arXiv subjects
Publications and source records attributed to Mark Williamson.
Over the past decade, the Python-based Simulations of Chemistry Framework (PySCF) has developed into a widely used open-source platform for electronic structure theory and quantum chemical method development. This article reviews the major advances since the previous overview in 2020, covering new modules and methodology, infrastructure changes, and performance benchmarks.
We analyze the effects of quantum correlations, such as entanglement and discord, on the efficiency of phase estimation by studying four quantum circuits that can be readily implemented using NMR techniques. These circuits define a standard strategy of repeated single-qubit measurements, a classical strategy where only classical correlations are allowed, and two quantum strategies where nonclassical correlations are allowed. In addition to counting space (number of qubits) and time (number of gates) requirements, we introduce mixedness as a key constraint of the experiment. We compare the efficiency of the four strategies as a function of the mixedness parameter. We find that the quantum strategy gives square-root of N enhancement over the standard strategy for the same amount of mixedness. This result applies even for highly mixed states that have nonclassical correlations but no entanglement.
We discuss the problem of the separation of total correlations in a given quantum state into entanglement, dissonance, and classical correlations using the concept of relative entropy as a distance measure of correlations. This allows us to put all correlations on an equal footing. Entanglement and dissonance, whose definition is introduced here, jointly belong to what is known as quantum discord. Our methods are completely applicable for multipartite systems of arbitrary dimensions. We investigate additivity relations between different correlations and show that dissonance may be present in pure multipartite states.
When an entangled state evolves under local unitaries, the entanglement in the state remains fixed. Here we show the dynamical phase acquired by an entangled state in such a scenario can always be understood as the sum of the dynamical phases of its subsystems. In contrast, the equivalent statement for the geometric phase is not generally true unless the state is separable. For an entangled state an additional term is present, the mutual geometric phase, that measures the change the additional correlations present in the entangled state make to the geometry of the state space. For $N$ qubit states we find this change can be explained solely by classical correlations for states with a Schmidt decomposition and solely by quantum correlations for W states.
Practical implementations of quantum cryptography use attenuated laser pulses as the signal source rather than single photons. The channels used to transmit are also lossy. Here we give a simple derivation of two beam-splitting attacks on quantum cryptographic systems using laser pulses, either coherent or mixed states with any mean photon number. We also give a simple derivation of a photon-number splitting attack, the most advanced, both in terms of performance and technology required. We find bounds on the maximum disturbance for a given mean photon number and observed channel transmission efficiency for which a secret key can be distilled. We start by reviewing two incoherent attacks that can be used on single photon quantum cryptographic systems. These results are then adapted to systems that use laser pulses and lossy channels.