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Maria-Carme Calderer

Publications and source records attributed to Maria-Carme Calderer.

4 recordsLinked to original sources

Three-dimensional soliton-like distortions in flexoelectric nematic liquid crystals: modeling and linear analysis

This article models experimentally observed three dimensional particle-like waves that develop in nematic liquid crystals, with negative dielectric and conductive anisotropy, when subject to an applied alternating electric field. The liquid crystal is confined in a thin region between two plates, perpendicular to the applied field. The horizontal, uniformly aligned director field is at equilibrium due to the negative anisotropy of the media. However, such a state is unstable to perturbations that manifest themselves as confined, bullet-like, director distortions traveling up and down the sample at a speed of several hundred microns per second. It is experimentally predicted that flexoelectricity plays a key role in generating the soliton-like behavior. We develop a variational model that accounts for ansiostropic dielectric, conductive, flexolectric, elastic and viscous forces. We perform a stability analysis of the uniformly aligned equilibrium state to determine the threshold wave numbers, size, phase-shift and speed of the soliton-like disturbance. We show that the model predictions are in very good agreement with the experimentally measured values. The work models and analyzes a three-dimensional soliton-like instability reported, for the first time in flexoelectric liquid crystals, pointing towards a potential application as a new type of nanotransport device.

cond-mat.soft

A Liquid Crystal Model of Viral DNA Encapsidation

A liquid crystal continuum modeling framework for icosahedra bacteriophage viruses is developed and tested. The main assumptions of the model are the chromonic columnar hexagonal structure of confined DNA, the high resistance to bending and the phase transition from solid to fluid-like states as the concentration of DNA in the capsid decreases during infection. The model predicts osmotic pressure inside the capsid and the ejection force of the DNA as well as the size of the isotropic volume at the center of the capsid. Extensions of the model are discussed.

cond-mat.soft

Effects of permeability and viscosity in linear polymeric gels

We propose and analyze a mathematical model of the mechanics of gels, consisting of the laws of balance of mass and linear momentum. We consider a gel to be an immiscible and incompressible mixture of a nonlinearly elastic polymer and a fluid. The problems that we study are motivated by predictions of the life cycle of body-implantable medical devices. Scaling arguments suggest neglecting inertia terms, and therefore, we consider the quasi-static approximation to the dynamics. We focus on the linearized system about relevant equilibrium solutions, and derive sufficient conditions for the solvability of the time dependent problems. These turn out to be conditions that guarantee local stability of the equilibrium solutions. The fact that some equilibrium solutions of interest are not stress free brings additional challenges to the analysis, and, in particular, to the derivation of the energy law of the systems. It also singles out the special role of the rotations in the analysis. From the point of view of applications, we point out that the conditions that guarantee stability of solutions also provide criteria to select material parameters for devices. The boundary conditions that we consider are of two types, first displacement-traction conditions for the governing equation of the polymer component, and secondly permeability conditions for the fluid equation. We present a rigorous study of these conditions in terms of balance laws of the fluid across the interface between the gel and its environment. We also consider the cases of viscous and inviscid solvent, assume Newtonian dissipation for the polymer component. We establish existence of weak solutions for the different boundary permeability conditions and viscosity assumptions. We present numerical simulations to study pressure concentration on edges (debonding).

math.AP

Numerical Study of Liquid Crystal Elastomer Using Mixed Finite Element Method

We aimed to use finite element method to simulate the unique behaviors of liquid crystal elastomer, such as semi-soft elasticity, stripe domain instabilities etc. We started from an energy functional with the 2D Bladon-Warner-Terentjev stored energy of elastomer, the Oseen-Frank energy of liquid crystals, plus the penalty terms for the incompressibility constraint on the displacement, and the unity constraint on the director. Then we applied variational principles to get the differential equations. Next we used mixed finite element method to do the numerical simulation. The existence, uniqueness, well-posedness and convergence of the numerical methods were investigated. The semi-soft elasticity was observed, and can be related to the rotation of the directors. The stripe domain phenomenon, however, wasn't observed. This might due to the relative coarse mesh we have used.

math.NA