arXiv subjects

Maurizio Toselli

Publications and source records attributed to Maurizio Toselli.

4 recordsLinked to original sources

arXiv2026

Electrical post-fabrication tuning of aluminum Josephson junctions at room temperature

Josephson junctions are key elements of superconducting quantum technology, serving as the core building blocks of superconducting qubits. We present an experimental study on room-temperature electrical tuning of aluminum junctions, showing that voltage pulses can controllably increase their resistance and adjust the Josephson energy while maintaining qubit quality factors above 1 million. We find that the rate of resistance increase scales exponentially with pulse amplitude during manipulation. Following the manipulation, the resistance increases spontaneously through contributions proportional to both the initial resistance and the preceding manipulation. We show that this spontaneous increase halts at cryogenic temperatures, and resumes again at room temperature. Using our stepwise protocol, we achieve up to a 270% increase in junction resistance, corresponding to a reduction of nearly 2 GHz of the qubit transition frequency. These results establish the achievable range, relaxation behavior, and practical limits of electrical tuning, enabling post-fabrication mitigation of frequency crowding in quantum processors.

quant-ph↗

arXiv2025

Finite strain continuum phenomenological model describing the shape-memory effects in multi-phase semi-crystalline networks

Thermally-driven semi-crystalline polymer networks are capable to achieve both the one-way shape-memory effect and two-way shape-memory effect under stress and stress-free conditions, therefore representing an appealing class of polymers for applications requiring autonomous reversible actuation and shape changes. In these materials, the shape-memory effects are achieved by leveraging the synergistic interaction between one or more crystalline phases and the surrounding amorphous ones that are present within the network itself. The present paper introduces a general framework for the finite strain continuum phenomenological modeling of the thermo-mechanical and shape-memory behavior of multi-phase semi-crystalline polymer networks. Model formulation, including the definition of phase and control variables, kinematic assumptions, and constitutive specifications, is introduced and thoroughly discussed. Theoretical derivations are general and easily adaptable to all cross-linked systems which include two or more crystalline domains or a single crystalline phase with a wide melting range and manifest macroscopically the one-way shape-memory effect and the two-way shape-memory effect under stress and stress-free conditions. Model capabilities are validated against experimental data for copolymer networks with two different crystalline phases characterized by well-separated melting and crystallization transitions. Results demonstrate the accuracy of the proposed model in predicting all the phenomena involved and in furnishing a useful support for future material and application design purposes.

cond-mat.soft↗

arXiv2025

Phenomenological modeling of the stress-free two-way shape-memory effect in semi-crystalline networks: Formulation, numerical simulation, and experimental validation

Polymers exhibiting the stress-free two-way shape-memory effect (SME) represent an appealing solution to achieve self-standing reversible actuation that is a fundamental feature required by numerous applications. The present paper proposes a one-dimensional continuum phenomenological framework to model single-component semi-crystalline polymer networks exhibiting both the one-way SME and the two-way SME under stress and stress-free conditions. A comprehensive experimental campaign is first performed on semi-crystalline networks based on poly($\varepsilon$-caprolactone) (PCL) to characterize the mechanical and thermal properties as well as the one-way and two-way shape memory behavior of the material under different thermo-mechanical conditions. The results guide the formulation of the model, elucidating the selection of the control and phase variables and motivating the choice of their evolution laws. Model capabilities are then demonstrated against experimental data. All the phenomena that influence the stress-free two-way SME, including the actuation temperature, heating/cooling rates, applied stress/strain, and the amount of skeleton and actuation phase, are analyzed and discussed, giving new important insight for application development.

cond-mat.soft↗

arXiv2025

Solvent-triggered shape change in gradient-based 4D printed bilayers: case study on semi-crystalline polymer networks

We propose an approach to 4D print solvent-triggered, gradient-based bilayers made of semi-crystalline crosslinked polymer networks. Out-of-plane bending is obtained after immersion in the solvent, exploiting the different swelling degrees of the layers resulting from crosslinking gradients. Lastly, a beam model of the shape transformation is applied and experimentally validated.

cond-mat.soft↗