arXiv subjects

Martin Rubin

Publications and source records attributed to Martin Rubin.

At least 19 recordsLinked to original sources

arXiv2025

Time-domain anode-decoupling co-design for a floating microchannel plate detector readout

We present a microchannel plate (MCP) detector for compact time-of-flight mass spectrometers (TOF-MS) that jointly optimizes the anode geometry and high-voltage AC-decoupling network for electrically floating operation. Undershoot-driven baseline artifacts and pulse broadening are addressed by a time-domain co-design of the anode geometry and decoupling network. The design is validated through a staged workflow that combines full-wave electromagnetic simulations, vector network analyzer measurements, circuit-level transient models, and end-to-end mass spectra. The resulting planar circular patch anode with anode-proximal decoupling confines fields, preserves peak amplitude, and suppresses post-pulse energy, leading to fast settling and minimal baseline wander. We show that the effective high-pass corner set by the decoupling capacitance directly governs undershoot decay and baseline recovery. Measurements in a representative TOF-MS test setup demonstrate waveguide-level pulse fidelity at a fraction of the mass and volume of heritage waveguide-based detectors, with residual ripples in the measured response originating from downstream cable and digitizer terminations rather than the detector itself. By limiting detector-induced temporal broadening and inter-peak baseline coupling, the design supports high mass resolution and dynamic range in miniaturized TOF-MS architectures. Variants of this planar flight-ready architecture are being implemented in several next-generation spaceborne TOF-MS instruments currently under development at the University of Bern.

physics.ins-det↗

arXiv2024

Electron-Induced Radiolysis of Water Ice and the Buildup of Oxygen

Irradiation by energetic ions, electrons, and UV photons induces sputtering and chemical processes (radiolysis) in the surfaces of icy moons, comets, and icy grains. Laboratory experiments, both of ideal surfaces and of more complex and realistic analog samples, are crucial to understand the interaction of surfaces of icy moons and comets with their space environment. This study shows the first results of mass spectrometry measurements from porous water ice regolith samples irradiated with electrons as a representative analogy to water-ice rich surfaces in the solar system. Previous studies have shown that most electron-induced H2O radiolysis products leave the ice as H2 and O2 and that O2 can be trapped under certain conditions in the irradiated ice. Our new laboratory experiments confirm these findings. Moreover, they quantify residence times and saturation levels of O2 in originally pure water ice. H2O may also be released from the water ice by irradiation, but the quantification of the released H2O is more difficult and the total amount is sensitive to the electron flux and energy.

astro-ph.EP↗

arXiv2024

Evidence for Abiotic Dimethyl Sulfide in Cometary Matter

Technological progress related to astronomical observatories such as the recently launched James Webb Space Telescope (JWST) allows searching for signs of life beyond our Solar System, namely in the form of unambiguous biosignature gases in exoplanetary atmospheres. The tentative assignment of a $1-2.4\sigma$ spectral feature observed with JWST in the atmosphere of exoplanet K2-18b to the biosignature gas dimethyl sulfide (DMS; sum formula C$_2$H$_6$S) raised hopes that, although controversial, a second genesis had been found. Terrestrial atmospheric DMS is exclusively stemming from marine biological activity and no natural abiotic source has been identified - neither on Earth nor in space. Therefore, DMS is considered a robust biosignature. Since comets possess a pristine inventory of complex organic molecules of abiotic origin, we have searched high-resolution mass spectra collected at comet 67P/Churyumov-Gerasimenko, target of the European Space Agency's Rosetta mission, for the signatures of DMS. Previous work reported the presence of a C2H6S signal when the comet was near its equinox but distinction of DMS from its structural isomer ethanethiol remained elusive. Here we reassess these and evaluate additional data. Based on differences in the electron ionization induced fragmentation pattern of the two isomers, we show that DMS is significantly better compatible with the observations. Deviations between expected and observed signal intensities for DMS are $<1\sigma$, while for ethanethiol they are $2-4\sigma$. The local abundance of DMS relative to methanol deduced from these data is (0.13$\pm$0.04)%. Our results provide the first evidence for the existence of an abiotic synthetic pathway to DMS in pristine cometary matter and hence motivate more detailed studies of the sulfur chemistry in such matter and its analogs. [...]

astro-ph.EP↗

arXiv2024

Interaction between a Coronal Mass Ejection and Comet 67P/Churyumov-Gerasimenko

The interaction between a Coronal Mass Ejection (CME) and a comet has been observed several times by in-situ observations from the Rosetta Plasma Consortium (RPC), which is designed to investigate the cometary magnetosphere of comet 67P/Churyumov-Gerasimenko (CG). Goetz et al. (2019) reported a magnetic field of up to 300 nT measured in the inner coma, which is among the largest interplanetary magnetic fields observed in the solar system. They suggested the large magnetic field observations in the inner coma come from magnetic field pile-up regions, which are generated by the interaction between a CME and/or corotating interaction region and the cometary magnetosphere. However, the detailed interaction between a CME and the cometary magnetosphere of comet CG in the inner coma has not been investigated by numerical simulations yet. In this manuscript, we will use a numerical model to simulate the interaction between comet CG and a Halloween class CME and investigate its magnetospheric response to the CME. We find that the plasma structures change significantly during the CME event, and the maximum value of the magnetic field strength is more than 500nT close to the nucleus. Virtual satellites at similar distances as Rosetta show that the magnetic field strength can be as large as 250nT, which is slightly less than what Goetz et al. (2019) reported.

astro-ph.EP↗

arXiv2023

Volatiles in the H$_2$O and CO$_2$ ices of comet 67P/Churyumov-Gerasimenko

ESA's Rosetta spacecraft at comet 67P/Churyumov-Gerasimenko (67P) was the first mission that accompanied a comet over a substantial fraction of its orbit. On board was the ROSINA mass spectrometer suite to measure the local densities of the volatile species sublimating from the ices inside the comet's nucleus. Understanding the nature of these ices was a key goal of Rosetta. We analyzed the primary cometary molecules at 67P, namely H$_2$O and CO$_2$, together with a suite of minor species for almost the entire mission. Our investigation reveals that the local abundances of highly volatile species, such as CH$_4$ and CO, are reproduced by a linear combination of both H$_2$O and CO$_2$ densities. These findings bear similarities to laboratory-based temperature programmed desorption experiments of amorphous ices and imply that highly volatile species are trapped in H$_2$O and CO$_2$ ices. Our results do not show the presence of ices dominated by these highly volatile molecules. Most likely, they were lost due to thermal processing of 67P's interior prior to its deflection to the inner solar system. Deviations in the proportions co-released with H$_2$O and CO$_2$ can only be observed before the inbound equinox, when the comet was still far from the sun and the abundance of highly volatile molecules associated with CO$_2$ outgassing were lower. The corresponding CO$_2$ is likely seasonal frost, which sublimated and lost its trapped highly volatile species before re-freezing during the previous apparition. CO, on the other hand, was elevated during the same time and requires further investigation.

astro-ph.EP↗

arXiv2023

Insight into the origin of cometary ices from Rosetta/ROSINA mass spectrometer data

Here we review some of the major findings of the mass spectrometer suite ROSINA on board of ESA's Rosetta spacecraft to comet 67P/Churyumov-Gerasimenko. For more than 2 years, ROSINA continuously measured the composition of the gases sublimating from the comet's nucleus. ROSINA measurements provided insight into the origin of the ices in 67P/Churyumov-Gerasimenko. The obtained molecular, elemental, and isotope abundances revealed a composition more complex than previously known. Furthermore, a subset of these measurements indicate that a substantial fraction of the molecules incorporated into the comet predate the formation of the solar system.

astro-ph.EP↗

arXiv2023

Neutral gas coma dynamics: modeling of flows and attempts to link inner coma structures to properties of the nucleus

Deriving properties of cometary nuclei from coma data is of significant importance for our understanding of cometary activity and has implications beyond. Ground-based data represent the bulk of measurements available for comets. Yet, to date these observations only access a comet's gas and dust coma at rather large distances from the surface and do not directly observe its surface. In contrast, spacecraft missions are one of the only tools that gain direct access to surface measurements. However, such missions are limited to roughly one per decade. We can overcome these challenges by recognising that the coma contains information about the nucleus's properties. In particular, the near-surface gas environment is most representative of the nucleus. It can inform us about the composition, regionality of activity, and sources of coma features and how they link to the topography, morphology, or other surface properties. The inner coma data is a particularly good proxy because it has not yet, or only marginally, been contaminated by coma chemistry or secondary gas sources. Additionally, the simultaneous observation of the innermost coma with the surface provides the potential to make a direct link between coma measurements and the nucleus. If we hope to link outer coma measurements obtained by Earth-based telescopes to the surface, we must first understand how the inner coma measurements are linked to the surface. Numerical models that describe the flow from the surface into the immediate surroundings are needed to make this connection. This chapter focuses on the advances made to understand the flow of the neutral gas coma from the surface to distances up to a few tens of nuclei radii. We describe both simple/heuristic models and state-of-the-art physically consistent models. Model limitations and what they each are best suited for are discussed.

astro-ph.EP↗

arXiv2023

Thermal Behavior of Astrophysical Amorphous Molecular Ices

Ice is a major component of astrophysical environment - from interstellar molecular clouds through protoplanetary disks to evolved solar systems. Ice and complex organic matter coexist in these environments as well, and it is thought primordial ice brought the molecules of life to Earth four billion years ago, which could have kickstarted the origin of life on Earth. To understand the journey of ice and organics from their origins to becoming a part of evolved planetary systems, it is important to complement high spatial and spectral resolution telescopes such as JWST with laboratory experimental studies that provide deeper insight into the processes that occur in these astrophysical environments. Our laboratory studies are aimed at providing this knowledge. In this article we present simultaneous mass spectrometric and infrared spectroscopic investigation on how molecular ice mixtures behave at different temperatures and how this information is critical to interpret observational data from protoplanetary disks as well as comets. We find that amorphous to crystalline water ice transformation is the most critical phenomenon that differentiates between outgassing of trapped volatiles such as CO2 vs. outgassing of pure molecular ice domains of the same in a mixed molecular ice. Crystalline water ice is found to trap only a small fraction of other volatiles (<5%), indicating ice grain composition in astrophysical and planetary environments must be different depending on whether the ice is in amorphous phase or transformed into crystalline phase, even if the crystalline ice undergoes radiation-induced amorphization subsequently. Crystallization of water ice is a key differentiator for many ices in astronomical environments as well as in our Solar System.

astro-ph.EP↗

arXiv2023

The ice composition close to the surface of comet 67P/Churyumov-Gerasimenko

The relation between ice composition in the nucleus of comet 67P/Churyumov-Gerasimenko on the one hand and relative abundances of volatiles in the coma on the other hand is important for the interpretation of density measurements in the environment of the cometary nucleus. For the 2015 apparition, in situ measurements from the two ROSINA (Rosetta Orbiter Spectrometer for Ion and Neutral Analysis) sensors COPS (COmet Pressure Sensor) and DFMS (Double Focusing Mass Spectrometer) determined gas densities at the spacecraft position for the 14 gas species H2O, CO2, CO, H2S, O2, C2H6, CH3OH, H2CO, CH4, NH3, HCN, C2H5OH, OCS, and CS2. We derive the spatial distribution of the gas emissions on the complex shape of the nucleus separately for 50 subintervals of the two-year mission time. The most active patches of gas emission are identified on the surface. We retrieve the relation between solar irradiation and observed emissions from these patches. The emission rates are compared to a minimal thermophysical model to infer the surface active fraction of H2O and CO2. We obtain characteristic differences in the ice composition close to the surface between the two hemispheres with a reduced abundance of CO2 ice on the northern hemisphere (locations with positive latitude). We do not see significant differences for the ice composition on the two lobes of 67P/C-G.

astro-ph.EP↗

arXiv2023

Multi-instrument analysis of 67P/Churyumov-Gerasimenko coma particles: COPS-GIADA data fusion

The European Space Agency's Rosetta mission to comet 67P/Churyumov-Gerasimenko has offered scientists the opportunity to study a comet in unprecedented detail. Four instruments of the Rosetta orbiter, namely, the Micro-Imaging Dust Analysis System (MIDAS), the Grain Impact Analyzer and Dust Accumulator (GIADA), the COmetary Secondary Ion Mass Analyser (COSIMA), and the Rosetta Orbiter Spectrometer for Ion and Neutral Analysis (ROSINA) have provided information on cometary dust particles. Cross-instrument comparisons are crucial to characterize cometary dust particles beyond the capabilities of individual sensors, as they are sensitive to different dust components. We present the first comparison between detections of the ROSINA COmet Pressure Sensor (COPS) and GIADA. These two instruments are complementary as the former is sensitive solely to volatiles of icy particles, while the latter measured the dust particle as a whole, including refractories and condensed (semi)volatiles. Our goal is to correlate the particles detected by COPS and GIADA and to assess whether they belong to a common group. We statistically analyzed the in situ data of COPS and GIADA by calculating Pearson correlation coefficients. Among the several types of particles detected by GIADA, we find that COPS particles are significantly correlated solely with GIADA fluffy agglomerates (Pearson correlation coefficient of 0.55 and p-value of $4.6\cdot 10^{-3}$). This suggests that fluffy particles are composed of both refractories and volatiles. COPS volatile volumes, which may be represented by equivalent spheres with a diameter in the range between 0.06 $\mu$m and 0.8 $\mu$m, are similar to the sizes of the fractal particle's subunits identified by MIDAS (i.e., 0.05-0.18 $\mu$m).

astro-ph.EP↗

arXiv2022

Chemistry of comet atmospheres

The composition of cometary ices provides key information on the thermal and chemical properties of the outer parts of the protoplanetary disk where they formed 4.6 Gy ago. This chapter reviews our knowledge of composition of cometary comae based on remote spectroscopy and in-situ investigations techniques. Cometary comae can be dominated by water vapour, CO or CO2. The abundances of several dozen of molecules, with a growing number of complex organics, have been measured in comets. Many species that are not directly sublimating from the nucleus ices have also been observed and traced out into the coma in order to determine their production mechanisms. Chemical diversity in the comet population and compositional heterogeneity of the coma are discussed. With the completion of the Rosetta mission, isotopic ratios, which hold additional clues on the origin of cometary material, have been measured in several species. Finally, important pending questions (e.g., the nitrogen deficiency in comets) and the need for further work in certain critical areas are discussed in order to answer questions and resolve discrepancies between techniques.

astro-ph.EP↗

arXiv2022

High D/H ratios in water and alkanes in comet 67P/Churyumov-Gerasimenko measured with the Rosetta/ROSINA DFMS

Isotopic abundances in comets are key to understanding the history and origin of material in the Solar System. Deuterium-to-hydrogen (D/H) ratios in water are available for several comets. However, no long-term studies of the D/H ratio in water of a comet during its passage around the Sun have been reported. Linear alkanes are important organic molecules, which have been found on several Solar System bodies, including comets. To date, only upper limits of isotopic ratios for D/H and 13C/12C in linear alkanes are available. The aim of this work is a detailed analysis of the D/H ratio in water during the whole Rosetta mission. In addition, a first determination of the D/H and 13C/12C ratios in the first four linear alkanes in the coma of 67P/Churyumov-Gerasimenko is provided. We analysed in situ measurements from the Rosetta/ROSINA Double Focusing Mass Spectrometer (DFMS). The D/H ratio from HDO/H2O and the 16O/17O ratio from H216O/H217O did not change during 67P's passage around the Sun between 2014 and 2016. All D/H ratio measurements were compatible, within 1$\sigma$, with the mean value of $5.01\times10^{-4}$ and its relative variation of 2.0%. This suggests that the D/H ratio in 67P's coma is independent of heliocentric distance, level of cometary activity, as well as spacecraft location with respect to the nucleus. Additionally, the 16O/17O ratio could be determined with a higher accuracy than previously possible, yielding a value of 2347 with a relative variation of 2.3%. For the alkanes, the D/H ratio is between 4.1 and 4.8 times higher than in H2O, while the 13C/12C ratio is compatible, within uncertainties, with data for other Solar System objects. The relatively high D/H ratio in alkanes is in line with other cometary organic molecules and suggests that these organics may be inherited from the presolar molecular cloud from which the Solar System formed.

astro-ph.EP↗

arXiv2021

Refractory elements in the gas phase for comet 67P/Churyumov-Gerasimenko

Results. We found that gas-phase silicon was present throughout the Rosetta mission. Furthermore, the presence of sodium and iron atoms near the comet's perihelion confirms that sputtering cannot be the sole release process for refractory elements into the gas phase. Nickel was found to be below the detection limit. The search for parent species of any of the identified gas phase refractories has not been successful. Upper limits for a suite of possible fragment species (SiH, SiC, NaH, etc.) of larger parent and daughter species have been obtained. Furthermore, Si did not exhibit the same drop in signal as do common cometary gases when the spacecraft is pointed away from the nucleus. The combined results suggest that a direct release of elemental species from small grains on the surface of the nucleus or from small grains in the surrounding coma is a more likely explanation than the previous assumption of release via the dissociation of gaseous parent molecules.

astro-ph.EP↗

arXiv2021

Detection of volatiles undergoing sublimation from 67P/Churyumov-Gerasimenko coma particles using ROSINA/COPS. II. The nude gauge

In an earlier study, we reported that the ram gauge of the COmet Pressure Sensor (COPS), one of the three instruments of the Rosetta Orbiter Spectrometer for Ion and Neutral Analysis (ROSINA), could be used to obtain information about the sublimating content of icy particles, made up of volatiles and conceivably refractories coming from comet 67P/Churyumov-Gerasimenko. In this work, we extend the investigation to the second COPS gauge, the nude gauge. In particular, we analyse the volume of the volatile content of coma particles, along with a search for possible dependencies between the nude gauge detection rate (i.e. the rate at which icy particles are detected by the nude gauge) and the position of the Rosetta spacecraft. We also investigate the correlations of the nude gauge detection rate with the quantities associated with cometary activity. Although it was not originally designed for such a purpose, the COPS nude gauge has been able to detect $\sim$67000 features generated by the sublimation of the volatile content of icy particles. The nude gauge detection rate follows a trend that is inversely proportional to the heliocentric distance. This result is interpreted as a confirmation of a possible relation between the nude gauge detection rate and cometary activity. Thus, we compared the former with parameters related to cometary activity and obtained significant correlations, indicating that the frequency of icy particle detection is driven by cometary activity. Furthermore, by representing the volatile part of the icy particles as equivalent spheres with a density of 1 g cm$^{-3}$, we obtained a range of diameters between 60 and 793 nanometres, with the smaller ones ($<390\,\mathrm{nm}$ in diameter) having a size distribution power index of $-4.79\pm 0.26$.

astro-ph.EP↗

arXiv2020

Detection of volatiles undergoing sublimation from 67P/Churyumov-Gerasimenko coma particles using ROSINA/COPS. I. The ram gauge

The ESA Rosetta mission has allowed an extensive in-situ study of comet 67P/Churyumov-Gerasimenko. In measurements performed by the ram gauge of the on-board COmet Pressure Sensor (COPS), features have been observed that deviate from the nominal ram gauge signal. These are attributable to the sublimation of the volatile fraction of cometary icy particles containing volatiles and refractories. The objective of this work is the investigation of the volatile content of icy particles that entered the COPS ram gauge. The ram gauge measurements are inspected for features that we associate to the sublimation of the volatile component of cometary particles impacting the instrument. All sublimation features with high enough signal to noise ratio are modelled by fitting one or more exponential decay functions. The parameters of these fits are used to categorise different compositions of the sublimating component. From features attributable to ice sublimation, we infer the detection of 73 icy particles containing volatiles. 25 detections have enough volatile content for an in-depth study. From the values of the exponential decay constants, we classified the 25 inferred icy particles into three types, interpreted as different volatile compositions, possibly further complicated by different morphologies. Available data do not give indication as to which molecules compose the different types. Nevertheless, we can estimate the total volume of volatiles, expressed as the diameter of an equivalent sphere of water (density of 1 g cm$^{-3}$). This was found to be on the order of hundreds of nanometres.

astro-ph.EP↗

arXiv2020

Prestellar grain-surface origins of deuterated methanol in comet 67P/Churyumov-Gerasimenko

Deuterated methanol is one of the most robust windows astrochemists have on the individual chemical reactions forming deuterium-bearing molecules and the physicochemical history of the regions where they reside. The first-time detection of mono- and di-deuterated methanol in a cometary coma is presented for comet 67P/Churyumov-Gerasimenko using Rosetta-ROSINA data. D-methanol (CH3OD and CH2DOH combined) and D2-methanol (CH2DOD and CHD2OH combined) have an abundance of 5.5+/-0.46 and 0.00069+/-0.00014 per cent relative to normal methanol. The data span a methanol deuteration fraction (D/H ratio) in the 0.71-6.6 per cent range, accounting for statistical corrections for the location of D in the molecule and including statistical error propagation in the ROSINA measurements. It is argued that cometary CH2DOH forms from CO hydrogenation to CH3OH and subsequent H-D substitution reactions in CH3-R. CHD2OH is likely produced from deuterated formaldehyde. Meanwhile, CH3OD and CH2DOD, could form via H-D exchange reactions in OH-R in the presence of deuterated water ice. Methanol formation and deuteration is argued to occur at the same epoch as D2O formation from HDO, with formation of mono-deuterated water, hydrogen sulfide, and ammonia occurring prior to that. The cometary D-methanol/methanol ratio is demonstrated to agree most closely with that in prestellar cores and low-mass protostellar regions. The results suggest that cometary methanol stems from the innate cold (10-20 K) prestellar core that birthed our Solar System. Cometary volatiles individually reflect the evolutionary phases of star formation from cloud to core to protostar.

astro-ph.EP↗

arXiv2020

First in-situ detection of the CN radical in comets and evidence for a distributed source

Although the debate regarding the origin of the cyano (CN) radical in comets has been ongoing for many decades, it has yielded no definitive answer to date. CN could previously only be studied remotely, strongly hampering efforts to constrain its origin because of very limited spatial information. Thanks to the European Space Agency's Rosetta spacecraft, which orbited comet 67P/Churyumov-Gerasimenko for two years, we can investigate, for the first time, CN around a comet at high spatial and temporal resolution. On board Rosetta's orbiter module, the high-resolution double-focusing mass spectrometer DFMS, part of the ROSINA instrument suite, analyzed the neutral volatiles (including HCN and the CN radical) in the inner coma of the comet throughout that whole two-year phase and at variable cometocentric distances. From a thorough analysis of the full-mission data, the abundance of CN radicals in the cometary coma has been derived. Data from a close flyby event in February 2015 indicate a distributed origin for the CN radical in comet 67P/Churyumov-Gerasimenko.

astro-ph.EP↗

arXiv2020

The gas production of 14 species from comet 67P/Churyumov-Gerasimenko based on DFMS/COPS data from 2014-2016

The coma of comet 67P/Churyumov-Gerasimenko has been probed by the Rosetta spacecraft and shows a variety of different molecules. The ROSINA COmet Pressure Sensor and the Double Focusing Mass Spectrometer provide in-situ densities for many volatile compounds including the 14 gas species H2O, CO2, CO, H2S, O2, C2H6, CH3OH, H2CO, CH4, NH3, HCN, C2H5OH, OCS, and CS2. We fit the observed densities during the entire comet mission between August 2014 and September 2016 to an inverse coma model. We retrieve surface emissions on a cometary shape with 3996 triangular elements for 50 separated time intervals. For each gas we derive systematic error bounds and report the temporal evolution of the production, peak production, and the time-integrated total production. We discuss the production for the two lobes of the nucleus and for the northern and southern hemispheres. Moreover we provide a comparison of the gas production with the seasonal illumination.

astro-ph.EP↗