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Matilde Mingozzi

Publications and source records attributed to Matilde Mingozzi.

At least 19 recordsLinked to original sources

CLASSY. XV. Kinematics and Spatial Distributions of Outflows in Local Highly Star-Forming Galaxies

Star-forming galaxies drive massive outflows that play an important role in galaxy evolution by regulating feedback and influencing the dynamics of surrounding media. Measuring galactic outflow rates is essential for quantifying feedback efficiency and the amount of mass, momentum, and energy deposited into the circumgalactic medium. In this paper, we examine 17 galactic outflows from the CLASSY survey with radiative transfer modeling of UV absorption lines presented in M. Huberty et al. (2024), to study their spatial distributions and kinematic properties. We study the SiII, SiIII, and SiIV ionization states that trace the cool and warm phases of the outflows and find that SiII traced winds generally behave differently than the warmer SiIII and SiIV traced winds. We derive the mass, momentum, and energy loading factors, which we find scale inversely proportional to stellar mass. We find that our measurements of the mass and momentum loading factors are in agreement with the hydrodynamic FIRE-2 simulations. We model the velocity profiles of the winds, with profiles reaching a maximum velocity of 620 km/s on average, in agreement with hydrodynamic simulations from CGOLS. We also investigate the relationship between outflow properties and the age of the stellar population from SED fitting. We find that outflows associated with young star forming regions are more likely to have a column density dominated by cooler gas and have mass outflow rates which decrease with radius.

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CCD Rotation Rates From Regular Dispersion Solution Monitoring

It has been previously studied that the STIS CCD exhibits a slow rotation, evident from changes in spectral traces and flat-field evolution. In this Instrument Science Report, we present an independent spectroscopic analysis of the CCD rotation angle and a comparison with previous studies. We describe the methodology used to derive rotation angles and rates across different gratings and central wavelengths, and report the corresponding median rotation rates over time. The results are broadly consistent within uncertainties with earlier measurements, indicating the CCD rotation has the same impact on all the CCD gratings. We also discuss key assumptions limiting our analysis. These findings contribute to the ongoing monitoring of STIS CCD rotation and its implications for calibration accuracy.

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Wavelength Calibration Accuracy Across the STIS CCD: Pipeline Update and User Guidance

We investigate the wavelength calibration accuracy of STIS CCD spectra as a function of detector position, focusing on the E1/E2 pseudo-apertures. Comparison between measured lamp line centroids and laboratory wavelengths shows that, while the standard calstis solution is stable at the detector center, significant offsets are present toward the CCD edges and increase with time. We used a test version of calstis in which the wavelength calibration step employs a row-selected cross-correlation, leading to improved wavelength calibration accuracy for edge extractions. Motivated by these results, we implemented an update to calstis4 that applies a row-selected wavecal procedure to observations taken with the E1/E2 pseudo-apertures, while preserving the standard procedure for nominal extractions. The updated pipeline was then used to reprocess the entire STIS archive in MAST. Validation tests confirm improved agreement between nominal and E1/E2 spectra without significant side effects for more than 97% of the datasets in the MAST archive. The main exceptions are the majority of G230MB and a few G230LB and G430M datasets, where the lower signal-to-noise at the CCD edge makes the lamp lines harder to detect and cosmic-ray residuals can dominate the cross-correlation, leading to incorrect wavelength shifts. A Jupyter Notebook is also provided to enable similar corrections in case the cross-correlation fails, for extractions at positions other than E1/E2, or for multiple extractions along the slit. Finally, we discuss the potential impact of the wavelength calibration accuracy on science results.

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Astronomical Advantages of a Boost Mission to Facilitate HST Science into the 2030s: Imaging the Circumgalactic Medium of Galaxies

We present the case for imaging ultraviolet line emission from highly ionized metals and HI Lya in the circumgalactic medium of galaxies, should the Hubble Space Telescope receive an orbital boost. Hubble can uniquely probe emission lines with ionization potentials between 13 and 200 electron-volts (Lya, CIV, OVI, NeVIII, etc). Spatial mapping of the diffuse material traced by these transitions is critical to constraining the physics of feedback and the energetic exchange between galaxies and their circumgalactic environments, as well as basic morphologies of the dominant mass component. Deep high-resolution mapping of these features will not be possible with any other observatory, existing or planned, until HWO is launched, which leaves HST as a critical observatory to test key science drivers for HWO. If HST receives an orbital boost, it can (a) provide the first statistical constraints on the spatial distribution of warm-hot CGM and (b) provide important avenues for science case development, as well as target/pointing selection, for HWO's upcoming spectroscopic facilities.

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High-S/N Quasar Observations with HST/COS: Deep Fields for Spectroscopy

Hubble is still in prime observing condition for making transformative discoveries in UV astronomy. In this white paper we describe the science case for a deep (S/N>30) UV spectroscopic survey with HST/COS targeting approximately 20 QSOs at 0.5<z<1.5 at good resolution (20 km/s). This survey would capitalize on our current UV capability, produce a legacy dataset enabling community science in many areas of galactic and extragalactic research, and pioneer a path for future UV science with the Habitable Worlds Observatory. Such high-S/N spectra are largely missing from the MAST archives, and would be analogous to the deep Hubble imaging fields (HDF, UDF, Frontier Fields) that have been enormously successful and far-reaching in their science impact. This legacy dataset would enable frontier science programs in several areas, including (1) studies of the CGM and IGM at unparalleled sensitivity, covering a wide range of UV metal lines and reaching very low H I column densities of log N=12.6 and low metallicities near [Z/H]=-2, enabling precision studies of the chemical abundances, ionization, temperature, and baryon and metal budgets of the CGM and IGM; (2) diffuse gas in the Milky Way and Local Group, including high-velocity clouds and gas streams from satellite mergers; (3) AGN outflows, which would be probed in the rest-frame extreme ultraviolet (EUV), covering continuum-generation mechanisms and diagnostics of gas in accretion-disk outflows.

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The First Empirical Calibration of the MIR Abundance Diagnostic Ne$_{23}$ with JWST

Large surveys of galaxies in the local and high-redshift Universe have, traditionally, relied on the intensity of rest-optical emission lines from metal ions in the Interstellar Medium (ISM) to indirectly estimate the O/H abundance in the gas. However, these optical strong line diagnostics are also sensitive to the electron gas temperature ($T_e$), resulting in large systematic uncertainties that inherently limit their utility as metallicity tracers, especially in dust-obscured and metal-rich environments. To this end, we provide the first empirical calibration of Ne$_{23}$, a novel abundance diagnostic using the mid-infrared (MIR) $T_e$-insensitive [Ne II]$\lambda$12.81$\mu$m and [Ne III]$\lambda$15.56$\mu$m fine-structure lines. We present new JWST/MIRI MRS observations of ten H II regions with optical measurements of $T_e$ and O/H from the CHAOS project, and we analyze MIRI observations of eight low-metallicity galaxies with similarly high-fidelity direct O/H. We measure Ne$_{23}$ from 1D MIR spectra extracted from apertures matched to the ground-based spectroscopy used to obtain O/H, a method that is unfeasible from MIR spectra acquired on prior space-based observatories. From these nebulae, Ne$_{23}$ is strongly correlated with O/H over 1.5 dex in 12+log(O/H). We calibrate the O/H-Ne$_{23}$ relation from the empirical data, finding a scatter of just 0.06 dex in O/H at fixed Ne$_{23}$. The O/H-Ne$_{23}$ relation presented here provides a means to reliably estimate 12+log(O/H) from JWST/MIRI MRS observations of ionized nebulae out to z$\approx$0.8, enabling new chemical abundance surveys of highly-attenuated regions and in the metal-rich ISM.

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CLASSY XIV: The Nitrogen Exception -- Multi-Phase Enrichment and Feedback in High-$z$ Analogs

We present a first-of-its-kind analysis of the metal content across two interstellar medium (ISM) phases in a sample of 31 local star-forming galaxies from the COS Legacy Archive Spectroscopic SurveY (CLASSY), selected as analogues of high-$z$ systems. Using co-spatial UV absorption and optical emission-line spectroscopy, we compare abundances of N, O, S, and Fe in the low-ionization (neutral) and high-ionization (ionized) gas, providing a multi-phase view of enrichment shortly after the current starburst and over longer timescales when ejecta from previous episodes have cooled and mixed. We find that O and S, produced predominantly in short-lived massive stars, are well mixed between the two phases, with scatter reflecting local inhomogeneities. Fe, predominantly produced by Type Ia supernovae on $\sim$1 Gyr timescales, is higher in the neutral gas, reflecting either delayed mixing of older Fe-enriched material or preferential depletion of Fe from the ionized phase through dust formation in core-collapse supernova ejecta. N exhibits the largest phase offset, with N/H$_{ion}$ systematically $\sim$0.7 dex higher than N/H$_{neu}$, and the magnitude of this offset correlates with stellar mass, metallicity, star-formation rate, and most strongly with the ISM outflow velocity. N/O ratios in the ionized phase rise rapidly within 3-6 Myr relative to the neutral gas, consistent with N enrichment dominated by Wolf-Rayet stars rather than intermediate-mass AGB stars on longer timescales. These results demonstrate that localized stellar feedback, outflows, and phase-dependent mixing collectively regulate the chemical evolution of star-forming galaxies, providing key insight into the extreme N/O abundances recently observed in galaxies at cosmic dawn.

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CLASSY XIII. Cutting through the Clouds - Comparing Indirect Tracers of Ionizing Photon Escape

The Epoch of Reionization (EoR) provides critical insights into the role of early galaxies in shaping the ionization state of the universe. However, because of the opacity of the intergalactic medium, it is often not possible to make direct measurements of the ionizing photon escape fraction ($f_{\mathrm{esc}}^{\: \mathrm{LyC}}$) of high-redshift ($z \gtrsim 4$) galaxies. To explore the agreement and systematics of common indirect approaches, we applied six empirically calibrated diagnostics to predict $f_{\mathrm{esc}}^{\: \mathrm{LyC}}$ for the 45 nearby star-forming galaxies from the COS Legacy Spectroscopic SurveY (CLASSY). These methods- based on ultraviolet (UV) absorption lines, the UV continuum slope, Ly$\alpha$ kinematics, a multivariate model, radiation-hydrodynamic simulations, and nebular emission line ratios- enable us to explore systematic differences between predictions and assess how galactic properties influence inferred LyC escape. Despite significant variations in method predictions, there is broad consistency in the resulting weak and strong LyC leaker classifications, with approximately half exhibiting predicted escape fractions $>$1%. We find evidence for two different pathways of LyC escape in nearby star-forming galaxies: (1) an early escape model driven by very young stellar populations, and (2) a delayed escape model that is consistent with supernova-driven outflows and time-dependent ISM clearing. The early escape model is favored among galaxies with a single, intense burst of recent star formation. In contrast, the delayed escape model is common among galaxies with more extended starburst histories. To interpret ionizing photon escape during the EoR, it will be necessary to recognize and understand this diversity in LyC escape mechanisms.

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JWST/MIRI-MRS view of the metal-poor galaxy CGCG 007-025: the spatial location of PAHs and very highly ionized gas

Polycyclic Aromatic Hydrocarbons (PAHs) are key diagnostics of the physical conditions in the interstellar medium and are widely used to trace star formation in the mid-infrared (mid-IR). The relative strengths of mid-IR PAH emission features (e.g., 6.2, 7.7, 11.3 um) are sensitive to both the size and ionization state of the molecules and can be strongly influenced by the local radiation field. However, at low metallicities ( Z < 0.2 Zsun), detecting PAHs remains notoriously difficult, likely reflecting a combination of suppressed formation and enhanced destruction mechanisms. We present new JWST/MIRI MRS observations of the metal-poor (Z = 0.1 Zsun) dwarf galaxy CGCG 007-025. We confirm the tentative PAH detection previously reported from Spitzer data and, for the first time, identify a compact (approx. 50 pc) PAH-emitting region nearly co-spatial with the newly detected [NeV](I.P. = 97 eV) emission and the galaxy's most metal-poor, strongly star-forming region. The 11.3 and 12.7 um PAH features are detected, while no emission is found from the other typically brighter features, suggesting a PAH population dominated by large, neutral molecules resilient to hard ionizing fields. When compared with models, mid-IR line ratios involving [NeIII], [OIV], and [NeV] can only be reproduced by a combination of star formation and AGN ionization, with the latter contributing 4--8%. The [OIV] and [NeV] luminosities exceed what massive stars or shocks can produce, highlighting a puzzling scenario in line with recent JWST observations of similar galaxies. This work provides a crucial reference for studying the physical conditions of the dust and star formation in low-metallicity starburst regions, environments typical of the early universe.

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The Interstellar Medium in I Zw 18 seen with JWST/MIRI: III. Spatially Resolved Three Ionization State Oxygen Abundance

We present observations of the nearby extremely metal-poor galaxy I Zw 18 using the Keck Cosmic Web Imager (KCWI) and the JWST Mid-InfraRed Instrument (MIRI) Integral Field Spectrographs (IFS). From optical and mid-IR oxygen emission lines, we measured direct-method abundances for three ionic states of oxygen, including O$^{3+}$/H$^+$. In contrast to previous studies of I Zw 18, the high spatial resolution afforded by KCWI and MIRI/MRS revealed chemical inhomogeneities on 60 pc scales in the form of metal-poor pockets and metal-enriched gas. These are located outside I Zw 18's star-forming complexes having possibly been dispersed beyond these regions via stellar feedback effects. We found that metallicities derived using a single low-ionization density tracer, and T$_{\rm e}$([O II]) derived from a temperature relationship commonly used in high-$z$ galaxy studies, exhibited the largest scatter and underestimated the metallicity compared to those derived using multi-ion densities and estimated T$_{\rm e}$([N II]). Finally, we compared O$^{3+}$/H$^+$ abundances from a theoretical ionization correction factor (ICF) against observed values and found that the oxygen ICF underestimates the O$^{3+}$/H$^+$ abundance by a factor of 2, indicating that either additional ionizing sources are needed or standard stellar population models are unable to produce the requisite ionizing flux.

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CLASSY XII: Nitrogen Enrichment Shaped by Gas Density and Feedback

We investigate the chemical evolution of N/O using a sample of 45 local star-forming galaxies (SFGs) from the CLASSY survey. This sample spans a wide range of galaxy properties, with robust determinations of nitrogen and oxygen abundances via the direct-$T_{\rm e}$ method. We explore how N/O relates to density structure, stellar mass, star formation rate (SFR), stellar age, compactness, and gas kinematics. In addition, we compare our results with those of galaxies at $z =2-10$ where N/O ratios were derived from optical or UV nitrogen lines, aiming to identify chemical enrichment pathways across cosmic time. Our analysis shows that the N/O-O/H relation in CLASSY galaxies aligns with the trends seen in local galaxies and extragalactic HII regions, and that galaxies at $z = 2-6$ exhibit similar N/O values, indicating no significant redshift evolution in N/O for a fixed metallicity. We identify a significant correlation between electron density $n_{\rm e}$([S II]) and N/O, suggesting that density structure contributes to the scatter in the N/O-O/H relation. The CLASSY galaxies with high SFRs or compact star formation show elevated N/O, though no strong correlation with stellar mass is found. We also find that high-velocity outflows (v$_{out}$ > 350 km/s) and low mass-loading factors are linked to elevated N/O, indicating that feedback plays a significant role. These results highlight the importance of density, star formation, and feedback from young stellar populations in shaping N/O enrichment and provide key insights for interpreting high-$z$ galaxies observed with JWST.

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Identifying the contributors to cosmic reionization with the Habitable World Observatory: LyC escape calibration in faint galaxies

Investigating how small-scale physical processes shape large-scale astrophysical phenomena is one of the key science themes of the Astro2020 decadal Survey. An example of this interplay is Cosmic Reionization, where ionizing photons from galaxies escaped into the intergalactic medium (IGM), driving its transition from neutral to ionized at $z>6$. Star-forming galaxies are thought to be the dominant sources of reionization. However, an open question remains as to whether bright or faint star-forming galaxies are the primary reionization contributors. This depends on the escape fraction $f_{~esc}^{LyC}$ -- the fraction of ionizing photons that successfully escape the galaxy's interstellar and circumgalactic medium to reach the IGM. Performing direct measurements of $f_{~esc}^{LyC}$ during the reionization epoch is not feasible, due to the near-zero transmission of the IGM at $z\gtrsim4$. However, by calibrating $f_{~esc}^{LyC}$ against indirect indicators (i.e. galaxy properties that correlate with $f_{~esc}^{LyC}$) at lower $z$, we can estimate its value in galaxies during reionization. Currently, $f_{~esc}^{LyC}$ calibrations are mostly limited to $\sim 90$ sources brighter $M_{UV} \sim -18$ at $z\sim0.3$. Yet, recent models suggest that fainter galaxies ($-19<M_{UV}<-13$) may be the major contributors to reionization. Our science goal is to extend $f_{~esc}^{LyC}$ calibrations to such faint magnitudes. With the Habitable Worlds Observatory, we aim to achieve a $\sim$ 20-fold increase in statistical power. Additionally, we plan to reach magnitudes as faint as 1/100 $L^*$ at $z\sim0.1$. Suitable targets will be selected from the upcoming Ultraviolet Explorer (UVEX) survey. Through this science case, we will be able to place robust constraints on the role of faint galaxies in the reionization of the Universe and identify its primary contributors.

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JWST/MIRI detection of [Ne V] and [Ne VI] in M83: Evidence for the long sought-after AGN?

We report the first detections of [Ne V] 14.3 {\mu}m and [Ne VI] 7.7 {\mu}m at high confidence (S/N>=6) in the nuclear region of the nearby spiral galaxy M83. Emission line maps of these high ionization lines show several compact structures. Specifically, the [Ne VI] emission is located at 140 pc from the optical nucleus and appears as a point source of size ~<18 pc (FWHM =<0.8"). We investigate the possible source of this extreme emission through comparison with photoionization models and ancillary data. We find that photoionization models of fast radiative shocks are able to reproduce the observed high excitation emission line fluxes only for the lowest preshock density available in the library, n =0.01 cm^-3. Additionally, tailored active galactic nuclei (AGN) photoionization models assuming a two-zone structure are compatible with the observed high ionization fluxes. Our simple AGN model shows that the emission at the location of the [Ne VI] source can be the result of a cloud being ionized by the radiation cone of an AGN. We stress, however, that to definitively confirm an AGN as the main source of the observed emission, more complex modeling accounting for different geometries is required. Previously known as a purely starburst system, these new findings of the nuclear region of M83 will require a reassessment of its nature and of objects similar to it, particularly now that we have access to the unparalleled infrared sensitivity and spatial resolution of the James Webb Space Telescope.

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Exploring the mysterious high-ionization source powering [Ne V] in high-z analog SBS0335-052 E with JWST/MIRI

Nearby blue compact dwarf galaxies (BCDs) share similar properties with objects from the Epoch of Reionization revealed by JWST, in terms of low stellar mass, low metallicity and high specific star-formation rate. Thus, they represent ideal local laboratories for detailed multi-wavelength studies to understand their properties and the mechanisms shaping them. We report the first JWST MIRI/MRS observations of the BCD SBS 0335-052 E, analyzing MIR emission lines tracing different levels of ionization (e.g., [NeII], [SIV], [NeIII], [OIV], [NeV]) of the ionized gas. SBS 0335-052 E MIR emission is characterized by a bright point source, located in one of the youngest and most embedded stellar clusters ($t\sim3$ Myr, $A_V\sim15$), and underlying extended high-ionization emission (i.e., [OIV], [NeV]) from the surroundings of the older and less dusty stellar clusters ($t< 20 $ Myr, $A_V\sim8$). From the comparison with state-of-the-art models, we can exclude shocks, X-ray binaries, and old stellar populations as the main sources of the high ionization. Interestingly, a 4-16% contribution of a $\sim10^5$ M$_\odot$ intermediate massive black hole (IMBH) is needed to justify the strong [NeV]/[NeII] and would be consistent with optical/UV line ratios from previous studies. However, even IMBH models cannot explain the strongest [OIV]/[NeIII]. Also, star-forming models (regardless of including X-ray binaries) struggle to reproduce even the lower ionization line ratios (e.g., [SIV]/[NeII]) typically observed in BCDs. Overall, while current models suggest the need to account for an accreting IMBH in this high-$z$ analog, limitations still exist in predicting high-ionization emission lines (I.P. $>54$ eV) when modeling these low-metallicity environments, thus other sources of ionization cannot be fully ruled out.

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On the Average Ultraviolet Emission Line Spectra of High-Redshift Galaxies: Hot and Cold, Carbon-poor, Nitrogen-modest, and Oozing Ionizing Photons

We determine the spectroscopic properties of ~1000 ostensibly star-forming galaxies at redshifts (z=4-10) using prism spectroscopy from JWST/NIRSpec. With rest-wavelength coverage between Lya and [S II] in the optical, we stack spectra as a function of nebular conditions, and compare UV spectral properties with stellar age. This reveals UV lines of N III], N IV], C III], C IV, He II, and O III] in the average high-z galaxy. All UV lines are more intense in younger starbursts. We measure electron temperatures from the collisionally excited [O III] line ratios, finding Te=18000-22000 K for the O++ regions. We also detect a significant nebular Balmer Jump from which we estimate only Te=8000-13000 K. Accounting for typical temperature offsets between zones bearing doubly and singly ionized oxygen, these two temperatures remain discrepant by around 40%. We use the [O III] temperatures to estimate abundances of carbon, nitrogen, and oxygen. We find that log(C/O) is consistently ~-1, with no evolution of C/O with metallicity or stellar age. The average spectra are mildly enhanced in Nitrogen, with higher N/O than low-z starbursts, but are less enhanced than samples of high-z galaxies with visible UV N III] and N IV]. Whatever processes produce the N-enhancement in the individual galaxies must also be ongoing, at lower levels, in the median galaxy in the early Universe. The strongest starbursts are a source of significant ionizing emission: ionizing photon production efficiencies reach 10^25.7 Hz/erg, and show multiple signatures of high Lyman continuum escape, including Mg II escape fractions nearing 100%, significant deficits in [S II] emission, high degrees of ionization, and blue UV colors.

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A JWST/MIRI View of the ISM in M83: I. Resolved Molecular Hydrogen Properties, Star Formation, and Feedback

We present a spatially-resolved (~3 pc pix$^{-1}$) analysis of the distribution, kinematics, and excitation of warm H2 gas in the nuclear starburst region of M83. Our JWST/MIRI IFU spectroscopy reveals a clumpy reservoir of warm H2 (> 200 K) with a mass of ~2.3 x 10$^{5}$ Msun in the area covered by all four MRS channels. We additionally use the [Ne II] 12.8 ${\mu}$m and [Ne III] 15.5 ${\mu}$m lines as tracers of the star formation rate, ionizing radiation hardness, and kinematics of the ionized ISM, finding tantalizing connections to the H2 properties and to the ages of the underlying stellar populations. Finally, qualitative comparisons to the trove of public, high-spatial-resolution multiwavelength data available on M83 shows that our MRS spectroscopy potentially traces all stages of the process of creating massive star clusters, from the embedded proto-cluster phase through the dispersion of ISM from stellar feedback.

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Shining a Light on the Connections between Galactic Outflows Seen in Absorption and Emission Lines

Galactic outflows provide important feedback effects to regulate the evolution of host galaxies. Two primary diagnostics of outflows are broad and/or blueshifted emission and absorption lines. Even though well-established methods exist to analyze these outflow signatures, connections between them are rarely studied and largely unknown. In this paper, we conduct such a study in a sample of 33 low-redshift starburst galaxies. Their UV absorption lines are detected by Hubble Space Telescope, and optical emission lines are observed by Keck or Very Large Telescope. We find outflow properties derived from emission and absorption lines are tightly correlated. These include outflow maximum velocity, line width, and radial extent. On average, in the same galaxy, the maximum velocity and line width of outflows measured from emission lines reach only 60 -- 70% of those from the absorption lines. We also find outflow rates derived from emission lines are consistently lower than those from absorption lines by 0.2 -- 0.5 dex. These findings can be explained by a radial decline in density and a corresponding increase in outflow velocity, combined with the fact that emission line luminosity scales with the square of the density while absorption line depth scales linearly. We test both spherical and bi-conical outflow models, and find the same radial outflow velocity and density distributions can explain the observed correlations. These results provide novel calibration between galactic outflow properties measured from the two diagnostics and underscore the need for high-fidelity UV and optical spectra to accurately assess galactic feedback effects in high-z galaxies.

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Mapping Multi-Phase Metals in Star-forming Galaxies: a spatially resolved UV + Optical Study of NGC 5253

We present a pioneering spatially-resolved, multi-phase gas abundance study on the blue compact dwarf galaxy NGC~5253, targeting 10 star-forming (SF) clusters inside six FUV HST/COS pointings with co-spatial optical VLT/MUSE observations throughout the galaxy. The SF regions span a wide range of ages (1--15 Myr) and are distributed at different radii (50 -- 230 pc). We performed robust absorption-line profile fitting on the COS spectra, covering 1065--1430 \AA\ in the FUV, allowing an accurate computation of neutral-gas abundances for 13 different ions sampling 8 elements. These values were then compared with the ionized-gas abundances, measured using the direct method on MUSE integrated spectra inside analog COS apertures. Our multi-phase, spatially resolved comparisons find abundances which are lower in the neutral gas than the ionized gas by 0.22 dex, 0.80 dex and 0.58 dex for log(O/H), log(N/H) and log(N/O), respectively. We modeled the chemical abundance distributions and evaluated correlations as a function of radius and age. It was found that while N, O and N/O abundances decrease as a function of age in the ionized gas, they increase with age in the neutral gas. No strong correlations for N, O or N/O were observed as a function of radius. The N/O and N/H offsets between the phases were found to decrease with age, providing evidence that chemical enrichment happens differentially, first in the ionized-gas phase around 2--5 Myrs (due to N-rich Wolf-Rayet stars) and then mixing out into the cold neutral gas on longer timescales of 10--15 Myr.

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