arXiv subjects

Masanari Shimada

Publications and source records attributed to Masanari Shimada.

15 recordsLinked to original sources

arXiv2026

Linear stability and viscoelastic response in weakly jammed frictional granular systems

Granular particles typically feature contact friction, which gives rise to various nontrivial properties of granular materials. In this work, we investigate the linear stability of static packings composed of frictional spheres, whose interactions are modeled using the discrete element method. We discuss a key difficulty in properly modeling static friction and address the problem of identifying rattlers. We also explore the spectrum of the energy matrix, which governs the linear viscoelastic response of the system. The intermediate- and high-frequency regimes of the spectrum remain qualitatively independent of both the friction coefficient and the packing fraction.

cond-mat.soft↗

arXiv2025

Statistical mechanics of fluids with hidden degrees of freedom

Although coarse-grained models have been widely used to explain exotic phenomena in complex fluids, such as droplet formation in living cells, these conventional approaches often fail to capture the intricate microscopic degrees of freedom that such fluids inherently possess. In this study, we propose a model that incorporates distinct microscopic degrees of freedom and their interactions, without directly relying on conventional coarse-grained descriptions. By introducing two key assumptions, we show that the system can exhibit equilibrium states characterized by heterogeneous density profiles with finite length scales, resembling those typically associated with non-equilibrium phenomena. These findings highlight the importance of distinguishing between equilibrium states and non-equilibrium steady states in highly complex systems.

cond-mat.soft↗

arXiv2024

Fermionic theory of nonequilibrium steady states

As the quantification of metabolism, nonequilibrium steady states play a central role in living matter, but are beyond the purview of equilibrium statistical mechanics. Here we develop a fermionic theory of nonequilibrium steady states in continuous-time Markovian systems, generalizing Boltzmann-Gibbs statistical mechanics to this case. The response to an arbitrary perturbation is computed, and simplified in canonical cases. Beyond response, we consider ensembles of nonequilibrium steady states and show that a general class of ensembles is described by a 2D statistical field theory with infinitesimally broken supersymmetry, which may form the basis of nontrivial solvable models of nonequilibrium steady states.

cond-mat.stat-mech↗

arXiv2024

Universal Slow Dynamics of Chemical Reaction Networks

Understanding the emergent behavior of chemical reaction networks (CRNs) is a fundamental aspect of biology and its origin from inanimate matter. A closed CRN monotonically tends to thermal equilibrium, but when it is opened to external reservoirs, a range of behaviors is possible, including transition to a new equilibrium state, a non-equilibrium state, or indefinite growth. This study shows that slowly driven CRNs are governed by the conserved quantities of the closed system, which are generally far fewer in number than the species. Considering both deterministic and stochastic dynamics, a universal slow dynamics equation is derived with singular perturbation methods, and is shown to be thermodynamically consistent. The slow dynamics is highly robust against microscopic details of the network, which may be unknown in practical situations. In particular, non-equilibrium states of realistic large CRNs can be sought without knowledge of bulk reaction rates. The framework is successfully tested against a suite of networks of increasing complexity and argued to be relevant in the treatment of open CRNs as chemical machines.

q-bio.MN↗

arXiv2024

Instantaneous normal modes of glass-forming liquids during the athermal relaxation process of the steepest descent algorithm

Understanding glass formation by quenching remains a challenge in soft condensed matter physics. Recent numerical studies on steepest descent dynamics, which is one of the simplest models of quenching, revealed that quenched liquids undergo slow relaxation with a power law towards mechanical equilibrium and that the late stage of this process is governed by local rearrangements of particles. These advances motivate the detailed study of instantaneous normal modes during the relaxation process because the glassy dynamics is considered to be governed by stationary points of the potential energy landscape. Here, we performed a normal mode analysis of configurations during the steepest descent dynamics and found that the dynamics is driven by almost flat directions of the potential energy landscape at long times. These directions correspond to localized modes and we characterized them in terms of their statistics and structure using methods developed in the study of local minima of the potential energy landscape.

cond-mat.soft↗

arXiv2022

Gas-liquid phase separation at zero temperature: mechanical interpretation and implications for gelation

The relationship between glasses and gels has been intensely debated for decades; however, the transition between these two phases remains elusive. To investigate a gel formation process in the zero-temperature limit and its relation to the glass phase, we conducted numerical experiments on athermal quasistatic decompression. During decompression, the system experiences a cavitation event similar to phase separation and this is a gelation process at zero temperature. A normal mode analysis revealed that the phase separation is signaled by the vanishing of the lowest eigenenergy, similar to plastic events of glasses under shear. One primary difference from the shear-induced plasticity is that the vanishing mode experiences a qualitative change in its spatial energy distribution at the phase separation point. These findings enable us to define the glass-gel phase boundary based on mechanics.

cond-mat.soft↗

arXiv2022

Vibrational density of states of jammed packing: mean-field theory

Several mean-field theories predict that Hessian matrices of amorphous solids can be written by using the random matrix in the limit of the large spatial dimensions $d\to\infty$. Motivated by these results, we here propose a way to map a Hessian of the amorphous solid to a random matrix. This is possible by determining the coefficients of a random matrix so that the trace of the random matrix coincides with the Hessian of the original system. We compare our result with that of previous numerical simulations of harmonic spheres in several spatial dimensions $d=3$, $5$, and $9$. For small pressure $p\ll 1$ (near jamming), we find a good agreement even in $d=3$, and obtain better agreements in larger $d$, suggesting that the approximation indeed becomes exact in the limit of large spatial dimensions.

cond-mat.dis-nn↗

arXiv2021

Random quench predicts universal properties of amorphous solids

Amorphous solids display numerous universal features in their mechanics, structure, and response. Current models assume heterogeneity in mesoscale elastic properties, but require fine-tuning in order to quantitatively explain vibrational properties. A complete model should derive the magnitude and character of elastic heterogeneity from an initially structureless medium, through a model of the quenching process during which the temperature is rapidly lowered and the solid is formed. Here we propose a field-theoretic model of a quench, and compute structural, mechanical, and vibrational observables in arbitrary dimension $d$. This allows us to relate the properties of the amorphous solid to those of the initial medium, and to those of the quench. We show that previous mean-field results are subsumed by our analysis and unify spatial fluctuations of elastic moduli, long-range correlations of inherent state stress, universal vibrational anomalies, and localized modes into one picture.

cond-mat.dis-nn↗

arXiv2020

Spatial structure of unstable normal modes in a glass-forming liquid

The phenomenology of glass-forming liquids is often described in terms of their underlying, high-dimensional potential energy surface. In particular, the statistics of stationary points sampled as a function of temperature provides useful insight into the thermodynamics and dynamics of the system. To make contact with the real space physics, however, analysis of the spatial structure of the normal modes is required. In this work, we numerically study the potential energy surface of a glass-forming ternary mixture. Starting from liquid configurations equilibrated over a broad range of temperatures using a swap Monte Carlo method, we locate the nearby stationary points and investigate the spatial architecture and the energetics of the associated unstable modes. Through this spatially-resolved analysis, originally developed to study local minima, we corroborate recent evidence that the nature of the unstable modes changes from delocalized to localized around the mode-coupling temperature. We find that the displacement amplitudes of the delocalized modes have a slowly decaying far field, whereas the localized modes consist of a core with large displacements and a rapidly decaying far field. The fractal dimension of unstable modes around the mobility edge is equal to 1, consistent with the scaling of the participation ratio. Finally, we find that around and below the mode-coupling temperature the unstable modes are localized around structural defects, characterized by a disordered local structure markedly different from the liquid's locally favored structure. These defects are similar to those associated to quasi-localized vibrations in local minima and are good candidates to predict the emergence of localized excitations at low temperature.

cond-mat.stat-mech↗

arXiv2020

Novel elastic instability of amorphous solids in finite spatial dimensions

Recently, progress has been made in the understanding of anomalous vibrational excitations in amorphous solids. In the lowest-frequency region, the vibrational spectrum follows a non-Debye quartic law, which persists up to zero frequency without any frequency gap. This gapless vibrational density of states (vDOS) suggests that glasses are on the verge of instability. This feature of marginal stability is now highlighted as a key concept in the theories of glasses. In particular, the elasticity theory based on marginal stability predicts the gapless vDOS. However, this theory yields a quadratic law and \textit{not} the quartic law. To address this inconsistency, we presented a new type of instability, which is different from the conventional one, and proposed that amorphous solids are marginally stable considering the new instability in the preceding study~[M. Shimada, H. Mizuno, and A. Ikeda, Soft Matter, {\bf 16}, 7279, 2020]. In this study, we further extend and detail the results for these instabilities. By analyzing various examples of disorder, we demonstrate that real glasses in finite spatial dimensions can be marginally stable by the proposed novel instability.

cond-mat.dis-nn↗

arXiv2019

Anharmonic properties of vibrational excitations in amorphous solids

Understanding the vibrational and thermal properties of amorphous solids is one of the most discussed and long-standing issues in condensed matter physics. Recent works have made significant steps towards understanding harmonic vibrational states. In particular, it has been established that quasi-localized vibrational modes emerge in addition to phonon-like vibrational modes. In this work, we study the anharmonic properties of these vibrational modes. We find that vibrational modes exhibit anharmonicities that induce particle rearrangements and cause transitions to different states. These anharmonicities are distinct from those in crystals, where particle rearrangements never occur. Remarkably, for both the phonon modes and quasi-localized modes, the vibrational modes exhibit strong anharmonicities, and the induced particle rearrangements are always localized in space and are composed of 1 to 1000 particles. Our findings contribute to the understanding of low-temperature thermal properties, for which anharmonic vibrations are crucial.

cond-mat.soft↗

arXiv2019

Low-frequency vibrations of jammed packings in large spatial dimensions

Amorphous packings prepared in the vicinity of the jamming transition play a central role in theoretical studies of the vibrational spectrum of glasses. Two mean-field theories predict that the vibrational density of states $g(ω)$ obeys a characteristic power law, $g(ω)\simω^2$, called the non-Debye scaling in the low-frequency region. Numerical studies have however reported that this scaling breaks down at low frequencies, due to finite dimensional effects. In this study, we prepare amorphous packings of up to $128000$ particles in spatial dimensions from $d=3$ to $d=9$ to characterise the range of validity of the non-Debye scaling. Our numerical results suggest that the non-Debye scaling is obeyed down to a frequency that gradually decreases as $d$ increases, and possibly vanishes for large $d$, in agreement with mean-field predictions. We also show that the prestress is an efficient control parameter to quantitatively compare packings across different spatial dimensions.

cond-mat.soft↗

arXiv2019

Vibrational spectrum derived from the local mechanical response in disordered solids

The low-frequency vibrations of glasses are markedly different from those of crystals. These vibrations have recently been categorized into two types: spatially extended vibrations, whose vibrational density of states (vDOS) follows a non-Debye quadratic law, and quasilocalized vibrations (QLVs), whose vDOS follows a quartic law. The former are explained by elasticity theory with quenched disorder and microscopic replica theory as being a consequence of elastic instability, but the origin of the latter is still debated. Here, we show that the latter can also be directly derived from elasticity theory with quenched disorder. We find another elastic instability that the theory encompasses but that has been overlooked so far, namely, the instability of the system against a local dipolar force. This instability gives rise to an additional contribution to the vDOS, and the spatial structure and energetics of the mode originating from this instability are consistent with those of the QLVs. Finally, we construct a model in which the additional contribution to the vDOS follows a quartic law.

cond-mat.soft↗

arXiv2018

Spatial structure of quasi-localized vibrations in nearly jammed amorphous solids

The low-temperature properties of amorphous solids are widely believed to be controlled by low-frequency quasi-localized modes. What governs their spatial structure and density is however debated. We study these questions numerically in very large systems as the jamming transition is approached and the pressure p vanishes. We find that these modes consist of an unstable core in which particles undergo the buckling motions and decrease the energy, and a stable far-field component which increases the energy and prevents the buckling of the core. The size of the core diverges as $p^{-1/4}$ and its characteristic volume as $p^{-1/2}$ These features are precisely those of the anomalous modes known to cause the Boson peak in the vibrational spectrum of weakly-coordinated materials. From this correspondence we deduce that the density of quasi-localized modes must go as $g_{\mathrm{loc}}(ω) \sim ω^4/p^2$ , in agreement with previous observations. Our analysis thus unravels the nature of quasi-localized modes in a class of amorphous materials.

cond-mat.dis-nn↗

arXiv2017

Anomalous vibrational properties in the continuum limit of glasses

The low-temperature thermal properties of glasses are anomalous with respect to those of crystals. These thermal anomalies indicate that the low-frequency vibrational properties of glasses differ from those of crystals. Recent studies revealed that, in the simplest model of glasses, i.e., the harmonic potential system, phonon modes coexist with soft localized modes in the low-frequency (continuum) limit. However, the nature of low-frequency vibrational modes of more realistic models is still controversial. In the present work, we study the Lennard-Jones (LJ) system using large-scale molecular-dynamics (MD) simulation and establish that the vibrational property of the LJ glass converges to coexistence of the phonon modes and the soft localized modes in the continuum limit as in the case of the harmonic potential system. Importantly, we find that the low-frequency vibrations are rather sensitive to the numerical scheme of potential truncation which is usually implemented in the MD simulation, and this is the reason why contradictory arguments have been reported by previous works. We also discuss the physical origin of this sensitiveness by means of a linear stability analysis.

cond-mat.soft↗