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Marie D'angelo

Publications and source records attributed to Marie D'angelo.

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Moir\'e pattern multiplicity driven by electronic effects in two-dimensional CrCl3/Au heterostructures

Moir\'e patterns are a central motif in van der Waals heterostructures arising from the superposition of two-dimensional (2D) incommensurate lattices. These patterns reveal a wealth of correlated effects, influencing electronic, magnetic, and structural phenomena. While diffraction techniques typically resolve multiple moir\'e wave-vectors corresponding to the incommensurate nature of the underlying lattices, Scanning Tunneling Microscopy (STM) often reveals only a dominant superperiod. In this work, we address this apparent discrepancy through an STM study of a twisted monolayer of CrCl3 on Au(111). We observe the coexistence of several moir\'e patterns at a fixed twist angle, whose relative intensity depends on the tunneling bias. Fourier analysis of STM data uncovers hidden higher-order moir\'e components not visible in STM topographic images, while spectroscopy maps reveal that the spectral weight of each pattern varies with electron energy. Our results establish that STM selectively probes on the same area distinct moir\'e modulations depending on electronic confinement, providing a unified framework that reconciles real space and reciprocal space observations of complex moir\'e superstructures.

cond-mat.other

Peculiar bonding associated with atomic doping and hidden honeycombs in borophene

Engineering atomic-scale structures allows great manipulation of physical properties and chemical processes for advanced technology. We show that the B atoms deployed at the centers of honeycombs in boron sheets, borophene, behave as nearly perfect electron donors for filling the graphitic $σ$ bonding states without forming additional in-plane bonds by first-principles calculations. The dilute electron density distribution owing to the weak bonding surrounding the center atoms provides easier atomic-scale engineering and is highly tunable via in-plane strain, promising for practical applications, such as modulating the extraordinarily high thermal conductance that exceeds the reported value in graphene. The hidden honeycomb bonding structure suggests an unusual energy sequence of core electrons that has been verified by our high-resolution core-level photoelectron spectroscopy measurements. With the experimental and theoretical evidence, we demonstrate that borophene exhibits a peculiar bonding structure and is distinctive among two-dimensional materials.

cond-mat.mtrl-sci