arXiv subjects

Michael J. Radke

Publications and source records attributed to Michael J. Radke.

3 recordsLinked to original sources

arXiv2026

Hydrolyzed Hazes on Water-rich Exoplanets: Optical Constants and Detectability

Observations of temperate sub-Neptunes suggest active chemical environments, finding evidence of both water vapor and photochemical hazes in their atmospheres. Hazes formed in water-rich atmospheres are chemically complex, containing molecules relevant to prebiotic chemistry, and their strong optical opacity obscures sought-after gaseous molecular absorption features. While many studies have investigated haze formation and properties across diverse atmospheric conditions, little is known about the evolution of these hazes in their environment once formed. In particular, interactions with water can drive hydrolysis reactions that alter haze composition and optical behavior, affecting our interpretations of habitability and observational spectroscopy. Here, we perform hydrolysis experiments on haze analogs of temperate water-rich exoplanets and measure their optical properties. Transmittance measurements from 0.4 to 28.5 $μ$m reveal changes in key functional groups after hydrolysis, along with an overall increase in sample absorbance. We report the derived optical constants for use in observational and modeling studies. Through synthetic atmospheric spectra, we demonstrate the need for physically informed haze optical properties in models, consistent with expected planetary conditions. The increased absorptivity and high imaginary refractive index of hydrolyzed hazes almost completely flatten features in model spectra, presenting critical consequences for atmospheric characterization of water-rich sub-Neptunes.

astro-ph.EP↗

arXiv2026

Plan 9: Detecting Atmospheric Deterrence Against Interstellar Monsters

Exoplanet atmospheres are usually discussed as tracers of climate, chemistry, and habitability, but they may also preserve signatures of planetary defense. We consider three folklore-motivated deterrents against monsters: reduced organosulfur gases as anti-hematophage repellents, argentiferous reflective aerosols as anti-lycanthropic countermeasures, and haline aerosols as a counting problem for specters. We show that globally-mixed garlic-smelly levels of DMS/DMDS could produce observable mid-infrared transmission features, that silver hazes would show up as anomalous optical brightening, and that sea-salt lofting sustained by strong near-surface winds appears as muted spectra. None of these signatures is unique, which is precisely the observational challenge. A defended world may first appear merely sulfur-rich, bright, or hazy. Therefore, some atmospheres may encode not only biosignatures, but also evidence that the local biosphere has stopped being afraid of the dark.

astro-ph.EP↗

arXiv2021

Triton Haze Analogues: the Role of Carbon Monoxide in Haze Formation

Triton is the largest moon of the Neptune system and possesses a thin nitrogen atmosphere with trace amounts of carbon monoxide and methane, making it of similar composition to that of the dwarf planet Pluto. Like Pluto and Saturn's moon Titan, Triton has a haze layer thought to be composed of organics formed through photochemistry. Here, we perform atmospheric chamber experiments of 0.5% carbon monoxide and 0.2% methane in molecular nitrogen at 90 K and 1 mbar to generate Triton haze analogues. We then characterize the physical and chemical properties of these particles. We measure their production rate, their bulk composition with combustion analysis, their molecular composition with very high resolution mass spectrometry, and their transmission and reflectance from the optical to the near-infrared (0.4 to 5 microns) with Fourier Transform Infrared (FTIR) spectroscopy. We compare these properties to existing measurements of Triton's tenuous atmosphere and its surface, as well as contextualize these results in view of all the small, hazy nitrogen-rich worlds of our solar system. We find that carbon monoxide present at greater mixing ratios than methane in the atmosphere can lead to significantly oxygen- and nitrogen-rich haze materials. These Triton haze analogues have clear observable signatures in their near-infrared spectra, which may help us differentiate the mechanisms behind haze formation processes across diverse solar system bodies.

astro-ph.EP↗