arXiv subjects

Mark H. Sherwood

Publications and source records attributed to Mark H. Sherwood.

6 recordsLinked to original sources

arXiv2025

Magnetic Resonance Imaging of Single Organic Radicals with Sub-Molecular Resolution

Interest in the magnetism of organic compounds is growing because of new organic magnets, spin-based electronics and the diverse properties of magnetic edge states in graphene nanoribbons. Electron spin resonance spectroscopy combined with the scanning tunneling microscopy has recently been developed as a powerful tool to address individual magnetic atoms and molecules at the atomic scale. Here we demonstrate electron spin resonance and magnetic resonance imaging of all-organic radical anions adsorbed on a protective thin insulating film grown on a metal support. We show that using the highly localized exchange field of the magnetic tip apex allows visualization of the delocalized spin density with sub-molecular resolution, enabling spin-density tomography that can distinguish similar molecular species. These results provide new opportunities for visualizing spin density and magnetic interactions at the atomic scale.

cond-mat.mes-hall↗

arXiv2001

Experimental realization of Shor's quantum factoring algorithm using nuclear magnetic resonance

The number of steps any classical computer requires in order to find the prime factors of an $l$-digit integer $N$ increases exponentially with $l$, at least using algorithms known at present. Factoring large integers is therefore conjectured to be intractable classically, an observation underlying the security of widely used cryptographic codes. Quantum computers, however, could factor integers in only polynomial time, using Shor's quantum factoring algorithm. Although important for the study of quantum computers, experimental demonstration of this algorithm has proved elusive. Here we report an implementation of the simplest instance of Shor's algorithm: factorization of ${N=15}$ (whose prime factors are 3 and 5). We use seven spin-1/2 nuclei in a molecule as quantum bits, which can be manipulated with room temperature liquid state nuclear magnetic resonance techniques. This method of using nuclei to store quantum information is in principle scalable to many quantum bit systems, but such scalability is not implied by the present work. The significance of our work lies in the demonstration of experimental and theoretical techniques for precise control and modelling of complex quantum computers. In particular, we present a simple, parameter-free but predictive model of decoherence effects in our system.

quant-ph↗

arXiv2001

Non-thermal nuclear magnetic resonance quantum computing using hyperpolarized Xenon

Current experiments in liquid-state nuclear magnetic resonance quantum computing are limited by low initial polarization. To address this problem, we have investigated the use of optical pumping techniques to enhance the polarization of a 2-qubit NMR quantum computer (13C and 1H in 13CHCl3). To efficiently use the increased polarization, we have generalized the procedure for effective pure state preparation. With this new, more flexible scheme, an effective pure state was prepared with polarization-enhancement of a factor of 10 compared to the thermal state. An implementation of Grover's quantum search algorithm was demonstrated using this new technique.

quant-ph↗

arXiv2000

Implementation of a three-quantum-bit search algorithm

We report the experimental implementation of Grover's quantum search algorithm on a quantum computer with three quantum bits. The computer consists of molecules of $^{13}$C-labeled CHFBr$_2$, in which the three weakly coupled spin-1/2 nuclei behave as the bits and are initialized, manipulated, and read out using magnetic resonance techniques. This quantum computation is made possible by the introduction of two techniques which significantly reduce the complexity of the experiment and by the surprising degree of cancellation of systematic errors which have previously limited the total possible number of quantum gates.

quant-ph↗

arXiv1999

Nuclear Magnetic Resonance Quantum Computing Using Liquid Crystal Solvents

Liquid crystals offer several advantages as solvents for molecules used for nuclear magnetic resonance quantum computing (NMRQC). The dipolar coupling between nuclear spins manifest in the NMR spectra of molecules oriented by a liquid crystal permits a significant increase in clock frequency, while short spin-lattice relaxation times permit fast recycling of algorithms, and save time in calibration and signal-enhancement experiments. Furthermore, the use of liquid crystal solvents offers scalability in the form of an expanded library of spin-bearing molecules suitable for NMRQC. These ideas are demonstrated with the successful execution of a 2-qubit Grover search using a molecule ($^{13}$C$^{1}$HCl$_3$) oriented in a liquid crystal and a clock speed eight times greater than in an isotropic solvent. Perhaps more importantly, five times as many logic operations can be executed within the coherence time using the liquid crystal solvent.

quant-ph↗

arXiv1999

Realization of logically labeled effective pure states for bulk quantum computation

We report the first use of "logical labeling" to perform a quantum computation with a room-temperature bulk system. This method entails the selection of a subsystem which behaves as if it were at zero temperature - except for a decrease in signal strength - conditioned upon the state of the remaining system. No averaging over differently prepared molecules is required. In order to test this concept, we execute a quantum search algorithm in a subspace of two nuclear spins, labeled by a third spin, using solution nuclear magnetic resonance (NMR), and employing a novel choice of reference frame to uncouple nuclei.

quant-ph↗