arXiv subjects

Merve Baksi

Publications and source records attributed to Merve Baksi.

5 recordsLinked to original sources

arXiv2025

Superconductivity in spin-orbit coupled BaBi$_3$ formed by in situ reduction of bismuthate films

Oxygen-scavenging at oxide heterointerfaces has emerged as a powerful route for stabilizing metastable phases that exhibit interesting phenomena, including high-mobility two-dimensional electron gases and high T$_{c}$ superconductivity. We investigate structural and chemical interactions at the heterointerface formed between Al or Eu and the charged-ordered insulator, BaBiO$_3$, leading to emergent superconductivity at 6 K. A combination of X-ray diffraction and electron microscopy measurements shows that oxygen scavenging by the Eu and Al adlayers leads to the formation of superconducting intermetallic BaBi$_3$ in nominal Eu/BaBiO$_3$ and Al/BaBiO$_3$ bilayers. Anisotropic magnetotransport measurements and current-voltage signatures of quasi two-dimensional superconductivity are observed. The mechanisms behind quasi-two-dimensional superconductivity and the role of disorder remain to be clarified. These findings highlight the potential for the use of in situ reduction of bismuthate heterostructures as a platform for stabilizing materials with exotic functional properties. Additionally, the strong spin-orbit coupling at the Bi sites may pave the way for the realization of high T$_{c}$ topological superconductivity.

cond-mat.supr-con↗

arXiv2025

Electrostatic control of quantum phases in KTaO3-based planar constrictions

Two-dimensional electron gases (2DEGs) formed at complex oxide interfaces offer a unique platform to engineer quantum nanostructures. However, scalable fabrication of locally addressable devices in these materials remains challenging. Here, we demonstrate an efficient fabrication approach by patterning narrow constrictions in a superconducting KTaO3-based heterostructure. The constrictions are individually tunable via the coplanar side gates formed within the same 2DEG plane. Our technique leverages the high dielectric permittivity of KTaO3 (epsilon_r ~ 5000) to achieve strong electrostatic modulation of the superconducting 2DEG. Transport measurements through the constriction reveal a range of transport regimes: Within the superconducting state, we demonstrate efficient modulation of the critical current and Berezinskii Kosterlitz Thouless (BKT) transition temperature at the weak link. Further tuning of the gate voltage reveals an unexpectedly regular Coulomb blockade pattern. All of these states are achievable with a side gate voltage |V_SG| < 1 V. The fabrication process is scalable and versatile, enabling a platform both to make superconducting field-effect transistors and to study a wide array of physical phenomena present at complex oxide interfaces.

cond-mat.supr-con↗

arXiv2025

Violation of Pauli Limit at KTaO3(110) Interfaces

The superconducting order parameter at the KTaO3 interfaces and its dependence on interface orientation remains a subject of debate. The superconductivity at these interfaces exhibits strong resilience against in-plane magnetic field and violates Pauli limit. The interface orientation dependence of critical field and violation of Pauli limit, however, have not been investigated. To address this problem, we grew epitaxial LaMnO3/KTaO3 heterostructures using molecular beam epitaxy. We show that superconductivity is extremely robust against the in-plane magnetic field. Our results indicate that the interface orientation, despite impacting the critical temperature, does not affect the ratio of critical field to the Pauli limiting field. These results offer opportunities to engineer superconductors which are resilient against magnetic field.

cond-mat.supr-con↗

arXiv2024

The structure of Ferroelectric BaBiO$_3$/BaTiO$_3$ Interfaces grown by Molecular Beam Epitaxy

We investigate the lattice structure of heterostructures comprising of ferroelectric BaTiO$_3$ (BTO) thin films and BaBiO$_3$ (BBO), the insulating parent-compound of the high Tc superconductor. Motivated by theoretical predictions of exotic phenomena in BBO-based heterostructures including interfacial conductivity, superconductivity and topologically-protected states, we synthesize BTO/BBO heterostructures by molecular beam epitaxy and characterize their structural properties by in-situ reflection high energy electron diffraction and ex-situ high-resolution synchrotron X-ray diffraction, Raman spectroscopy and piezoforce microscopy. For heterostructures with 4 uc BBO layers, reciprocal space maps indicate strain relaxation relative to the SrTiO$_3$ substrate. We observe a strong tetragonal distortion for heterostructures with 2 unit cells BBO coherently strained to the BTO layers. Raman spectroscopy measurements indicate a suppression of the breathing mode distortion associated with the charge density wave in bulk BBO. The ferroelectric properties of the system are confirmed by piezoforce microscopy measurements. The coupling between the ferroelectric polarization and the electronic states in BBO may potentially serve as a starting point for tunable electrostatic doping to realize the novel predicted states in the atomically-thin BBO layers.

cond-mat.mtrl-sci↗

arXiv2023

In-situ scattering studies of superconducting vacancy-ordered monoclinic TiO thin films

We investigate the structural and transport properties of vacancy-ordered monoclinic superconducting $\mathrm{TiO}$ thin films grown by molecular beam epitaxy. The evolution of the crystal structure during growth is monitored by in-situ synchrotron X-ray diffraction. Long-range ordering of Ti and O vacancies in the disordered cubic phase stabilizes the vacancy-ordered monoclinic TiO phase. The reduced structural disorder arising from vacancy-ordering is correlated with a superconductor-metal transition (SMT) in contrast to the superconductor-insulator transition (SIT) observed in cubic TiO, orthorhombic $Ti_2O_3$, and the Magneli $γ-Ti_3O_5$ and $γ-Ti_4O_7$ phase. Magnetoresistance measurements for the SIT phases indicate superconducting fluctuations persisting in the normal phase. These results confirm the role of disorder related to Ti and O vacancies and structural inhomogeneity in determining the electronic properties of the normal state of titanium oxide-based superconductors.

cond-mat.supr-con↗