arXiv subjects

Mathis Fricke

Publications and source records attributed to Mathis Fricke.

At least 19 recordsLinked to original sources

arXiv2025

Beyond the Cassie-Baxter Model: New Insights for Predicting Imbibition in Complex Systems

We revisit the classical problem of liquid imbibition in a single pore with spatially varying wettability. Starting from the Lucas-Washburn equation, we derive analytical solutions for the imbibition time (crossing time) in systems where wettability alternates between two materials. For ordered arrangements, we demonstrate that the imbibition speed depends non-trivially on the spatial distribution, with the "more hydrophobic-first" configuration being optimal. For disordered systems, where segment lengths follow a Gaussian distribution, we show that the classical Cassie-Baxter contact angle, originally derived for static wetting, fails to predict the dynamics of capillary-driven flow. To address this, we propose a new weighted harmonic averaging method for the contact angle, which accurately describes the viscous crossing time in such heterogeneous systems. Our findings reveal fundamental insights into the role of wettability heterogeneity in capillary-driven flow, offering a basis for understanding imbibition dynamics in complex heterogeneous systems. The research data and the software supporting this study are openly available at DOI:10.5281/zenodo.14537452.

physics.flu-dyn↗

arXiv2024

A consistent treatment of dynamic contact angles in the sharp-interface framework with the generalized Navier boundary condition

In this work, we revisit the Generalized Navier Boundary condition (GNBC) introduced by Qian et al.\ in the sharp interface Volume-of-Fluid context. We replace the singular uncompensated Young stress by a smooth function with a characteristic width $\varepsilon > 0$ that is understood as a physical parameter of the model. Therefore, we call the model the ``Contact Region GNBC'' (CR-GNBC). We show that the model is consistent with the fundamental kinematics of the contact angle transport described by Fricke, K\"ohne and Bothe. We implement the model in the geometrical Volume-of-Fluid solver Basilisk using a ``free angle'' approach. This means that the dynamic contact angle is not prescribed but reconstructed from the interface geometry and subsequently applied as an input parameter to compute the uncompensated Young stress. We couple this approach to the two-phase Navier Stokes solver and study the withdrawing tape problem with a receding contact line. It is shown that the model allows for grid-independent solutions and leads to a full regularization of the singularity at the moving contact line, which is in accordance with the thin-film equation subject to this boundary condition. In particular, it is shown that the curvature at the moving contact line is finite and mesh converging. As predicted by the fundamental kinematics, the parallel shear stress component vanishes at the moving contact line for quasi-stationary states (i.e. for $\dot{\theta}_d=0$) and the dynamic contact angle is determined by a balance between the uncompensated Young stress and an effective contact line friction. Furthermore, a non-linear generalization of the model is proposed, which aims at reproducing the Molecular Kinetic Theory of Blake and Haynes for quasi-stationary states.

physics.flu-dyn↗

arXiv2024

On the problem of optimal fluid transport in capillaries

In this note, we revisit the problem of the pressure-driven transport of a meniscus through a narrow cylindrical capillary or pore. This generic process finds many applications in science and technology. As it is known that Direct Numerical Simulations of moving contact line problems are highly demanding in terms of computational costs, simplified models in the form of ordinary differential equations offer an interesting alternative to perform a mathematical optimization of the flow. Blake and De Coninck studied the pressure-driven transport of a meniscus and identified two major competing mechanisms. While a hydrophilic surface is favorable to enhance the spontaneous imbibition into the pore, the friction is known to be significantly reduced on a hydrophobic surface. Blake and De Coninck showed that, depending on the applied pressure difference, there exists an optimal wettability that minimizes the time required to move the meniscus over a certain distance. We revisit this problem and derive analytical solutions in the limiting cases of negligible inertia and negligible contact line friction.

physics.flu-dyn↗

arXiv2024

Scale-bridging within a complex model hierarchy for investigation of a metal-fueled circular energy economy by use of Bayesian model calibration with model error quantification

Metal energy carriers recently gained growing interest in research as a promising storage and transport material for renewable electricity. Within the development of a metal-fueled circular energy economy, research involves a model hierarchy spanning from micro to macro scales, making the transfer of information among different levels of complexity a crucial task for the implementation of the new technology. Chemical reactor networks (CRNs) are models of reduced complexity and a promising approach to accomplish the scale-bridging task. This holds if valid information from CRNs can be obtained on a much denser set of operating conditions than available from experiments and elaborated simulation methods like Computational Fluid Dynamics (CFD). An approach for CRN calibration from recent literature, including model error quantification, is further developed to construct a CRN model of a laboratory reactor for flash ironmaking, using data from the literature. By introducing a meta model of a CRN parameter, a simple CRN model on an extended set of operating conditions has successfully been calibrated. This way, the employed coupled calibration and uncertainty quantification framework has proven promising for the task of scale-bridging in the model hierarchy under investigation.

physics.comp-ph↗

arXiv2024

twoPhaseInterTrackFoam: an OpenFOAM module for Arbitrary Lagrangian/Eulerian Interface Tracking with Surfactants and Subgrid-Scale Modeling

We provide an implementation of the unstructured Finite-Volume Arbitrary Lagrangian / Eulerian (ALE) Interface-Tracking method for simulating incompressible, immiscible two-phase flows as an OpenFOAM module. In addition to interface-tracking capabilities that include tracking of two fluid phases, an implementation of a Subgrid-Scale (SGS) modeling framework for increased accuracy when simulating sharp boundary layers is enclosed. The SGS modeling framework simplifies embedding subgrid-scale profiles into the unstructured Finite Volume discretization. Our design of the SGS model library significantly simplifies adding new SGS models and applying SGS modeling to Partial Differential Equations (PDEs) in OpenFOAM.

physics.comp-ph↗

arXiv2024

Experimental study of dynamic wetting behavior through curved microchannels with automated image analysis

Preventing fluid penetration poses a challenging reliability concern in the context of power electronics, which is usually caused by unforeseen microfractures along the sealing joints. A better and more reliable product design heavily depends on the understanding of the dynamic wetting processes happening inside these complex microfractures, i.e. microchannels. A novel automated image processing procedure is proposed in this work for analyzing the moving interface and the dynamic contact angle in microchannels. In particular, the developed method is advantageous for experiments involving non-transparent samples, where extracting the fluid interface geometry poses a significant challenge. The developed method is validated with theoretical values and manual measurements and exhibits high accuracy. The implementation is made publicly available. The developed method is validated and applied to experimental investigations of forced wetting with two working fluids (water and 50 wt% glycerin/water mixture) in four distinct microchannels characterized by different dimensions and curvature. The comparison between the experimental results and molecular kinetic theory (MKT) reveals that the dynamic wetting behavior can be described well by MKT, even in highly curved microchannels. The dynamic wetting behavior shows a strong dependency on the channel geometry and curvature.

physics.flu-dyn↗

arXiv2023

Bridging the scales in capillary rise dynamics with complexity-reduced models

Dynamic wetting processes inherently manifest as multiscale phenomena. While the capillary length is typically millimeters, solid-liquid interactions occur at the nanometer scale. These short-range interactions significantly affect macroscopic behaviors like droplet spreading and menisci dynamics. The Navier slip length, determined by liquid viscosity and solid-liquid friction, plays a crucial role in three-phase contact line dynamics. It varies from nanometers (hydrophilic) to microns (hydrophobic). However, resolving it in computational fluid dynamics (CFD) simulations can be computationally expensive. In this study, we propose simplified ordinary differential equation (ODE) models, leveraging local dissipation rates from Stokes flow solutions near the moving contact line, to bridge the nanoscale physics and macroscopic dynamics. Our ODE model accurately predicts the impact of the slip parameter in fully resolved CFD simulations, focusing on capillary rise dynamics.

physics.flu-dyn↗

arXiv2023

Imaging and simulation-based analysis of evaporation flows over wetting edges

We monitor the evaporation of a volatile liquid (ethanol) from an inkjet-printed liquid film, consisting of a mixture of ethanol and ethylene glycol. Interferometric video imaging technology is used for recording 2D vapor concentration profiles over the evaporating film. The vapor flow is reconstructed using numerical simulations. In this way, we reconstruct the complete flow velocity profile, and distinguish diffusive and convective gas transport flows, with quantitative tracking of the transport balances. The convective flows are driven by the buoyancy of the solvent vapor in the ambient air. In particular, we reconstruct the evaporation process from the interface of the two-component liquid. We monitor the evaporation flows, implement Raoult's and Henry's laws of vapor pressure reduction, as well as evaporation resistivity. We observe the edge-enhancement of evaporation flows at the wetting rims of the liquid film, and decompose the vapor flows in the diffusive and the convective contribution. We demonstrate how Langmuir's evaporation resistivity can be identified using vapor pressure profiles in the gas phase data and mass transfer balances.

physics.flu-dyn↗

arXiv2023

Analytical and numerical validation of a plate-plate tribometer for measuring wall slip

We model the Darmstadt Slip Length Tribometer (DSLT), specially designed to measure viscosity and slip length simultaneously for lubrication gaps in the range of approximately 10 micrometres at relevant temperatures and surface roughness. We investigate the inlet effect of the flow on the results by varying the inner radius of the fluid inlet pipe. The outcomes of numerical simulations suggest that variations in the diameter of this inner radius have minimal impact on the results. Specifically, any alterations in the velocity profile near the inlet, brought about by changes in the diameter, quickly revert to the profile predicted by the analytical model. The main conclusion drawn from this study is the validation of the Navier-Slip boundary condition as an effective model for technical surface roughness in CFD simulations and the negligible influence of the inlet effect on the fluid dynamics between the tribometer's plates.

physics.flu-dyn↗

arXiv2023

Mathematical analysis of modified level-set equations

The linear transport equation allows to advect level-set functions to represent moving sharp interfaces in multiphase flows as zero level-sets. A recent development in computational fluid dynamics is to modify the linear transport equation by introducing a nonlinear term to preserve certain geometrical features of the level-set function, where the zero level-set must stay invariant under the modification. The present work establishes mathematical justification for a specific class of modified level-set equations on a bounded domain, generated by a given smooth velocity field in the framework of the initial/boundary value problem of Hamilton-Jacobi equations. The first main result is the existence of smooth solutions defined in a time-global tubular neighborhood of the zero level-set, where an infinite iteration of the method of characteristics within a fixed small time interval is demonstrated; the smooth solution is shown to possess the desired geometrical feature. The second main result is the existence of time-global viscosity solutions defined in the whole domain, where standard Perron's method and the comparison principle are exploited. In the first and second main results, the zero level-set is shown to be identical with the original one. The third main result is that the viscosity solution coincides with the local-in-space smooth solution in a time-global tubular neighborhood of the zero level-set, where a new aspect of localized doubling the number of variables is utilized.

math.AP↗

arXiv2023

Spreading of a viscoelastic drop on a solid substrate

We study the spreading of viscous and viscoelastic drops on solid substrates with different wettability. In the early stages of spreading, we find that the viscoelastic drop spreads with faster and a different power law than the Newtonian drop (i.e. aqueous glycerine solution) for the same zero shear rate viscosity. We argue that the effect of viscoelasticity is only observable for experimental time scales in the order of the internal relaxation time of the polymer solution or longer times. Near the contact line, the effective viscosity is lower for the viscoelastic drop than for the Newtonian drop. Together with its shear rate dependency, this difference in effective viscosity can explain the different spreading dynamics. We support our experimental findings with a simple perturbation model that qualitatively agrees with our findings.

cond-mat.soft↗

arXiv2023

Studying Macro- and Mesoscopic Wetting Dynamics of a Spreading Oil Droplet Using Multiple Wavelength Interferometry

In this study we present an interferometric technique based on multiple wavelengths to capture the transient free surface contour of nanoliter drops spreading on a wettable surface, in particular close to the three-phase contact line. Various data analysis procedures are evaluated in terms of error and noise sensitivity. The technique allows an unambiguous determination of the local liquid film thickness for optical path differences up to $\Delta s \approx 3.19\,\mathrm{\mu m}$ without the need of a known reference height. Film thicknesses as low as $0.1\,\mathrm{\mu m}$ can be measured with the present optical configuration. The entire three-dimensional droplet shape is investigated for different capillary numbers, allowing also reliable measurements of the time-resolved contact angle.

physics.flu-dyn↗

arXiv2023

Enhanced Modeling of Back-Mixing in Chemical Reactor Networks

Chemical reactor networks (CRNs) enable simulations of combustion reactors with detailed chemical kinetics and strongly simplified flow structure. In this paper, the implementation of a reactor component with less idealized flow structure, namely axial dispersion, to the CRN software NetSMOKE is presented. It is shown exemplarily that different flow models can lead to strongly different results in species prediction. However, computational efficiency remains an issue for this reactor class, which is still to be solved.

physics.flu-dyn↗

arXiv2023

An analytical study of capillary rise dynamics: Critical conditions and hidden oscillations

The rise of a liquid column inside a thin capillary against the action of gravity is a prototypical example of a dynamic wetting process and plays an important role for applications but also for fundamental research in the area of multiphase fluid dynamics. Since the pioneering work by Lucas and Washburn, many research articles have been published which aim at a simplified description of the capillary rise dynamics using complexity-reduced models formulated as ordinary differential equations. Despite the fact that these models are based on profound simplifications, they may still be able to describe the essential physical mechanisms and their interplay. In this study, we focus on the phenomenon of oscillations of the liquid column. The latter has been observed experimentally for liquids with sufficiently small viscosity leading to comparably small viscous dissipation. Back in 1999, Quere et al. formulated a condition for the appearance of rise height oscillations for an ODE model introduced by Bosanquet in 1923. This model has later been extended to include further dissipative mechanisms. In this work, we extend the mathematical analysis to a larger class of models including additional channels of dissipation. We show that Quere's critical condition is generalized to $\Omega + \beta < 2$, where $\Omega$ was introduced earlier and $\beta$ is an additional non-dimensional parameter describing, e.g., contact line friction. A quantitative prediction of the oscillation dynamics is achieved from a linearization of the governing equations. We apply the theory to experimental data by Quere et al. and, in particular, reveal the oscillatory behavior of dynamics for the nearly critically damped case of ethanol.

physics.flu-dyn↗

arXiv2023

Numerical wetting benchmarks -- advancing the plicRDF-isoAdvector unstructured Volume-of-Fluid (VOF) method

The numerical simulation of wetting and dewetting of geometrically complex surfaces benefits from unstructured numerical methods because they discretize the domain with second-order accuracy. A recently developed unstructured geometric Volume-of-Fluid (VOF) method, the plicRDF-isoAdvector method, is chosen to investigate wetting processes because of its volume conservation property and high computational efficiency. The present work verifies and validates the plicRDF-isoAdvector method for wetting problems. We present four verification studies. The first study investigates the accuracy of the interface advection near walls. The method is further investigated for the spreading of droplets on a flat and a spherical surface, respectively, for which excellent agreement with the reference solutions is obtained. Furthermore, a 2D capillary rise is considered, and a benchmark comparison based on results from previous work is performed. The benchmark suite, input data, and Jupyter Notebooks used in this study are publicly available to facilitate further research and comparison with other numerical codes.

physics.flu-dyn↗

arXiv2022

A locally signed-distance preserving level set method (SDPLS) for moving interfaces

It is well-known that the standard level set advection equation does not preserve the signed distance property, which is a desirable property for the level set function representing a moving interface. Therefore, reinitialization or redistancing methods are frequently applied to restore the signed distance property while keeping the zero-contour fixed. As an alternative approach to these methods, we introduce a modified level set advection equation that intrinsically preserves the norm of the gradient at the interface, i.e. the local signed distance property. Mathematically, this is achieved by introducing a carefully chosen source term being proportional to the local rate of interfacial area generation. The introduction of the source term turns the problem into a non-linear one. However, we show that by discretizing the source term explicitly in time, it is sufficient to solve a linear equation in each time step. Notably, without further adjustment, the method works in the case of a moving contact line. This is a major advantage since redistancing is known to be an issue when contact lines are involved. We provide a first implementation of the method in a simple first-order upwind scheme in both two and three spatial dimensions.

math.NA↗

arXiv2020

A geometry-based model for spreading drops applied to drops on a silicon wafer and a swellable polymer brush film

We investigate the dynamics of spreading in a regime where the shape of the drop is close to a spherical cap. The latter simplification is applicable in the late (viscous) stage of spreading for highly viscous drops with a diameter below the capillary length. Moreover, it applies to the spreading of a drop on a swellable polymer brush, where the complex interaction with the substrate leads to a very slow spreading dynamics. The spherical cap geometry allows to derive a closed ordinary differential equation (ODE) for the spreading if the capillary number is a function of the contact angle as it is the case for empirical contact angle models. The latter approach has been introduced by de Gennes (Reviews of Modern Physics, 1985) for small contact angles. In the present work, we generalize the method to arbitrary contact angles. The method is applied to experimental data of spreading water-glycerol drops on a silicon wafer and spreading water drops on a PNIPAm coated silicon wafer. It is found that the ODE-model is able to describe the spreading kinetics in the case of partial wetting. Moreover, the model can predict the spreading dynamics of spherical cap-shaped droplets if the relationship between the contact angle and the capillary number is universal.

physics.flu-dyn↗

arXiv2019

Boundary conditions for dynamic wetting -- A mathematical analysis

The moving contact line paradox discussed in the famous paper by Huh and Scriven has lead to an extensive scientific discussion about singularities in continuum mechanical models of dynamic wetting in the framework of the two-phase Navier-Stokes equations. Since the no-slip condition introduces a non-integrable and therefore unphysical singularity into the model, various models to relax the singularity have been proposed. Many of the relaxation mechanisms still retain a weak (integrable) singularity, while other approaches look for completely regular solutions with finite curvature and pressure at the moving contact line. In particular, the model introduced recently in (Lukyanov, Pryer, Langmuir 2017) aims for regular solutions through modified boundary conditions. The present work applies the mathematical tool of compatibility analysis to continuum models of dynamic wetting. The basic idea is that the boundary conditions have to be compatible at the contact line in order to allow for regular solutions. Remarkably, the method allows to compute explicit expressions for the pressure and the curvature locally at the moving contact line for regular solutions to the model of Lukyanov and Pryer. It is found that solutions may still be singular for the latter model.

physics.flu-dyn↗