arXiv subjects

Mathias Zambach

Publications and source records attributed to Mathias Zambach.

6 recordsLinked to original sources

arXiv2026

The impact of sample insulation on estimating the heating power of magnetic nanoparticles by AC calorimetry

Correct estimation of the heating power of magnetic nanoparticles is important for magnetic hyperthermia treatment. This work investigates the impact of sample insulation in AC calorimetry. We show that temperature increase in the insulation can lead to systematic errors when estimating the heating power by the corrected slope method. The errors arise if the temperature of the sample environment is kept fixed at its initial temperature in the data analysis. To correct for this, we propose the use of a local temperature difference between the sample and the sample environment.

physics.app-ph↗

arXiv2026

Enhanced nanocomposite susceptibility by field-alignment of superparamagnetic particles

Nanocomposites comprised of insulated magnetic single-domain particles are promising candidates for high-frequency, eddy current free, soft magnetic materials, but tend to suffer from low magnetic susceptibility ($<20$). Particle alignment has been proposed to increase nanocomposite susceptibility and reduce magnetic losses but experimental verification has been lacking. Here, magnetic nanocomposites containing 3-57 vol\% field-aligned 11$\pm$3 nm maghemite particles in a poly-vinyl matrix were investigated for potential use as high-frequency inductor core materials. The particles were aligned by a homogenous static alignment field during nanocomposite drying, fixating the particle orientation. Particle aggregation was disproved by small-angle scattering. The dependence of the alignment field strength and particle concentration on the nanocomposite's susceptibility and hysteresis losses were investigated from DC up to 922 kHz by vibrating sample magnetometry, AC-susceptibility and high-frequency hysteresis measurements. Nanocomposite susceptibility increased super-linearly with particle fraction due to weak particle interactions. Alignment of the particles increased the nanocomposite susceptibility from 21 to 50 for samples with a particle content of 57 vol\%. Hence, the synergy between particle alignment and interaction allows for a higher than expected susceptibility of nanocomposites. The results show that magnetically aligning particles in a nanocomposite reduces magnetic losses when using well-dispersed single-domain superparamagnetic nanoparticles. Measured nanocomposite susceptibility could be modelled by a combination of directional dependent Debye-models including mean-field interaction effects and partial particle alignment. Measured susceptibility of 50 is among the highest obtained for nanocomposites, making it a relevant candidate for applications in power electronics.

physics.app-ph↗

arXiv2025

AC Magnetometry Loop Tracer Compatible with Magnetic Calorimetry for Power Loss Analysis

Magnetic nanoparticles (MNPs) have garnered significant attention for various applications in the high-kHz-to-MHz range, although their magnetic characterization at these operational conditions has been limited. However, a number of recent studies have showcased high-frequency and high-field amplitude AC magnetometry loop tracers capable of retrieving the magnetic AC hysteresis curve and the associated magnetic properties. In this paper, we present an easily constructable loop tracer that is retrofitted into an existing AC calorimetry setup. This enables the loop tracer to function simultaneously with the AC calorimetry setup and also to be run as a high-frequency AC susceptometer. The loop tracer is shown to work in the frequency range 160-922 kHz with maximum applied fields from 18 to 46 mT depending on the frequency. An iron oxide nanoflower sample is used to test the loop tracer, showcasing high reproducibility in measured magnetic parameters as well as quantitative agreement between the different measurement methods in the setup.

physics.ins-det↗

arXiv2025

Printable Nanocomposites with Superparamagnetic Maghemite ($\gamma$-Fe$_2$O$_3$) Particles for Microinductor-core Applications

We here present printable and castable magnetic nanocomposites containing superparamagnetic 11$\pm$3 nm $\gamma$-Fe$_2$O$_3$ particles in an insulating poly-vinyl alcohol polymer matrix. The nanocomposites feature well-dispersed particles with volume fractions between 10 and 45 \%, as confirmed by small-angle neutron scattering. The magnetic volume susceptibility is as high as 17, together with negligible hysteresis at low frequency, and constant AC-response up to the high-kHz range. Measured hysteresis curves at 100-900 kHz with up to 110 mT induced $B$-fields in the nanocomposite show that power losses depend on $B$-field squared, and frequency to the power of 1-1.3. The only loss mechanism in the nanocomposite is hysteresis losses at $>$100 kHz frequencies, where the largest particles in the 11$\pm$3 nm distribution transition from the superparamagnetic to blocked regime. To mitigate the resulting hysteresis losses (up 10$^2$-10$^5$ kW/m$^3$) a more narrow particle size distribution could be used for future materials. The presented material is eddy current-free and easily integrated into micro-fabrication protocols, as we demonstrate by fabrication of 3-turn print circuit board based inductors with cast/manual printed nanocomposite inductor cores, on which induction has been measured up to 100 MHz.

cond-mat.mes-hall↗

arXiv2025

The effect of demagnetization on the susceptibility of single-domain particles and assemblies

According to the classical laws of magnetism, the shape of magnetically soft objects limits the effective susceptibility. For example, spherical soft magnets cannot display an effective susceptibility larger than 3. Although this is true for macroscopic multi-domain magnetic materials, we explain why magnetic nanoparticles in a single-domain state do not suffer from this limitation. For single-domain particles, the differences between demagnetization factors along principal axes are relevant and can influence susceptibility but do not limit the susceptibility to an upper value as in the case for multi-domain particles. We experimentally validated this result on spherical nanoparticles with varying diameter (9 to 150 nm) and varying volume fraction (0.1 to 47 vol%). In agreement with our predictions, we measure single-domain particle susceptibilities largely above 3, in fact up to more than 250. Moreover, contrary to an existing model for assemblies of particles, we find that the susceptibility of materials composed of non-interacting single-domain particles in a non-magnetic matrix scales linearly with the volume fraction of particles. This implies that high susceptibilities (>100) are achievable for nanoparticle-based composites and is relevant for the design of magnetically soft materials that are operational at MHz-GHz frequencies with negligible power losses.

cond-mat.mes-hall↗

arXiv2023

Design of superparamagnetic nanoparticle-materials for high-frequency inductor cores

The progress in the semiconductor industry has resulted in great demand for high-frequency magnetic materials applicable in microfabricated inductor cores. Nanocomposite materials, containing magnetic nanoparticles in a non-conducting matrix, may provide a solution for materials with high susceptibility or permeability and low power loss in the MHz regime, where traditional ferrites fail in performance. Here, we present a design guide for usage of magnetic nanoparticles in such materials. We use statistical mechanics methods to derive the magnetic susceptibility of nanoparticles in case of uniaxial or cubic anisotropy, as function of particle size and applied field direction, and investigate shape and interaction effects on the susceptibility. Using the derived susceptibilities, with inductor-core applications in mind, we show that close-to-spherical particles of materials with high saturation magnetization and low magnetic anisotropy, such as FeNi$_3$, are optimal. Additionally, the particle size shall be optimized to be as large as possible while maintaining superparamagnetic behaviour at the relevant frequency. Based on this, we predict that high particle susceptibilities of $>$700 (/$>$1500) are possible for randomly oriented (/uniaxially aligned) 20$\pm$1 nm diameter FeNi$_3$ particles, together with high-frequency stability, shown by low out-of-phase component at 2 MHz. This implies that materials containing nanoparticles have the potential to be tuned to outperform state-of-the-art ferrite inductor-core materials at MHz-frequencies.

cond-mat.mes-hall↗