arXiv subjects

Martin Cordiner

Publications and source records attributed to Martin Cordiner.

16 recordsLinked to original sources

arXiv2026

An Enriched Methane D/H Ratio in the Interstellar Object 3I/ATLAS

Interstellar objects are interlopers from other planetary systems, and their volatile compositions provide a glimpse into planet formation around their host star. We present near-infrared spectra of the coma of interstellar object 3I/ATLAS measured with the James Webb Space Telescope. Our results demonstrate an unexpectedly high D/H = $(3.33\pm0.31)\%$ for methane and represent an exceedingly rare detection of deuterated organic molecules in an interstellar object. This D/H ratio exceeds any other value for methane measured in the solar system, and is a factor of $14\pm2$ higher than that measured in comet 67P/Churyumov-Gerasimenko by the Rosetta spacecraft, the only other comet for which CH$_3$D has been detected. Both 3I/ATLAS and 67P/Churyumov-Gerasimenko show a higher degree of methane dueteration compared to water, consistent with trends seen in other solar system bodies and the nearby interstellar medium, where deuteration in organics exceeds that of water by up to an order of magnitude. The D/H ratio in methane itself is observationally unconstrained in extrasolar sources to date, but the enriched ratio in 3I/ATLAS is similar to those measured in methanol and formaldehyde toward primitive environments. The elevated D/H ratio for methane in 3I/ATLAS is consistent with the hypothesis that its ices formed in a cold, low metallicity interstellar or protostellar environment under a high cosmic ray irradiation rate (Cordiner et al. 2026).

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arXiv2026

Isotopic Evidence for a Cold and Distant Origin of the Interstellar Object 3I/ATLAS

Interstellar objects provide the only directly observable samples of icy planetesimals formed around other stars, and can therefore provide insight into the diversity of physical and chemical conditions occurring during exoplanet formation. Here we report isotopic measurements of the interstellar comet 3I/ATLAS, which reveal an elemental composition unlike any Solar System body. The water in 3I/ATLAS is enriched in deuterium, at a level of D/H = (0.95 +- 0.06)%, which is more than an order of magnitude higher than in known comets, while its range of 12C/13C ratios (141-191 for CO2 and 123-172 for CO) exceeds typical values found in the Solar System, as well as nearby interstellar clouds and protoplanetary disks. Such extreme isotopic signatures indicate formation at temperatures $\lesssim30$ K in a relatively metal-poor environment, early in the history of the Galaxy. When interpreted with respect to models for Galactic chemical evolution, the carbon isotopic composition implies that 3I/ATLAS accreted roughly 10-12 billion years ago, following an early period of intense star formation. 3I/ATLAS thus represents a preserved fragment of an ancient planetary system, and provides direct evidence for active ice chemistry and volatile-rich planetesimal formation in the young Milky Way.

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arXiv2026

Satellites and small bodies with ALMA: Insights into Solar System formation & evolution

Our understanding of the formation and evolution of planetary systems has made major advances in the past decade. This progress has been driven in large part by the Atacama Large Millimeter/submillimeter Array (ALMA), which has given us an unprecedented view of Solar System bodies themselves, and of the structure and chemistry of forming exoplanetary systems. Within our own Solar System, ALMA has enabled the detection of new molecules and isotopologues across moons and comets, as well as placing new constraints on the compositions and histories of small bodies through thermal emission observations. In this article, we highlight some key areas where ALMA has contributed to a deeper understanding of our Solar System's formation and evolution, and place these discoveries in the context of our evolving understanding of protoplanetary disks.

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arXiv2025

Zonal winds in Titan's middle atmosphere from a stellar occultation observed with Keck adaptive optics

We present spatially resolved Keck/NIRC2 images of a stellar occultation by Titan on September 5, 2022 and compare them to predictions from concurrent ALMA observations and a suite of General Circulation Model (GCM) simulations. ALMA data and GCM simulations can predict middle atmosphere zonal wind distributions, which in turn produce diagnostic occultation image sequences. We construct an occultation forward model using the temperature profile measured by the Huygens Atmospheric Structure Instrument, which is then distorted using latitudinal zonal wind profiles from the ALMA data or GCM simulations. The occultation forward model yields simulated light distributions around Titan's limb, which we compare directly to the light distributions observed during the occultation. The GCM zonal wind profile corresponding to slightly before the time of the stellar occultation provides the best overall match to the data. The ALMA wind profile provides the best match to the occultation data when only the ingress data were considered, but is not the best match when data from ingress and egress are combined. Our data support the presence of stronger winds in the southern hemisphere during late northern summer.

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arXiv2025

Isotopic composition of cometary water and the origin of Earth's oceans

Studies of the water content and isotopic composition of water-rich asteroids and comets are of key interest for understanding the late accretion stage of the Solar System cometary and chondritic materials. The PRobe far-infrared Mission for Astrophysics (PRIMA) can make an important contribution to solving this long-standing problem by carrying out direct measurements of the D/H ratio in a significant sample of Oort cloud and Kuiper belt comets, sampling the isotopic composition of the present-day outer Solar System. This would allow comparisons between different comet reservoirs, and with inner Solar System measurements in meteorites, as well as searching for correlations with physical parameters, such as hyperactivity, providing quantitative constraints on the dynamical and chemical models of the early Solar System.

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arXiv2025

The robust detection and spatial distribution of acetaldehyde in Orion KL: ALMA observations and chemical modeling

Despite the organic molecule inventory detected in Orion KL, acetaldehyde (CH3CHO) -- one of the most ubiquitous interstellar aldehydes -- has not been firmly identified with mm-wave interferometry. We analyze extensive ALMA archival datasets (142-355 GHz) to search for acetaldehyde, revealing two distinct acetaldehyde emission peaks and one component with more complex kinematic structures. One peak aligns with MF10/IRc2, where emissions of other O-bearing complex organic molecules are rarely reported, while the other is coincident with the ethanol peak in the hot core-SW. The MF10/IRc2 detection suggests unique chemistry, possibly influenced by repeated heating events. In contrast, co-detection with ethanol indicates an ice origin and suggests a potential chemical relationship between the two species. We determined acetaldehyde column densities and its kinetic temperatures toward these two peaks under LTE assumptions and compare its distribution with ethanol and other molecules that have an aldehyde (HCO) group, such as methyl formate, glycolaldehyde, and formic acid. Toward the ethanol peak, observed abundance ratios between HCO-containing species are analyzed using a chemical model. The model suggests two key points: 1) the destruction of ethanol to form acetaldehyde in the ice may contribute to the observed correlation between the two species, 2) a long cold-collapse timescale and a methyl formate binding energy similar to or lower than water are needed to explain the observations. The relative abundance ratios obtained from the model are highly sensitive to the assumed kinetic temperature, which accounts for the high spatial variability of the aldehyde ratios observed toward Orion KL.

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arXiv2023

The EDIBLES Survey. VII. A survey of C2 and C3 in interstellar clouds

We carried out a sensitive survey of C$_2$ and C$_3$ using the EDIBLES data set. We also expanded our searches to C$_4$, C$_5$, and $^{13}$C$^{12}$C isotopologue in the most molecule-rich sightlines. We fit synthetic spectra generated following a physical excitation model to the C$_2$ (2-0) Phillips band to obtain the C$_2$ column density ($N$) as well as the kinetic temperature ($T_\textrm{kin}$) and number density ($n$) of the host cloud. The C$_3$ molecule was measured through its $\tilde{A} - \tilde{X}$ (000-000) electronic origin band system. We simulated the excitation of this band with a double-temperature Boltzmann distribution. We present the largest combined survey of C$_2$ and C$_3$ to date in which the individual transitions can be resolved. In total we detected C$_2$ in 51 velocity components along 40 sightlines, and C$_3$ in 31 velocity components along 27 sightlines. The two molecules are detected in the same velocity components. We find a very good correlation between $N$(C$_2$) and $N$(C$_3$) with Pearson $r = 0.93$ and an average $N$(C$_2$)/$N$(C$_3$) ratio of 15.5$\pm$1.4. A comparison with the behaviour of the C$_2$ DIBs shows that there are no clear differences among sightlines with and without detection of C$_2$ and C$_3$. This is in direct contrast to the better-studied non-C$_2$ DIBs who have reduced strengths in molecule-rich environments. We also identify for the first time the $Q$(2), $Q$(3), and $Q$(4) transitions of the $^{13}$C$^{12}$C (2-0) Phillips band in a stacked average spectrum, and estimate the isotopic ratio of carbon $^{12}$C/$^{13}$C as 79$\pm$8. Our search for the C$_4$ and C$_5$ optical bands was unsuccessful.

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arXiv2022

The Detection of Deuterated Water in the Large Magellanic Cloud with ALMA

We report the first detection of deuterated water (HDO) toward an extragalactic hot core. The HDO 2$_{11}$-2$_{12}$ line has been detected toward hot cores N105-2A and 2B in the N105 star-forming region in the low-metallicity Large Magellanic Cloud (LMC) dwarf galaxy with the Atacama Large Millimeter/submillimeter Array (ALMA). We have compared the HDO line luminosity ($L_{\rm HDO}$) measured toward the LMC hot cores to those observed toward a sample of seventeen Galactic hot cores covering three orders of magnitude in $L_{\rm HDO}$, four orders of magnitude in bolometric luminosity ($L_{\rm bol}$), and a wide range of Galactocentric distances (thus metallicities). The observed values of $L_{\rm HDO}$ for the LMC hot cores fit very well into the $L_{\rm HDO}$ trends with $L_{\rm bol}$ and metallicity observed toward the Galactic hot cores. We have found that $L_{\rm HDO}$ seems to be largely dependent on the source luminosity, but metallicity also plays a role. We provide a rough estimate of the H$_2$O column density and abundance ranges toward the LMC hot cores by assuming that HDO/H$_2$O toward the LMC hot cores is the same as that observed in the Milky Way; the estimated ranges are systematically lower than Galactic values. The spatial distribution and velocity structure of the HDO emission in N105-2A is consistent with HDO being the product of the low-temperature dust grain chemistry. Our results are in agreement with the astrochemical model predictions that HDO is abundant regardless of the extragalactic environment and should be detectable with ALMA in external galaxies.

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arXiv2022

ALMA Observations of Molecular Complexity in the Large Magellanic Cloud: The N105 Star-Forming Region

The Large Magellanic Cloud (LMC) is the nearest laboratory for detailed studies on the formation and survival of complex organic molecules (COMs), including biologically important ones, in low-metallicity environments--typical for earlier cosmological epochs. We report the results of 1.2 mm continuum and molecular line observations of three fields in the star-forming region N105 with the Atacama Large Millimeter/submillimeter Array (ALMA). N105 lies at the western edge of the LMC bar with on-going star formation traced by H$_2$O, OH, and CH$_3$OH masers, ultracompact H II regions, and young stellar objects. Based on the spectral line modeling, we estimated rotational temperatures, column densities, and fractional molecular abundances for twelve 1.2 mm continuum sources. We identified sources with a range of chemical make-ups, including two bona fide hot cores and four hot core candidates. The CH$_3$OH emission is widespread and associated with all the continuum sources. COMs CH$_3$CN and CH$_3$OCH$_3$ are detected toward two hot cores in N105 together with smaller molecules typically found in Galactic hot cores (e.g., SO$_2$, SO, and HNCO) with the molecular abundances roughly scaling with metallicity. We report a tentative detection of the astrobiologically relevant formamide molecule (NH$_2$CHO) toward one of the hot cores; if confirmed, this would be the first detection of NH$_2$CHO in an extragalactic sub-solar metallicity environment. We suggest that metallicity inhomogeneities resulting from the tidal interactions between the LMC and the Small Magellanic Cloud (SMC) might have led to the observed large variations in COM abundances in LMC hot cores.

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arXiv2021

No evidence of phosphine in the atmosphere of Venus by independent analyses

The detection of phosphine (PH3) in the atmosphere of Venus has been recently reported based on millimeter-wave radio observations (Greaves et al. 2020), and its re-analyses (Greaves et al. 2021a/b). In this Matters Arising we perform an independent reanalysis, identifying several issues in the interpretation of the spectroscopic data. As a result, we determine sensitive upper-limits for PH3 in Venus' atmosphere (>75 km, above the cloud decks) that are discrepant with the findings in G2020 and G2021a/b. The measurements target the fundamental first rotational transition of PH3 (J=1-0) at 266.944513 GHz, which was observed with the James Clerk Maxwell Telescope (JCMT) in June 2017 and with the Atacama Large Millimeter/submillimeter Array (ALMA) in March 2019. This line's center is near the SO2 (J=309,21-318,24) transition at 266.943329 GHz (only 1.3 km/s away from the PH3 line) which represents a potential source of contamination. The JCMT and ALMA data, as presented in G2020, are at spectral resolutions comparable to the frequency separation of the two lines. Moreover, the spectral features identified are several km/s in width, and therefore do not permit distinct spectroscopic separation of the candidate spectral lines of PH3 and SO2. We present the radiative transfer modelling we have performed and then discuss the ALMA and JCMT analyses in turn.

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arXiv2020

Synergies between ground-based and space-based observations in the solar system and beyond

Telescope and detector developments continuously enable deeper and more detailed studies of astronomical objects. Larger collecting areas, improvement in dispersion and detector techniques, and higher sensitivities allow detection of more molecules in a single observation, at lower abundances, resulting in better constraints of the targets physical and chemical conditions. Improvements on current telescopes, and not to mention future observatories, both in space and on the ground, will continue this trend, ever improving our understanding of the Universe. Planetary exploration missions carry instrumentation to unexplored areas, and reveal details impossible to observe from the Earth by performing in-situ measurements. Space based observatories allow observations of object at wavelength ranges absorbed by the Earths atmosphere. The depth of understanding from all of these studies can be greatly enhanced by combining observations: ground-based and space-based, low-resolution and high-resolution, local and global-scale, similar observations over a broader or different spectra range, or by providing temporal information through follow-ups. Combined observations provide context and a broader scope of the studied object, and in this white paper, we outline a number of studies where observations are synergistically applied to increase the scientific value of both datasets. Examples include atmospheric studies of Venus, Mars, Titan, comets, Jupiter, as well as more specific cases describing synergistic studies in the Juno mission, and ground-based radar studies for near Earth objects. The examples aim to serve as inspiration for future synergistic observations, and recommendations are made based on the lessons learned from these examples.

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arXiv2020

The Crucial Role of Ground- and Space-Based Remote Sensing Studies of Cometary Volatiles in the Next Decade (2023-2032)

The study of comets affords a unique window into the birth, infancy, and subsequent history of the solar system. There is strong evidence that comets incorporated pristine interstellar material as well as processed nebular matter, providing insights into the composition and prevailing conditions over wide swaths of the solar nebula at the time of planet formation. Dynamically new Oort cloud comets harbor primitive ices that have been stored thousands of astronomical units from the Sun and have suffered minimal thermal or radiative processing since their emplacement ~4.5 Gyr ago. Periodic, more dynamically evolved comets such as the Halley-type and Jupiter-family comets reveal the effects of lives spent over a range of heliocentric distances, including perihelion passages into the very inner solar system. Systematically characterizing the information imprinted in the native ice compositions of these objects is critical to understanding the formation and evolution of the solar system, the presence of organic matter and water on the terrestrial planets, the chemistry present in protoplanetary disks around other stars, and the nature of interstellar interlopers such as 2I/Borisov. Although comet rendezvous and sample return missions can provide remarkable insights into the properties of a few short-period comets, the on-sky capacity necessary to perform population-level comet studies while simultaneously remaining sensitive to the paradigm-challenging science that individual comets can reveal can only be provided by remote sensing observations. Here we report the state-of-the-art in ground- and space-based remote sensing of cometary volatiles, review the remarkable progress of the previous decade, articulate the pressing questions that ground- and space-based work will address over the next ten years, and advocate for the technology and resources necessary to realize these aspirations.

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arXiv2020

CO, Water, and Possible Methanol in Eta Carinae Approaching Periastron

In circumstellar gas, the complex organic molecule methanol has been found almost exclusively around young stellar objects, and is thus regarded as a signpost of recent star formation. Here we report the first probable detection of methanol around an evolved high-mass star, in the complex circumstellar environment around the Luminous Blue Variable $η$ Carinae, while using ALMA to investigate molecular cloud conditions traced by CO (2-1) in an orbit phase of the massive binary preceding the 2020 periastron. Favoring methanol over a $^{13}$CS alternative, the emission originates from hot ($T_{\rm{gas}} \simeq$ 700 K) material, $\sim$2$''$ (0.02 pc) across, centered on the dust-obscured binary in contrast to the CO which traces inner layers of the extended massive equatorial torus, and is accompanied by prominent absorption in a cooler ($T_{\rm{gas}} \simeq$ 110 K) layer of gas. We also report detections of water in $Herschel$/HIFI observations at 557 GHz and 988 GHz. The methanol abundance is several to 50 times higher than observed towards several lower mass stars, while water abundances are similar to those observed in cool, dense molecular clouds. The very high methanol:water abundance ratio in the core of $η$ Carinae may suggest methanol formation processes similar to Fischer-Tropsch-type catalytic reactions on dust grains. These observations prove that complex molecule formation can occur in the chemically evolved environments around massive stars in the end stages of their evolution, given sufficient gas densities and shielding conditions as may occur in material around massive interacting companions and merger remnants.

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arXiv2017

The ESO Diffuse Interstellar Bands Large Exploration Survey: EDIBLES I. Project description, survey sample and quality assessment

The carriers of the diffuse interstellar bands (DIBs) are largely unidentified molecules ubiquitously present in the interstellar medium (ISM). After decades of study, two strong and possibly three weak near-infrared DIBs have recently been attributed to the C60+ fullerene based on observational and laboratory measurements. There is great promise for the identification of the over 400 other known DIBs, as this result could provide chemical hints towards other possible carriers. In an effort to systematically study the properties of the DIB carriers, we have initiated a new large-scale observational survey: the ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES). The main objective is to build on and extend existing DIB surveys to make a major step forward in characterising the physical and chemical conditions for a statistically significant sample of interstellar lines-of-sight, with the goal to reverse-engineer key molecular properties of the DIB carriers. EDIBLES is a filler Large Programme using the Ultraviolet and Visual Echelle Spectrograph at the Very Large Telescope at Paranal, Chile. It is designed to provide an observationally unbiased view of the presence and behaviour of the DIBs towards early-spectral-type stars whose lines-of-sight probe the diffuse-to-translucent ISM. Such a complete dataset will provide a deep census of the atomic and molecular content, physical conditions, chemical abundances and elemental depletion levels for each sightline. Achieving these goals requires a homogeneous set of high-quality data in terms of resolution (R ~ 70000 -- 100000), sensitivity (S/N up to 1000 per resolution element), and spectral coverage (305--1042 nm), as well as a large sample size (100+ sightlines). In this first paper the goals, objectives and methodology of the EDIBLES programme are described and an initial assessment of the data is provided.

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arXiv2015

The Composition of Comets

This paper is the result of the International Cometary Workshop, held in Toulouse, France in April 2014, where the participants came together to assess our knowledge of comets prior to the ESA Rosetta Mission. In this paper, we look at the composition of the gas and dust from the comae of comets. With the gas, we cover the various taxonomic studies that have broken comets into groups and compare what is seen at all wavelengths. We also discuss what has been learned from mass spectrometers during flybys. A few caveats for our interpretation are discussed. With dust, much of our information comes from flybys. They include {\it in situ} analyses as well as samples returned to Earth for laboratory measurements. Remote sensing IR observations and polarimetry are also discussed. For both gas and dust, we discuss what instruments the Rosetta spacecraft and Philae lander will bring to bear to improve our understanding of comet 67P/Churyumov-Gerasimenko as "ground-truth" for our previous comprehensive studies. Finally, we summarize some of the initial Rosetta Mission findings.

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arXiv2012

The abundance of C3H2 and other small hydrocarbons in the diffuse interstellar medium

Hydrocarbons are ubiquitous in the interstellar medium, observed in diverse environments ranging from diffuse to molecular dark clouds and strong photon-dominated regions near HII regions. Recently, two broad diffuse interstellar bands (DIBs) at 4881Å and 5450Å were attributed to the linear version of propynylidene l-C3H2, a species whose more stable cyclic conformer c-C3H2 has been widely observed in the diffuse interstellar medium at radio wavelengths. This attribution has already been criticized on the basis of indirect plausibility arguments because the required column densities are quite large, N(l-C3H2)/EB-V = 4 \times 1014 cm-2 mag-1. Here we present new measurements of N(l-C3H2) based on simultaneous 18-21 GHz VLA absorption profiles of cyclic and linear C3H2 taken along sightlines toward extragalactic radiocontinuum background sources with foreground Galactic reddening EB-V = 0.1 - 1.6 mag. We find that N(l-C3H2)/N(c-C3H2) ? 1/15 - 1/40 and N(l-C3H2)/EB-V ? 2 \pm 1 \times 1011 cm-2 mag-1, so that the column densities of l-C3H2 needed to explain the diffuse interstellar bands are some three orders of magnitude higher than what is observed. We also find N(C4H)/EB-V < 1.3 \times 1013 cm-2 mag-1 and N(C4H-)/EB-V < 1 \times 1011 cm-2 mag-1 (3?). Using available data for CH and C2H we compare the abundances of small hydrocarbons in diffuse and dark clouds as a guide to their ability to contribute as DIB carriers over a wide range of conditions in the interstellar medium.

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