arXiv subjects

Marrick Braam

Publications and source records attributed to Marrick Braam.

14 recordsLinked to original sources

arXiv2026

Detecting habitable exoplanet atmospheres with LIFE, the Large Interferometer for Exoplanets

A key goal of astronomers with the next generation telescopes is to detect signs of life in exoplanet atmospheres. NASA's next flagship is the Habitable Worlds Observatory (HWO). In the context of ESA's Voyage 2050 program, the Senior Committee report prioritises detecting habitable exoplanet atmospheres in the mid-IR. The most suited mission for this is the Large Interferometer for Exoplanets (LIFE) which can detect an even wider range of biosignatures than HWO and at lower concentrations. LIFE is a global science collaboration based out of ETH Z\"urich. With the UK's expertise in building infrared instruments we could play a leading role in realising an ambitious European-led mission. Notably, LIFE is able to detect necessary planetary context like surface temperature and pressure, along with a key discriminator molecule for biosignature false positives, methane, which will be much harder or impossible with HWO. Also, LIFE will be able to investigate many of the nearby rocky exoplanets known from radial velocity searches that are inaccessible to HWO due to its limited spatial resolution.

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arXiv2026

Atmospheric Supply of Hydrogen Cyanide Is Not the Rate-limiting Step for Prebiotic Chemistry across Rocky Exoplanets

Hydrogen cyanide (HCN) is crucial for the RNA World hypothesis, forming biomolecules essential for early life. Life likely emerged around 4 billion years ago during the early Archean Eon, a period on Earth with a fainter sun, frequent impacts, and a weakly reducing atmosphere. Warm little ponds (WLPs) are hypothetical protective aqueous environments that help explain the emergence and evolution of fragile prebiotic chemistry in such a hostile environment. WLPs need to undergo cycles of evaporation and rehydration, concentrating prebiotic molecules that increase the likelihood of (de-)polymerisation and forming early RNA molecules. We use a 1-D model of atmospheric chemistry to compare atmospheric HCN delivery to WLPs with exogenous sources. Using early Archean Earth as our baseline, we examine the sensitivity of atmospheric HCN delivery to the atmospheric C/O ratio, semi-major axis, assumed stellar host type, and methane budget, exploring conditions across rocky exoplanets. We find that atmospheric HCN delivery is sensitive to these parameters but its values generally exceed that of meteoritic delivery and our baseline Archean Earth. Planetary atmospheres with higher C/O ratios within the habitable zones of G stars and those closely orbiting M-dwarfs deliver the most atmospheric HCN. We find that atmospheric HCN delivery is remarkably robust, so this molecule is likely not the rate limiting step for the emergence of prebiotic chemistry on rocky exoplanets. This finding, with important caveats, potentially increases the probability of life emerging on other worlds.

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arXiv2026

Hydrocarbon complexity and photochemical shielding of prebiotic feedstock molecules in exoplanet atmospheres

The potential of prebiotic chemistry to propagate on an exoplanet fundamentally depends on whether the atmospheric conditions can facilitate the production of prebiotic feedstock molecules. Photochemical simulations of exoplanet atmospheres can be used to explore this potential atmospheric synthesis, but require a comprehensive chemical network. We present the implementation of the CRAHCN-O network, constructed to simulate the formation of feedstock molecules such as HCN, H$_2$CO, and simple hydrocarbons, into the VULCAN photochemical kinetics code. We investigate the production of feedstock molecules driven by M-star radiation and compare these to predictions by the N-C-H-O network in VULCAN, for N$_2$-dominated atmospheres with C/O ratios between 0.5-1.5. Predicted abundances are similar for C/O${=}$0.5. Once CH$_4$ is included (i.e., for C/O${>}$0.5), the abundance profiles diverge in the photochemical regions. By analysing the attenuation of UV radiation, we find that hydrocarbon photochemical shielding causes the diverging profiles. CRAHCN-O accumulates C$_2$H$_6$, while N-C-H-O accumulates C$_4$H$_3$ and C$_3$H$_4$. Importantly, C$_2$H$_6$ is photochemically active whereas C$_4$H$_3$ and C$_3$H$_4$ are assumed inactive. With mixing ratios up to a few percent in CRAHCN-O, C$_2$H$_6$ shields CH$_4$ and CO$_2$ from photodissociation and weakens the destruction of HCN and H$_2$CO. Maximum HCN mixing ratios reach 1000 ppm with CRAHCN-O compared to only 3 ppm with N-C-H-O. Other feedstock molecules like HC$_3$N and C$_2$H$_2$ form more efficiently in N-C-H-O. The shielding mechanism and its impact on feedstock molecules persist for radiation from distinct M-star types. These results demonstrate the crucial role of chemical kinetics in understanding prebiotic processes in exoplanet atmospheres, including important considerations for the construction and applicability of chemical networks.

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arXiv2026

Climates of Terrestrial Exoplanets and Biosignatures

Understanding the climates of terrestrial exoplanets and the detectability of biosignatures is an inherently interdisciplinary challenge, requiring the integration of insights from Solar System exploration, exoplanet observations and climate science. Building from Earth as the only known inhabited planet, NCCR PlanetS has developed models, tools and observational strategies to assess planetary environments far beyond direct reach. Between 2018 and 2025, PlanetS made major contributions across theory, modelling, instrumentation and mission preparation. On the modelling side, the Generic Planetary Climate Model enabled climate studies across a wide range of planetary regimes, from early Venus to temperate terrestrial exoplanets including Proxima b, incorporating advanced developments such as a dynamical slab ocean. In parallel, the THOR global climate model was developed to avoid Earth-centric assumptions and to stably simulate diverse atmospheric regimes. PlanetS has also advanced atmospheric retrieval techniques combining forward modelling, Bayesian inference and machine learning, applied to targets ranging from Solar System bodies to exoplanet phase curves and directly imaged spectra. These efforts have helped assess the scientific return of future missions, notably the Large Interferometer for Exoplanets (LIFE) and to define instrumental requirements for detecting Earth-like atmospheres and biosignatures. Within the Solar System, PlanetS contributed key technologies for biosignature detection, including ORIGIN and SenseLife, enabling in-situ and remote detection of organics, isotopic ratios and microstructures. Finally, PlanetS has played a major role in preparing the next generation of observatories, from JWST, VLT and ELT instruments to LIFE and the Habitable Worlds Observatory. Together, these contributions form an integrated framework advancing the search for life beyond Earth.

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arXiv2025

Observing spatial and temporal variations in the atmospheric chemistry of rocky exoplanets: prospects for mid-infrared spectroscopy

Future telescopes such as the Large Interferometer For Exoplanets (LIFE) will enable mid-infrared characterisation of the atmospheres of nearby rocky exoplanets. Whilst 4D spatial and temporal variations of Earth as an exoplanet are below spectroscopic detection limits, such variability is planet-specific. We investigate LIFE's ability to detect 4D variability in the atmospheres of tidally locked exoplanets. We create daily synthetic LIFE observations of Proxima Centauri b in a 1:1 and an eccentric 3:2 spin-orbit resonance (SOR), using LIFEsim on spectra from daily 3D climate-chemistry model output of an aquaplanet with Earth-like composition. Hemispheric distributions of temperature, clouds, and chemical species determine spectral signatures and variability with orbital phase angle. Such variability dictates the extent to which parameters can be reliably inferred from snapshot spectra at arbitrary viewing geometries. In the 1:1 SOR, MIR spectra vary significantly with viewing geometry and indirectly probe atmospheric circulation. Nightside temperature inversions generate O3, CO2, and H2O emission features, though these lie below LIFE's detection threshold, and instead O3 features disappear at certain phase angles. In contrast, the 3:2 SOR yields a more homogeneous atmosphere with weaker phase variability but enhanced bolometric flux due to eccentric heating. Phase-resolved LIFE observations confidently distinguish between the SORs and capture seasonal O3 variability for golden targets like Proxima Centauri b. In case of abiotic O2/O3 build-up, the O3 variability presents a potential false positive scenario. Hence, LIFE can disentangle different spin-orbit states and resolve 4D atmospheric variability, enabling daily characterisation of the 4D physical and chemical state of nearby terrestrial worlds. Importantly, this characterisation requires phase-resolved rather than snapshot spectra.

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arXiv2025

The Oxygen Valve on Hydrogen Escape Since the Great Oxidation Event

The Great Oxidation Event (GOE) was a $200$ Myr transition circa 2.4 billion years ago that converted the Earth's anoxic atmosphere to one where molecular oxygen (O$_2$) was abundant (volume mixing ratio $>10^{-4}$). This significant rise in O$_2$ is thought to have substantially throttled hydrogen (H) escape and the associated water (H$_2$O) loss. Atmospheric estimations from the GOE onward place O$_2$ concentrations ranging between 0.1% to 150% PAL, where PAL is the present atmospheric level of 21% by volume. In this study we use WACCM6, a three-dimensional Earth System Model to simulate Earth's atmosphere and predict the diffusion-limited escape rate of hydrogen due to varying O$_2$ post-GOE. We find that O$_2$ indirectly acts as a control valve on the amount of hydrogen atoms reaching the homopause in the simulations: less O$_2$ leads to decreased O$_3$ densities that reduce local tropical tropopause temperatures by up to 17 K, which increases H$_2$O freeze-drying and thus reduces the primary source of hydrogen in the considered scenarios. The maximum differences between all simulations in the total H mixing ratio at the homopause and the associated diffusion-limited escape rates are a factor of 3.2 and 4.7, respectively. The prescribed CH$_4$ mixing ratio (0.8 ppmv) sets a minimum diffusion escape rate of $\approx 2 \times 10^{10}$ mol H yr$^{-1}$, effectively a negligible rate when compared to pre-GOE estimates ($\sim10^{12}-10^{13}$ mol H yr$^{-1}$). Because the changes in our predicted escape rates are comparatively minor, our numerical predictions support geological evidence that the majority of Earth's hydrogen escape occurred prior to the GOE. Our work demonstrates that estimations of how the hydrogen escape rate evolved through Earth's history requires 3D chemistry-climate models which include a global treatment of water vapour microphysics.

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arXiv2025

Lightning activity on a tidally locked terrestrial exoplanet in storm-resolving simulations for a range of surface pressures

Cloudy atmospheres produce electric discharges, including lightning. Lightning, in turn, provides sufficient energy to break down air molecules into reactive species and thereby affects the atmospheric composition. The climate of tidally locked rocky exoplanets orbiting M-dwarf stars may have intense and highly localised thunderstorm activity associated with moist convection on their day side. The distribution and structure of lightning-producing convective clouds is shaped by various climate parameters, of which a key one is atmospheric mass, i.e. surface air pressure. In this study, we use a global storm-resolving climate model to predict thunderstorm occurrence for a tidally locked exoplanet over a range of surface pressures. We compare two lightning parameterisations: one based on ice cloud microphysics and one based on the vertical extent of convective clouds. We find that both parameterisations predict that the amount of lightning monotonically decreases with surface pressure due to weaker convection and fewer ice clouds. The spatial distribution of lightning on the planet changes with respect to the surface pressure, responding to the changes in the large-scale circulation and the vertical stratification of the atmosphere. Our study provides revised, high-resolution estimates for lightning activity on a tidally locked Earth-like exoplanet, with implications for global atmospheric chemistry.

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arXiv2024

Earth-like exoplanets in spin-orbit resonances: climate dynamics, 3D atmospheric chemistry, and observational signatures

Terrestrial exoplanets around M- and K-type stars are important targets for atmospheric characterisation. Such planets are likely tidally locked with the order of spin-orbit resonances (SORs) depending on eccentricity. We explore the impact of SORs on 3D atmospheric dynamics and chemistry, employing a 3D coupled Climate-Chemistry Model to simulate Proxima Centauri b in 1:1 and 3:2 SOR. For a 1:1 SOR, Proxima Centauri b is in the Rhines rotator circulation regime with dominant zonal gradients (global mean surface temperature 229 K). An eccentric 3:2 SOR warms Proxima Centauri b to 262 K with gradients in the meridional direction. We show how a complex interplay between stellar radiation, orbit, atmospheric circulation, and (photo)chemistry determines the 3D ozone distribution. Spatial variations in ozone column densities align with the temperature distribution and are driven by stratospheric circulation mechanisms. Proxima Centauri b in a 3:2 SOR demonstrates additional atmospheric variability, including daytime-nighttime cycles in water vapour of ${+}$55% to ${-}$34% and ozone ($\pm5.2$%) column densities and periastron-apoastron water vapour cycles of ${+}$17% to ${-}$10%. Synthetic emission spectra for the spectral range of the Large Interferometer For Exoplanets fluctuate by up to 36 ppm with orbital phase angle for a 1:1 SOR due to 3D spatial and temporal asymmetries. The homogeneous atmosphere for the 3:2 SOR results in relatively constant emission spectra and provides an observational discriminant from the 1:1 SOR. Our work emphasizes the importance of understanding the 3D nature of exoplanet atmospheres and associated spectral variations to determine habitability and interpret atmospheric spectra.

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arXiv2024

Large Interferometer For Exoplanets (LIFE). XIV. Finding terrestrial protoplanets in the galactic neighborhood

The increased brightness temperature of young rocky protoplanets during their magma ocean epoch makes them potentially amenable to atmospheric characterization to distances from the solar system far greater than thermally equilibrated terrestrial exoplanets, offering observational opportunities for unique insights into the origin of secondary atmospheres and the near surface conditions of prebiotic environments. The Large Interferometer For Exoplanets (LIFE) mission will employ a space-based mid-infrared nulling interferometer to directly measure the thermal emission of terrestrial exoplanets. Here, we seek to assess the capabilities of various instrumental design choices of the LIFE mission concept for the detection of cooling protoplanets with transient high-temperature magma ocean atmospheres, in young stellar associations in particular. Using the LIFE mission instrument simulator (LIFEsim) we assess how specific instrumental parameters and design choices, such as wavelength coverage, aperture diameter, and photon throughput, facilitate or disadvantage the detection of protoplanets. We focus on the observational sensitivities of distance to the observed planetary system, protoplanet brightness temperature using a blackbody assumption, and orbital distance of the potential protoplanets around both G- and M-dwarf stars. Our simulations suggest that LIFE will be able to detect (S/N $\geq$ 7) hot protoplanets in young stellar associations up to distances of $\approx$100 pc from the solar system for reasonable integration times (up to $\sim$hours). Detection of an Earth-sized protoplanet orbiting a solar-sized host star at 1 AU requires less than 30 minutes of integration time. M-dwarfs generally need shorter integration times. The contribution from wavelength regions $<$6 $\mu$m is important for decreasing the detection threshold and discriminating emission temperatures.

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arXiv2024

The impact of Ozone on Earth-like exoplanet climate dynamics: the case of Proxima Centauri b

The emergence of the James Webb Space Telescope and the development of other advanced observatories (e.g., ELTs, LIFE and HWO) marks a pivotal moment in the quest to characterize the atmospheres of Earth-like exoplanets. Motivated by these advancements, we conduct theoretical explorations of exoplanetary atmospheres, focusing on refining our understanding of planetary climate and habitability. Our study investigates the impact of ozone on the atmosphere of Proxima Centauri b in a synchronous orbit, utilizing coupled climate chemistry model simulations and dynamical systems theory. The latter quantifies compound dynamical metrics in phase space through the inverse of co-persistence ($\theta$) and co-dimension (d), of which low values correspond to stable atmospheric states. Initially, we scrutinized the influence of ozone on temperature and wind speed. Including interactive ozone (i.e., coupled atmospheric (photo)chemistry) reduces the hemispheric difference in temperature from 68 K to 64 K, increases ($\sim+$7 K) atmospheric temperature at an altitude range of $\sim$20-50 km, and increases variability in the compound dynamics of temperature and wind speed. Moreover, with interactive ozone, wind speed during highly temporally stable states is weaker than for unstable ones, and ozone transport to the nightside gyres during unstable states is enhanced compared to stable ones ($\sim+$800 DU). We conclude that including interactive ozone significantly influences Earth-like exoplanets' chemistry and climate dynamics. This study establishes a novel pathway for comprehending the influence of photochemical species on the climate dynamics of potentially habitable Earth-like exoplanets. We envisage an extension of this framework to other exoplanets.

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arXiv2023

Stratospheric dayside-to-nightside circulation drives the 3-D ozone distribution on synchronously rotating rocky exoplanets

Determining the habitability and interpreting future atmospheric observations of exoplanets requires understanding the atmospheric dynamics and chemistry from a 3-D perspective. Previous studies have shown significant spatial variability in the ozone layer of synchronously rotating M-dwarf planets, assuming an Earth-like initial atmospheric composition. We use a 3-D Coupled Climate-Chemistry model to understand this distribution of ozone and identify the mechanism responsible for it. We document a previously unreported connection between the ozone production regions on the photochemically active dayside hemisphere and the nightside devoid of stellar radiation and thus photochemistry. We find that stratospheric dayside-to-nightside overturning circulation can advect ozone-rich air to the nightside. On the nightside, ozone-rich air subsides at the locations of two quasi-stationary Rossby gyres, resulting in an exchange between the stratosphere and troposphere and the accumulation of ozone at the gyre locations. We identify the hemispheric contrast in radiative heating and cooling as the main driver of this ozone circulation. Dynamically-driven chemistry also impacts other tracer species in the atmosphere (gaseous and non-gaseous phase) as long as chemical lifetimes exceed dynamical lifetimes. These findings illustrate the 3-D nature of planetary atmospheres, predicting spatial and temporal variability that will impact spectroscopic observations of exoplanet atmospheres.

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arXiv2022

3D modelling of the impact of stellar activity on tidally locked terrestrial exoplanets: atmospheric composition and habitability

Stellar flares present challenges to the potential habitability of terrestrial planets orbiting M dwarf stars through inducing changes in the atmospheric composition and irradiating the planet's surface in large amounts of ultraviolet light. To examine their impact, we have coupled a general circulation model with a photochemical kinetics scheme to examine the response and changes of an Earth-like atmosphere to stellar flares and coronal mass ejections. We find that stellar flares increase the amount of ozone in the atmosphere by a factor of 20 compared to a quiescent star. We find that coronal mass ejections abiotically generate significant levels of potential bio-signatures such as N$_2$O. The changes in atmospheric composition cause a moderate decrease in the amount of ultraviolet light that reaches the planets surface, suggesting that while flares are potentially harmful to life, the changes in the atmosphere due to a stellar flare act to reduce the impact of the next stellar flare.

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arXiv2022

Lightning-induced chemistry on tidally-locked Earth-like exoplanets

Determining the habitability and interpreting atmospheric spectra of exoplanets requires understanding their atmospheric physics and chemistry. We use a 3-D Coupled Climate-Chemistry Model, the Met Office Unified Model with the UK Chemistry and Aerosols framework, to study the emergence of lightning and its chemical impact on tidally-locked Earth-like exoplanets. We simulate the atmosphere of Proxima Centauri b orbiting in the Habitable Zone of its M-dwarf star, but the results apply to similar M-dwarf orbiting planets. Our chemical network includes the Chapman ozone reactions and hydrogen oxide (HO$_{\mathrm{x}}$=H+OH+HO$_2$) and nitrogen oxide (NO$_{\mathrm{x}}$=NO+NO$_2$) catalytic cycles. We find that photochemistry driven by stellar radiation (177-850 nm) supports a global ozone layer between 20-50 km. We parameterise lightning flashes as a function of cloud-top height and the resulting production of nitric oxide (NO) from the thermal decomposition of N$_2$ and O$_2$. Rapid dayside convection over and around the substellar point results in lightning flash rates of up to 0.16 flashes km$^{-2}$yr$^{-1}$, enriching the dayside atmosphere below altitudes of 20 km in NO$_{\mathrm{x}}$. Changes in dayside ozone are determined mainly by UV irradiance and the HO$_{\mathrm{x}}$ catalytic cycle. ~45% of the planetary dayside surface remains at habitable temperatures (T$_{\mathrm{surf}}$>273.15 K) and the ozone layer reduces surface UV radiation levels to 15%. Dayside-nightside thermal gradients result in strong winds that subsequently advect NO$_{\mathrm{x}}$ towards the nightside, where the absence of photochemistry allows NO$_{\mathrm{x}}$ chemistry to involve reservoir species. Our study also emphasizes the need for accurate UV stellar spectra to understand the atmospheric chemistry of exoplanets.

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arXiv2020

Evidence for chromium hydride in the atmosphere of Hot Jupiter WASP-31b

Context. The characterisation of exoplanet atmospheres has shown a wide diversity in compositions. Hot Jupiters have the appropriate temperatures to host metallic compounds, which should be detectable through transmission spectroscopy. Aims. We aim to detect exotic species in transmission spectra of hot Jupiters, specifically WASP-31b, by testing a variety of chemical species to explain the spectrum. Methods. We conduct a re-analysis of publicly available transmission data of WASP-31b using the Bayesian retrieval framework TauREx II. We retrieve various combinations of the opacities of 25 species to determine the minimum set needed to fit the observed spectrum. Results. We report evidence for the spectroscopic signatures of chromium hydride (CrH), H2O and K in WASP-31b. Compared to a flat model without any signatures, a CrH-only model is preferred with a statistical significance of ~3.9 sigma. A model consisting of both CrH+H2O is found with ~2.6 sigma and ~3 sigma confidence over a CrH-only and H2O-only model respectively. Weak evidence for the addition of K is found at ~2.2 sigma over the H2O+CrH model, although the fidelity of the data point associated with this signature was questioned in earlier studies. Finally, the inclusion of collision-induced absorption and a Rayleigh scattering slope is found with ~3.5 sigma confidence over a flat model. This analysis presents the first evidence for signatures of CrH in a hot Jupiter atmosphere. At a retrieved temperature of ~1481 K, the atmosphere of WASP-31b is hot enough to host gaseous Cr-bearing species. The retrieved abundances agree well with predictions from thermal equilibrium chemistry and with the abundance found in an L-type brown dwarf atmosphere. However, additional retrievals using VLT FORS2 data lead to a non-detection of CrH. Future coverage with JWST has the potential to confirm the detection and discover other CrH features.

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