arXiv subjects

Michael Lorke

Publications and source records attributed to Michael Lorke.

31 records · Page 2Linked to original sources

arXiv2018

Hybridized indirect excitons in MoS2/WS2 heterobilayers

Ensembles of indirect or interlayer excitons (IXs) are intriguing systems to explore classical and quantum phases of interacting bosonic ensembles. IXs are composite bosons that feature enlarged lifetimes due to the reduced overlap of the electron-hole wave functions. We demonstrate electric Field control of indirect excitons in MoS2/WS2 hetero-bilayers embedded in a field effect structure with few-layer hexagonal boron nitrite as insulator and few-layer graphene as gate-electrodes. The different strength of the excitonic dipoles and a distinct temperature dependence identify the indirect excitons to stem from optical interband transitions with electrons and holes located in different valleys of the hetero-bilayer featuring highly hybridized electronic states. For the energetically lowest emission lines, we observe a field-dependent level anticrossing at low temperatures. We discuss this behavior in terms of coupling of electronic states from the two semiconducting monolayers resulting in spatially delocalized excitons of the hetero-bilayer behaving like an artificial van der Waals solid. Our results demonstrate the design of novel nano-quantum materials prepared from artificial van der Waals solids with the possibility to in-situ control their physical properties via external stimuli such as electric fields.

cond-mat.mes-hall↗

arXiv2018

Interplay of structural design and interaction processes in tunnel-injection semiconductor lasers

Tunnel-injection lasers promise various advantages in comparison to conventional laser designs. In this paper, we present a theoretical analysis for the physics of the tunnel-injection process in quantum-dot based laser devices. We describe the carrier dynamics in terms of scattering between states of the coupled system consisting of injector quantum-well, tunnel-barrier, and quantum-dots. Our analysis demonstrates how current quantum-dot based lasers can benefit from the tunnel-injection design. We find that the often assumed LO-phonon resonance condition for the level alignment only weakly influences the injection rate of carriers into the quantum-dot states. On the other hand, our investigations show that the energetic alignment of quantum-dot and quantum-well states modifies the injection efficiency, as it controls the hybridization strength. Our description of tunneling includes the phonon-mediated and the Coulomb scattering contributions and is based on material realistic electronic structure calculations.

physics.app-ph↗

arXiv2018

Electronic and Optical Properties of Functionalized GaN (10-10) Surfaces using Hybrid-Density Functionals

Adsorption of small ligands on semiconductor surfaces is a possible route to modify these surfaces so that they can be used in biosensing and optoelectronic devices. In this work we perform density-functional theory calculations of electronic and optical properties of small ligands on GaN-(10$\bar1$0) surfaces. From the investigated anchor groups we show that thiol groups introduce states into the GaN band gap. However, these state are not optically active, at least for these perfect surfaces. This means that more realistic surfaces need to be considered to suggest how surface modification can enhance the optical properties of GaN non-polar surfaces.

cond-mat.mtrl-sci↗

arXiv2018

Hybrid density-functional theory calculations of electronic and optical properties of mercaptocarboxylic acids on ZnO $(10{\overline 1}0)$ surfaces

In this work we investigate the electronic properties of mercaptocarboxylic acids with several carbon chain lengths adsorbed on ZnO-(10-10) surfaces via density functional theory calculations using semi-local and hybrid exchange-correlation functionals. Amongst the investigated structures, we identify the monodentate adsorption mode to be stable. Moreover, this mode introduces optically active states in the ZnO gap, is further confirmed by the calculation of the dielectric function at PBE0 and TD-PBE0 levels. One interesting finding is that adsorption mode and the dielectric properties of the hybrid system are both rather insensitive to the chain length, since the acceptor molecular state is very localized on the sulphur atom. This indicates that even small molecules can be used to stabilize ZnO surface and to enhance its functionality for opto-electronic applications.

cond-mat.mtrl-sci↗

arXiv2018

Prospects and limitations of transition-metal dichalcogenide laser gain materials

Nanolasers operate with a minimal amount of active material and low losses. In this regime, single layers of transition-metal dichalcogenides (TMDs) are being investigated as next generation gain materials due to their high quantum efficiency. We provide results from microscopic gain calculations of highly excited TMD monolayers and specify requirements to achieve lasing with four commonly used TMD semiconductors. Our approach includes band-structure renormalizations due to excited carriers that trigger a direct-to-indirect band-gap transition. As a consequence, we predict a rollover for the gain that limits the excitation regime where laser operation is possible. A parametrization of the peak gain is provided that is used in combination with a rate-equation theory to discuss consequences for experimentally accessible laser characteristics.

cond-mat.mes-hall↗

arXiv2018

Performance of quantum-dot-based tunnel-injection lasers: A theoretical analysis

Tunnel-injection lasers promise advantages in modulation bandwidth and temperature stability in comparison to conventional laser designs. In this paper, we present results of a microscopic theory for laser properties of tunnel-injection devices and a comparison to a conventional quantum-dot laser structure. In general, the modulation bandwidth of semiconductor lasers is affected by the steady-state occupations of electrons and holes via the presence of spectral hole burning. For tunnel-injection lasers with InGaAs quantum dot emitting at the telecom wavelength of 1,55$μ$m, we demonstrate that the absence of spectral hole burning favors this concept over conventional quantum-dot based lasers.

cond-mat.mes-hall↗

arXiv2018

Highly Efficient Carrier Multiplication in van der Waals layered Materials

Carrier multiplication (CM), a photo-physical process to generate multiple electron-hole pairs by exploiting excess energy of free carriers, is explored for efficient photovoltaic conversion of photons from the blue solar band, predominantly wasted as heat in standard solar cells. Current state-of-the-art approaches with nanomaterials have demonstrated improved CM but are not satisfactory due to high energy loss and inherent difficulties with carrier extraction. Here, we report ultra-efficient CM in van der Waals (vdW) layered materials that commences at the energy conservation limit and proceeds with nearly 100% conversion efficiency. A small threshold energy, as low as twice the bandgap, was achieved, marking an onset of quantum yield with enhanced carrier generation. Strong Coulomb interactions between electrons confined within vdW layers allow rapid electron-electron scattering to prevail over electron-phonon scattering. Additionally, the presence of electron pockets spread over momentum space could also contribute to the high CM efficiency. Combining with high conductivity and optimal bandgap, these superior CM characteristics identify vdW materials for third-generation solar cell.

cond-mat.mes-hall↗

arXiv2017

Non-invasive control of excitons in two-dimensional materials

We investigate how external screening shapes excitons in two-dimensional (2d) semiconductors embedded in laterally structured dielectric environments. An atomic scale view of these elementary excitations is developed using models which apply to a variety of materials including transition metal dichalcogenides (TMDCs). We find that structured dielectrics imprint a peculiar potential energy landscape on excitons in these systems: While the ground-state exciton is least influenced, higher excitations are attracted towards regions with high dielectric constant of the environment. This landscape is "inverted" in the sense that low energy excitons are less strongly affected than their higher energy counterparts. Corresponding energy variations emerge on length scales of the order of a few unit cells. This opens the prospect of trapping and guiding of higher excitons by means of tailor-made dielectric substrates on ultimately small spatial scales.

cond-mat.mtrl-sci↗

arXiv2017

Coupled Mode Theory for Semiconductor Nanowires

We present a model to describe the spatiotemporal evolution of guided modes in semiconductor nanowires based on a coupled mode formalism. Light-matter interaction is modelled based on semiconductor Bloch equations, including many-particle effects in the screened Hartree-Fock approximation. Appropriate boundary conditions are used to incorporate reflections at waveguide endfacets, thus allowing for the simulation of nanowire lasing. We compute the emission characteristics and temporal dynamics of CdS and ZnO nanowire lasers and compare our results both to Finite-Difference Time-Domain simulations and to experimental data. Finally, we explore the dependence of the lasing emission on the nanowire cavity and on the materials relaxation time.

physics.optics↗

arXiv2016

Nonequilibrium Carrier Dynamics in Transition Metal Dichalcogenide Semiconductors

When exploring new materials for their potential in (opto)electronic device applications, it is important to understand the role of various carrier interaction and scattering processes. Research on transition metal dichalcogenide (TMD) semiconductors has recently progressed towards the realisation of working devices, which involve light-emitting diodes, nanocavity lasers, and single-photon emitters. In these two-dimensional atomically thin semiconductors, the Coulomb interaction is known to be much stronger than in quantum wells of conventional semiconductors like GaAs, as witnessed by the 50 times larger exciton binding energy. The question arises, whether this directly translates into equivalently faster carrier-carrier Coulomb scattering of excited carriers. Here we show that a combination of ab-initio band-structure and many-body theory predicts carrier relaxation on a 50-fs time scale, which is less than an order of magnitude faster than in quantum wells. These scattering times compete with the recently reported sub-ps exciton recombination times, thus making it harder to achieve population inversion and lasing.

cond-mat.mtrl-sci↗

arXiv2014

Light-Matter Interaction and Lasing in Semiconductor Nanowires: A combined FDTD and Semiconductor Bloch Equation Approach

We present a time-domain model for the simulation of light-matter interaction in semiconductors in arbitrary geometries and across a wide range of excitation conditions. The electromagnetic field is treated classically using the finite-difference time-domain method. The polarization and occupation numbers of the semiconductor material are described using the semiconductor Bloch equations including many-body effects in the screened Hartree-Fock approximation. Spontaneous emission noise is introduced using stochastic driving terms. As an application of the model, we present simulations of the dynamics of a nanowire laser including optical pumping, seeding by spontaneous emission and the selection of lasing modes.

physics.optics↗

arXiv2013

Dynamical properties of nanolasers based on few discrete emitters

We investigate the dynamical properties of nanolasers comprising a few two-level emitters coupled to an optical cavity. A set of rate equations is derived, which agree very well with a solution of the full master equation model and makes it simple to investigate the properties of the system. Using a linearized version of these rate equations, we can analytically express the response of the nanolaser to a modulation of the pumping rate. These results are compared to the modulation response obtained directly from the master equation using a novel method. Using the rate equation method, we calculate the modulation bandwidth and show that, contrary to conventional semiconductor lasers, the nanolaser is typically over-damped and displays a dip in the modulation bandwidth as the two-level systems become inverted. Both these features can be traced back to the modeling of the emitters as two-level systems that are incoherently pumped.

physics.optics↗

arXiv2005

Coulomb scattering in nitride based self-assembled quantum-dot systems

We study the carrier capture and relaxation due to Coulomb scattering in nitride-based quantum dots on the basis of population kinetics. For the states involved in the scattering processes the combined influence of the quantum-confined Stark effect and many-body renormalizations is taken into account. The charge separation induced by the built-in field has important consequences on the capture and relaxation rates. It is shown that its main effect comes through the renormalization of the energies of the states involved in the collisions, and leads to an increase in the scattering efficency.

cond-mat.mes-hall↗