arXiv subjects

Merel L. R. van 't Hoff

Publications and source records attributed to Merel L. R. van 't Hoff.

At least 37 records · Page 2Linked to original sources

arXiv2021

The VLA/ALMA Nascent Disk and Multiplicity (VANDAM) Survey of Orion Protostars V. A Characterization of Protostellar Multiplicity

We characterize protostellar multiplicity in the Orion molecular clouds using ALMA 0.87~mm and VLA 9~mm continuum surveys toward 328 protostars. These observations are sensitive to projected spatial separations as small as $\sim$20~au, and we consider source separations up to 10$^4$~au as potential companions. The overall multiplicity fraction (MF) and companion fraction (CF) for the Orion protostars are 0.30$\pm$0.03 and 0.44$\pm$0.03, respectively, considering separations from 20 to 10$^4$~au. The MFs and CFs are corrected for potential contamination by unassociated young stars using a probabilistic scheme based on the surface density of young stars around each protostar. The companion separation distribution as a whole is double peaked and inconsistent with the separation distribution of solar-type field stars, while the separation distribution of Flat Spectrum protostars is consistent solar-type field stars. The multiplicity statistics and companion separation distributions of the Perseus star-forming region are consistent with those of Orion. Based on the observed peaks in the Class 0 separations at $\sim$100~au and $\sim$10$^3$~au, we argue that multiples with separations $<$500~au are likely produced by both disk fragmentation and turbulent fragmentation with migration, and those at $\ga$10$^3$~au result primarily from turbulent fragmentation. We also find that MFs/CFs may rise from Class 0 to Flat Spectrum protostars between 100 and 10$^3$~au in regions of high YSO density. This finding may be evidence for migration of companions from $>$10$^3$~au to $<$10$^3$~au, and that some companions between 10$^3$ and 10$^4$~au must be (or become) unbound.

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arXiv2021

Imaging the water snowline around protostars with water and HCO$^+$ isotopologues

The water snowline location in protostellar envelopes provides crucial information about the thermal structure and the mass accretion process as it can inform about the occurrence of recent ($\lesssim$1,000 yr) accretion bursts. In addition, the ability to image water emission makes these sources excellent laboratories to test indirect snowline tracers such as H$^{13}$CO$^+$. We study the water snowline in five protostellar envelopes in Perseus using a suite of molecular line observations taken with the Atacama Large Millimeter/submillimeter Array (ALMA) at $\sim$0.2$^{\prime\prime}-$0.7$^{\prime\prime}$ (60--210 au) resolution. B1-c provides a textbook example of compact H$_2^{18}$O ($3_{1,3}-2_{2,0}$) and HDO ($3_{1,2}-2_{2,1}$) emission surrounded by a ring of H$^{13}$CO$^+$ ($J=2-1$) and HC$^{18}$O$^+$ ($J=3-2$). Compact HDO surrounded by H$^{13}$CO$^+$ is also detected toward B1-bS. The optically thick main isotopologue HCO$^+$ is not suited to trace the snowline and HC$^{18}$O$^+$ is a better tracer than H$^{13}$CO$^+$ due to a lower contribution from the outer envelope. However, since a detailed analysis is needed to derive a snowline location from H$^{13}$CO$^+$ or HC$^{18}$O$^+$ emission, their true value as snowline tracer will lie in the application in sources where water cannot be readily detected. For protostellar envelopes, the most straightforward way to locate the water snowline is through observations of H$_2^{18}$O or HDO. Including all sub-arcsecond resolution water observations from the literature, we derive an average burst interval of $\sim$10,000 yr, but high-resolution water observations of a larger number of protostars is required to better constrain the burst frequency.

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arXiv2021

Molecules with ALMA at Planet-forming Scales (MAPS) V: CO gas distributions

Here we present high resolution (15-24 au) observations of CO isotopologue lines from the Molecules with ALMA on Planet-forming Scales (MAPS) ALMA Large Program. Our analysis employs $^{13}$CO and C$^{18}$O ($J$=2-1), (1-0), and C$^{17}$O (1-0) line observations of five protoplanetary disks. We retrieve CO gas density distributions, using three independent methods: (1) a thermo-chemical modeling framework based on the CO data, the broadband spectral energy distribution, and the mm-continuum emission; (2) an empirical temperature distribution based on optically thick CO lines; and (3) a direct fit to the C$^{17}$O hyperfine lines. Results from these methods generally show excellent agreement. The CO gas column density profiles of the five disks show significant variations in the absolute value and the radial shape. Assuming a gas-to-dust mass ratio of 100, all five disks have a global CO-to-H$_2$ abundance of 10-100 times lower than the ISM ratio. The CO gas distributions between 150-400 au match well with models of viscous disks, supporting the long-standing theory. CO gas gaps appear to be correlated with continuum gap locations, but some deep continuum gaps do not have corresponding CO gaps. The relative depths of CO and dust gaps are generally consistent with predictions of planet-disk interactions, but some CO gaps are 5-10 times shallower than predictions based on dust gaps. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.

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arXiv2021

Molecules with ALMA at Planet-forming Scales (MAPS) I: Program Overview and Highlights

Planets form and obtain their compositions in dust and gas-rich disks around young stars, and the outcome of this process is intimately linked to the disk chemical properties. The distributions of molecules across disks regulate the elemental compositions of planets, including C/N/O/S ratios and metallicity (O/H and C/H), as well as access to water and prebiotically relevant organics. Emission from molecules also encodes information on disk ionization levels, temperature structures, kinematics, and gas surface densities, which are all key ingredients of disk evolution and planet formation models. The Molecules with ALMA at Planet-forming Scales (MAPS) ALMA Large Program was designed to expand our understanding of the chemistry of planet formation by exploring disk chemical structures down to 10 au scales. The MAPS program focuses on five disks - around IM Lup, GM Aur, AS 209, HD 163296, and MWC 480 - in which dust substructures are detected and planet formation appears to be ongoing. We observed these disks in 4 spectral setups, which together cover ~50 lines from over 20 different species. This paper introduces the ApJS MAPS Special Issue by presenting an overview of the program motivation, disk sample, observational details, and calibration strategy. We also highlight key results, including discoveries of links between dust, gas, and chemical sub-structures, large reservoirs of nitriles and other organics in the inner disk regions, and elevated C/O ratios across most disks. We discuss how this collection of results is reshaping our view of the chemistry of planet formation.

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arXiv2021

Molecules with ALMA at Planet-forming Scales (MAPS). XV. Tracing protoplanetary disk structure within 20 au

Constraining the distribution of gas and dust in the inner 20 au of protoplanetary disks is difficult. At the same time, this region is thought to be responsible for most planet formation, especially around the water ice line at 3-10 au. Under the assumption that the gas is in a Keplerian disk, we use the exquisite sensitivity of the Molecules with ALMA at Planet-forming Scales (MAPS) ALMA large program to construct radial surface brightness profiles with a ~3 au effective resolution for the CO isotopologue J=2-1 lines using the line velocity profile. IM Lup reveals a central depression in 13CO and C18O that is ascribed to a pileup of ~500 $M_\oplus$ of dust in the inner 20 au, leading to a gas-to-dust ratio of around <10. This pileup is consistent with efficient drift of grains ($\gtrsim$ 100 $M_\oplus$ Myr$^{-1}$) and a local gas-to-dust ratio that suggests that the streaming instability could be active. The CO isotopologue emission in the GM Aur disk is consistent with a small (~15 au), strongly depleted gas cavity within the ~40 au dust cavity. The radial surface brightness profiles for both the AS 209 and HD 163296 disks show a local minimum and maximum in the C18O emission at the location of a known dust ring (~14 au) and gap (~10 au), respectively. This indicates that the dust ring has a low gas-to-dust ratio ($>$ 10) and that the dust gap is gas-rich enough to have optically thick C18O.

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arXiv2021

Molecules with ALMA at Planet-forming Scales (MAPS). VII. Sub-stellar O/H and C/H and super-stellar C/O in planet feeding gas

The elemental composition of the gas and dust in a protoplanetary disk influences the compositions of the planets that form in it. We use the Molecules with ALMA at Planet-forming Scales (MAPS) data to constrain the elemental composition of the gas at the locations of potentially forming planets. The elemental abundances are inferred by comparing source-specific gas-grain thermochemical models, with variable C/O ratios and small-grain abundances, from the DALI code with CO and C2H column densities derived from the high-resolution observations of the disks of AS 209, HD 163296, and MWC 480. Elevated C/O ratios (~2.0), even within the CO ice line, are necessary to match the inferred C2H column densities, over most of the pebble disk. Combined with constraints on the CO abundances in these systems, this implies that both the O/H and C/H ratios in the gas are substellar by a factor of 4-10, with the O/H depleted by a factor of 20-50, resulting in the high C/O ratios. This necessitates that even within the CO ice line, most of the volatile carbon and oxygen is still trapped on grains in the midplane. Planets accreting gas in the gaps of the AS 209, HD 163296, and MWC 480 disks will thus acquire very little carbon and oxygen after reaching the pebble isolation mass. In the absence of atmosphere-enriching events, these planets would thus have a strongly substellar O/H and C/H and superstellar C/O atmospheric composition.

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arXiv2021

Molecules with ALMA at Planet-forming Scales (MAPS) XIX. Spiral Arms, a Tail, and Diffuse Structures Traced by CO around the GM Aur Disk

The concentric gaps and rings commonly observed in protoplanetary disks in millimeter continuum emission have lent the impression that planet formation generally proceeds within orderly, isolated systems. While deep observations of spatially resolved molecular emission have been comparatively limited, they are increasingly suggesting that some disks interact with their surroundings while planet formation is underway. We present an analysis of complex features identified around GM Aur in $^{12}$CO $J=2-1$ images at a spatial resolution of $\sim40$ au. In addition to a Keplerian disk extending to a radius of $\sim550$ au, the CO emission traces flocculent spiral arms out to radii of $\sim$1200 au, a tail extending $\sim1800$ au southwest of GM Aur, and diffuse structures extending from the north side of the disk up to radii of $\sim1900$ au. The diffuse structures coincide with a "dust ribbon" previously identified in scattered light. The large-scale asymmetric gas features present a striking contrast with the mostly axisymmetric, multi-ringed millimeter continuum tracing the pebble disk. We hypothesize that GM Aur's complex gas structures result from late infall of remnant envelope or cloud material onto the disk. The morphological similarities to the SU Aur and AB Aur systems, which are also located in the L1517 cloud, provide additional support to a scenario in which interactions with the environment are playing a role in regulating the distribution and transport of material in all three of these Class II disk systems. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.

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arXiv2021

Which molecule traces what: chemical diagnostics of protostellar sources

The physical and chemical conditions in Class 0/I protostars are fundamental in unlocking the protostellar accretion process and its impact on planet formation. The aim is to determine which physical components are traced by different molecules at sub-arcsecond scales (100 - 400 au). We use a suite of Atacama Large Millimeter/submillimeter Array (ALMA) datasets in Band 6 (1 mm), Band 5 (1.8 mm) and Band 3 (3 mm) at spatial resolutions 0.5 - 3" for 16 protostellar sources. The protostellar envelope is well traced by C$^{18}$O, DCO$^+$ and N$_2$D$^+$, with the freeze-out of CO governing the chemistry at envelope scales. Molecular outflows are seen in classical shock tracers like SiO and SO, but ice-mantle products such as CH$_3$OH and HNCO released with the shock are also observed. The molecular jet is prominent not only in SiO and SO but also occasionally in H$_2$CO. The cavity walls show tracers of UV-irradiation such as C$_2$H c-C$_3$H$_2$ and CN. The hot inner envelope, apart from showing emission from complex organic molecules (COMs), also presents compact emission from small molecules like H$_2$S, SO, OCS and H$^{13}$CN, most likely related to ice sublimation and high-temperature chemistry. Sub-arcsecond millimeter-wave observations allow to identify those (simple) molecules that best trace each of the physical components of a protostellar system. COMs are found both in the hot inner envelope (high excitation lines) and in the outflows (lower-excitation lines) with comparable abundances. COMs can coexist with hydrocarbons in the same protostellar sources, but they trace different components. In the near future, mid-IR observations with JWST-MIRI will provide complementary information about the hottest gas and the ice mantle content, at unprecedented sensitivity and at resolutions comparable to ALMA for the same sources.

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arXiv2020

Temperature structures of embedded disks: young disks in Taurus are warm

The chemical composition of gas and ice in disks around young stars set the bulk composition of planets. In contrast to protoplanetary disks (Class II), young disks that are still embedded in their natal envelope (Class 0 and I) are predicted to be too warm for CO to freeze out, as has been confirmed observationally for L1527 IRS. To establish whether young disks are generally warmer than their more evolved counterparts, we observed five young (Class 0/I and Class I) disks in Taurus with the Atacama Large Millimeter/submillimeter Array (ALMA), targeting C$^{17}$O $2-1$, H$_2$CO $3_{1,2}-2_{1,1}$, HDO $3_{1,2}-2_{2,1}$ and CH$_3$OH $5_K-4_K$ transitions at $0.48^{\prime\prime} \times 0.31^{\prime\prime}$ resolution. The different freeze-out temperatures of these species allow us to derive a global temperature structure. C$^{17}$O and H$_2$CO are detected in all disks, with no signs of CO freeze-out in the inner $\sim$100 au, and a CO abundance close to $\sim$10$^{-4}$. H$_2$CO emission originates in the surface layers of the two edge-on disks, as witnessed by the especially beautiful V-shaped emission pattern in IRAS~04302+2247. HDO and CH$_3$OH are not detected, with column density upper limits more than 100 times lower than for hot cores. Young disks are thus found to be warmer than more evolved protoplanetary disks around solar analogues, with no CO freeze-out (or only in the outermost part of $\gtrsim$100 au disks) or CO processing. However, they are not as warm as hot cores or disks around outbursting sources, and therefore do not have a large gas-phase reservoir of complex molecules.

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arXiv2020

Carbon-grain sublimation: a new top-down component of protostellar chemistry

Earth's carbon deficit has been an outstanding problem in our understanding of the formation of our Solar System. A possible solution would be the sublimation of carbon grains at the so-called soot line (~300 K) early in the planet-formation process. Here, we argue that the most likely signatures of this process are an excess of hydrocarbons and nitriles inside the soot line, and a higher excitation temperature for these molecules compared to oxygen-bearing complex organics that desorb around the water snowline (~100 K). Such characteristics have been reported in the literature, for example, in Orion KL, although not uniformly, potentially due to differences in observational settings and analysis methods of different studies or related to the episodic nature of protostellar accretion. If this process is active, this would mean that there is a heretofore unknown component to the carbon chemistry during the protostellar phase that is acting from the top down - starting from the destruction of larger species - instead of from the bottom up from atoms. In the presence of such a top-down component, the origin of organic molecules needs to be re-explored.

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arXiv2019

Temperature profiles of young disk-like structures: The case of IRAS 16293A

Temperature is a crucial parameter in circumstellar disk evolution and planet formation, because it governs the resistance of the gas to gravitational instability and sets the chemical composition of the planet-forming material. We set out to determine the gas temperature of the young disk-like structure around the Class 0 protostar IRAS 16293$-$2422A. We use Atacama Large Millimeter/submillimeter Array (ALMA) observations of multiple H$_2$CS $J=7-6$ and $J=10-9$ lines from the Protostellar Interferometric Line Survey (PILS) to create a temperature map for the inner $\sim$200 AU of the disk-like structure. This molecule is a particularly useful temperature probe because transitions between energy levels with different $K_{\rm{a}}$ quantum numbers operate only through collisions. Based on the H$_2$CS line ratios, the temperature is between $\sim$100$-$175 K in the inner $\sim$150 AU, and drops to $\sim$75 K at $\sim$200 AU. At the current resolution (0.5$^{\prime\prime} \sim$70 AU), no jump is seen in the temperature at the disk-envelope interface. The temperature structure derived from H$_2$CS is consistent with envelope temperature profiles that constrain the temperature from 1000 AU scales down to $\sim$100 AU, but does not follow the temperature rise seen in these profiles at smaller radii. Higher angular resolution observations of optically thin temperature tracers are needed to establish whether cooling by gas-phase water, the presence of a putative disk or the dust optical depth influences the gas temperature at $\lesssim$100 AU scales. The temperature at 100 AU is higher in IRAS 16293A than in the embedded Class 0/I disk L1527, consistent with the higher luminosity of the former.

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arXiv2018

Methanol and its relation to the water snowline in the disk around the young outbursting star V883 Ori

We report the detection of methanol in the disk around the young outbursting star V883 Ori with the Atacama Large Millimeter/submillimeter Array (ALMA). Four transitions are observed with upper level energies ranging between 115 and 459 K. The emission is spatially resolved with the 0.14" beam and follows the Keplerian rotation previously observed for C$^{18}$O. Using a rotational diagram analysis, we find a disk-averaged column density of $\sim10^{17}$ cm$^{-2}$ and a rotational temperature of $\sim90-100$ K, suggesting that the methanol has thermally desorbed from the dust grains. We derive outer radii between 120 and 140 AU for the different transitions, compared to the 360 AU outer radius for C$^{18}$O. Depending on the exact physical structure of the disk, the methanol emission could originate in the surface layers beyond the water snowline. Alternatively, the bulk of the methanol emission originates inside the water snowline, which can then be as far out as ~100 AU, instead of 42 AU as was previously inferred from the continuum opacity. In addition, these results show that outbursting young stars like V883 Ori are good sources to study the ice composition of planet forming material through thermally desorbed complex molecules, which have proven to be hard to observe in more evolved protoplanetary disks.

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arXiv2018

Linking interstellar and cometary O$_2$: a deep search for $^{16}$O$^{18}$O in the solar-type protostar IRAS 16293--2422

Recent measurements carried out at comet 67P/C-G with the ${\it Rosetta}$ probe revealed that molecular oxygen, O$_2$, is the fourth most abundant molecule in comets. Models show that O$_2$ is likely of primordial nature, coming from the interstellar cloud from which our Solar System was formed. However, gaseous O$_2$ is an elusive molecule in the interstellar medium with only one detection towards quiescent molecular clouds, in the $ρ$ Oph A core. We perform a deep search for molecular oxygen, through the $2_1 - 0_1$ rotational transition at 234 GHz of its $^{16}$O$^{18}$O isotopologue, towards the warm compact gas surrounding the nearby Class 0 protostar IRAS 16293--2422 B with the ALMA interferometer. The targeted $^{16}$O$^{18}$O transition is surrounded by two brighter transitions at $\pm 1$ km s$^{-1}$ relative to the expected $^{16}$O$^{18}$O transition frequency. After subtraction of these two transitions, residual emission at a 3$σ$ level remains, but with a velocity offset of $0.3 - 0.5$ km s$^{-1}$ relative to the source velocity, rendering the detection "tentative". We derive the O$_2$ column density for two excitation temperatures $T_{\rm ex}$ of 125 and 300 K, as indicated by other molecules, in order to compare the O$_2$ abundance between IRAS16293 and comet 67P/C-G. Assuming that $^{16}$O$^{18}$O is not detected and using methanol CH$_3$OH as a reference species, we obtain a [O$_2$]/[CH$_3$OH] abundance ratio lower than $2-5$, depending on the assumed $T_{\rm ex}$, a three to four times lower abundance than the [O$_2$]/[CH$_3$OH] ratio of $5-15$ found in comet 67P/C-G. Such a low O$_2$ abundance could be explained by the lower temperature of the dense cloud precursor of IRAS16293 with respect to the one at the origin of our Solar System that prevented an efficient formation of O$_2$ in interstellar ices.

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arXiv2018

Unveiling the physical conditions of the youngest disks: A warm embedded disk in L1527

[Abridged] Protoplanetary disks have been studied extensively, both physically and chemically, to understand the environment in which planets form. However, the first steps of planet formation are likely to occur already when the protostar and disk are still embedded in their natal envelope. The initial conditions for planet formation may thus be provided by these young embedded disks, of which the physical and chemical structure is poorly characterized. We aim to constrain the midplane temperature structure, one of the critical unknowns, of the embedded disk around L1527. In particular, we set out to determine whether there is an extended cold outer region where CO is frozen out, as is the case for Class II disks. We use archival ALMA data to directly observe the midplane of the near edge-on L1527 disk. Optically thick $^{13}$CO ($J=2-1$) and C$^{18}$O ($J=2-1$) emission is observed throughout the disk and inner envelope, while N$_2$D$^+ (J=3-2$), which can only be abundant when CO is frozen out, is not detected. Both CO isotopologues have brightness temperatures $\gtrsim$ 25 K along the midplane. Disk and envelope emission can be disentangled kinematically, because the largest velocities are reached in the disk. A power law radial temperature profile constructed using the highest midplane temperature at these velocities suggest that the temperature is above 20 K out to at least 75 AU, and possibly throughout the entire 125 AU disk. Radiative transfer models show that a model without CO freeze-out in the disk matches the C$^{18}$O observations better than a model with the CO snowline at $\sim$70 AU. In addition, there is no evidence for a large (order of magnitude) depletion of CO. The disk around L1527 is likely to be warm enough to have CO present in the gas phase throughout the disk, suggesting that young embedded disks can indeed be warmer than the more evolved Class II disks.

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arXiv2018

Imaging the water snowline in a protostellar envelope with H$^{13}$CO$^+$

Snowlines are key ingredients for planet formation. Providing observational constraints on the locations of the major snowlines is therefore crucial for fully connecting planet compositions to their formation mechanism. Unfortunately, the most important snowline, that of water, is very difficult to observe directly in protoplanetary disks due to its close proximity to the central star. Based on chemical considerations, HCO$^+$ is predicted to be a good chemical tracer of the water snowline, because it is particularly abundant in dense clouds when water is frozen out. This work maps the optically thin isotopologue H$^{13}$CO$^+$ ($J=3-2$) toward the envelope of the low-mass protostar NGC1333-IRAS2A (observed with NOEMA at ~0.9" resolution), where the snowline is at larger distance from the star than in disks. The H$^{13}$CO$^+$ emission peaks ~2" northeast of the continuum peak, whereas the previously observed H$_2^{18}$O shows compact emission on source. Quantitative modeling shows that a decrease in H$^{13}$CO$^+$ abundance by at least a factor of six is needed in the inner ~360 AU to reproduce the observed emission profile. Chemical modeling predicts indeed a steep increase in HCO$^+$ just outside the water snowline; the 50% decrease in gaseous H$_2$O at the snowline is not enough to allow HCO$^+$ to be abundant. This places the water snowline at 225 AU, further away from the star than expected based on the 1D envelope temperature structure for NGC1333-IRAS2A. In contrast, DCO$^+$ observations show that the CO snowline is at the expected location, making an outburst scenario unlikely. The spatial anticorrelation of the H$^{13}$CO$^+$ and H$_2^{18}$O emission provide a proof of concept that H$^{13}$CO$^+$ can be used as a tracer of the water snowline.

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arXiv2017

Imaging the water snowline in protostellar envelopes

Determining the locations of the major snowlines in protostellar environments is crucial to fully understand the planet formation process and its outcome. Despite being located far enough from the central star to be spatially resolved with ALMA, the CO snowline remains difficult to detect directly in protoplanetary disks. Instead, its location can be derived from N$_2$H$^+$ emission, when chemical effects like photodissociation of CO and N$_2$ are taken into account. The water snowline is even harder to observe than that for CO, because in disks it is located only a few AU from the protostar, and from the ground only the less abundant isotopologue H$_2^{18}$O can be observed. Therefore, using an indirect chemical tracer, as done for CO, may be the best way to locate the water snowline. A good candidate tracer is HCO$^+$, which is expected to be particularly abundant when its main destructor, H$_2$O, is frozen out. Comparison of H$_2^{18}$O and H$^{13}$CO$^+$ emission toward the envelope of the Class 0 protostar IRAS2A shows that the emission from both molecules is spatially anticorrelated, providing a proof of concept that H$^{13}$CO$^+$ can indeed be used to trace the water snowline in systems where it cannot be imaged directly.

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arXiv2017

Unveiling the physical and chemical conditions in the young disk around L1527

Planets form in disks around young stars. The planet formation process may start when the protostar and disk are still deeply embedded within their infalling envelope. However, unlike more evolved protoplanetary disks, the physical and chemical structure of these young embedded disks are still poorly constrained. We have analyzed ALMA data for $^{13}$CO, C$^{18}$O and N$_2$D$^+$ to constrain the temperature structure, one of the critical unknowns, in the disk around L1527. The spatial distribution of $^{13}$CO and C$^{18}$O, together with the kinetic temperature derived from the optically thick $^{13}$CO emission and the non-detection of N$_2$D$^+$, suggest that this disk is warm enough ($\gtrsim$ 20 K) to prevent CO freeze-out.

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arXiv2016

Robustness of N2H+ as tracer of the CO snowline

[Abridged] Snowlines in protoplanetary disks play an important role in planet formation and composition. Since the CO snowline is difficult to observe directly with CO emission, its location has been inferred in several disks from spatially resolved ALMA observations of DCO+ and N2H+. N2H+ is considered to be a good tracer of the CO snowline based on astrochemical considerations predicting an anti-correlation between N2H+ and gas-phase CO. In this work, the robustness of N2H+ as a tracer of the CO snowline is investigated. A simple chemical network is used in combination with the radiative transfer code LIME to model the N2H+ distribution and corresponding emission in the disk around TW Hya. The assumed CO and N2 abundances, corresponding binding energies, cosmic ray ionization rate, and degree of large-grain settling are varied to determine the effects on the N2H+ emission and its relation to the CO snowline. For the adopted physical structure of the TW Hya disk and molecular binding energies for pure ices, the balance between freeze-out and thermal desorption predicts a CO snowline at 19 AU, corresponding to a CO midplane freeze-out temperature of 20 K. A model with a total, i.e. gas plus ice, CO abundance of 3e-6 with respect to H2 fits the position of the emission peak observed by Qi et al. 2013 for the TW Hya disk. However, the relationship between N2H+ and the CO snowline is more complicated than generally assumed: for the investigated parameters, the N2H+ column density peaks at least 5 AU outside the CO snowline. Moreover, the N2H+ emission can peak much further out, as far as ~50 AU beyond the snowline. Hence, chemical modeling, as done here, is necessary to derive a CO snowline location from N2H+ observations.

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