arXiv subjects

Maxim Trushin

Publications and source records attributed to Maxim Trushin.

At least 19 recordsLinked to original sources

arXiv2026

Ferroelectric brightening of spin forbidden dark excitons in a WSe2/hybrid perovskite heterostructure

Long-lived dark excitons in monolayer WSe2 present promising candidates for carrying spin and valley information, but their optical access and spin manipulation have conventionally required the use of strong external magnetic fields. Here, using a ferroelectric hybrid perovskite heterostructure, we leverage the ferroelectric proximity effect to break the WSe2's in-plane rotational symmetry and brighten the spin-forbidden dark excitons under zero magnetic field conditions. Furthermore, we show that the twist angle between the WSe2 and perovskite crystals controls the ferroelectric coupling strength and valley-contrasting polarization. Our proposed mechanism, supported by a four-band tight-binding model, suggests that the ferroelectric proximity effect induces an asymmetric intersublattice interaction, generating an effective in-plane spin-orbit coupling (SOC) field that rotates spin/valley polarization and brightens dark excitons. Our work establishes ferroelectric proximity coupling as an electrically reconfigurable, magnetic-field-free strategy for spin exciton control in two-dimensional semiconductors.

cond-mat.mtrl-sci↗

arXiv2026

Resonant field emission from noble-metal/graphene heterostructures

Field emission from metals underpinned early vacuum-tube technology, and recent nanoscale engineering made field-emission devices compatible with modern silicon platforms. However, the limited tunability of electron transport in metals has restricted their applicability. Here, we show that noble metals coated with graphene exhibit clean non-monotonic $I-V$ characteristics arising from resonant tunneling through graphene's electronic states, enabled by graphene's atomic thinness and weak electronic hybridization with noble metals. Our approach combines ab-initio interface parameters with exact solutions of the Schr\"odinger equation for electron transmission across the interface. We analyze two experimentally relevant geometries: a vertical configuration with a flat suspended emitter and a coplanar configuration with sharp electrodes allowing for strong field enhancement and gating. These results establish a practical route to tunable electron transport in metal heterostructures, positioning them as competitive components for air-channel field-emission nanoelectronics.

cond-mat.mes-hall↗

arXiv2025

Structure and flow of low-dimensional water

Water, a subject of human fascination for millennia, is likely the most studied substance on Earth, with an entire scientific field -- hydrodynamics -- dedicated to understanding water in motion. However, when water flows through one-dimensional or two-dimensional channels, its behavior deviates substantially from the principles of hydrodynamics. This is because reducing the dimensionality of any interacting physical system amplifies interaction effects that are beyond the reach of traditional hydrodynamic equations. In low-dimensional water, hydrogen bonds can become stable enough to arrange water molecules into an ordered state, causing water to behave not only like a liquid but also like a solid in certain respects. In this review, we explore the relationship between water's ordering and its ability to flow in low-dimensional channels, using viscosities of bulk water, vapor, and ice as benchmarks. We also provide a brief overview of the key theoretical approaches available for such analyses and discuss ionic transport, which is heavily influenced by the molecular structure of water.

cond-mat.soft↗

arXiv2025

Electrical generation of surface plasmon polaritons in plasmonic heterostructures

Surface plasmon polaritons (SPPs) can be understood as two-dimensional light confined to a conductor-dielectric interface via plasmonic excitations. While low-energy SPPs behave similarly to photons, higher-frequency SPPs resemble surface plasmons. Electrically generating mid-range SPPs is particularly challenging because it requires compensating for momentum mismatch, a process conventionally achieved through inelastic electron transport in nanostructures. Here, we theoretically demonstrate that electrical SPP generation is possible by directly coupling electron-hole dipoles to the quantized SPP field across an insulating spacer without accompanying electron transport. This approach can be realized in plasmonic van der Waals heterostructures composed of strongly-biased monolayer graphene as the emitter, few-layer hexagonal boron nitride as the spacer, and silver (or gold) as the plasmonic material. In this configuration, graphene's remarkable ability to support a strongly non-equilibrium steady-state electron-hole population results in non-thermal, bias-tunable SPP emission that is uniform along the hBN/Ag interface, achieving a power conversion efficiency of up to 1% and a Purcell factor of up to 100. These findings pave the way for integrating photonic and electronic functionalities within a single two-dimensional heterostructure.

cond-mat.mes-hall↗

arXiv2022

High conductivity from cross-band electron pairing in flat-band systems

Electrons in condensed matter may transition into a variety of broken-symmetry phase states due to electron-electron interactions. Applying diverse mean-field approximations to the interaction term is arguably the simplest way to identify the phase states theoretically possible in a given setting. Here, we explore electron-electron attraction in a two-band system comprising symmetric conduction and valence bands touching each other at a single point. We assume a mean-field pairing between the electrons having opposite spins, momenta, and, in contrast to the conventional superconducting pairing, residing in opposite bands, i.e., having opposite energies. We show that electrons transition into a novel correlated ground state if and only if the bands are flat enough, i.e. the transition is impossible in the case of conventional parabolic bands. Although this state is not superconducting in the usual sense and does not exhibit a gap in its excitation spectrum, it is nevertheless immune to elastic scattering caused by any kind of disorder, and is therefore expected to exhibit high electric conductivity at low temperature, mimicking the behavior of a real superconductor. Having in mind the recent experimental realizations of flat-band electronic systems in twisted multilayers, we foresee an exciting opportunity for observing a new class of highly conductive materials.

cond-mat.str-el↗

arXiv2022

Interlayer excitonic insulator in two-dimensional double-layer semiconductor junctions: An explicitly solvable model

Excitonic insulators conduct neither electrons nor holes but bound electron-hole pairs, excitons. Unfortunately, it is not possible to inject and detect the electron and hole currents independently within a single semiconducting layer. However, interlayer excitonic insulators provide a spatial separation of electrons and holes enabling exciton current measurements. The problem is that the spatial separation weakens electron-hole pairing and may lead to interlayer exciton disassociation. Here we develop an explicitly solvable model to determine an interlayer separation that is strong enough to prevent electron and hole hopping across the layers but still allows for electron-hole pairing sufficient for transition into an interlayer excitonic insulator state. An ideal junction to realize such a state would comprise a pair of identical narrow-gap two-dimensional semiconductors separated by a wide-gap dielectric layer with low dielectric permittivity. The present study quantifies parameters of such a junction by taking into account interlayer coherence effects.

cond-mat.mes-hall↗

arXiv2022

Two-dimensional non-linear hydrodynamics and nanofluidics

A water monolayer squeezed between two solid planes experiences strong out-of-plane confinement effects while expanding freely within the plane. As a consequence, the transport of such two-dimensional water combines hydrodynamic and nanofluidic features, intimately linked with each other. In this paper, we propose and explicitly solve a non-linear hydrodynamic equation describing two-dimensional water flow with viscosity parameters deduced from molecular dynamic simulations. We demonstrate that the very ability of two-dimensional water to flow in short channels is governed by the second (dilatational) viscosity coefficient, leading to flow compression and velocity saturation in the high-pressure limit. The viscosity parameter values depend strongly on whether graphene or hexoganal boron nitride layers are used to confine 2D water that offers an interesting opportunity to obtain various nanofluids out of the same water molecules just by using alternate materials to fabricate the 2D channels.

cond-mat.mtrl-sci↗

arXiv2022

Edge-Driven Phase Transitions in 2D Ice

2D water, confined by atomically flat layered materials, may transit into various crystalline phases even at room temperature. However, to gain full control over the crystalline state, we should not only confine water in the out of plane direction but also restrict its in plane motion, forming 2D water clusters or ribbons. One way to do this is by using an electric field, in particular the intrinsic electric field of an adjacent polar material. We have found that the crystalline phases of 2D water clusters placed between two hexagonal boron nitride hBN nanoribbons are crucially determined by the nanoribbons edges, the resulting polarity of the nanoribbons, and their interlayer distance. We make use of density functional theory with further assistance of molecular dynamics simulations to establish the comprehensive phase diagrams demonstrating transitions between liquid and solid phases and between the states of different crystalline orders. We also show that the crystalline orders are maintained when water flows between hBN channels under external pressure. Our results open a promising pathway towards the control of water structure and its flow by the use of the microscopic electric field of polar materials.

cond-mat.mtrl-sci↗

arXiv2021

Stability of a Rolled-Up Conformation State for Two-Dimensional Materials in Aqueous Solutions

Two-dimensional (2D) materials can roll up, forming stable scrolls under suitable conditions. However, the great diversity of materials and fabrication techniques has resulted in a huge parameter space significantly complicating the theoretical description of scrolls. In this Letter, we describe a universal binding energy of scrolls determined solely by their material parameters, the bending stiffness, and the Hamaker coefficient. Aiming to predict the stability of functionalized scrolls in water solutions, we consider the electrostatic double-layer repulsion force that may overcome the binding energy and flatten the scrolls. Our predictions are represented as comprehensive maps indicating the stable and unstable regions of a rolled-up conformation state in the space of material and external parameters. While focusing mostly on functionalized graphene in this work, our approach is applicable to the whole range of 2D materials able to form scrolls.

cond-mat.mtrl-sci↗

arXiv2021

Phonon-assisted carrier cooling in h-BN/graphene van der Waals heterostructures

Being used in optoelectronic devices as ultra-thin conductor-insulator junctions, detailed investigations are needed about how exactly h-BN and graphene hybridize. Here, we present a comprehensive ab initio study of hot carrier dynamics governed by electron-phonon scattering at the h-BN/graphene interface, using graphite (bulk), monolayer and bilayer graphene as benchmark materials. In contrast to monolayer graphene, all multilayer structures possess low-energy optical phonon modes that facilitate carrier thermalization. We find that the h-BN/graphene interface represents an exception with comparatively weak coupling between low-energy optical phonons and electrons. As a consequence, the thermalization bottleneck effect, known from graphene, survives hybridization with h-BN but is substantially reduced in all other bilayer and multilayer cases considered. In addition, we show that the quantum confinement in bilayer graphene does not have a significant influence on the thermalization time compared to graphite and that bilayer graphene can hence serve as a minimal model for the bulk counterpart.

cond-mat.mes-hall↗

arXiv2021

Collective Excitations in 2D Materials

Research on 2D materials has been one of the fastest-growing fields in condensed matter physics and materials science in the past 10 years. The low dimensionality and strong correlations of 2D systems give rise to electronic and structural properties, in the form of collective excitations, that do not have counterparts in ordinary 3D materials used in modern technology. These 2D materials present extraordinary opportunities for new technologies, such as in flexible electronics. In this Review, we focus on plasmons, excitons, phonons and magnons in 2D materials. We discuss the theoretical formalism of these collective excitations and elucidate how they differ from their 3D counterparts.

cond-mat.mes-hall↗

arXiv2021

Charge-carrier thermalization in bulk and monolayer CdTe from first principles

While cadmium telluride (CdTe) thin films are being used in solar cell prototyping for decades, the recent advent of two-dimensional (2D) materials challenges the fundamental limit for thickness of conventional CdTe layers. Here, we report our theoretical predictions on photocarrier dynamics in an ultimately thin (about 1 nm) CdTe slab. It corresponds to a layer that is just a single unit cell thick, when the bulk parent crystal in the zinc blende phase is cleaved along the [110] facet. Using an \textit{ab-initio} method based on density functional theory (DFT) and the Boltzmann equation in the relaxation time approximation (RTA), we determine the thermalization time for charge carriers excited to a certain energy for instance through laser irradiation. Our calculations include contributions arising from all phonon branches in the first Brillouin zone (BZ), thus capturing all relevant inter- and intraband carrier transitions due to electron-phonon scattering. We find that the photocarrier thermalization time is strongly reduced, by one order of magnitude for holes and by three orders of magnitude for electrons, once the CdTe crystal is thinned down from the bulk to a monolayer. Most surprisingly, the electron thermalization time becomes independent of the electron excess energy up to about 0.5~eV, when counted from the conduction band minimum (CBM). We relate this peculiar behavior to the degenerate and nearly parabolic lowest conduction band that yields a constant density of states (DOS) in the 2D limit. Our findings may be useful for designing novel CdTe-based optoelectronic devices, which employ nonequilibrium photoexcited carriers to improve the performance.

cond-mat.mtrl-sci↗

arXiv2020

Two-dimensional adaptive membranes with programmable water and ionic channels

Membranes are ubiquitous in nature with primary functions that include adaptive filtering and selective transport of chemical and molecular species. Being critical to cellular functions, they are also fundamental in many areas of science and technology. Of particular importance are the adaptive and programmable membranes that can change their permeability or selectivity depending on the environment. Here, we explore implementation of such biological functions in artificial membranes and demonstrate two dimensional self assembled heterostructures of graphene oxide and polyamine macromolecules, forming a network of ionic channels that exhibit regulated permeability of water and monovalent ions. This permeability can be tuned by a change of pH or the presence of certain ions. Unlike traditional membranes, the regulation mechanism reported here relies on specific interactions between the membranes internal components and ions. This allows fabrication of membranes with programmable, predetermined permeability and selectivity, governed by the choice of components, their conformation and their charging state.

cond-mat.mtrl-sci↗

arXiv2020

Evidence of Rotational Fröhlich Coupling in Polaronic Trions

Electrons commonly couple through Fröhlich interactions with longitudinal optical phonons to form polarons. However, trions possess a finite angular momentum and should therefore couple instead to rotational optical phonons. This creates a polaronic trion whose binding energy is determined by the crystallographic orientation of the lattice. Here, we demonstrate theoretically within the Fröhlich approach and experimentally by photoluminescence emission that the bare trion binding energy (20 meV) is significantly enhanced by the phonons at the interface between the two-dimensional semiconductor MoS$_2$ and the bulk transition metal oxide SrTiO$_3$. The low-temperature {binding energy} changes from 60 meV in [001]-oriented substrates to 90 meV for [111] orientation, as a result of the counter-intuitive interplay between the rotational axis of the MoS$_2$ trion and that of the SrTiO$_3$ phonon mode.

cond-mat.mes-hall↗

arXiv2020

Harnessing Exciton-Exciton Annihilation in Two-Dimensional Semiconductors

Strong many-body interactions in two-dimensional (2D) semiconductors give rise to efficient exciton-exciton annihilation (EEA). This process is expected to result in the generation of unbound high energy carriers. Here, we report an unconventional photoresponse of van der Waals heterostructure devices resulting from efficient EEA. Our heterostructures, which consist of monolayer transition metal dichalcogenide (TMD), hexagonal boron nitride (hBN), and few-layer graphene, exhibit photocurrent when photoexcited carriers possess sufficient energy to overcome the high energy barrier of hBN. Interestingly, we find that the device exhibits moderate photocurrent quantum efficiency even when the semiconducting TMD layer is excited at its ground exciton resonance despite the high exciton binding energy and large transport barrier. Using ab initio calculations, we show that EEA yields highly energetic electrons and holes with unevenly distributed energies depending on the scattering condition. Our findings highlight the dominant role of EEA in determining the photoresponse of 2D semiconductor optoelectronic devices.

cond-mat.mes-hall↗

arXiv2019

Thermalization of photoexcited carriers in two-dimensional transition metal dichalcogenides and internal quantum efficiency of van der Waals heterostructures

Van der Waals semiconductor heterostructures could be a platform to harness hot photoexcited carriers in the next generation of optoelectronic and photovoltaic devices. The internal quantum efficiency of hot-carrier devices is determined by the relation between photocarrier extraction and thermalization rates. Using \textit{ab-initio} methods we show that the photocarrier thermalization time in single-layer transition metal dichalcogenides strongly depends on the peculiarities of the phonon spectrum and the electronic spin-orbit coupling. In detail, the lifted spin degeneracy in the valence band suppresses the hole scattering on acoustic phonons, slowing down the thermalization of holes by one order of magnitude as compared to electrons. Moreover, the hole thermalization time behaves differently in MoS$_2$ and WSe$_2$ because spin-orbit interactions differ in these seemingly similar materials. We predict that the internal quantum efficiency of a tunneling van der Waals semiconductor heterostructure depends qualitatively on whether MoS$_2$ or WSe$_2$ is used.

cond-mat.mes-hall↗

arXiv2019

Superconductivity from collective excitations in magic angle twisted bilayer graphene

A purely electronic mechanism is proposed for the unconventional superconductivity recently observed in twisted bilayer graphene (tBG) close to the magic angle. Using the Migdal-Eliashberg framework on a one parameter effective lattice model for tBG we show that a superconducting state can be achieved by means of collective electronic modes in tBG. We posit robust features of the theory, including an asymmetrical superconducting dome and the magnitude of the critical temperature that are in agreement with experiments.

cond-mat.mes-hall↗

arXiv2019

Universal Fermi-surface anisotropy renormalization for interacting Dirac fermions with long-range interactions

Recent experimental and numerical evidence suggest an intriguing universal relationship between the Fermi surface anisotropy of the non-interacting parent two-dimensional electron gas and the strongly correlated composite Fermi liquid formed in a strong magnetic field close to half-filing. Inspired by these observations, we explore more generally the question of anisotropy renormalization in interacting 2D Fermi systems. Using a recently developed non-perturbative and numerically-exact projective quantum Monte Carlo simulation as well as other numerical and analytic techniques, only for Dirac fermions with long-range Coulomb interactions do we find a universal square-root decrease of the Fermi-surface anisotropy. For the half-filled composite Fermi liquid, this result is surprising since a Dirac fermion ground state was only recently proposed as an alternative to the usual HLR state. The importance of the long-range interaction, expected for Dirac systems, is also consistent with recent transport measurements. Our proposed universality can be tested in several anisotropic Dirac materials including graphene, topological insulators organic conductors, and magic-angle twisted bilayer graphene.

cond-mat.str-el↗