arXiv subjects

Mazhar N. Ali

Publications and source records attributed to Mazhar N. Ali.

At least 19 recordsLinked to original sources

arXiv2026

Band's Geometry Origin of Quantum Spin Transport Phenomena

We develop a geometric description of spin-dependent transport based on the local geometric structure of electronic bands and the Fermi surfaces. For quasi-two-dimensional systems, we show that hyperbolic regions of constant-energy surfaces generate a geometrical contribution to the Fermi velocity that couples naturally to electron spin and produces a spin-current response. We further show that, in the presence of time-reversal symmetry, the algebra of spin operators can be related to the exterior algebra of the band's tangent space, providing an additional geometric interpretation of spin in momentum space. This framework motivates a symplectic description of spin-separated transport on Fermi surfaces and its extension to three-dimensional band manifolds through contact geometry. Our results establish a direct connection between Fermi-surface geometry and intrinsic spin transport.

cond-mat.mes-hall↗

arXiv2026

Pseudo-superconducting-diode effect in ferroelectric Josephson junctions

The superconducting diode effect (SDE), characterized by unequal critical supercurrents in opposite current directions, enables supercurrent rectification. We propose a magnetic-field-free pseudo-superconducting-diode effect in ferroelectric Josephson junctions with broken inversion symmetry. Using a coupled dynamical model that combines a polarization-dependent RCSJ description with Landau-Khalatnikov-Tani ferroelectric dynamics, we show that ferroelectric polarization switching induces asymmetric critical and retrapping currents under current sweeps. The resulting nonreciprocity is highly tunable via ferroelectric parameters and the sweep protocol and remains robust at finite temperatures. Our work identifies ferroelectric Josephson junctions as a promising platform for magnetic-field-free nonreciprocal superconducting devices.

cond-mat.supr-con↗

arXiv2025

Driving the field-free Josephson diode effect using Kagome Mott insulator barriers

Josephson junctions (JJs), devices consisting of two superconductors separated by a barrier, are of great technological importance, being a cornerstone of quantum information processing. Classical understanding of superconductor-insulator-superconductor JJs is that conventional insulator's properties, other than magnetism, do not significantly influence the junction's behavior. However, recent work on quantum material (QM) JJs - using Mott insulator Nb3Br8 - resulted in magnetic field-free non-reciprocal superconductivity, termed the Josephson diode effect (JDE), implying the QM's intrinsic properties can modulate superconductivity in non-trivial ways. To date, the underlying mechanism and dependence of the JDE on correlation strength (U/t) has not been elucidated. Here we fabricate QMJJs using correlated Kagome insulators with varying U/t, Nb3X8 (X=Cl, Br, I), observing a decreasing trend of the field-free JDE with Nb3Cl8 reaching ~48% efficiency, Nb3Br8 ~6%, and Nb3I8 having no discernible JDE, matching the trend of decreasing U/t from Cl to I and suggesting correlation in insulators drives the field-free JDE.

cond-mat.supr-con↗

arXiv2025

Polarization Controlled Supercurrent in Ferroelectric Josephson Junction

Josephson junctions are essential devices in superconducting electronics and quantum computing hardware. Here we predict electrical control of the supercurrent in composite superconductor-insulator-ferroelectric-insulator-superconductor (S-I-FE-I-S) Josephson junctions. Inversion symmetry broken by unequal dielectric barrier thicknesses and/or potentials converts ferroelectric polarization reversal into a substantial change of the critical current. With a WKB tunneling model we obtain non-volatile switching of the critical current with on-off efficiency up to 0.9 for physically realistic parameters. This can be achieved by optimizing the thicknesses and potential barriers of the insulating layers, as well as the thickness and dielectric constant of the ferroelectric layer. We also derive a compact linear expression for the critical current valid for small polarizations. Our results identify ferroelectric Josephson junctions as electrically programmable superconducting current switches for cryogenic memory and logic applications.

cond-mat.supr-con↗

arXiv2025

Supercurrent interference and its transfer in a kagome superconductor

Superconductivity represents a macroscopic quantum state notable for its rich manifestations of electronic coherence and collective behavior. Kagome materials AV3Sb5 (A= K, Cs, Rb) possess cascade intertwined quantum phases including superconductivity, symmetry-breaking charge orders, nematic orders and topological states, making them attractive materials for exploring exotic superconducting states. However, the superconducting properties and the Cooper pairing behaviors have not been fully explored and understood. In this work, by studying both the magnetoresistance and critical current behaviors in KV3Sb5 ring and pristine flakes, we reveal the charge 2e paring in KV3Sb5 although anomalous oscillations with smaller periodicity were observed, and report the intrinsic superconducting phase coherence in KV3Sb5 flakes. The former is demonstrated by the careful verification of the Little-Parks oscillations in differential resistance colormaps, and the latter indicates the existence of superconducting domains in KV3Sb5. Moreover, we observed a special phenomenon: the transfer of supercurrent interference patterns between the superconducting ring and the superconducting flake, which demonstrates the global critical current effect of the superconducting phase coherence. These findings provide new insights into the Cooper pairing behaviors in KV3Sb5 and highlight the importance of global effect of superconducting phase coherence in the understanding of the superconducting behaviors.

cond-mat.supr-con↗

arXiv2025

A Fermi Surface Descriptor Quantifying the Correlations between Anomalous Hall Effect and Fermi Surface Geometry

In the last few decades, basic ideas of topology have completely transformed the prediction of quantum transport phenomena. Following this trend, we go deeper into the incorporation of modern mathematics into quantum material science focusing on geometry. Here we investigate the relation between the geometrical type of the Fermi surface and Anomalous and Spin Hall Effects. An index, $\mathbb{H}_F$, quantifying the hyperbolic geometry of the Fermi surface, shows a universal correlation (R$^2$ = 0.97) with the experimentally measured intrinsic anomalous Hall conductivity, of 16 different compounds spanning a wide variety of crystal, chemical, and electronic structure families, including those where topological methods give R$^2$ = 0.52. This raises a question about the predictive limits of topological physics and its transformation into a wider study of bandstructures' and Fermi surfaces' geometries and relating them to the quantum geometry theory of a more general metric of eigenstates, opening horizon for the prediction of phenomena beyond topological understanding.

cond-mat.str-el↗

arXiv2025

From strong to weak correlations in breathing-mode kagome van der Waals materials: Nb$_3$(F,Cl,Br,I)$_8$ as a robust and versatile platform for many-body engineering

By combining ab initio downfolding with cluster dynamical mean-field theory, we study the degree of correlations in monolayer, bilayer and bulk breathing-mode kagome van der Waals materials Nb$_3$(F,Cl,Br,I)$_8$. Our new material-specific many-body model library shows that in low-temperature bulk structures the Coulomb correlation strength steadily increases from I to F, allowing us to identify Nb$_3$I$_8$ as a weakly correlated insulator, Nb$_3$Br$_8$ and Nb$_3$Cl$_8$ as strongly correlated insulators, and Nb$_3$F$_8$ as a prototypical bulk Mott-insulator. Angle-resolved photoemission spectroscopy measurements comparing Nb$_3$Br$_8$ and Nb$_3$I$_8$ allow us to experimentally confirm these findings by revealing spectroscopic footprints of the degree of correlation. Our calculations uncover how the thickness and the stacking affect the degree of correlations and predict that the entire material family can be tuned into correlated charge-transfer or Mott-insulating phases upon doping. Our magnetic property analysis based on our model parameter library additionally confirms that inter-layer magnetic interactions drive the lattice phase transition to the low-temperature structures. The accompanying bilayer hybridization through inter-layer dimerization yields magnetic singlet-like ground states in the Cl, Br, and I compounds. We further prove that all low-temperature compounds are dynamically stable and that electron-phonon coupling to the low-energy subspace is suppressed. Our findings establish Nb$_3$X$_8$ as a robust, versatile, and tunable class for van der Waals-based Coulomb and Mott engineering with a rich phase diagram and allow us to speculate on the symmetry-breaking effects necessary for the recently observed Josephson diode effect in NbSe$_2$/Nb$_3$Br$_8$/NbSe$_2$ heterostructures.

cond-mat.str-el↗

arXiv2025

Anomalous refractive index modulation and giant birefringence in 2D ferrielectric CuInP$_2$S$_6$

2D ferroelectric (FE) materials have opened new opportunities in non-volatile memories, computation and non-linear optics due to their robust polarization in the ultra-thin limit and inherent flexibility in device integration. Recently, interest has grown in the use of 2D FEs in electro-optics, demanding the exploration of their electronic and optical properties. In this work, we report the discovery of an unprecedented anomalous thickness-dependent change in refractive index, as large as $δn$ $\sim$ 23.2$\%$, in the 2D ferrielectric CuInP$_2$S$_6$, far above the ultra-thin limit, and at room temperature. Furthermore, CuInP$_2$S$_6$ exhibits a giant birefringence in the blue-ultraviolet regime, with a maximum $\vert n_{OOP} - n_{IP}\vert$ $\sim$ 1.24 at $t \sim$ 22 nm and $λ$ = 339.5 nm, which is, to the best of our knowledge, the largest of any known material in this wavelength regime. We relate changes in CuInP$_2$S$_6$ optical constants to changes in the Cu(I) FE polarization contribution, influenced by its ionic mobility, opening the door to electronic control of its optical response for use in photonics and electro-optics.

cond-mat.mtrl-sci↗

arXiv2025

Unveiling Topological Hinge States in the Higher-Order Topological Insulator WTe$_2$ Based on the Fractional Josephson Effect

Higher-order topological insulators (HOTIs) represent a novel class of topological materials, characterised by the emergence of topological boundary modes at dimensions two or more lower than those of bulk materials. Recent experimental studies have identified conducting channels at the hinges of HOTIs, although their topological nature remains unexplored. In this study, we investigated Shapiro steps in Al-WTe$_2$-Al proximity Josephson junctions (JJs) under microwave irradiation and examined the topological properties of the hinge states in WTe$_2$. Specifically, we analysed the microwave frequency dependence of the absence of the first Shapiro step in hinge-dominated JJs, attributing this phenomenon to the 4$π$-periodic current-phase relationship characteristic of topological JJs. These findings may encourage further research into topological superconductivity with topological hinge states in superconducting hybrid devices based on HOTIs. Such advances could lead to the realisation of Majorana zero modes for topological quantum physics and pave the way for applications in spintronic devices.

cond-mat.mes-hall↗

arXiv2024

The global critical current effect of superconductivity

Superconductivity has been investigated for over a century, but there are still open questions about what determines the critical current; the maximum current a superconductor can carry before switching to its normal state. For a given superconductor, the zero-field critical current is widely believed to be determined by its inherent properties and be related to its critical magnetic field. Here, by studying superconducting polycrystalline films, single crystal flakes, and layered heterostructures, we find that the critical current of a superconductor can vary with measurement configuration. It can be influenced, or even determined, by adjacent superconducting segments along the applied current trajectory, whereas the critical magnetic field and critical temperature remain unaffected. This global critical current effect both reveals the need to revisit fundamental theory describing superconductivity, as well as implies that superconductors can transfer critical current related properties to each other. We demonstrate this by designing and fabricating a simple superconducting structure that transferred a superconducting diode effect from one segment to another segment which could not manifest the effect on its own. This observation merits a reconsideration of contemporary superconducting circuit design, and developing a full understanding will lead to a new paradigm of superconducting electronics.

cond-mat.supr-con↗

arXiv2024

Roadmap on Quantum Magnetic Materials

Fundamental research on two-dimensional (2D) magnetic systems based on van der Waals materials has been gaining traction rapidly since their recent discovery. With the increase of recent knowledge, it has become clear that such materials have also a strong potential for applications in devices that combine magnetism with electronics, optics, and nanomechanics. Nonetheless, many challenges still lay ahead. Several fundamental aspects of 2D magnetic materials are still unknown or poorly understood, such as their often-complicated electronic structure, optical properties, and magnetization dynamics, and their magnon spectrum. To elucidate their properties and facilitate integration in devices, advanced characterization techniques and theoretical frameworks need to be developed or adapted. Moreover, developing synthesis methods which increase critical temperatures and achieve large-scale, high-quality homogeneous thin films is crucial before these materials can be used for real-world applications. Therefore, the field of 2D magnetic materials provides many challenges and opportunities for the discovery and exploration of new phenomena, as well as the development of new applications. This Roadmap presents the background, challenges, and potential research directions for various relevant topics in the field on the fundamentals, synthesis, characterization, and applications. We hope that this work can provide a strong starting point for young researchers in the field and provide a general overview of the key challenges for more experienced researchers.

cond-mat.mtrl-sci↗

arXiv2024

Pressure-dependent magnetotransport measurement in Kagome metal Yb$_{0.5}$Co_3Ge$_3$

Kagome materials are known to be an ideal platform that hosts a plethora of interesting phases such as topological states, electronic correlation, and magnetism, owing to their unique band structure and geometry. We report magnetotransport measurement in Kagome metal Yb$_{0.5}$Co_3Ge$_3$ as a function of pressure. Below $\sim25^\circ$ K the temperature dependence of resistance shows an upturn that is accompanied by a strong negative magnetoresistance, which could be attributed to Kondo effect. Upon pressurization above 1 GPa the resistance shows a reduction as a function of temperature below $4^\circ$ K, along with a further enhanced negative magnetoresistance. This might indicate an onset of a pressure-induced Kondo coherence effect.

cond-mat.str-el↗

arXiv2024

Momentum-Resolved Fingerprint of Mottness in Layer-Dimerized Nb$_3$Br$_8$

In a well-ordered crystalline solid, insulating behaviour can arise from two mechanisms: electrons can either scatter off a periodic potential, thus forming band gaps that can lead to a band insulator, or they localize due to strong interactions, resulting in a Mott insulator. For an even number of electrons per unit cell, either band- or Mott-insulators can theoretically occur. However, unambiguously identifying an unconventional Mott-insulator with an even number of electrons experimentally has remained a longstanding challenge due to the lack of a momentum-resolved fingerprint. This challenge has recently become pressing for the layer dimerized van der Waals compound Nb$_3$Br$_8$, which exhibits a puzzling magnetic field-free diode effect when used as a weak link in Josephson junctions, but has previously been considered to be a band-insulator. In this work, we present a unique momentum-resolved signature of a Mott-insulating phase in the spectral function of Nb$_3$Br$_8$: the top of the highest occupied band along the out-of-plane dimerization direction $k_z$ has a momentum space separation of $Δk_z=2π/d$, whereas the valence band maximum of a band insulator would be separated by less than $Δk_z=π/d$, where $d$ is the average spacing between the layers. As the strong electron correlations inherent in Mott insulators can lead to unconventional superconductivity, identifying Nb$_3$Br$_8$ as an unconventional Mott-insulator is crucial for understanding its apparent time-reversal symmetry breaking Josephson diode effect. Moreover, the momentum-resolved signature employed here could be used to detect quantum phase transition between band- and Mott-insulating phases in van der Waals heterostructures, where interlayer interactions and correlations can be easily tuned to drive such transition.

cond-mat.str-el↗

arXiv2023

Quantum states and intertwining phases in kagome materials

In solid materials, nontrivial topological states, electron correlations, and magnetism are central ingredients for realizing quantum properties, including unconventional superconductivity, charge and spin density waves, and quantum spin liquids. The Kagome lattice, made up of connected triangles and hexagons, can host these three ingredients simultaneously and has proven to be a fertile platform for studying diverse quantum phenomena including those stemming from the interplay of these ingredients. In this review, we introduce the fundamental properties of the Kagome lattice as well as discuss the complex observed phenomena seen in several emergent material systems such as the intertwining of charge order and superconductivity in some Kagome metals, modulation of magnetism and topology in some Kagome magnets, and symmetry breaking with Mott physics in the breathing Kagome insulators. We also highlight many open questions in the field as well as future research directions of Kagome systems.

cond-mat.str-el↗

arXiv2023

Anisotropic proximity-induced superconductivity and edge supercurrent in Kagome metal, K1-xV3Sb5

Materials with transition metals in triangular lattices are of great interest for their potential combination of strong correlation, exotic magnetism and electronic topology. Kagome nets are of particular importance since the discovery of geometrically frustrated magnetism and topological band structures in crystals like Herbertsmithite and Fe3Sn2, respectively. KV3Sb5 was discovered to be a layered topological metal with a Kagome net of vanadium. Here, we fabricated Josephson Junctions (JJ) of K1-xV3Sb5 and induced superconductivity over long junction lengths. Through magnetoresistance and current vs. phase measurements, we observed magnetic field sweeping direction dependent magnetoresistance, and an anisotropic interference pattern with a Fraunhofer pattern for in-plane magnetic field, but a suppression of critical current for out-of-plane magnetic field. These results indicate an anisotropic internal magnetic field in K1-xV3Sb5 which influences the superconducting coupling in the junction, possibly giving rise to spin-triplet superconductivity. In addition, the observation of long-lived fast oscillations shows evidence of spatially localized conducting channels arising from edge states. These observations pave the way for studying unconventional superconductivity and Josephson device based on Kagome metals with electron correlation and topology.

cond-mat.supr-con↗

arXiv2022

Electronic properties and phase transition in Kagome metal, Yb0.5Co3Ge3

The Kagome lattice is an important fundamental structure in condensed matter physics for investigating the interplay of electron correlation, topology, and frustrated magnetism. Recent work on Kagome metals in the AV3Sb5 (A = K, Rb, Cs) family, has shown a multitude of correlation-driven distortions, including symmetry breaking charge density waves and nematic superconductivity at low temperatures. Here we study the new Kagome metal Yb0.5Co3Ge3 and find a temperature-dependent kink in the resistivity that is highly similar to the AV3Sb5 behavior and is commensurate with an in-plane structural distortion of the Co Kagome lattice along with a doubling of the c-axis. The space group is found to lower from P6/mmm to P63/m below the transition temperature, breaking the in-plane mirror planes and C6 rotation, while gaining a screw axis along the c-direction. At very low temperatures, anisotropic negative magnetoresistance is observed, which may be related to anisotropic magnetism. This raises questions about the types of the distortions in Kagome nets and their resulting physical properties including superconductivity and magnetism.

cond-mat.str-el↗

arXiv2022

Realization of the field-free Josephson Diode

The superconducting analog to the semiconducting diode, the Josephson diode, has long been sought, with multiple avenues to realization proposed by theorists. Exhibiting magnetic-field free, single directional superconductivity with Josephson coupling of the supercurrent across a tunnel barrier, it would serve as the building-block for next-generation superconducting circuit technology. Here we realized the field-free Josephson diode using an inversion symmetry breaking heterostructure of $\mathrm{NbSe_2/Nb_3Br_8/NbSe_2}$. We demonstrate, for the first time without magnetic field, the junction can be superconducting in one direction while normal in the opposite direction. Based on that, half-wave rectification of a square-wave excitation was achieved with low switching current density ($~2.2\times 10^2 \mathrm{A/cm^2}$), high rectification ratio ($~10^4$) and high robustness (at least $10^4$ cycles). We also demonstrate symmetric $ΔI_\mathrm{c}$ (the difference between positive and negative critical currents) behavior with field and the expected Fraunhofer current phase relation of a Josephson junction. This realization raises fundamental questions about the Josephson effect through an insulator when breaking symmetry, and opens the door to ultralow power, high speed, superconducting circuits for logic and signal modulation.

cond-mat.supr-con↗

arXiv2021

Spin-orbit Torque Switching in an All-Van der Waals Heterostructure

Current-induced control of magnetization in ferromagnets using spin-orbit torque (SOT) has drawn attention as a new mechanism for fast and energy efficient magnetic memory devices. Energy-efficient spintronic devices require a spin-current source with a large SOT efficiency ($ξ$) and electrical conductivity ($σ$), and an efficient spin injection across a transparent interface. Herein, we use single crystals of the van der Waals (vdW) topological semimetal WTe$_2$ and vdW ferromagnet Fe$_3$GeTe$_2$ to satisfy the requirements in their all-vdW-heterostructure with an atomically sharp interface. The results exhibit values of $ξ{\approx}4.6$ and $σ{\approx}2.25{\times}10^5 Ω^{-1} m^{-1}$ for WTe$_2$. Moreover, we obtain the significantly reduced switching current density of $3.90{\times}10^6 A/cm^2$ at 150 K, which is an order of magnitude smaller than those of conventional heavy-metal/ ferromagnet thin films. These findings highlight that engineering vdW-type topological materials and magnets offers a promising route to energy-efficient magnetization control in SOT-based spintronics.

cond-mat.mes-hall↗