arXiv subjects

Mark G. Wolfire

Publications and source records attributed to Mark G. Wolfire.

At least 37 records · Page 2Linked to original sources

arXiv2021

The Case for Thermalization as a Contributor to the [CII] Deficit

The [CII] deficit, which describes the observed decrease in the ratio of [CII] 158 micron emission to continuum infrared emission in galaxies with high star formation surface densities, places a significant challenge to the interpretation of [CII] detections from across the observable universe. In an attempt to further decode the cause of the [CII] deficit, the [CII] and dust continuum emission from 18 Local Volume galaxies has been split based on conditions within the interstellar medium where it originated. This is completed using the Key Insights in Nearby Galaxies: a Far-Infrared Survey with Herschel (KINGFISH) and Beyond the Peak (BtP) surveys and the wide-range of wavelength information, from UV to far-infrared emission lines, available for a selection of star-forming regions within these samples. By comparing these subdivided [CII] emissions to isolated infrared emission and other properties, we find that the thermalization (collisional de-excitation) of the [CII] line in HII regions plays a significant role in the deficit observed in our sample.

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arXiv2019

Using [CII] 158 micron Emission From Isolated ISM Phases as a Star-Formation Rate Indicator

The brightest observed emission line in many star-forming galaxies is the [CII] 158 micron line, making it detectable up to z~7. In order to better understand and quantify the [CII] emission as a tracer of star-formation, the theoretical ratio between the [NII] 205 micron emission and the [CII] 158 micron emission has been employed to empirically determine the fraction of [CII] emission that originates from the ionized and neutral phases of the ISM. Sub-kiloparsec measurements of the [CII] 158 micron and [NII] 205 micron line in nearby galaxies have recently become available as part of the Key Insights in Nearby Galaxies: a Far Infrared Survey with Herschel (KINGFISH) and Beyond the Peak (BtP) programs. With the information from these two far-infrared lines along with the multi-wavelength suite of KINGFISH data, a calibration of the [CII] emission line as a star formation rate indicator and a better understanding of the [CII] deficit are pursued. [CII] emission is also compared to PAH emission in these regions to compare photoelectric heating from PAH molecules to cooling by [CII] in the neutral and ionized phases of the ISM. We find that the [CII] emission originating in the neutral phase of the ISM does not exhibit a deficit with respect to the infrared luminosity and is therefore preferred over the [CII] emission originating in the ionized phase of the ISM as a star formation rate indicator for the normal star-forming galaxies included in this sample.

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arXiv2019

The Structure of Dark Molecular Gas in the Galaxy -- II. Physical State of "CO-Dark" Gas in the Perseus Arm

We report the results from a new, highly sensitive ($ΔT_{mb} \sim 3 $mK) survey for thermal OH emission at 1665 and 1667 MHz over a dense, 9 x 9-pixel grid covering a $1°$ x $1°$ patch of sky in the direction of $l = 105°, b = +2.50°$ towards the Perseus spiral arm of our Galaxy. We compare our Green Bank Telescope (GBT) 1667 MHz OH results with archival CO J=1-0 observations from the Five College Radio Astronomy Observatory (FCRAO) Outer Galaxy Survey within the velocity range of the Perseus Arm at these galactic coordinates. Out of the 81 statistically-independent pointings in our survey area, 86% show detectable OH emission at 1667 MHz, and 19% of them show detectable CO emission. We explore the possible physical conditions of the observed features using a set of diffuse molecular cloud models. In the context of these models, both OH and CO disappear at current sensitivity limits below an A$_{\rm v}$ of 0.2, but the CO emission does not appear until the volume density exceeds 100-200 cm$^{-3}$. These results demonstrate that a combination of low column density A$_{\rm v}$ and low volume density $n_{H}$ can explain the lack of CO emission along sight lines exhibiting OH emission. The 18-cm OH main lines, with their low critical density of $n^{*}$ $ \sim 1 $ cm$^{-3}$, are collisionally excited over a large fraction of the quiescent galactic environment and, for observations of sufficient sensitivity, provide an optically-thin radio tracer for diffuse H$_2$.

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arXiv2019

Probing ISM Structure in Trumpler 14 & Carina I Using The Stratospheric Terahertz Observatory 2

We present observations of the Trumpler 14/Carina I region carried out using the Stratospheric Terahertz Observatory 2 (STO2). The Trumpler 14/Carina I region is in the west part of the Carina Nebula Complex, which is one of the most extreme star-forming regions in the Milky Way. We observed Trumpler 14/Carina I in the 158 $μ$m transition of [C\,{\sc ii}] with a spatial resolution of 48$''$ and a velocity resolution of 0.17 km s$^{-1}$. The observations cover a 0.25$^\circ$ by 0.28$^\circ$ area with central position {\it l} = 297.34$^\circ$, {\it b} = -0.60$^\circ$. The kinematics show that bright [C\,{\sc ii}] structures are spatially and spectrally correlated with the surfaces of CO clouds, tracing the photodissociation region and ionization front of each molecular cloud. Along 7 lines of sight that traverse Tr 14 into the dark ridge to the southwest, we find that the [C\,{\sc ii}] luminosity from the HII region is 3.7 times that from the PDR. In same los we find in the PDRs an average ratio of 1:4.1:5.6 for the mass in atomic gas:dark-CO gas: molecular gas traced by CO. Comparing multiple gas tracers including HI 21cm, [C\,{\sc ii}], CO, and radio recombination lines, we find that the HII regions of the Carina Nebula Complex are well-described as HII regions with one-side freely expanding towards us, consistent with the champagne model of ionized gas evolution. The dispersal of the GMC in this region is dominated by EUV photoevaporation; the dispersal timescale is 20-30 Myr.

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arXiv2019

A Simple and Accurate Network for Hydrogen and Carbon Chemistry in the ISM

Chemistry plays an important role in the interstellar medium (ISM), regulating heating and cooling of the gas, and determining abundances of molecular species that trace gas properties in observations. Although solving the time-dependent equations is necessary for accurate abundances and temperature in the dynamic ISM, a full chemical network is too computationally expensive to incorporate in numerical simulations. In this paper, we propose a new simplified chemical network for hydrogen and carbon chemistry in the atomic and molecular ISM. We compare results from our chemical network in detail with results from a full photo-dissociation region (PDR) code, and also with the Nelson & Langer (1999) (NL99) network previously adopted in the simulation literature. We show that our chemical network gives similar results to the PDR code in the equilibrium abundances of all species over a wide range of densities, temperature, and metallicities, whereas the NL99 network shows significant disagreement. Applying our network in 1D models, we find that the $\mathrm{CO}$-dominated regime delimits the coldest gas and that the corresponding temperature tracks the cosmic ray ionization rate in molecular clouds. We provide a simple fit for the locus of $\mathrm{CO}$ dominated regions as a function of gas density and column. We also compare with observations of diffuse and translucent clouds. We find that the $\mathrm{CO}$, $\mathrm{CHx}$ and $\mathrm{OHx}$ abundances are consistent with equilibrium predictions for densities $n=100-1000~\mathrm{cm^{-3}}$, but the predicted equilibrium $\mathrm{C}$ abundance is higher than observations, signaling the potential importance of non-equilibrium/dynamical effects.

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arXiv2018

Mapping low frequency carbon radio recombination lines towards Cassiopeia A at 340, 148, 54 and 43 MHz

Quantitative understanding of the interstellar medium requires knowledge of its physical conditions. Low frequency carbon radio recombination lines (CRRLs) trace cold interstellar gas, and can be used to determine its physical conditions (e.g., electron temperature and density). In this work we present spatially resolved observations of the low frequency ($\leq390$ MHz) CRRLs centered around C$268α$, C$357α$, C$494α$ and C$539α$ towards Cassiopeia A on scales of $\leq1.2$ pc. We compare the spatial distribution of CRRLs with other ISM tracers. This comparison reveals a spatial offset between the peak of the CRRLs and other tracers, which is very characteristic for photodissociation regions and that we take as evidence for CRRLs being preferentially detected from the surfaces of molecular clouds. Using the CRRLs we constrain the gas electron temperature and density. These constraints on the gas conditions suggest variations of less than a factor of two in pressure over $\sim1$ pc scales, and an average hydrogen density of $200$-$470$ cm$^{-3}$. From the electron temperature and density maps we also constrain the ionized carbon emission measure, column density and path length. Based on these, the hydrogen column density is larger than $10^{22}$ cm$^{-2}$, with a peak of $\sim4\times10^{22}$ cm$^{-2}$ towards the South of Cassiopeia A. Towards the southern peak the line of sight length is $\sim40$ pc over a $\sim2$ pc wide structure, which implies that the gas is a thin surface layer on a large (molecular) cloud that is only partially intersected by Cassiopeia A. These observations highlight the utility of CRRLs as tracers of low density extended HI and CO-dark gas halo's around molecular clouds.

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arXiv2017

The cosmic ray ionization rate in the Galactic disk, as determined from observations of molecular ions

We have obtained estimates for the cosmic-ray ionization rate (CRIR) in the Galactic disk, using a detailed model for the physics and chemistry of diffuse interstellar gas clouds to interpret previously-published measurements of the abundance of four molecular ions: ArH$^+$, OH$^+$, H$_2$O$^+$ and H$_3^+$. For diffuse $atomic$ clouds at Galactocentric distances in the range $R_g \sim 4 - 9$ kpc, observations of ArH$^+$, OH$^+$, and H$_2$O$^+$ imply a mean primary CRIR of $(2.2 \pm 0.3) \exp [(R_0-R_g)/4.7\,\rm{kpc}] \times 10^{-16} \rm \, s^{-1}$ per hydrogen atom, where $R_0=8.5$ kpc. Within diffuse $molecular$ clouds observed toward stars in the solar neighborhood, measurements of H$_3^+$ and H$_2$ imply a primary CRIR of $(2.3 \pm 0.6) \times 10^{-16}\,\,\rm s^{-1}$ per H atom, corresponding to a total ionization rate per H$_2$ molecule of $(5.3 \pm 1.1) \times 10^{-16}\,\,\rm s^{-1},$ in good accord with previous estimates. These estimates are also in good agreement with a rederivation, presented here, of the CRIR implied by recent observations of carbon and hydrogen radio recombination lines along the sight-line to Cas A. Here, our best-fit estimate for the primary CRIR is $2.9 \times 10^{-16}\,\,\rm s^{-1}$ per H atom. Our results show marginal evidence that the CRIR in diffuse molecular clouds decreases with cloud extinction, $A_{\rm V}({\rm tot})$, with a best-fit dependence $\propto A_{\rm V}({\rm tot})^{-1}$ for $A_{\rm V}({\rm tot}) \ge 0.5$.

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arXiv2017

The PAH emission characteristics of the reflection nebula NGC2023

We present 5-20 micron spectral maps of the reflection nebula NGC2023 obtained with the Infrared Spectrograph SL and SH modes on board the Spitzer Space Telescope which reveal emission from polycyclic aromatic hydrocarbons (PAHs), C60, and H2 superposed on a dust continuum. We show that several PAH emission bands correlate with each other and exhibit distinct spatial distributions revealing a spatial sequence with distance from the illuminating star. We explore the distinct morphology of the 6.2, 7.7 and 8.6 micron PAH bands and find that at least two spatially distinct components contribute to the 7--9 micron PAH emission in NGC2023. We report that the PAH features behave independently of the underlying plateaus. We present spectra of compact oval PAHs ranging in size from C_66 to C_210, determined computationally using density functional theory, and investigate trends in the band positions and relative intensities as a function of PAH size, charge and geometry. Based on the NASA Ames PAH database, we discuss the 7--9 micron components in terms of band assignments and relative intensities. We assign the plateau emission to very small grains with possible contributions from PAH clusters and identify components in the 7--9 micron emission that likely originates in these structures. Based on the assignments and the observed spatial sequence, we discuss the photochemical evolution of the interstellar PAH family as they are more and more exposed to the radiation field of the central star in the evaporative flows associated with the PDRs in NGC2023.

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arXiv2016

The chemistry of interstellar argonium and other probes of the molecular fraction in diffuse clouds

We present a general parameter study, in which the abundance of interstellar argonium (ArH$^+$) is predicted using a model for the physics and chemistry of diffuse interstellar gas clouds. Results have been obtained as a function of UV radiation field, cosmic-ray ionization rate, and cloud extinction. No single set of cloud parameters provides an acceptable fit to the typical ArH$^+$, OH$^+$ and $\rm H_2O^+$ abundances observed in diffuse clouds within the Galactic disk. Instead, the observed abundances suggest that ArH$^+$ resides primarily in a separate population of small clouds of total visual extinction of at most 0.02 mag per cloud, within which the column-averaged molecular fraction is in the range $10^{-5} - 10^{-2}$, while OH$^+$ and $\rm H_2O^+$ reside primarily in somewhat larger clouds with a column-averaged molecular fraction $\sim 0.2$. This analysis confirms our previous suggestion that the argonium molecular ion is a unique tracer of almost purely atomic gas.

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arXiv2015

Extended Carbon Line Emission in the Galaxy: Searching for Dark Molecular Gas along the G328 Sightline

We present spectral data cubes of the [CI] 809GHz, 12CO 115GHz, 13CO 110GHz and HI 1.4GHz line emission from an 1 square degree region along the l = 328° (G328) sightline in the Galactic Plane. Emission arises principally from gas in three spiral arm crossings along the sight line. The distribution of the emission in the CO and [CI] lines is found to be similar, with the [CI] slightly more extended, and both are enveloped in extensive HI. Spectral line ratios per voxel in the data cubes are found to be similar across the entire extent of the Galaxy. However, towards the edges of the molecular clouds the [CI]/13CO and 12CO/13CO line ratios rise by ~50%, and the [CI]/HI ratio falls by ~10$%. We attribute this to these sightlines passing predominantly through the surfaces of photodissociation regions (PDRs), where the carbon is found mainly as C or C+, while the H2 is mostly molecular, and the proportion of atomic gas also increases. We undertake modelling of the PDR emission from low density molecular clouds excited by average interstellar radiation fields and cosmic-ray ionization to quantify this comparison, finding that depletion of sulfur and reduced PAH abundance is needed to match line fluxes and ratios. Roughly one-third of the molecular gas along the sightline is found to be associated with this surface region, where the carbon is largely not to be found in CO. ~10% of the atomic hydrogen along the sightline is cold gas within PDRs.

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arXiv2015

Herschel observations of interstellar chloronium. II - Detections toward G29.96-0.02, W49N, W51, and W3(OH), and determinations of the ortho-to-para and $^{35}$Cl/$^{37}$Cl isotopic ratios

We report additional detections of the chloronium molecular ion, H$_2$Cl$^+$, toward four bright submillimeter continuum sources: G29.96, W49N, W51, and W3(OH). With the use of the HIFI instrument on the Herschel Space Observatory, we observed the $2_{12}-1_{01}$ transition of ortho-H$_2^{35}$Cl$^+$ at 781.627 GHz in absorption toward all four sources. Much of the detected absorption arises in diffuse foreground clouds that are unassociated with the background continuum sources and in which our best estimates of the $N({\rm H_2Cl^+})/N({\rm H})$ ratio lie in the range $(0.9 - 4.8) \times 10^{-9}$. These chloronium abundances relative to atomic hydrogen can exceed the predictions of current astrochemical models by up to a factor of 5. Toward W49N, we have also detected the $2_{12}-1_{01}$ transition of ortho-H$_2^{37}$Cl$^+$ at 780.053 GHz and the $1_{11}-0_{00}$ transition of para-H$_2^{35}$Cl$^+$ at 485.418 GHz. These observations imply $\rm H_2^{35}Cl^+/H_2^{37}Cl^+$ column density ratios that are consistent with the solar system $^{35}$Cl/$^{37}$Cl isotopic ratio of 3.1, and chloronium ortho-to-para ratios consistent with 3, the ratio of spin statistical weights.

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arXiv2014

Herschel Survey of Galactic OH+, H2O+, and H3O+: Probing the Molecular Hydrogen Fraction and Cosmic-Ray Ionization Rate

In diffuse interstellar clouds the chemistry that leads to the formation of the oxygen bearing ions OH+, H2O+, and H3O+ begins with the ionization of atomic hydrogen by cosmic rays, and continues through subsequent hydrogen abstraction reactions involving H2. Given these reaction pathways, the observed abundances of these molecules are useful in constraining both the total cosmic-ray ionization rate of atomic hydrogen (zeta_H) and molecular hydrogen fraction, f(H2). We present observations targeting transitions of OH+, H2O+, and H3O+ made with the Herschel Space Observatory along 20 Galactic sight lines toward bright submillimeter continuum sources. Both OH+ and H2O+ are detected in absorption in multiple velocity components along every sight line, but H3O+ is only detected along 7 sight lines. From the molecular abundances we compute f(H2) in multiple distinct components along each line of sight, and find a Gaussian distribution with mean and standard deviation 0.042+-0.018. This confirms previous findings that OH+ and H2O+ primarily reside in gas with low H2 fractions. We also infer zeta_H throughout our sample, and find a log-normal distribution with mean log(zeta_H)=-15.75, (zeta_H=1.78x10^-16 s^-1), and standard deviation 0.29 for gas within the Galactic disk, but outside of the Galactic center. This is in good agreement with the mean and distribution of cosmic-ray ionization rates previously inferred from H3+ observations. Ionization rates in the Galactic center tend to be 10--100 times larger than found in the Galactic disk, also in accord with prior studies.

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arXiv2014

C$_{60}$ in Photodissociation Regions

Recent studies have confirmed the presence of buckminsterfullerene (C$_{60}$) in different interstellar and circumstellar environments. However, several aspects regarding C$_{60}$ in space are not well understood yet, such as the formation and excitation processes, and the connection between C$_{60}$ and other carbonaceous compounds in the interstellar medium, in particular polycyclic aromatic hydrocarbons (PAHs). In this paper we study several photodissociation regions (PDRs) where C$_{60}$ and PAHs are detected and the local physical conditions are reasonably well constrained, to provide observational insights into these questions. C$_{60}$ is found to emit in PDRs where the dust is cool ($T_d = 20-40$ K) and even in PDRs with cool stars. These results exclude the possibility for C$_{60}$ to be locked in grains at thermal equilibrium in these environments. We observe that PAH and C$_{60}$ emission are spatially uncorrelated and that C$_{60}$ is present in PDRs where the physical conditions (in terms of radiation field and hydrogen density) allow for full dehydrogenation of PAHs, with the exception of Ced 201. We also find trends indicative of an increase in C$_{60}$ abundance within individual PDRs, but these trends are not universal. These results support models where the dehydrogenation of carbonaceous species is the first step towards C$_{60}$ formation. However, this is not the only parameter involved and C$_{60}$ formation is likely affected by shocks and PDR age.

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arXiv2014

The CO-to-H2 Conversion Factor across the Perseus Molecular Cloud

We derive the CO-to-H2 conversion factor, X_CO = N(H2)/I_CO, across the Perseus molecular cloud on sub-parsec scales by combining the dust-based N(H2) data with the I_CO data from the COMPLETE Survey. We estimate an average X_CO ~ 3 x 10^19 cm^-2 K^-1 km^-1 s and find a factor of ~3 variations in X_CO between the five sub-regions in Perseus. Within the individual regions, X_CO varies by a factor of ~100, suggesting that X_CO strongly depends on local conditions in the interstellar medium. We find that X_CO sharply decreases at Av < 3 mag but gradually increases at Av > 3 mag, with the transition occurring at Av where I_CO becomes optically thick. We compare the N(HI), N(H2), I_CO, and X_CO distributions with two models of the formation of molecular gas, a one-dimensional photodissociation region (PDR) model and a three-dimensional magnetohydrodynamic (MHD) model tracking both the dynamical and chemical evolution of gas. The PDR model based on the steady state and equilibrium chemistry reproduces our data very well but requires a diffuse halo to match the observed N(HI) and I_CO distributions. The MHD model generally matches our data well, suggesting that time-dependent effects on H2 and CO formation are insignificant for an evolved molecular cloud like Perseus. However, we find interesting discrepancies, including a broader range of N(HI), likely underestimated I_CO, and a large scatter of I_CO at small Av. These discrepancies likely result from strong compressions/rarefactions and density fluctuations in the MHD model.

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arXiv2013

PDR Model Mapping of Obscured H2 Emission and the Line-of-Sight Structure of M17-SW

We observed H2 line emission with Spitzer-IRS toward M17-SW and modeled the data with our PDR code. Derived gas density values of up to few times 10^7 cm^-3 indicate that H2 emission originates in high-density clumps. We discover that the PDR code can be utilized to map the amount of intervening extinction obscuring the H2 emission layers, and thus we obtain the radial profile of A_V relative to the central ionizing cluster NGC 6618. The extinction has a positive radial gradient, varying between 15--47 mag over the projected distance of 0.9--2.5 pc from the primary ionizer, CEN 1. These high extinction values are in good agreement with previous studies of A_V toward stellar targets in M17-SW. The ratio of data to PDR model values is used to infer the global line-of-sight structure of the PDR surface, which is revealed to resemble a concave surface relative to NGC 6618. Such a configuration confirms that this PDR can be described as a bowl-shaped boundary of the central H II region in M17. The derived structure and physical conditions are important for interpreting the fine-structure and rotational line emission from the PDR.

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arXiv2012

Submillimetre line spectrum of the Seyfert galaxy NGC1068 from the Herschel-SPIRE Fourier Transform Spectrometer

The first complete submillimetre spectrum (190-670um) of the Seyfert 2 galaxy NGC1068 has been observed with the SPIRE Fourier Transform Spectrometer onboard the {\it Herschel} Space Observatory. The sequence of CO lines (Jup=4-13), lines from water, the fundamental rotational transition of HF, two o-H_2O+ lines and one line each from CH+ and OH+ have been detected, together with the two [CI] lines and the [NII]205um line. The observations in both single pointing mode with sparse image sampling and in mapping mode with full image sampling allow us to disentangle two molecular emission components, one due to the compact circum-nuclear disk (CND) and one from the extended region encompassing the star forming ring (SF-ring). Radiative transfer models show that the two CO components are characterized by density of n(H_2)=10^4.5 and 10^2.9 cm^-3 and temperature of T=100K and 127K, respectively. The comparison of the CO line intensities with photodissociation region (PDR) and X-ray dominated region (XDR) models, together with other observational constraints, such as the observed CO surface brightness and the radiation field, indicate that the best explanation for the CO excitation of the CND is an XDR with density of n(H_2) 10^4 cm^-3 and X-ray flux of 9 erg s^-1 cm^-2, consistent with illumination by the active galactic nucleus, while the CO lines in the SF-ring are better modeled by a PDR. The detected water transitions, together with those observed with the \her \sim PACS Spectrometer, can be modeled by an LVG model with low temperature (T_kin \sim 40K) and high density (n(H_2) in the range 10^6.7-10^7.9 cm^-3).

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arXiv2012

Herschel observations of interstellar chloronium

Using the Herschel Space Observatory's Heterodyne Instrument for the Far-Infrared (HIFI), we have observed para-chloronium (H2Cl+) toward six sources in the Galaxy. We detected interstellar chloronium absorption in foreground molecular clouds along the sight-lines to the bright submillimeter continuum sources Sgr A (+50 km/s cloud) and W31C. Both the para-H2-35Cl+ and para-H2-37Cl+ isotopologues were detected, through observations of their 1(11)-0(00) transitions at rest frequencies of 485.42 and 484.23 GHz, respectively. For an assumed ortho-to-para ratio of 3, the observed optical depths imply that chloronium accounts for ~ 4 - 12% of chlorine nuclei in the gas phase. We detected interstellar chloronium emission from two sources in the Orion Molecular Cloud 1: the Orion Bar photodissociation region and the Orion South condensation. For an assumed ortho-to-para ratio of 3 for chloronium, the observed emission line fluxes imply total beam-averaged column densities of ~ 2.0E+13 cm-2 and ~ 1.2E+13 cm-2, respectively, for chloronium in these two sources. We obtained upper limits on the para-H2-35Cl+ line strengths toward H2 Peak 1 in the Orion Molecular cloud and toward the massive young star AFGL 2591. The chloronium abundances inferred in this study are typically at least a factor ~10 larger than the predictions of steady-state theoretical models for the chemistry of interstellar molecules containing chlorine. Several explanations for this discrepancy were investigated, but none has proven satisfactory, and thus the large observed abundances of chloronium remain puzzling.

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arXiv2011

The 15-20 um emission in the reflection nebula NGC2023

We present 15-20 um spectral maps towards the reflection nebula NGC2023 obtained with the Infrared Spectrograph in short-wavelength, high-resolution mode on board the Spitzer Space Telescope. These spectra reveal emission from PAHs, C60, and H2 superposed on a dust continuum. These emission components exhibit distinct spatial distributions: with increasing distance from the illuminating star, we observe the PAH emission followed by the dust continuum emission and the H2 emission. The C60 emission is located closest to the illuminating star in the south while in the north, it seems to be associated with the H/H2 transition. Emission from PAHs and PAH-related species produce features at 15.8, 16.4, 17.4, and 17.8 um and the 15-18 um plateau. These different PAH features show distinct spatial distributions. The 15.8 um band and 15-18 um plateau correlate with the 11.2 um PAH band and with each other, and are attributed to large, neutral PAHs. Conversely, the 16.4 um feature correlates with the 12.7 um PAH band, suggesting that both arise from species that are favored by the same conditions that favor PAH cations. The PAH contribution to the 17.4 um band is displaced towards the illuminating star with respect to the 11.2 and 12.7 um emission and is assigned to doubly ionized PAHs and/or a subset of cationic PAHs. The spatial distribution of the 17.8 um band suggests it arises from both neutral and cationic PAHs. In contrast to their intensities, the profiles of the PAH bands and the 15-18 um plateau do not vary spatially. Consequently, we conclude that the carrier of the 15-18 um plateau is distinct from that of the PAH bands.

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