SearcharxivSearch

arXiv subjects

Markus Zobel

Publications and source records attributed to Markus Zobel.

2 recordsLinked to original sources

Quantile characterization of univariate unimodality

Unimodal univariate distributions can be characterized as piecewise convex-concave cumulative distribution functions. In this note we transfer this shape constraint characterization to the quantile function. We show that this characterization comes with the upside that the quantile function of a unimodal distribution is always absolutely continuous and consequently unimodality is equivalent to the quasi-convexity of its Radon-Nikodym derivative, i.e., the quantile density. Our analysis is based on the theory of generalized inverses of non-decreasing functions and relies on a version of the inverse function rule for non-decreasing functions.

math.ST

Drift Models on Complex Projective Space for Electron-Nuclear Double Resonance

ENDOR spectroscopy is an important tool to determine the complicated three-dimensional structure of biomolecules and in particular enables measurements of intramolecular distances. Usually, spectra are determined by averaging the data matrix, which does not take into account the significant thermal drifts that occur in the measurement process. In contrast, we present an asymptotic analysis for the homoscedastic drift model, a pioneering parametric model that achieves striking model fits in practice and allows both hypothesis testing and confidence intervals for spectra. The ENDOR spectrum and an orthogonal component are modeled as an element of complex projective space, and formulated in the framework of generalized Fréchet means. To this end, two general formulations of strong consistency for set-valued Fréchet means are extended and subsequently applied to the homoscedastic drift model to prove strong consistency. Building on this, central limit theorems for the ENDOR spectrum are shown. Furthermore, we extend applicability by taking into account a phase noise contribution leading to the heteroscedastic drift model. Both drift models offer improved signal-to-noise ratio over pre-existing models.

math.ST