arXiv subjects

Marie-Luise Steinmeyer

Publications and source records attributed to Marie-Luise Steinmeyer.

8 recordsLinked to original sources

arXiv2026

Volatile depletion in rocky planets as a chemical fingerprint of hybrid accretion

Volatile depletion in rocky planets relative to their host stars is commonplace in both the Solar System and exoplanetary systems, yet the connections between planet formation and composition remain elusive. Here we model devolatilization during pebble accretion in combination with collisional growth from volatile-depleted planetesimals to explore the formation pathways of Earth and Mars. Using Bayesian inference, we find that bulk silicate Earth is best reproduced by ${\gtrsim}$75% contribution from two protoplanets formed via pebble accretion, supplemented by up to $\sim$25% material from planetesimals that are compositionally akin to the asteroid Vesta. Using instead a planetesimal volatile-depletion curve that is not observed among known meteorite parent bodies would allow the planetesimal contribution to reach 40$^{+15}_{-14}$%. In comparison, bulk silicate Mars reflects 27$\pm$5% pebble-accreted material and 73${\pm}$5% Vesta-like planetesimals. We identify volatile depletion as a chemical fingerprint of hybrid accretion, in which both pebble accretion and collisional assembly contribute to terrestrial planet growth. By quantitatively linking formation pathways to volatile budgets, our findings demonstrate how planetary accretion histories can be inferred from elemental signatures, with broad implications for interpreting the chemical diversity of rocky exoplanets.

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arXiv2026

Evolution and Observable Properties of Rocky Planet Atmospheres

The atmospheric composition of rocky exoplanets offers an important tool for constraining the properties of the interior of this type of planet, beyond what is possible from measurements of their mass and radius alone. However, the interpretation of these observations requires an understanding of the complex interplay of a larger number of coupled planetary and atmospheric processes. This review provides an overview of the current state of knowledge regarding rocky exoplanet atmospheres, beginning with their formation and escape mechanisms. We specifically highlight the importance of long-term interaction between the atmosphere, the surface, and the interior on rocky planets. Furthermore, this review addresses the influence of biological activity and photochemical reactions on the atmospheric compositions. Consequently, establishing how these different processes contribute to shaping the atmospheres of rocky exoplanets during their evolution is fundamental for the characterization of these planets with future space missions and ground-based surveys.

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arXiv2026

A New Global Chemical Equilibrium Code: Refractory Element Signatures in Super-Earths and Sub-Neptunes

The atmospheres of super-Earths and sub-Neptunes can be strongly modified by chemical exchange with their molten interiors during long-lived magma ocean phases. Interpreting atmospheric observations requires fast models that self-consistently couple atmospheric chemistry to the composition of the planetary interior. We present an updated implementation of the global chemical equilibrium (GCE) framework from (Schlichting & Young 2022), which computes the equilibrium composition of a coupled metal-silicate-gas system. The numerical solver has been improved using a gradient-based optimizer, reducing the computational cost of solving the chemical network by more than two orders of magnitude and enabling large parameter studies. We apply the framework to a large synthetic population of planets and explore the imprint of bulk refractory composition of Mg, Si, and Fe on atmospheric properties. We consider planets with different masses, thermal states, and volatile inventories. We find that the atmospheric mass fraction and atmospheric metal mass fraction are primarily controlled by the temperature at the atmosphere-magma ocean interface and the planetary water budget, while the accreted hydrogen mass fraction plays a minor role because most hydrogen dissolves into the interior. For planets that accreted water, the refractory ratios Mg/Si and Fe/Si strongly influence carbon partitioning between the gas, silicate, and metal phases, producing large variations in atmospheric atmospheric metal mass fraction and C/O ratios. These results demonstrate that atmospheric compositions of sub-Neptunes depend sensitively on both the volatile inventory and the bulk composition of rocky material, providing new constraints for interpreting atmospheric observations. The new GCE code is open-source.

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arXiv2026

Coupled Thermal-Chemical Evolution Models of Sub-Neptunes Reveal Atmospheric Signatures of Their Formation Location

The observed masses and radii of sub-Neptunes are typically explained by the gas dwarf and the water world scenarios. While their evolutionary history on a population level has been proposed as a method to distinguish between these compositions, previous evolutionary models, neglected the crucial role of atmosphere-interior chemical interaction. We present a novel evolution framework for sub-Neptunes that combines the thermal evolution with the chemical coupling of the atmosphere and interior. Using this model, we examine how planets formed inside and outside the water-ice line can be observationally distinguished, with an emphasis on their atmospheric properties. Young sub-Neptunes store the majority of their volatile budget in the interior, regardless of formation location. Nevertheless, the atmospheric metallicity is a factor 4 higher for the planet formed outside the water-ice line. During cooling, hydrogen and oxygen exsolve from the interior, increasing the atmospheric mass fraction and counteracting the thermal contraction. Consequently, radius evolution alone cannot distinguish between the two formation scenarios. Instead, the primary discriminators are the abundance of carbon-bearing species and the resulting atmospheric C/O ratio. For sub-Neptunes formed beyond the water-ice line, nearly all carbon resides in the gaseous phase. We find that high molar fractions of CH$_4$ ($>10^{-2}$) and H$_2$O ($> 5\times10^{-2}$), and a high C/O ratio $(> 5\times10^{-1})$ are indicative of formation outside the water-ice line. In contrast, sub-Neptunes formed inside the water-ice line exhibit strongly suppressed CH$_4$ abundances, yielding C/O ratios ranging from $10^{-7}$ to $10^{-1}$.

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arXiv2026

Densities of small planets around the M dwarfs TOI-4336 A and TOI-4342 with ESPRESSO: Three sub-Neptunes, one super-Earth, and a Neptune-mass candidate

We present the characterization of two planetary systems orbiting the M dwarfs TOI-4336 A (M3.5V) and TOI-4342 (M0V), each hosting two transiting planets previously validated with TESS and ground-based observations. We refined the photometry of the TOI-4342 system using TESS and LCOGT data, and characterized the host stars with NIRPS and ESPRESSO spectroscopy. High-precision ESPRESSO radial velocities allowed us to constrain the planetary masses and investigate their potential compositions. The TOI-4336 A system is composed of a sub-Neptune with a period of 16.34 days, a radius of $2.14 \pm 0.08$ Re, and a mass of $3.33 \pm 0.36$ Me, along with an inner super-Earth on a 7.59-day orbit with a radius of $1.25 \pm 0.07$ Re and a mass of $1.55 \pm 0.13$ Me. The TOI-4342 system hosts two sub-Neptunes of similar sizes ($2.33 \pm 0.09$ Re and $2.35 \pm 0.09$ Re), with periods of 5.54 and 10.69 days. Their masses are measured to be $7.3 \pm 1.3$ Me and $4.8 \pm 1.4$ Me, respectively. The RVs also reveal a planet candidate around TOI-4342, likely non-transiting, with a period of 47.5 days and a minimum mass of $17.8 \pm 3.0$ Me. With precise radii and masses, we derived bulk densities and explored possible compositions. The TOI-4336 A sub-Neptune and super-Earth have densities of $1.87 \pm 0.30$ and $4.35 \pm 0.79$ g cm$^{-3}$, while the two similar-sized sub-Neptunes in TOI-4342 show distinct densities of $3.18 \pm 0.67$ and $2.01 \pm 0.63$ g cm$^{-3}$. All four planets are excellent targets for future atmospheric characterization with JWST, and their multi-planet nature makes them especially interesting for comparative planetology. Notably, TOI-4336 A b stands out as one of the best-known targets in its size and temperature regime, with a TSM of 138, comparable to benchmark planets such as K2-18 b and LHS 1140 b.

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arXiv2025

Fundamentals of interior modelling and challenges in the interpretation of observed rocky exoplanets

Most our knowledge about rocky exoplanets is based on their measure of mass and radius. These two parameters are routinely measured and are used to categorise different populations of observed exoplanets. They are also tightly linked to the planet's properties, in particular those of the interior. As such they offer the unique opportunity to interpret the observations and potentially infer the planet's chemistry and structure. Required for the interpretation are models of planetary interiors, calculated a priori, constrained using other available data, and based on the physiochemical properties of mineralogical phases. This article offers an overview of the current knowledge about exoplanet interiors, the fundamental aspects and tools for interior modelling and how to improve the contraints on the models, along with a discussion on the sources of uncertainty. The origin and fate of volatiles, and their role in planetary evolution is discussed. The chemistry and structure of planetary interiors have a pivotal role in the thermal evolution of planets and the development of large scale properties that might become observables with future space missions and ground-based surveys. As such, having reliable and well constrained interior models is of the utmost importance for the advancement of the field.

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arXiv2024

Vapor equilibrium models of accreting rocky planets demonstrate direct core growth by pebble accretion

The gaseous envelope of an accreting rocky planet becomes hot enough to sublimate silicates and other refractory minerals. For this work, we studied the effect of the resulting envelope enrichment with a heavy vapor species on the composition and temperature of the envelope. For simplification, we used the gas-phase molecule SiO to represent the sublimation of silicate material. We solved the equilibrium structure equations in 1D for planets in the mass range of $0.1$ to $3\,M_\oplus$. The convective stability criterion was extended to take the stabilizing effect of the condensation of SiO clouds into account. We assumed that the envelope is both in hydrostatic equilibrium and in vapor equilibrium with the underlying magma ocean. This means that pebbles do not undergo sublimation in the envelope and therefore survive until they plunge into the magma ocean. We find that the emergence of an inner radiative region, where SiO condensation suppresses convection, increases the pressure and temperature in the inner envelope compared to pure H$_2$/He envelopes once $M_\mathrm{pl} \gtrsim 0.3\,M_\oplus$. For $M_\mathrm{pl}>0.75\,M_\oplus$, the temperature and pressure close to the surface reach the supercritical point of SiO. The amount of SiO stored in the envelope is lower than the total planet mass for low mass planets. However, for $M_\mathrm{pl}>2.0\,M_\oplus$, all accreted pebble material must contribute to maintain the vapor equilibrium in the envelope. Therefore, the non-vapor mass of the planet ceases to increase beyond this threshold. Overall, our vapor equilibrium model of the planetary envelope allows for direct core growth by pebble accretion up to much higher masses than previously thought.

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arXiv2023

Sublimation of refractory minerals in the gas envelopes of accreting rocky planets

Protoplanets growing within the protoplanetary disk by pebble accretion acquire hydrostatic gas envelopes. Due to accretion heating, the temperature in these envelopes can become high enough to sublimate refractory minerals which are the major components of the accreted pebbles. Here we study the sublimation of different mineral species and determine whether sublimation plays a role during the growth by pebble accretion. For each snapshot in the growth process, we calculate the envelope structure and sublimation temperature of a set of mineral species representing different levels of volatility. Sublimation lines are determined using and equilibrium scheme for the chemical reactions responsible for destruction and formation of the relevant minerals. We find that the envelope of the growing planet reaches temperatures high enough to sublimate all considered mineral species when the mass is larger than 0.4 Earth masses. The sublimation lines are located within the gravitionally bound envelope of the planet. We make a detailed analysis of the sublimation of FeS at around 720 K, beyond which the mineral is attacked by H2 to form gaseous H2S and solid Fe. We calculate the sulfur concentration in the planet under the assumption that all sulfur released as H2S is lost from the planet by diffusion back to the protoplanetary disk. Our calculated values are in good agreement with the slightly depleted sulfur abundance of Mars, while the model overpredicts the extensive sulfur depletion of Earth by a factor of approximately 2. We show that a collision with a sulfur-rich body akin to Mars in the moon-forming impact lifts the Earth's sulfur abundance to approximately 10% of the solar value for all impactor masses above 0.05 Earth masses.

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