arXiv subjects

Martin C. Korzeczek

Publications and source records attributed to Martin C. Korzeczek.

4 recordsLinked to original sources

arXiv2025

PHIP Sequences and Dipolar Fields

Para-hydrogen induced polarization (PHIP) achieves efficient hyperpolarisation of nuclear spins with the transfer of the singlet order of parahydrogen to target molecules through catalytic hydrogenation reactions and subsequent coherent control of the spin dynamics. However, in realistic conditions B0/B1 inhomogeneities lead to significant reduction in the polarization transfer efficiency. Moreover, in high-concentration samples, dipolar fields arising from the magnetisation of the sample can degrade polarisation transfer efficiency significantly. In this work, we present a theoretical framework and a comprehensive analysis of both pulsed and continuous-wave (CW) control sequences designed to mitigate the detrimental effects of dipolar fields, $B_0/B_1$ inhomogeneities, and moderate chemical shifts. By combining tools from average Hamiltonian theory with detailed numerical simulations, we introduce and characterise a wide range of transfer sequences, including dipolar-field adjusted and dipolar-field suppressing protocols. We identify conditions under which dipolar interactions either hinder or, perhaps surprisingly, stabilise polarization transfer, depending on the sequence structure. Our results offer practical guidance for the selection and design of PHIP transfer sequences under realistic experimental constraints and open pathways toward robust hyperpolarisation in concentrated liquid-state NMR samples.

quant-ph↗

arXiv2024

Robust Parahydrogen-Induced Polarization at High Concentrations

Parahydrogen-Induced Polarization (PHIP) is a potent technique for generating target molecules with high nuclear spin polarization. The PHIP process involves a chemical reaction between parahydrogen and a target molecule, followed by the transformation of nuclear singlet spin order into magnetization of a designated nucleus through magnetic field manipulations. Although the singlet-to-magnetization polarization transfer process works effectively at moderate concentrations, it is observed to become much less efficient at high molar polarization, defined as the product of polarization and concentration. This strong dependence on the molar polarization is attributed to interference from the field produced by the sample's magnetization during polarization transfer, which leads to complex dynamics and can severely impact the scalability of the technique. We address this challenge with a pulse sequence that negates the influence of the distant dipolar field, while simultaneously achieving singlet-to-magnetization polarization transfer to the desired target spins, free from restrictions on the molar polarization.

physics.chem-ph↗

arXiv2023

Towards a unified picture of polarization transfer -- pulsed DNP and chemically equivalent PHIP

Nuclear spin hyperpolarization techniques, such as dynamic nuclear polarization (DNP) and parahydrogen-induced polarization (PHIP), have revolutionized nuclear magnetic resonance and magnetic resonance imaging. In these methods, a readily available source of high spin order, either electron spins in DNP or singlet states in hydrogen for PHIP, is brought into close proximity with nuclear spin targets, enabling efficient transfer of spin order under external quantum control. Despite vast disparities in energy scales and interaction mechanisms between electron spins in DNP and nuclear singlet states in PHIP, a pseudo-spin formalism allows us to establish an intriguing equivalence. As a result, the important low-field polarization transfer regime of PHIP can be mapped onto an analogous system equivalent to pulsed-DNP. This establishes a correspondence between key polarization transfer sequences in PHIP and DNP, facilitating the transfer of sequence development concepts. This promises fresh insights and significant cross-pollination between DNP and PHIP polarization sequence developers.

quant-ph↗

arXiv2022

Quantum-router: Storing and redirecting light at the photon level

We propose a method for spatially re-routing single photons or light in a coherent state with small average photon number by purely electronic means, i.e. without using mechanical devices such as micro-mirror arrays. The method is based on mapping the quantum state of the incoming light onto a spin-wave in an atomic ensemble as is done in quantum memories of light. Then the wavevector of the spin-wave is modified in a controlled way by an applied magnetic field gradient. Finally, by re-applying the same control beam as for storing, the signal pulse is released in a new direction that depends on the deflected wavevector of the spin-wave. We show by numerical simulation that efficiencies can be achieved for arbitrary deflection angles in the plane that are comparable with simple photon storage and re-emission in forward direction, and propose a new method for eliminating the stored momentum as source of decoherence in the quantum memory. In a reasonable parameter regime, the re-routing should be achievable on a time-scale on the order of few to $\sim100$ microseconds, depending on the deflection angle. The shifts in the wavevector that can be achieved using the Zeeman-effect, with otherwise minimal changes to the spin-wave, can also be used to complement existing ac-Stark spin-wave manipulation methods.

quant-ph↗