Learning Spin Hamiltonians from Terahertz Two-Dimensional Coherent Spectroscopy
Effective Hamiltonians connect microscopic interactions to measurable collective behavior in quantum materials, but determining their parameters directly from experiment remains a challenging inverse problem. We introduce a supervised machine-learning framework that infers Hamiltonian parameters from nonlinear terahertz two-dimensional coherent spectra. A calibrated forward model generates spectra from candidate Hamiltonians, a common preprocessing pipeline maps simulated and experimental spectra into the same representation, and a neural network learns the inverse map from spectral fingerprints to microscopic parameters. We demonstrate the approach for rare-earth orthoferrites using a two-sublattice Landau--Lifshitz--Gilbert spin model with exchange, Dzyaloshinskii--Moriya interaction, anisotropies, and damping. Synthetic benchmarks show that nonlinear spectra encode parameters beyond those fixed by the linear response, with inference accuracy tracking the physical spectral sensitivity and robustness against noise improved by using multiple inter-pulse delays. Applied to experimental THz-2DCS data from Sm$_{0.4}$Er$_{0.6}$FeO$_3$, the inferred parameters yield physically reasonable forward simulations, while remaining discrepancies identify limitations of the reduced model. These results establish THz-2DCS as a data-rich platform for effective-Hamiltonian inference and model refinement, enabling experimentally driven identification of microscopic interactions while providing a foundation for understanding, predicting, and ultimately controlling the emergent properties of quantum materials.