arXiv subjects

Michael Krisch

Publications and source records attributed to Michael Krisch.

24 records · Page 2Linked to original sources

arXiv2007

Anharmonic effects in MgB2? A comparative inelastic X-ray scattering and Raman study

We study anharmonic effects in MgB2 by comparing Inelastic X-ray and Ramanscattering together with ab-initio calculations. Using high statistics and high q resolution measurements we show that the E2g mode linewidth is independent of temperature along Gamma-A. We show, contrary to previous claims, that the Raman-peak energy decreases as a function of increasing temperature, a behaviour inconsistent with all the anharmonic ab-initio calculations of the E2g mode at Gamma available in literature. These findings and the excellent agreement between the X-ray measured and ab-initio calculated phonon spectra suggest that anharmonicity is not the main mechanism determining the temperature behaviour of the Raman-peak energy. The Raman E2g peak position and linewidth can be explained by large dynamical effects in the phonon self-energy. In light of the present findings, the commonly accepted explanation of the reduced isotope effect in terms of anharmonic effects needs to be reconsidered.

cond-mat.mtrl-sci↗

arXiv2006

Liquid-like behavior of supercritical fluids

The high frequency dynamics of fluid oxygen have been investigated by Inelastic X-ray Scattering. In spite of the markedly supercritical conditions ($T\approx 2 T_c$, $P>10^2 P_c$), the sound velocity exceeds the hydrodynamic value of about 20%, a feature which is the fingerprint of liquid-like dynamics. The comparison of the present results with literature data obtained in several fluids allow us to identify the extrapolation of the liquid vapor-coexistence line in the ($P/P_c$, $T/T_c$) plane as the relevant edge between liquid- and gas-like dynamics. More interestingly, this extrapolation is very close to the non metal-metal transition in hot dense fluids, at pressure and temperature values as obtained by shock wave experiments. This result points to the existence of a connection between structural modifications and transport properties in dense fluids.

cond-mat.dis-nn↗

arXiv2004

Low-q dispersion of transverse acoustic phonons in YBa$_2$Cu$_3$O$_{7-δ}$

High-resolution ($ΔE$=1.3 meV) inelastic X-ray scattering (IXS) in optimally doped untwinned YBa$_2$Cu$_3$O$_{7-δ}$ single crystals show that the dispersion of transverse acoustic phonons in the a-direction remains linear with no softening due to bending modes in the long wavelength limit, down to q=0.02. The sound velocity is found to be 2700 +/- 70 m s$^{-1}$, in excellent agreement with ultrasound measurements, and unchanged upon cooling from room temperature to 98 K. These results rule out a strong coupling between bending dynamics of the CuO$_2$ planes and charge carriers in cuprates.

cond-mat.supr-con↗

arXiv2003

Phonon dispersion in 1-layer cuprate HgBa2CuO4+d

We investigate the low energy acoustical and optical modes in $\mathrm{HgBa_2CuO_{4+δ}}$ using inelastic x-ray scattering (IXS). The experimental phonon dispersion and the dynamical structure factor are compared with an atomic shell model, and the set of the atomic potentials obtained are discussed. Our results are also compared with those obtained by Raman spectroscopy and with density-of-state data measured by inelastic neutron scattering.

cond-mat.supr-con↗

arXiv2003

Phonon dispersion and lifetimes in MgB2

We measure phonon dispersion and linewidth in a single crystal of MgB_2 along the Gamma-A, Gamma-M and A-L directions using inelastic X-Ray scattering. We use Density Functional Theory to compute the effect of both electron-phonon coupling and anharmonicity on the linewidth, obtaining excellent agreement with experiment. Anomalous broadening of the E_2g phonon mode is found all along Gamma-A. The dominant contribution to the linewidth is always the electron-phonon coupling.

cond-mat.supr-con↗

arXiv2000

Observation of Umklapp processes in non-crystalline materials

Umklapp processes are known to exist in cristalline materials, where they control important properties such as thermal conductivity, heat capacity and electrical conductivity. In this work we report the provocative observation of Umklapp processes in a non-periodical system, namely liquid Lithium. The lack of a well defined periodicity seems then not to prevent the existence of these scattering processes mechanisms provided that the local order of the systems i.e. the maxima of the static structure factor supply the equivalent of a reciprocal lattice vector in the case of cristalline materials.

cond-mat.dis-nn↗