) to identify the supercritical (percolative), the subcritical (arrested), separated by the critical regime. Here we show that to quantify the Covid-19 spreading rate with containment measures (CSRwCM) there is a need of a 3D expanded parameter space phase diagram built by the combination of Rt(t) and doubling time Td(t). In this space we identify the dynamics of the Covid-19 dynamics Italy and its administrative Regions. The supercritical regime is mathematically characterized by i) the power law of Td vs. [Rt(t)-1] and ii) the exponential behaviour of Td vs. time, either in the first and in the second wave. The novel 3D phase diagram shows clearly metastable states appearing before and after the second wave critical regime. for loosening quarantine and tracing of actives cases. The metastable states are precursors of the abrupt onset of a next nascent wave supercritical regime. This dynamic description allows epidemics predictions needed by policymakers to activate non-pharmaceutical interventions (NPIs), a key issue for avoiding economical losses, reduce fatalities and avoid new virus variant during vaccination campaign

q-bio.PE↗

Possible Fano resonance for high Tc multi-gap superconductivity in p-Terphenyl doped by K at the Lifshitz transition

Recent experiments have reported the emergence of high temperature superconductivity with critical temperature $T_c$ between 43K and 123K in a potassium doped aromatic hydrocarbon para-Terphenyl or p-Terphenyl. This achievement provides the record for the highest Tc in an organic superconductor overcoming the previous record of Tc=38 K in Cs3C60 fulleride. Here we propose that the driving mechanism is the quantum resonance between superconducting gaps near a Lifshitz transition which belongs to the class of Fano resonances called shape resonances. For the case of p-Terphenyl our numerical solutions of the multi gap equation shows that high Tc is driven by tuning the chemical potential by K doping and it appears only in a narrow energy range near a Lifshitz transition. At the maximum critical temperature, Tc=123K, the condensate in the appearing new small Fermi surface pocket is in the BCS-BEC crossover while the Tc drops below 0.3 K where it is in the BEC regime. Finally we predict the experimental results which can support or falsify our proposed mechanism: a) the variation of the isotope coefficient as a function of the critical temperature and b) the variation of the gaps and their ratios 2Delta/Tc as a function of Tc.

cond-mat.supr-con↗