arXiv subjects

Matthew G. Jackson

Publications and source records attributed to Matthew G. Jackson.

3 recordsLinked to original sources

arXiv2019

Reverse chemistry of iron in the deep Earth

In this work, we demonstrate a remarkable change of chemical trend of Iron under high pressure that is of great importance for understanding the distribution of elements in the Earth's mantle and core. Using first principles crystal structure search method, we conduct a systematic study of the propensity of p block elements to chemically bind with iron under high pressures ranging from ambient conditions to that of Earth's core. We show that under increasing pressure, iron tends to reverse its chemical nature, changing from an electron donor (reductant) to an electron acceptor, and oxidizes p-block elements in many compounds. Such reverse chemistry has a significant impact on the stoichiometries, bond types and strengths, structures and properties of iron compounds under deep planetary conditions.

physics.chem-ph↗

arXiv2016

Silicon isotopes reveal recycled altered oceanic crust in the mantle sources of Ocean Island Basalts

The study of silicon (Si) isotopes in ocean island basalts (OIB) has the potential to discern between different models for the origins of geochemical heterogeneities in the mantle. Relatively large (several per mil per atomic mass unit) Si isotope fractionation occurs in low-temperature environments during biochemical and geochemical precipitation of dissolved Si, where the precipitate is preferentially enriched in the lighter isotopes relative to the dissolved Si. In contrast, only a limited range (tenths of a per mil) of Si isotope fractionation has been observed from high-temperature igneous processes. Therefore, Si isotopes may be useful as tracers for the presence of crustal material within OIB mantle source regions that experienced relatively low-temperature surface processes in a manner similar to other stable isotope systems, such as oxygen. Characterizing the isotopic composition of the mantle is also of central importance to the use of the Si isotope system as a basis for comparisons with other planetary bodies (e.g., Moon, Mars, asteroids). Here we present the first comprehensive suite of high-precision Si isotope data obtained by MC-ICP-MS for a diverse suite of OIB. Samples originate from ocean islands in the Pacific, Atlantic, and Indian Ocean basins and include representative end-members for the EM-1, EM-2, and HIMU mantle components. On average, Si isotope compositions of OIB are in general agreement with previous estimates for the Si isotope composition of bulk silicate Earth. Nonetheless, some small systematic variations are present; specifically, most HIMU-type (Mangaia; Cape Verde; La Palma, Canary Islands) and Iceland OIB are enriched in the lighter isotopes of Si, consistent with recycled altered oceanic crust and lithospheric mantle in their mantle sources.

astro-ph.EP↗

arXiv2013

Interstellar dust properties of M51 from AKARI mid-infrared images

Using mid-infrared (MIR) images of four photometric bands of the Infrared Camera (IRC) onboard the AKARI satellite, S7 (7 um), S11 (11 um), L15 (15 um), and L24 (24 um), we investigate the interstellar dust properties of the nearby pair of galaxies M51 with respect to its spiral arm structure. The arm and interarm regions being defined based on a spatially filtered stellar component model image, we measure the arm-to-interarm contrast for each band. The contrast is lowest in the S11 image, which is interpreted as that among the four AKARI MIR bands the S11 image best correlates with the spatial distribution of dust grains including colder components, while the L24 image with the highest contrast traces warmer dust heated by star forming activities. The surface brightness ratio between the bands, i.e. color, is measured over the disk of the main galaxy, M51a, at 300 pc resolution. We find that the distribution of S7/S11 is smooth and well traces the global spiral arm pattern while L15/S11 and L24/S11 peak at individual HII regions. This result indicates that the ionization state of PAHs is related to the spiral structure. Comparison with observational data and dust models also supports the importance of the variation in the PAH ionization state within the M51a disk. However, the mechanism driving this variation is not yet clear from currently available data sets. Another suggestion from the comparison with the models is that the PAH fraction to the total dust mass is higher than previously estimated.

astro-ph.CO↗