arXiv subjects
Publications and source records attributed to Masahiko Isobe.
The nuclear spin-lattice relaxation rate (1/T1) at the V sites in CaV2O5 was measured. The result was compared with the calculation for the two-leg ladder with the strong-coupling expansion. We found a good agreement on the temperature and magnetic field dependence but a discrepancy between the exchange parameters deduced from 1/T1 and the magnetic susceptibility.
23Na NMR spectrum measurements in alpha'-NaV2O5 with a single- crystalline sample are reported. In the charge-ordered phase, the number of inequivalent Na sites observed is more than that expected from the low-temperature structures of space group Fmm2 reported so far. This disagreement indicates that the real structure including both atomic displacement and charge disproportionation is of lower symmetry. It is suggested that zigzag ordering is the most probable. The temperature variation of the NMR spectra near the transition temperature is incompatible with that of second-order transitions. It is thus concluded that the charge ordering transition is first-order.