arXiv subjects

Marina E. Gemma

Publications and source records attributed to Marina E. Gemma.

7 recordsLinked to original sources

arXiv2026

Sinking Silicates I: Characterizing the benchmark system containing the T0 brown dwarf CWISE J210640.16+250729.0 using JWST

In this study, we present the full (97.3\% complete) 0.8--12.5 $μ$m spectral energy distribution (SED) of an L/T transition object, CWISE J210640.16+250729.0 (CW2106), using the James Webb Space Telescope (JWST). We provide a full characterization of the host star's elemental abundances and age. We empirically derive the bolometric luminosity ($L_{\rm bol}\approx-4.825$ $\textup{L}_\odot$) of CW2106, and obtain estimates of its mass (M$\approx50-62$ M$_{\rm Jup}$), radius (R$\approx0.83-0.87$ R$_{\rm Jup}$), effective temperature ($T_{\rm eff}$$\approx1213$ K), and surface gravity ($\log~g$$\approx5.28$ dex). We find the near-infrared (near-IR) spectrum ($0.8-2.5 ~μ$m) is best reproduced with cloudy atmospheric models while the mid-infrared (mid-IR) spectrum ($5-12.5 ~μ$m) is best reproduced with cloudless models. This suggests a cloud layer restricted to only the deepest observable parts of the atmosphere and is qualified by the lack of a 9 $μ$m silicate feature. Making use of the Mg/Si ratio of the primary, alongside thermochemical models, we predict the clouds in CW2106 to be composed primarily of enstatite (MgSiO$_3$), removing $\sim23\%$ of the bulk oxygen out of the atmosphere. Future retrieval studies will be able to help investigate the existence and full impact of these cloud species.

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arXiv2026

The Rocky Planet Picture Show: Implementation of Surface Reflection and Emission in $\texttt{POSEIDON}$ with Application to and Interpretation of JWST Data

The surface characterization of rocky exoplanets via emission spectroscopy represents a frontier of current (JWST) and future (HWO) observational efforts. Here, we implement new features in the open-source retrieval code $\texttt{POSEIDON (v1.4)}$ to fully account for an emitting and reflecting planetary surface and an overlying absorbing and scattering atmosphere. We show that realistic rocky surfaces (with wavelength-dependent albedos derived from laboratory measurements) affect emission spectra by imparting mid-infrared diagnostic absorption features, imprinting pseudo-features due to atmospheric transparency windows, and flipping absorption features to emission via surface-atmosphere interface pseudo-temperature inversions. We demonstrate that current JWST spectral data can distinguish between tenuous (low surface pressure, $\leq$ 1 bar) and thick (high surface pressures, $\geq$ 0.1 bar) atmospheres by performing atmosphere + surface retrievals on published JWST emission data of the rocky worlds TOI-1685b and 55 Cancri e. We then explore JWST MIRI LRS's capability to constrain surface geology of rocky worlds, finding that with sufficient SNR retrievals can distinguish between granite-like and basaltic surfaces for synthetic datasets. Finally, we provide an open-source database of lab-derived surface albedos (in the form of directional-hemispherical reflectances), organized by geologic classification and include supplemental tables developed to foster future collaboration between geology and exoplanet science. Our atmosphere + surface retrieval technique provides a pathway to probe geologic processes on rocky exoplanets, showing that upcoming JWST data for terrestrial worlds will enable a deeper exploration of rocky surfaces beyond our Solar System.

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arXiv2026

Bridging the Gap: Using Brown Dwarfs to Examine Silicate Clouds in Giant Exoplanet Atmospheres

We present results from examining the silicate cloud modeling of four JWST-observed hot Jupiters in the context of brown dwarf theory to further explore signatures of formation in present-day atmospheres. We contextualize our understanding of protoplanetary disk refractory chemistry with empirical evidence from chondritic meteorites to show that giant planets forming and accreting in the outer disk adopt their stellar Mg/Si value. We show that current silicate cloud species determinations of WASP-17 b, WASP-107 b, WASP-39 b and HD 189733 b are in line with predictions laid out in Calamari et al. 2024 based on each system's host star Mg/Si ratio, further supporting this hypothesis. We discuss physical motivations for potential atmospheric scenarios where apparent silicate cloud species is not in agreement with that predicted by its host star chemistry. Additionally, we compare current transit spectroscopy for three of these four exoplanets against brown dwarf spectra to examine molecular absorption trends across the substellar mass temperature regime.

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arXiv2024

Abundance, Sizes, and Major Element Compositions of Components in CR and LL Chondrites: Formation from Single Reservoirs

Abundances, apparent sizes, and individual chemical compositions of chondrules, refractory inclusions, other objects and surrounding matrix have been determined for Semarkona (LL3.00) and Renazzo (CR2) using consistent methods and criteria on x-ray element intensity maps. These represent the non-carbonaceous (NC, Semarkona) and carbonaceous chondrite (CC, Renazzo) superclans of chondrite types. We compare object and matrix abundances with similar data for CM, CO, K, and CV chondrites. We assess, pixel-by-pixel, the major element abundance in each object and in the entire matrix. We determine the abundance of "metallic chondrules" in LL chondrites. Chondrules with high Mg/Si and low Fe/Si and matrix carrying opposing ratios complement each other to make whole rocks with near-solar major element ratios in Renazzo. Similar Mg/Si and Fe/Si chondrule-matrix relationships are seen in Semarkona, which is within 11% of solar Mg/Si but significantly Fe-depleted. These results provide a robust constraint in support of single-reservoir models for chondrule formation and accretion, ruling out whole classes of astrophysical models and constraining processes of chondrite component formation and accretion into chondrite parent bodies.

astro-ph.EP↗

arXiv2024

Predicting Cloud Conditions in Substellar Mass Objects Using Ultracool Dwarf Companions

We present results from conducting a theoretical chemical analysis of a sample of benchmark companion brown dwarfs whose primary star is of type F, G or K. We summarize the entire known sample of these types of companion systems, termed "compositional benchmarks", that are present in the literature or recently published as key systems of study in order to best understand brown dwarf chemistry and condensate formation. Via mass balance and stoichiometric calculations, we predict a median brown dwarf atmospheric oxygen sink of $17.8^{+1.7}_{-2.3}\%$ by utilizing published stellar abundances in the local solar neighborhood. Additionally, we predict a silicate condensation sequence such that atmospheres with bulk Mg/Si $\lesssim$ 0.9 will form enstatite (MgSiO$_3$) and quartz (SiO$_2$) clouds and atmospheres with bulk Mg/Si $\gtrsim$ 0.9 will form enstatite and forsterite (Mg$_2$SiO$_4$) clouds. Implications of these results on C/O ratio trends in substellar mass objects and utility of these predictions in future modeling work are discussed.

astro-ph.SR↗

arXiv2023

Trace Element Partitioning between CAI-Type Melts and Grossite, Melilite, Hibonite, and Olivine

We determined the mineral-melt partition coefficients (Di's) and the compositional and/or temperature dependency between grossite, melilite, hibonite, olivine and Ca-, Al-inclusion (CAI)-type liquids for a number of light (LE), high field strength (HFSE), large ion lithophile (LILE), and rare earth (REE) elements including Li, Be, B, Sr, Zr, Nb, Ba, La, Ce, Eu, Dy, Ho, Yb, Hf, Ta, Th. A series of isothermal crystallization experiments was conducted at 5 kbar pressure and IW+1 in graphite capsules. The starting compositions were selected based on the calculated and experimentally confirmed phase relations during condensation in CI dust-enriched systems (Ebel and Grossman, 2000; Ebel, 2006; Ustunisik et al., 2014). Partition coefficients between melt and gehlenite, hibonite, and grossite show that the trace element budget of igneous CAIs is controlled by these three major Al-bearing phases in addition to pyroxene. In general, LE, LILE, REE, and HFSE partition coefficients (by mass) decrease in the order of Di(Gehlenite-Melt) > Di(Hibonite-Melt) > Di(Grossite-Melt). Results suggest that Di(Gehlenite-Melt) vary by a factor of 2-3 in different melt compositions at the same T (~1500 C). Increased melt Al and Ca, relative to earlier work, increases the compatibility of Di(Gehlenite-Melt), and also the compatibility of Di(Hibonite-Melt), especially for La and Ce. Olivine partitioning experiments confirm that olivine contribution to the trace element budget of CAIs is small due to the low Di(Olivine-Melt) at a range of temperatures while D-Eu, Yb(Olivine-Melt) are sensitive to changes in T and oxygen fugacity. The development of a predictive model for partitioning in CAI-type systems would require more experimental data and the use of analytical instruments capable of obtaining single phase analyses for crystals < 5 micron.

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arXiv2022

Patchy Forsterite Clouds in the Atmospheres of Two Highly Variable Exoplanet Analogs

We present an atmospheric retrieval analysis of a pair of highly variable, $\sim200~$Myr old, early-T type planetary-mass exoplanet analogs SIMP J01365662+0933473 and 2MASS J21392676+0220226 using the Brewster retrieval framework. Our analysis, which makes use of archival $1-15~μ$m spectra, finds almost identical atmospheres for both objects. For both targets, we find that the data is best described by a patchy, high-altitude forsterite (Mg$_2$SiO$_4$) cloud above a deeper, optically thick iron (Fe) cloud. Our model constrains the cloud properties well, including the cloud locations and cloud particle sizes. We find that the patchy forsterite slab cloud inferred from our retrieval may be responsible for the spectral behavior of the observed variability. Our retrieved cloud structure is consistent with the atmospheric structure previously inferred from spectroscopic variability measurements, but clarifies this picture significantly. We find consistent C/O ratios for both objects which supports their formation within the same molecular cloud in the Carina-Near Moving Group. Finally, we note some differences in the constrained abundances of H$_2$O and CO which may be caused by data quality and/or astrophysical processes such as auroral activity and their differing rotation rates. The results presented in this work provide a promising preview of the detail with which we will characterize extrasolar atmospheres with JWST, which will yield higher quality spectra across a wider wavelength range.

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