arXiv subjects

Martin B. Plenio

Publications and source records attributed to Martin B. Plenio.

At least 55 records · Page 3Linked to original sources

arXiv2025

Quantum Fisher information from tensor network integration of Lyapunov equation

The Quantum Fisher Information (QFI) is a geometric measure of state deformation calculated along the trajectory parameterizing an ensemble of quantum states. It serves as a key concept in quantum metrology, where it is linked to the fundamental limit on the precision of the parameter that we estimate. However, the QFI is notoriously difficult to calculate due to its non-linear mathematical form. For mixed states, standard numerical procedures based on eigendecomposition quickly become impractical with increasing system size. To overcome this limitation, we introduce a novel numerical approach based on Lyapunov integrals that combines the concept of symmetric logarithmic derivative and tensor networks. Importantly, this approach requires only the elementary matrix product states algorithm for time-evolution, opening a perspective for broad usage and application to many-body systems. We discuss the advantages and limitations of our methodology through an illustrative example in quantum metrology, where the thermal state of the transverse-field Ising model is used to measure magnetic field amplitude.

quant-ph↗

arXiv2025

The Thermodynamic Costs of Pure Dephasing in Quantum Heat Engines: Quasistatic Efficiency at Finite Power

Quantum heat engines are commonly believed to achieve their optimal efficiency only when operated quasi-statically. When running at finite power, however, they suffer effective friction due to the generation of coherences and transitions between energy eigenstates. It was noted that it is possible to increase the power of a quantum heat engine using external control schemes or suitable dephasing noise. Here, we investigate the thermodynamic cost associated with dephasing noise schemes using both numerical and analytical methods. Our findings unveil that the observed gain in power is generally not free of thermodynamic costs, as it involves energy costs of the control fields or heat flows between thermal and dephasing baths. These contributions must be duly accounted for when determining the engine's overall efficiency. Interestingly, we identify a particular working regime where these costs become negligible, demonstrating that quantum heat engines can be operated at any power with an efficiency per cycle that approaches arbitrarily closely that under quasistatic operation.

quant-ph↗

arXiv2025

On a gap in the proof of the generalised quantum Stein's lemma and its consequences for the reversibility of quantum resources

We show that the proof of the generalised quantum Stein's lemma [Brandão & Plenio, Commun. Math. Phys. 295, 791 (2010)] is not correct due to a gap in the argument leading to Lemma III.9. Hence, the main achievability result of Brandão & Plenio is not known to hold. This puts into question a number of established results in the literature, in particular the reversibility of quantum entanglement [Brandão & Plenio, Commun. Math. Phys. 295, 829 (2010); Nat. Phys. 4, 873 (2008)] and of general quantum resources [Brandão & Gour, Phys. Rev. Lett. 115, 070503 (2015)] under asymptotically resource non-generating operations. We discuss potential ways to recover variants of the newly unsettled results using other approaches.

quant-ph↗

arXiv2025

Full Microscopic Simulations Uncover Persistent Quantum Effects in Primary Photosynthesis

The presence of quantum effects in photosynthetic excitation energy transfer has been intensely debated over the past decade. Nonlinear spectroscopy cannot unambiguously distinguish coherent electronic dynamics from underdamped vibrational motion, and rigorous numerical simulations of realistic microscopic models have been intractable. Experimental studies supported by approximate numerical treatments that severely coarse-grain the vibrational environment have claimed the absence of long-lived quantum effects. Here, we report the first non-perturbative, accurate microscopic model simulations of the Fenna-Matthews-Olson photosynthetic complex and demonstrate the presence of long-lived excitonic coherences at 77 K and room temperature, which persist on picosecond time scales, similar to those of excitation energy transfer. Furthermore, we show that full microscopic simulations of nonlinear optical spectra are essential for identifying experimental evidence of quantum effects in photosynthesis, as approximate theoretical methods can misinterpret experimental data and potentially overlook quantum phenomena.

physics.chem-ph↗

arXiv2025

Towards quantum error correction with two-body gates for quantum registers based on nitrogen-vacancy centers in diamond

Color centers in diamond provide a possible hardware for quantum computation, where the most basic quantum information processing unit are nitrogen-vacancy (NV) centers, each in contact with adjacent carbon nuclear spins. With specifically tailored dynamical decoupling sequences, it is possible to execute selective, high-fidelity two-body gates between the electron spin of the NV center and a targeted nuclear spin. In this work, we present a method to determine the optimal execution time that balances the trade-off between fidelity and execution speed for gates generated by adaptive XY sequences. With these optimized gates, we use the nuclear spin environment as a code space for quantum error correction within a color center register.

quant-ph↗

arXiv2024

Making Quantum Collision Models Exact

Quantum collision describe open quantum systems through repeated interactions with a coarse-grained environment. However, a complete certification of these models is lacking, as no complete error bounds on the simulation of system observables have been established. Here, we show that Markovian and non-Markovian collision models can be recovered analytically from chain mapping techniques starting from a general microscopic Hamiltonian. This derivation reveals a previously unidentified source of error -- induced by an unfaithful sampling of the environment -- in dynamics obtained with collision models that can become dominant for small but finite time-steps. With the complete characterization of this error, all collision models errors are now identified and quantified, which enables the promotion of collision models to the class of numerically exact methods. To confirm the predictions of our equivalence results, we implemented a non-Markovian collision model of the Spin Boson Model, and identified, as predicted, a regime in which the collision model is fundamentally inaccurate.

quant-ph↗

arXiv2024

Accelerating two-dimensional electronic spectroscopy simulations with a probe qubit protocol

Two-dimensional electronic spectroscopy (2DES) is a powerful tool for exploring quantum effects in energy transport within photosynthetic systems and investigating novel material properties. However, simulating the dynamics of these experiments poses significant challenges for classical computers due to the large system sizes, long timescales and numerous experiment repetitions involved. This paper introduces the probe qubit protocol (PQP)-for quantum simulation of 2DES on quantum devices-addressing these challenges. The PQP offers several enhancements over standard methods, notably reducing computational resources, by requiring only a single-qubit measurement per circuit run and achieving Heisenberg scaling in detection frequency resolution, without the need to apply expensive controlled evolution operators in the quantum circuit. The implementation of the PQP protocol requires only one additional ancilla qubit, the probe qubit, with one-to-all connectivity and two-qubit interactions between each system and probe qubits. We evaluate the computational resources necessary for this protocol in detail, demonstrating its function as a dynamic frequency-filtering method through numerical simulations. We find that simulations of the PQP on classical and quantum computers enable a reduction on the number of measurements, i.e. simulation runtime, and memory savings of several orders of magnitude relatively to standard quantum simulation protocols of 2DES. The paper discusses the applicability of the PQP on near-term quantum devices and highlights potential applications where this spectroscopy simulation protocol could provide significant speedups over standard approaches such as the quantum simulation of 2DES applied to the Fenna-Matthews-Olson (FMO) complex in green sulphur bacteria.

quant-ph↗

arXiv2024

Time dependent Markovian master equation beyond the adiabatic limit

We derive a Markovian master equation that models the evolution of systems subject to driving and control fields. Our approach combines time rescaling and weak-coupling limits for the system-environment interaction with a secular approximation. The derivation makes use of the adiabatic time-evolution operator in a manner that allows for the efficient description of strong driving, while recovering the well-known adiabatic master equation in the appropriate limit. To illustrate the effectiveness of our approach, firstly we apply it to the paradigmatic case of a two-level (qubit) system subject to a form of periodic driving that remains unsolvable using a Floquet representation and lastly we extend this scenario to the situation of two interacting qubits, the first driven while the second one directly in contact with the environment. We demonstrate the reliability and broad scope of our approach by benchmarking the solutions of the derived reduced time evolution against numerically exact simulations using tensor networks. Our results provide rigorous conditions that must be satisfied by phenomenological master equations for driven systems that do not rely on first-principles derivations.

quant-ph↗

arXiv2024

Spectral Density Modulation and Universal Markovian Closure of Fermionic Environments

The combination of chain-mapping and tensor-network techniques provides a powerful tool for the numerically exact simulation of open quantum systems interacting with structured environments. However, these methods suffer from a quadratic scaling with the physical simulation time, and therefore they become challenging in the presence of multiple environments. This is particularly true when fermionic environments, well-known to be highly correlated, are considered. In this work we first illustrate how a thermo-chemical modulation of the spectral density allows replacing the original fermionic environments with equivalent, but simpler, ones. Moreover, we show how this procedure reduces the number of chains needed to model multiple environments. We then provide a derivation of the fermionic Markovian closure construction, consisting of a small collection of damped fermionic modes undergoing a Lindblad-type dynamics and mimicking a continuum of bath modes. We describe, in particular, how the use of the Markovian closure allows for a polynomial reduction of the time complexity of chain-mapping based algorithms when long-time dynamics are needed.

quant-ph↗

arXiv2024

Resolving single molecule structures with nitrogen-vacancy centers in diamond

We present theoretical proposals for two-dimensional nuclear magnetic resonance spectroscopy protocols based on Nitrogen-vacancy (NV) centers in diamond that are strongly coupled to the target nuclei. Continuous microwave and radio-frequency driving fields together with magnetic field gradients achieve Hartmann-Hahn resonances between NV spin sensor and selected nuclei for control of nuclear spins and subsequent measurement of their polarization dynamics. The strong coupling between the NV sensor and the nuclei facilitates coherence control of nuclear spins and relaxes the requirement of nuclear spin polarization to achieve strong signals and therefore reduced measurement times. Additionally, we employ a singular value thresholding matrix completion algorithm to further reduce the amount of data required to permit the identification of key features in the spectra of strongly sub-sampled data. We illustrate the potential of this combined approach by applying the protocol to a shallowly implanted NV center addressing a small amino acid, alanine, to target specific hydrogen nuclei and to identify the corresponding peaks in their spectra.

quant-ph↗

arXiv2024

Quantum resource-theoretical analysis of the role of vibrational structure in photoisomerization

Thermodynamical systems at the nanoscale, such as single molecules interacting with highly structured vibrational environments, typically undergo non-equilibrium physical processes that lack precise microscopic descriptions. Photoisomerization is such an example which has emerged as a platform on which to study single-molecule ultrafast photochemical processes from a quantum resource theoretic perspective. However, upper bounds on its efficiency have only been obtained under significant simplifications that make the mathematics of the resource-theoretical treatment manageable. Here we generalize previous models for the photoisomers, while retaining the full vibrational structure, and still get analytical bounds on the efficiency of hotoisomerization. We quantify the impact of such vibrational structure on the optimal photoisomerization quantum yield both when the vibrational coordinate has no dynamics of its own and when we take into account the vibrational dynamics. This work serves as an example of how to bridge the gap between the abstract language of quantum resource theories and the open system formulation of nanoscale processes.

quant-ph↗

arXiv2024

Multicritical dissipative phase transitions in the anisotropic open quantum Rabi model

We investigate the nonequilibrium steady state of the anisotropic open quantum Rabi model, which exhibits first-order and second-order dissipative phase transitions upon varying the degree of anisotropy between the coupling strengths of rotating and counterrotating terms. Using both semiclassical and quantum approaches, we find a rich phase diagram resulting from the interplay between the anisotropy and the dissipation. First, there exists a bistable phase where both the normal and superradiant phases are stable. Second, there are multicritical points where the phase boundaries for the first- and second-order phase transitions meet. We show that a new set of critical exponents governs the scaling of the multicritical points. Finally, we discuss the feasibility of observing the multicritical transitions and bistability using a pair of trapped ions where the anisotropy can be tuned by controlling the intensity of the Raman transitions. Our study enlarges the scope of critical phenomena that may occur in finite-component quantum systems, which could be useful for applications in critical quantum sensing.

quant-ph↗

arXiv2024

Testing the quantum nature of gravity without entanglement

Given a unitary evolution $U$ on a multi-partite quantum system and an ensemble of initial states, how well can $U$ be simulated by local operations and classical communication (LOCC) on that ensemble? We answer this question by establishing a general, efficiently computable upper bound on the maximal LOCC simulation fidelity -- what we call an 'LOCC inequality'. We then apply our findings to the fundamental setting where $U$ implements a quantum Newtonian Hamiltonian over a gravitationally interacting system. Violation of our LOCC inequality can rule out the LOCCness of the underlying evolution, thereby establishing the non-classicality of the gravitational dynamics, which can no longer be explained by a local classical field. As a prominent application of this scheme we study systems of quantum harmonic oscillators initialised in coherent states following a normal distribution and interacting via Newtonian gravity, and discuss a possible physical implementation with torsion pendula. One of our main technical contributions is the analytical calculation of the above LOCC inequality for this family of systems. As opposed to existing tests based on the detection of gravitationally mediated entanglement, our proposal works with coherent states alone, and thus it does not require the generation of largely delocalised states of motion nor the detection of entanglement, which is never created at any point in the process.

quant-ph↗

arXiv2024

Robust external spin hyperpolarization of quadrupolar nuclei enabled by strain

In a theoretical study, we investigate the spin dynamics of interacting nitrogen-vacancy (NV) centers and quadrupolar I = 3/2 nuclear spins, specifically 11B spins in hexagonal boron nitride (h-BN) nanosheets located near the microdiamond surface. We demonstrate the possibility of obtaining external spin-polarization by magnetic-field sweeps across the level anticrossings around zero-field. To achieve this, we leverage crystal strains to establish a polarization transfer mechanism that remains robust against variations in NV orientation, crystal strain inhomogeneity, and electron-nuclear effective couplings. These results pave the way for hyperpolarization of spins in nanomaterials near the diamond surface without experiencing polarization loss to intrinsic nuclear spin-1/2 species, such as 13C and 1H nuclear spins in diamond. The 11B spins in h-BN nanosheets, with their extended relaxation time and large surface area, present a promising alternative for relayed nuclear polarization to the liquid phase and for the development of quantum simulators based on surface nuclear spins.

quant-ph↗

arXiv2024

Criticality-enhanced Electric Field Gradient Sensor with Single Trapped Ions

We propose and analyze a driven-dissipative quantum sensor that is continuously monitored close to a dissipative critical point. The sensor relies on the critical open Rabi model with the spin and phonon degrees of freedom of a single trapped ion to achieve criticality-enhanced sensitivity. Effective continuous monitoring of the sensor is realized via a co-trapped ancilla ion that switches between dark and bright internal states conditioned on a `jump' of the phonon population which, remarkably, achieves nearly perfect phonon counting despite a low photon collection efficiency. By exploiting both dissipative criticality and efficient continuous readout, the sensor device achieves highly precise sensing of oscillating electric field gradients at a criticality-enhanced precision scaling beyond the standard quantum limit, which we demonstrate is robust to the experimental imperfections in real-world applications.

quant-ph↗

arXiv2024

$^{13}$C Hyperpolarization with Nitrogen-Vacancy Centers in Micro- and Nanodiamonds for Sensitive Magnetic Resonance Applications

Nuclear hyperpolarization is a known method to enhance the signal in nuclear magnetic resonance (NMR) by orders of magnitude. The present work addresses the $^{13}$C hyperpolarization in diamond micro- and nanoparticles, using the optically-pumped nitrogen-vacancy center (NV) to polarize $^{13}$C spins at room temperature. Consequences of the small particle size are mitigated by using a combination of surface treatment improving the $^{13}$C relaxation ($T_1$) time, as well as that of NV, and applying a technique for NV illumination based on a microphotonic structure. Monitoring the light-induced redistribution of the NV spin state populations with electron paramagnetic resonance, a strong polarization enhancement for the NV spin state is observed in a narrow spectral region corresponding to about 4\% of these defect centers. By combining adjustments to the `PulsePol' sequence and slow sample rotation, the NV-$^{13}$C polarization transfer rate is improved further. The hyperpolarized $^{13}$C NMR signal is observed in particles of 2 $μ$m and 100 nm median sizes, with enhancements over the thermal signal (at 0.29 T magnetic field), of 1500 and 940, respectively. The present demonstration of room-temperature hyperpolarization anticipates the development of agents based on nanoparticles for sensitive magnetic resonance applications.

quant-ph↗

arXiv2024

Simulating Gaussian Boson Sampling with Tensor Networks in the Heisenberg picture

Although the Schr{ö}dinger and Heisenberg pictures are equivalent formulations of quantum mechanics, simulations performed choosing one over the other can greatly impact the computational resources required to solve a problem. Here we demonstrate that in Gaussian boson sampling, a central problem in quantum computing, a good choice of representation can shift the boundary between feasible and infeasible numerical simulability. To achieve this, we introduce a novel method for computing the probability distribution of boson sampling based on the time evolution of tensor networks in the Heisenberg picture. In addition, we overcome limitations of existing methods enabling simulations of realistic setups affected by non-uniform photon losses. Our results demonstrate the effectiveness of the method and its potential to advance quantum computing research.

quant-ph↗

arXiv2024

Systematic coarse-graining of environments for the non-perturbative simulation of open quantum systems

Conducting precise electronic-vibrational dynamics simulations of molecular systems poses significant challenges when dealing with realistic environments composed of numerous vibrational modes. Here, we introduce a technique for the construction of effective phonon spectral densities that capture accurately open system dynamics over a finite time interval of interest. When combined with existing non-perturbative simulation tools, our approach can reduce significantly the computational costs associated with many-body open system dynamics.

quant-ph↗