arXiv subjects

Mauro Guerra

Publications and source records attributed to Mauro Guerra.

12 recordsLinked to original sources

arXiv2026

Theoretical ab initio Evolution of Satellite Intensity near Threshold for Cu K-shell transitions

In this work, we have investigated the evolution of satellite intensity near the ionization threshold for Cu K-shell transitions through theoretical methods. Employing standard state-of-the-art ab initio methods, we have calculated all Cu K-shell transitions and simulated the full K$α_1$ and K$α_2$ spectrum where all transition parameters, as well as shake probabilities were determined theoretically. Through these calculations we show that standard state-of-the-art ab initio methods achieve good agreement with experiment and enable us to simulate the intensity evolution near ionization thresholds within a good margin of error. Below-threshold satellite intensity was found to originate from resonant 1s$\rightarrow$3d and 1s$\rightarrow$4p excitations in Cu(I) and Cu(II) oxide phases respectively, which were included in our simulations.

physics.atom-ph↗

arXiv2026

Aluminum-Based Superconducting Tunnel Junction Sensors for Nuclear Recoil Spectroscopy

The BeEST experiment is searching for sub-MeV sterile neutrinos by measuring nuclear recoil energies from the decay of $^7$Be implanted into superconducting tunnel junction (STJ) sensors. The recoil spectra are affected by interactions between the radioactive implants and the sensor materials. We are therefore developing aluminum-based STJs (Al-STJs) as an alternative to existing tantalum devices (Ta-STJs) to investigate how to separate material effects in the recoil spectrum from potential signatures of physics beyond the Standard Model. Three iterations of Al-STJs were fabricated. The first had electrode thicknesses similar to existing Ta-STJs. They had low responsivity and reduced resolution, but were used successfully to measure $^7$Be nuclear recoil spectra. The second iteration had STJs suspended on thin SiN membranes by backside etching. These devices had low leakage current, but also low yield. The final iteration was not backside etched, and the Al-STJs had thinner electrodes and thinner tunnel barriers to increase signal amplitudes. These devices achieved 2.96 eV FWHM energy resolution at 50 eV using a pulsed 355 nm (~3.5 eV) laser. These results establish Al-STJs as viable detectors for systematic material studies in the BeEST experiment.

physics.ins-det↗

arXiv2026

Shake-up and shake-off spectra in the electron capture decay of atomic $^7$Be

The most stringent laboratory-based experimental limits on the existence of sub-MeV sterile neutrinos are currently set by decay spectroscopy of radioactive $^7$Be embedded into superconducting sensors. The systematic uncertainties are dominated by the modeling of the electron shake-up and shake-off spectra that are not based on state-of-the-art atomic theory and do not include electron correlations or relativistic effects. We have used the multiconfiguration Dirac-Fock formalism to obtain correlated wavefunctions ab initio and compute all single and double shake processes in the electron capture decay of atomic $^7$Be. The simulations can explain some but not all of the observed spectral features, likely because the wave functions are modified by the Ta sensor material that the $^7$Be is embedded into. The new models also show that the L/K electron capture ratio of $^7$Be in Ta has previously been slightly underestimated revising the previous value of 0.070(7) to a new value of 0.0756(20).

physics.atom-ph↗

arXiv2025

A Bayesian Approach for Strong Field QED Tests with He-like Ions

Detailed comparisons between theory and experiment for quantum electrodynamics (QED) effects in He-like ions have been performed in the literature to search for hints of new physics. Different frequentist statistical analyses of the existing atomic transition energy data have shown contradictory conclusions as to the presence of possible deviations from the theory predictions. We present here an approach using Bayesian statistics which allows to assign quantitative probabilities to the different deviation models from theory for He-like ions for $Z = 5$ to 92. Potential deviations beyond the standard model or higher order QED effects are modeled with $f(Z) \propto Z^k$ functions. Considering the currently available data, no significant difference between theory and experiment is found, and we show that recent experiments have reduced the possible deviations previously observed in the literature. Using past measurements and a weighted average on the different deviation models, we indicate the accuracy required for future measurements to investigated possible divergences.

physics.atom-ph↗

arXiv2025

Signal processing and spectral modeling for the BeEST experiment

The Beryllium Electron capture in Superconducting Tunnel junctions (BeEST) experiment searches for evidence of heavy neutrino mass eigenstates in the nuclear electron capture decay of $^7$Be by precisely measuring the recoil energy of the $^7$Li daughter. In Phase-III, the BeEST experiment has been scaled from a single superconducting tunnel junction (STJ) sensor to a 36-pixel array to increase sensitivity and mitigate gamma-induced backgrounds. Phase-III also uses a new continuous data acquisition system that greatly increases the flexibility for signal processing and data cleaning. We have developed procedures for signal processing and spectral fitting that are sufficiently robust to be automated for large data sets. This article presents the optimized procedures before unblinding the majority of the Phase-III data set to search for physics beyond the standard model.

physics.ins-det↗

arXiv2025

Towards Precision Spectroscopy of Antiprotonic Atoms for Probing Strong-field QED

PAX (antiProtonic Atom X-ray spectroscopy) is a new experiment with the aim to test strong-field quantum electrodynamics (QED) effects by performing high-precision x-ray spectroscopy of antiprotonic atoms. By utilizing advanced microcalorimeter detection techniques and a low-energy antiproton beam provided by the ELENA ring at CERN, gaseous targets will be used for the creation of antiprotonic atoms, and the measurement of transitions between circular Rydberg states will be conducted with up to two orders of magnitude improved accuracy over previous studies using high-purity germanium detectors. Our approach eliminates the longstanding issue of nuclear uncertainties that have hindered prior studies using highly charged ions, thus enabling direct and purely QED-focused measurements. By precisely probing atomic systems with electric fields up to two orders of magnitude above the Schwinger limit, PAX will test vacuum polarization and second-order QED corrections, opening new frontiers in fundamental physics and uncovering potential pathways to physics beyond the Standard Model.

physics.atom-ph↗

arXiv2024

Direct Experimental Constraints on the Spatial Extent of a Neutrino Wavepacket

Despite their high relative abundance in our Universe, neutrinos are the least understood fundamental particles of nature. They also provide a unique system to study quantum coherence and the wavelike nature of particles in fundamental systems due to their extremely weak interaction probabilities. In fact, the quantum properties of neutrinos emitted in experimentally relevant sources are virtually unknown and the spatial extent of the neutrino wavepacket is only loosely constrained by reactor neutrino oscillation data with a spread of 13 orders of magnitude. Here, we present the first direct limits of this quantity through a new experimental concept to extract the energy width, $σ_{\textrm{N},E}$, of the recoil daughter nucleus emitted in the nuclear electron capture (EC) decay of $^7$Be. The final state in the EC decay process contains a recoiling $^7$Li nucleus and an electron neutrino ($ν_e$) which are entangled at their creation. The $^7$Li energy spectrum is measured to high precision by directly embedding $^7$Be radioisotopes into a high resolution superconducting tunnel junction that is operated as a cryogenic sensor. The lower limit on the spatial uncertainty of the recoil daughter was found to be $σ_{\textrm{N}, x} \geq 6.2$\,pm, which implies the final-state system is localized at a scale more than a thousand times larger than the nucleus itself. From this measurement, the first direct lower limits on the spatial extent of the neutrino wavepacket were extracted using two different theoretical methods. These results have wide-reaching implications in several areas including the nature of spatial localization at sub-atomic scales, interpretation of neutrino physics data, and the potential reach of future large-scale experiments.

nucl-ex↗

arXiv2021

Experimental and theoretical approaches for determining the K-shell fluorescence yield of carbon

The knowledge of atomic fundamental parameters, such as the fluorescence yields with low uncertainties, is of decisive importance in elemental quantification involving X-ray fluorescence analysis techniques. However, especially for the low-Z elements, the available literature data are either of poor quality, of unknown or very large uncertainty, or both. For this reason, the K-shell fluorescence yield of carbon was determined in the PTB laboratory at the synchrotron radiation facility BESSY II. In addition, theoretical calculations of the same parameter were performed using the multiconfiguration Dirac-Fock method, including relativistic and quantum electrodynamics (QED) corrections. Both values obtained in this work are compared to the corresponding available literature data.

physics.atom-ph↗

arXiv2019

Relativistic electron impact ionization cross sections of carbon ions and application to an optically thin plasma

Aims. Determination of K- and L-shell cross sections of the carbon atom and ions using the modified relativistic binary encounter Bethe (MRBEB) method, a simple analytical scheme based on one atomic parameter that allows determining electron-impact ionization cross sections. The quality of the cross sections calculated with the MRBEB method is shown through: (i) comparison with those obtained with the general ionization processes in the presence of electrons and radiation (GIPPER) code and the flexible atomic code (FAC), and (ii) determination of their effects on the ionic structure and cooling of an optically thin plasma. Results. The three sets of cross sections show deviations among each other in different energy regions. The largest deviations occur near and in the peak maximum. Ion fractions and plasma emissivities of an optically thin plasma that evolves under collisional ionization equilibrium, derived using each set of cross sections, show deviations that decrease with increase in temperature and ionization degree. In spite of these differences, the calculations using the three sets of cross sections agree overall. Conclusions. A simple model like the MRBEB is capable of providing cross sections similar to those calculated with more sophisticated quantum mechanical methods in the GIPPER and FAC codes.

astro-ph.IM↗

arXiv2018

Assessment of toxic metals and hazardous substances in tattoo inks using Sy-XRF, AAS and Raman spectroscopy

A set of tattoo inks from a top brand was analysed by means of Synchrotron-based X-ray Fluorescence spectrometry (Sy-XRF), Atomic Absorption spectrometry (AAS) and Raman Spectroscopy to investigate the presence of toxic metals and hazardous substances. Quantitative analysis shows that Cr, Cu and Pb content is above the maximum allowed levels established by the Council of Europe in the resolution ResAP(2008)1 on requirements and criteria for the safety of tattoos and permanent make-up. Raman analysis reveals the presence of pigments Blue 15, Green 7 and Violet 23 in blue, green and violet inks that belong to a list of prohibited substances mentioned in ResAP(2008)1. Besides, Pigment White 6, carbon black, Pigment Red 8 and a diazo yellow were also identified in white, black, red and yellow inks. The results presented in this study show the importance of regulating tattoo ink composition.

physics.med-ph↗

arXiv2015

Relativistic evaluation of the two-photon decay of the metastable ${1s}^{2} 2s 2p~^3\mbox{P}_0$ state in berylliumlike ions with an active-electron model

The two-photon ${1s}^{2} 2s 2p~^3\mbox{P}_0 \rightarrow {1s}^{2} {2s}^2$ $^1\mbox{S}_0$ transition in berylliumlike ions is theoretically investigated within a full relativistic framework and a second-order perturbation theory. We focus our analysis on how electron correlation, as well as the negative-energy spectrum can affect the forbidden $E1M1$ decay rate. For this purpose we include the electronic correlation by an effective potential and within an active-electron model. Due to its experimental interest, evaluation of decay rates are performed for berylliumlike xenon and uranium. We find that the negative-energy contribution can be neglected in the present decay rate. On the other hand, if contributions of electronic correlation are not carefully taken into account, it may change the lifetime of the metastable state by 20\%. By performing a full-relativistic $jj$-coupling calculation, we found discrepancies for the decay rate of an order of 2 compared to non-relativistic $LS$-coupling calculations, for the selected heavy ions.

physics.atom-ph↗

arXiv2012

A vacuum double-crystal spectrometer for reference-free highly charged ions X-ray spectroscopy

We have built a vacuum double crystal spectrometer, which coupled to an electron-cyclotron resonance ion source, allows to measure low-energy x-ray transitions in highly-charged ions with accuracies of the order of a few parts per million. We describe in detail the instrument and its performances. Furthermore, we present a few spectra of transitions in Ar$^{14+}$, Ar$^{15+}$ and Ar$^{16+}$. We have developed an ab initio simulation code that allows us to obtain accurate line profiles. It can reproduce experimental spectra with unprecedented accuracy. The quality of the profiles allows the direct determination of line width.

physics.atom-ph↗