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Martí Perarnau-Llobet

Publications and source records attributed to Martí Perarnau-Llobet.

At least 55 records · Page 3Linked to original sources

Experimental verification of the work fluctuation-dissipation relation for information-to-work conversion

We study experimentally work fluctuations in a Szilard engine that extracts work from information encoded as the occupancy of an electron level in a semiconductor quantum dot. We show that as the average work extracted per bit of information increases towards the Landauer limit $k_BT \ln 2$, the work fluctuations decrease in accordance with the work fluctuation-dissipation relation. We compare the results to a protocol without measurement and feedback and show that when no information is used, the work output and fluctuations vanish simultaneously contrasting the information-to-energy conversion case where increasing amount of work is produced with decreasing fluctuations. Our work highlights the importance of fluctuations in the design of information-to-work conversion processes.

cond-mat.mes-hall↗

Geometric optimisation of quantum thermodynamic processes

Differential geometry offers a powerful framework for optimising and characterising finite-time thermodynamic processes, both classical and quantum. Here, we start by a pedagogical introduction to the notion of thermodynamic length. We review and connect different frameworks where it emerges in the quantum regime: adiabatically driven closed systems, time-dependent Lindblad master equations, and discrete processes. A geometric lower bound on entropy production in finitetime is then presented, which represents a quantum generalisation of the original classical bound. Following this, we review and develop some general principles for the optimisation of thermodynamic processes in the linear-response regime. These include constant speed of control variation according to the thermodynamic metric, absence of quantum coherence, and optimality of small cycles around the point of maximal ratio between heat capacity and relaxation time for Carnot engines.

quant-ph↗

Quantum speed-up in collisional battery charging

We present a collision model for the charging of a quantum battery by identical nonequilibrium qubit units. When the units are prepared in a mixture of energy eigenstates, the energy gain in the battery can be described by a classical random walk, where both average energy and variance grow linearly with time. Conversely, when the qubits contain quantum coherence, interference effects buildup in the battery and lead to a faster spreading of the energy distribution, reminiscent of a quantum random walk. This can be exploited for faster and more efficient charging of a battery initialized in the ground state. Specifically, we show that coherent protocols can yield higher charging power than any possible incoherent strategy, demonstrating a quantum speed-up at the level of a single battery. Finally, we characterize the amount of extractable work from the battery through the notion of ergotropy.

quant-ph↗

Optimal Quantum Thermometry with Coarse-grained Measurements

Precise thermometry for quantum systems is important to the development of new technology, and understanding the ultimate limits to precision presents a fundamental challenge. It is well known that optimal thermometry requires projective measurements of the total energy of the sample. However, this is infeasible in even moderately-sized systems, where realistic energy measurements will necessarily involve some coarse graining. Here, we explore the precision limits for temperature estimation when only coarse-grained measurements are available. Utilizing tools from signal processing, we derive the structure of optimal coarse-grained measurements and find that good temperature estimates can generally be attained even with a small number of outcomes. We apply our results to many-body systems and nonequilibrium thermometry. For the former, we focus on interacting spin lattices, both at and away from criticality, and find that the Fisher-information scaling with system size is unchanged after coarse-graining. For the latter, we consider a probe of given dimension interacting with the sample, followed by a measurement of the probe. We derive an upper bound on arbitrary, nonequilibrium strategies for such probe-based thermometry and illustrate it for thermometry on a Bose-Einstein condensate using an atomic quantum-dot probe.

quant-ph↗

Contributions from populations and coherences in non-equilibrium entropy production

The entropy produced when a quantum system is driven away from equilibrium can be decomposed in two parts, one related with populations and the other with quantum coherences. The latter is usually based on the so-called relative entropy of coherence, a widely used quantifier in quantum resource theories. In this paper we argue that, despite satisfying fluctuation theorems and having a clear resource-theoretic interpretation, this splitting has shortcomings. First, it predicts that at low temperatures the entropy production will always be dominated by the classical term, irrespective of the quantum nature of the process. Second, for infinitesimal quenches, the radius of convergence diverges exponentially as the temperature decreases, rendering the functions non-analytic. Motivated by this, we provide here a complementary approach, where the entropy production is split in a way such that the contributions from populations and coherences are written in terms of a thermal state of a specially dephased Hamiltonian. The physical interpretation of our proposal is discussed in detail. We also contrast the two approaches by studying work protocols in a transverse field Ising chain, and a macrospin of varying dimension.

quant-ph↗

Minimizing back-action through entangled measurements

When an observable is measured on an evolving coherent quantum system twice, the first measurement generally alters the statistics of the second one, which is known as measurement back-action. We introduce, and push to its theoretical and experimental limits, a novel method of back-action evasion, whereby entangled collective measurements are performed on several copies of the system. This method is inspired by a similar idea designed for the problem of measuring quantum work [Perarnau-Llobet \textit{et al}., (https://doi.org/10.1103/PhysRevLett.118.070601) Phys. Rev. Lett. \textbf{118}, 070601 (2017)]. By utilizing entanglement as a resource, we show that the back-action can be extremely suppressed compared to all previous schemes. Importantly, the back-action can be eliminated in highly coherent processes.

quant-ph↗

Speed-ups to isothermality: Enhanced quantum thermal machines through control of the system-bath coupling

Isothermal transformations are minimally dissipative but slow processes, as the system needs to remain close to thermal equilibrium along the protocol. Here, we show that smoothly modifying the system-bath interaction can significantly speed up such transformations. In particular, we construct protocols where the overall dissipation $W_{\rm diss}$ decays with the total time $τ_{\rm tot}$ of the protocol as $W_{\rm diss} \propto τ_{\rm tot}^{-2α-1}$, where each value $α> 0$ can be obtained by a suitable modification of the interaction, whereas $α=0$ corresponds to a standard isothermal process where the system-bath interaction remains constant. Considering heat engines based on such speed-ups, we show that the corresponding efficiency at maximum power interpolates between the Curzon-Ahlborn efficiency for $α=0$ and the Carnot efficiency for $α\to \infty$. Analogous enhancements are obtained for the coefficient of performance of refrigerators. We confirm our analytical results with two numerical examples where $α= 1/2$, namely the time-dependent Caldeira-Leggett and resonant-level models, with strong system-environment correlations taken fully into account. We highlight the possibility of implementing our proposed speed-ups with ultracold atomic impurities and mesoscopic electronic devices.

quant-ph↗

Optimal cycles for low-dissipation heat engines

We consider the optimization of a finite-time Carnot engine characterized by small dissipations. We bound the power with a simple inequality and show that the optimal strategy is to perform small cycles around a given working point, which can be thus chosen optimally. Remarkably, this optimal point is independent of the figure of merit combining power and efficiency that is being maximized. Furthermore, for a general class of dynamics the power output becomes proportional to the heat capacity of the working substance. Since the heat capacity can scale supra-extensively with the number of constituents of the engine, this enables us to design optimal many-body Carnot engines reaching maximum efficiency at finite power per constituent in the thermodynamic limit.

quant-ph↗

Work fluctuations in slow processes: quantum signatures and optimal control

An important result in classical stochastic thermodynamics is the work fluctuation--dissipation relation (FDR), which states that the dissipated work done along a slow process is proportional to the resulting work fluctuations. Here we show that slowly driven quantum systems violate this FDR whenever quantum coherence is generated along the protocol, and derive a quantum generalisation of the work FDR. The additional quantum terms in the FDR are found to lead to a non-Gaussian work distribution. Fundamentally, our result shows that quantum fluctuations prohibit finding slow protocols that minimise both dissipation and fluctuations simultaneously, in contrast to classical slow processes. Instead, we develop a quantum geometric framework to find processes with an optimal trade-off between the two quantities.

quant-ph↗

Thermodynamic length in open quantum systems

The dissipation generated during a quasistatic thermodynamic process can be characterised by introducing a metric on the space of Gibbs states, in such a way that minimally-dissipating protocols correspond to geodesic trajectories. Here, we show how to generalize this approach to open quantum systems by finding the thermodynamic metric associated to a given Lindblad master equation. The obtained metric can be understood as a perturbation over the background geometry of equilibrium Gibbs states, which is induced by the Kubo-Mori-Bogoliubov (KMB) inner product. We illustrate this construction on two paradigmatic examples: an Ising chain and a two-level system interacting with a bosonic bath with different spectral densities.

quant-ph↗

Collective operations can extremely reduce work fluctuations

We consider work extraction from $N$ copies of a quantum system. When the same work-extraction process is implemented on each copy, the relative size of fluctuations is expected to decay as $1/\sqrt{N}$. Here, we consider protocols where the copies can be processed collectively, and show that in this case work fluctuations can disappear exponentially fast in $N$. As a consequence, a considerable proportion of the average extractable work $\mathcal{W}$ can be obtained almost deterministically by globally processing a few copies of the state. This is derived in the two canonical scenarios for work extraction: (i) in thermally isolated systems, where $\mathcal{W}$ corresponds to the energy difference between initial and passive states, known as the ergotropy, and (ii) in the presence of a thermal bath, where $\mathcal{W}$ is given by the free energy difference between initial and thermal states.

quant-ph↗

Imperfect Thermalizations Allow for Optimal Thermodynamic Processes

Optimal (reversible) processes in thermodynamics can be modelled as step-by-step processes, where the system is successively thermalized with respect to different Hamiltonians by an external thermal bath. However, in practice interactions between system and thermal bath will take finite time, and precise control of their interaction is usually out of reach. Motivated by this observation, we consider finite-time and uncontrolled operations between system and bath, which result in thermalizations that are only partial in each step. We show that optimal processes can still be achieved for any non-trivial partial thermalizations at the price of increasing the number of operations, and characterise the corresponding tradeoff. We focus on work extraction protocols and show our results in two different frameworks: A collision model and a model where the Hamiltonian of the working system is controlled over time and the system can be brought into contact with a heat bath. Our results show that optimal processes are robust to noise and imperfections in small quantum systems, and can be achieved by a large set of interactions between system and bath.

quant-ph↗

Experimentally reducing the quantum measurement back-action in work distributions by a collective measurement

In quantum thermodynamics, the standard approach to estimate work fluctuations in unitary processes is based on two projective measurements, one performed at the beginning of the process and one at the end. The first measurement destroys any initial coherence in the energy basis, thus preventing later interference effects. In order to decrease this back-action, a scheme based on collective measurements has been proposed in~[PRL 118, 070601 (2017)]. Here, we report its experimental implementation in an optical system. The experiment consists of a deterministic collective measurement on identically prepared two qubits, encoded in the polarisation and path degree of a single photon. The standard two projective measurement approach is also experimentally realized for comparison. Our results show the potential of collective schemes to decrease the back-action of projective measurements, and capture subtle effects arising from quantum coherence.

quant-ph↗

Fluctuating work in coherent quantum systems: proposals and limitations

One of the most important goals in quantum thermodynamics is to demonstrate advantages of thermodynamic protocols over their classical counterparts. For that, it is necessary to (i) develop theoretical tools and experimental set-ups to deal with quantum coherence in thermodynamic contexts, and to (ii) elucidate which properties are genuinely quantum in a thermodynamic process. In this short review, we discuss proposals to define and measure work fluctuations that allow to capture quantum interference phenomena. We also discuss fundamental limitations arising due to measurement back-action, as well as connections between work distributions and quantum contextuality. We hope the different results summarised here motivate further research on the role of quantum phenomena in thermodynamics.

quant-ph↗

Markovian master equations for quantum thermal machines: local vs global approach

The study of quantum thermal machines, and more generally of open quantum systems, often relies on master equations. Two approaches are mainly followed. On the one hand, there is the widely used, but often criticized, local approach, where machine sub-systems locally couple to thermal baths. On the other hand, in the more established global approach, thermal baths couple to global degrees of freedom of the machine. There has been debate as to which of these two conceptually different approaches should be used in situations out of thermal equilibrium. Here we compare the local and global approaches against an exact solution for a particular class of thermal machines. We consider thermodynamically relevant observables, such as heat currents, as well as the quantum state of the machine. Our results show that the use of a local master equation is generally well justified. In particular, for weak inter-system coupling, the local approach agrees with the exact solution, whereas the global approach fails for non-equilibrium situations. For intermediate coupling, the local and the global approach both agree with the exact solution and for strong coupling, the global approach is preferable. These results are backed by detailed derivations of the regimes of validity for the respective approaches.

quant-ph↗

Low-temperature thermometry can be enhanced by strong coupling

We consider the problem of estimating the temperature $ T $ of a very cold equilibrium sample. The temperature estimates are drawn from measurements performed on a quantum probe strongly coupled to it. We model this scenario by resorting to the canonical Caldeira-Leggett Hamiltonian and find analytically the exact stationary state of the probe for arbitrary coupling strength. In general, the probe does not reach thermal equilibrium with the sample, due to their non-perturbative interaction. We argue that this is advantageous for low temperature thermometry, as we show in our model that: (i) The thermometric precision at low $ T $ can be significantly enhanced by strengthening the probe-sampling coupling, (ii) the variance of a suitable quadrature of our Brownian thermometer can yield temperature estimates with nearly minimal statistical uncertainty, and (iii) the spectral density of the probe-sample coupling may be engineered to further improve thermometric performance. These observations may find applications in practical nanoscale thermometry at low temperatures---a regime which is particularly relevant to quantum technologies.

quant-ph↗

Quantum Thermal Machine as a Thermometer

We propose the use of a quantum thermal machine for low-temperature thermometry. A hot thermal reservoir coupled to the machine allows for simultaneously cooling the sample while determining its temperature without knowing the model-dependent coupling constants. In its most simple form, the proposed scheme works for all thermal machines which perform at Otto efficiency and can reach Carnot efficiency. We consider a circuit QED implementation which allows for precise thermometry down to $\sim$15 mK with realistic parameters. Based on the quantum Fisher information, this is close to the optimal achievable performance. This implementation demonstrates that our proposal is particularly promising in systems where thermalization between different components of an experimental setup cannot be guaranteed.

quant-ph↗