arXiv subjects

Matteo Cucchi

Publications and source records attributed to Matteo Cucchi.

4 recordsLinked to original sources

arXiv2024

Bistable Organic Electrochemical Transistors: Enthalpy vs. Entropy

Organic electrochemical transistors (OECTs) underpin a range of emerging technologies, from bioelectronics to neuromorphic computing, owing to their unique coupling of electronic and ionic charge carriers. In this context, various OECT systems exhibit significant hysteresis in their transfer curve, which is frequently leveraged to achieve non-volatility. Meanwhile, a general understanding of its physical origin is missing. Here, we introduce a thermodynamic framework that readily explains the emergence of bistable OECT operation via the interplay of enthalpy and entropy. We validate this model through temperature-resolved characterizations, material manipulation, and thermal imaging. Further, we reveal deviations from Boltzmann statistics for the subthreshold swing and reinterpret existing literature. Capitalizing on these findings, we finally demonstrate a single-OECT Schmitt trigger, thus compacting a multi-component circuit into a single device. These insights provide a fundamental advance for OECT physics and its application in non-conventional computing, where symmetry-breaking phenomena are pivotal to unlock new paradigms of information processing.

physics.app-ph↗

arXiv2023

Threshold Voltage Control in Dual-Gate Organic Electrochemical Transistors

Organic electrochemical transistors (OECTs) based on Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonic acid) (PEDOT:PSS) are a benchmark system in organic bioelectronics. In particular, the superior mechanical properties and the ionic-electronic transduction yield excellent potential for the field of implantable or wearable sensing technology. However, depletion-mode operation PEDOT:PSS-based OECTs cause high static power dissipation in electronic circuits, limiting their application in electronic systems. Hence, having control over the threshold voltage is of utmost technological importance. Here we demonstrate PEDOT:PSS-based dual-gate OECTs with solid-state electrolyte where the threshold voltage is seamlessly adjustable during operation. We show that the degree of threshold voltage tuning linearly depends on the gate capacitance, which is a straightforward approach for circuit designers to adjust the threshold voltage only by the device dimensions. The PEDOT:PSS-based dual-gate OECTs show excellent device performance and can be pushed to accumulation-mode operation, resulting in a simplified and relaxed design of complementary inverters.

physics.app-ph↗

arXiv2022

In-Liquido Computation with Electrochemical Transistors and Mixed Conductors for Intelligent Bioelectronics

Next-generation implantable computational devices require long-term stable electronic components capable of operating in, and interacting with, electrolytic surroundings without being damaged. Organic electrochemical transistors (OECTs) emerged as fitting candidates. However, while single devices feature impressive figures of merit, integrated circuits (ICs) immersed in a common electrolytes are hard to realize using electrochemical transistors, and there is no clear path forward for optimal top-down circuit design and high-density integration. The simple observation that two OECTs immersed in the same electrolytic medium will inevitably interact hampers their implementation in complex circuitry. The electrolyte's ionic conductivity connects all the devices in the liquid, producing unwanted and often unforeseeable dynamics. Minimizing or harnessing this crosstalk has been the focus of very recent studies. In this Perspective, we discuss the main challenges, trends, and opportunities for realizing OECT-based circuitry in a liquid environment that could circumnavigate the hard limits of engineering and human physiology. We analyze the most successful approaches in autonomous bioelectronics and information processing. Elaborating on the strategies to circumvent and harness device crosstalk proves that platforms capable of complex computation and even machine learning can be realized in-liquido using mixed ionic-electronic conductors.

cond-mat.mtrl-sci↗

arXiv2021

Structural evolution and on-demand growth of artificial synapses via field-directed polymerization

Interconnectivity, fault tolerance, and dynamic evolution of the circuitry are long sought-after objectives of bio-inspired engineering. Here, we propose dendritic transistors composed of organic semiconductors as building blocks for neuromorphic computing. These devices, owning to their voltage-triggered growth and resemblance to neural structures, respond to action potentials to achieve complex brain-like features, such as Pavlovian learning, pattern recognition, and spike-timing-dependent plasticity. The dynamic formation of the connections is reminiscent of a biological learning mechanism known as synaptogenesis, and it is carried out by an electrochemical reaction that we name field-directed polymerization. We employ it to dendritic connections and, by modulating the growth parameters, control material properties such as the resistance and the time constants relevant for plasticity. We believe these results will inspire further research towards the complex integration of polymerized synapses for brain-inspired computing.

cs.ET↗