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Michael R. Line

Publications and source records attributed to Michael R. Line.

At least 55 records · Page 3Linked to original sources

The metal-poor atmosphere of a Neptune/Sub-Neptune planet progenitor

Young transiting exoplanets offer a unique opportunity to characterize the atmospheres of fresh and evolving products of planet formation. We present the transmission spectrum of V1298 Tau b; a 23 Myr old warm Jovian sized planet orbiting a pre-main sequence star. We detect a primordial atmosphere with an exceptionally large atmospheric scale height and a water vapour absorption at 5$σ$ level of significance. We estimate a mass and density upper limit (24$\pm$5$M_{\oplus}$, 0.12gm/$cm^{3}$ respectively). V1298 Tau b is one of the lowest density planets discovered till date. We retrieve a low atmospheric metallicity (logZ=$-0.1^{+0.66}_{-0.72}$ solar), consistent with solar/sub-solar values. Our findings challenge the expected mass-metallicity from core-accretion theory. Our observations can be explained by in-situ formation via pebble accretion together with ongoing evolutionary mechanisms. We do not detect methane, which hints towards a hotter than expected interior from just the formation entropy of this planet. Our observations suggest that V1298 Tau b is likely to evolve into a Neptune/sub-Neptune type of planet.

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Inferring Chemical Disequilibrium Biosignatures for Proterozoic Earth-Like Exoplanets

Chemical disequilibrium quantified via available free energy has previously been proposed as a potential biosignature. However, exoplanet biosignature remote sensing work has not yet investigated how observational uncertainties impact the ability to infer a life-generated available free energy. We pair an atmospheric retrieval tool to a thermodynamics model to assess the detectability of chemical disequilibrium signatures of Earth-like exoplanets, emphasizing the Proterozoic Eon where atmospheric abundances of oxygen-methane disequilibrium pairs may have been relatively high. Retrieval model studies applied across a range of gas abundances revealed that order-of-magnitude constraints on disequilibrium energy are achieved with simulated reflected-light observations at the high abundance scenario and signal-to-noise ratios (50) while weak constraints are found at moderate SNRs (20\,--\,30) for med\,--\,low abundance cases. Furthermore, the disequilibrium energy constraints are improved by modest thermal information encoded in water vapor opacities at optical and near-infrared wavelengths. These results highlight how remotely detecting chemical disequilibrium biosignatures can be a useful and metabolism-agnostic approach to biosignature detection.

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Methane Throughout the Atmosphere of the Warm Exoplanet WASP-80b

The abundances of major carbon and oxygen bearing gases in the atmospheres of giant exoplanets provide insights into atmospheric chemistry and planet formation processes. Thermochemistry suggests that methane should be the dominant carbon-bearing species below $\sim$1000 K over a range of plausible atmospheric compositions; this is the case for the Solar System planets and has been confirmed in the atmospheres of brown dwarfs and self-luminous directly imaged exoplanets. However, methane has not yet been definitively detected with space-based spectroscopy in the atmosphere of a transiting exoplanet, but a few detections have been made with ground-based, high-resolution transit spectroscopy including a tentative detection for WASP-80b. Here we report transmission and emission spectra spanning 2.4-4.0 micrometers of the 825 K warm Jupiter WASP-80b taken with JWST's NIRCam instrument, both of which show strong evidence for methane at greater than 6-sigma significance. The derived methane abundances from both viewing geometries are consistent with each other and with solar to sub-solar C/O and ~5$\times$ solar metallicity, which is consistent with theoretical predictions.

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Modelling the effect of 3D temperature and chemistry on the cross-correlation signal of transiting ultra-hot Jupiters: A study of 5 chemical species on WASP-76b

Ultra-hot Jupiters are perfect targets for transmission spectroscopy. However, their atmospheres feature strong spatial variations in temperature, chemistry, dynamics, cloud coverage, and scale height. This makes transit observations at high spectral resolution challenging to interpret. In this work, we model the cross-correlation signal of five chemical species (Fe, CO, H$_\text{2}$O, OH, and TiO) on WASP-76b, a benchmark ultra-hot Jupiter. We compute phase-dependent high-resolution transmission spectra of 3D SPARC/MITgcm models. The spectra are obtained with gCMCRT, a 3D Monte-Carlo radiative-transfer code. We find that, on top of atmospheric dynamics, the phase-dependent Doppler shift of the absorption lines in the planetary rest frame is shaped by the combined effect of planetary rotation and the unique 3D spatial distribution of chemical species. For species probing the dayside (e.g., refractories or molecules like CO and OH), the two effects act in tandem, leading to increasing blueshifts with orbital phase. For species that are depleted on the dayside (e.g., H$_\text{2}$O and TiO), the two effects act in an opposite manner, and could lead to increasing redshifts during the transit. This behaviour yields species-dependent offsets from a planet's expected $K_\text{p}$ value that can be much larger than planetary wind speeds. The offsets are usually negative for refractory species. We provide an analytical formula to estimate the size of a planet's $K_\text{p}$ offsets, which can serve as a prior for atmospheric retrievals. We conclude that observing the phase-resolved absorption signal of multiple species is key to constraining the 3D thermochemical structure and dynamics of ultra-hot Jupiters.

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Earth as a Transiting Exoplanet: A Validation of Transmission Spectroscopy and Atmospheric Retrieval Methodologies for Terrestrial Exoplanets

The James Webb Space Telescope (JWST) will enable the search for and characterization of terrestrial exoplanet atmospheres in the habitable zone via transmission spectroscopy. However, relatively little work has been done to use solar system data, where ground truth is known, to validate spectroscopic retrieval codes intended for exoplanet studies, particularly in the limit of high resolution and high signal-to-noise (S/N). In this work, we perform such a validation by analyzing a high S/N empirical transmission spectrum of Earth using a new terrestrial exoplanet atmospheric retrieval model with heritage in Solar System remote sensing and gaseous exoplanet retrievals. We fit the Earth's 2-14 um transmission spectrum in low resolution (R=250 at 5 um) and high resolution (R=100,000 at 5 um) under a variety of assumptions about the 1D vertical atmospheric structure. In the limit of noiseless transmission spectra, we find excellent agreement between model and data (deviations < 10%) that enable the robust detection of H2O, CO2, O3, CH4, N2, N2O, NO2, HNO3, CFC-11, and CFC-12 thereby providing compelling support for the detection of habitability, biosignature, and technosignature gases in the atmosphere of the planet using an exoplanet-analog transmission spectrum. Our retrievals at high spectral resolution show a marked sensitivity to the thermal structure of the atmosphere, trace gas abundances, density-dependent effects, such as collision-induced absorption and refraction, and even hint at 3D spatial effects. However, we used synthetic observations of TRAPPIST-1e to verify that the use of simple 1D vertically homogeneous atmospheric models will likely suffice for JWST observations of terrestrial exoplanets transiting M dwarfs.

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Brown Dwarf Retrievals on FIRE!: Atmospheric Constraints and Lessons Learned from High Signal-to-Noise Medium Resolution Spectroscopy of a T9 Dwarf

Brown dwarf spectra offer vital testbeds for our understanding of the chemical and physical processes that sculpt substellar atmospheres. Recently, atmospheric retrieval approaches have been applied to a number of low-resolution (R~100) spectra of brown dwarfs, yielding constraints on the abundances of chemical species and temperature structures of these atmospheres. Medium-resolution (R~1e3) spectra of brown dwarfs offer significant additional insight, as molecular features are more easily disentangled from one another and the thermal structure of the upper atmosphere is more readily probed. We present results from a GPU-based retrieval analysis of a high signal-to-noise, medium-resolution (R~6000) FIRE spectrum from 0.85-2.5 microns of a T9 dwarf. At 60x higher spectral resolution than previous brown dwarf retrievals, a number of novel challenges arise. We examine the strong effect of different opacity sources on our retrieved constraints, in particular for CH4. Furthermore, we find that flaws in the data such as errors from order stitching can greatly bias our results. We compare these results to those obtained for a R~100 spectrum of the same object, revealing how constraints on atmospheric abundances and temperatures improve by an order of magnitude or more (depending on the species) with increased spectral resolution. In particular, we precisely constrain the abundance of H2S, which is undetectable at lower spectral resolution. While these medium-resolution retrievals offer the potential of precise, stellar-like constraints on atmospheric abundances (~0.02 dex), our retrieved radius is unphysically small (R~0.50 R$_{Jup}$), indicating lingering shortcomings with our modeling framework. This work is an initial investigation into brown dwarf retrievals at medium spectral resolution, offering guidance for future ground-based studies and JWST observations of substellar objects.

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Awesome SOSS: Transmission Spectroscopy of WASP-96b with NIRISS/SOSS

The future is now - after its long-awaited launch in December 2021, JWST began science operations in July 2022 and is already revolutionizing exoplanet astronomy. The Early Release Observations (ERO) program was designed to provide the first images and spectra from JWST, covering a multitude of science cases and using multiple modes of each on-board instrument. Here, we present transmission spectroscopy observations of the hot-Saturn WASP-96b with the Single Object Slitless Spectroscopy (SOSS) mode of the Near Infrared Imager and Slitless Spectrograph, observed as part of the ERO program. As the SOSS mode presents some unique data reduction challenges, we provide an in-depth walk-through of the major steps necessary for the reduction of SOSS data: including background subtraction, correction of 1/f noise, and treatment of the trace order overlap. We furthermore offer potential routes to correct for field star contamination, which can occur due to the SOSS mode's slitless nature. By comparing our extracted transmission spectrum with grids of atmosphere models, we find an atmosphere metallicity between 1x and 5x solar, and a solar carbon-to-oxygen ratio. Moreover, our models indicate that no grey cloud deck is required to fit WASP-96b's transmission spectrum, but find evidence for a slope shortward of 0.9$μ$m, which could either be caused by enhanced Rayleigh scattering or the red wing of a pressure-broadened Na feature. Our work demonstrates the unique capabilities of the SOSS mode for exoplanet transmission spectroscopy and presents a step-by-step reduction guide for this new and exciting instrument.

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A broadband thermal emission spectrum of the ultra-hot Jupiter WASP-18b

Close-in giant exoplanets with temperatures greater than 2,000 K (''ultra-hot Jupiters'') have been the subject of extensive efforts to determine their atmospheric properties using thermal emission measurements from the Hubble and Spitzer Space Telescopes. However, previous studies have yielded inconsistent results because the small sizes of the spectral features and the limited information content of the data resulted in high sensitivity to the varying assumptions made in the treatment of instrument systematics and the atmospheric retrieval analysis. Here we present a dayside thermal emission spectrum of the ultra-hot Jupiter WASP-18b obtained with the NIRISS instrument on JWST. The data span 0.85 to 2.85 $μ$m in wavelength at an average resolving power of 400 and exhibit minimal systematics. The spectrum shows three water emission features (at $>$6$σ$ confidence) and evidence for optical opacity, possibly due to H$^-$, TiO, and VO (combined significance of 3.8$σ$). Models that fit the data require a thermal inversion, molecular dissociation as predicted by chemical equilibrium, a solar heavy element abundance (''metallicity'', M/H = 1.03$_{-0.51}^{+1.11}$ $\times$ solar), and a carbon-to-oxygen (C/O) ratio less than unity. The data also yield a dayside brightness temperature map, which shows a peak in temperature near the sub-stellar point that decreases steeply and symmetrically with longitude toward the terminators.

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Emergent Spectral Fluxes of Hot Jupiters: an Abrupt Rise in Day Side Brightness Temperature Under Strong Irradiation

We study the emergent spectral fluxes of transiting hot Jupiters, using secondary eclipses from Spitzer. To achieve a large and uniform sample, we have re-analyzed all secondary eclipses for all hot Jupiters observed by Spitzer at 3.6- and/or 4.5 microns. Our sample comprises 457 eclipses of 122 planets, including eclipses of 13 planets not previously published. We use these eclipse depths to calculate the spectral fluxes emergent from the exoplanetary atmospheres, and thereby infer temperature and spectral properties of hot Jupiters. We find that an abrupt rise in brightness temperature, similar to a phase change, occurs on the day side atmospheres of the population at an equilibrium temperature between 1714K and 1818K (99-percent confidence limits). The amplitude of the rise is 291 +/-49 Kelvins, and two viable causes are the onset of magnetic drag that inhibits longitudinal heat redistribution, and/or the rapid dissipation of day side clouds. We also study hot Jupiter spectral properties with respect to metallicity and temperature inversions. Models exhibiting 4.5 micron emission from temperature inversions reproduce our fluxes statistically for the hottest planets, but the transition to emission is gradual, not abrupt. The Spitzer fluxes are sensitive to metallicity for planets cooler than approximately 1200 Kelvins, and most of the hot Jupiter population falls between model tracks having solar to 30X-solar metallicity.

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Early Release Science of the exoplanet WASP-39b with JWST NIRCam

Measuring the metallicity and carbon-to-oxygen (C/O) ratio in exoplanet atmospheres is a fundamental step towards constraining the dominant chemical processes at work and, if in equilibrium, revealing planet formation histories. Transmission spectroscopy provides the necessary means by constraining the abundances of oxygen- and carbon-bearing species; however, this requires broad wavelength coverage, moderate spectral resolution, and high precision that, together, are not achievable with previous observatories. Now that JWST has commenced science operations, we are able to observe exoplanets at previously uncharted wavelengths and spectral resolutions. Here we report time-series observations of the transiting exoplanet WASP-39b using JWST's Near InfraRed Camera (NIRCam). The long-wavelength spectroscopic and short-wavelength photometric light curves span 2.0 - 4.0 $μ$m, exhibit minimal systematics, and reveal well-defined molecular absorption features in the planet's spectrum. Specifically, we detect gaseous H$_2$O in the atmosphere and place an upper limit on the abundance of CH$_4$. The otherwise prominent CO$_2$ feature at 2.8 $μ$m is largely masked by H$_2$O. The best-fit chemical equilibrium models favour an atmospheric metallicity of 1-100$\times$ solar (i.e., an enrichment of elements heavier than helium relative to the Sun) and a sub-stellar carbon-to-oxygen (C/O) ratio. The inferred high metallicity and low C/O ratio may indicate significant accretion of solid materials during planet formation or disequilibrium processes in the upper atmosphere.

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Early Release Science of the Exoplanet WASP-39b with JWST NIRSpec G395H

Measuring the abundances of carbon and oxygen in exoplanet atmospheres is considered a crucial avenue for unlocking the formation and evolution of exoplanetary systems. Access to an exoplanet's chemical inventory requires high-precision observations, often inferred from individual molecular detections with low-resolution space-based and high-resolution ground-based facilities. Here we report the medium-resolution (R$\sim$600) transmission spectrum of an exoplanet atmosphere between 3-5 $μ$m covering multiple absorption features for the Saturn-mass exoplanet WASP-39b, obtained with JWST NIRSpec G395H. Our observations achieve 1.46x photon precision, providing an average transit depth uncertainty of 221 ppm per spectroscopic bin, and present minimal impacts from systematic effects. We detect significant absorption from CO$_2$ (28.5$σ$) and H$_2$O (21.5$σ$), and identify SO$_2$ as the source of absorption at 4.1 $μ$m (4.8$σ$). Best-fit atmospheric models range between 3 and 10x solar metallicity, with sub-solar to solar C/O ratios. These results, including the detection of SO$_2$, underscore the importance of characterising the chemistry in exoplanet atmospheres, and showcase NIRSpec G395H as an excellent mode for time series observations over this critical wavelength range.

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Early Release Science of the exoplanet WASP-39b with JWST NIRISS

Transmission spectroscopy provides insight into the atmospheric properties and consequently the formation history, physics, and chemistry of transiting exoplanets. However, obtaining precise inferences of atmospheric properties from transmission spectra requires simultaneously measuring the strength and shape of multiple spectral absorption features from a wide range of chemical species. This has been challenging given the precision and wavelength coverage of previous observatories. Here, we present the transmission spectrum of the Saturn-mass exoplanet WASP-39b obtained using the SOSS mode of the NIRISS instrument on the JWST. This spectrum spans $0.6 - 2.8 μ$m in wavelength and reveals multiple water absorption bands, the potassium resonance doublet, as well as signatures of clouds. The precision and broad wavelength coverage of NIRISS-SOSS allows us to break model degeneracies between cloud properties and the atmospheric composition of WASP-39b, favoring a heavy element enhancement ("metallicity") of $\sim 10 - 30 \times$ the solar value, a sub-solar carbon-to-oxygen (C/O) ratio, and a solar-to-super-solar potassium-to-oxygen (K/O) ratio. The observations are best explained by wavelength-dependent, non-gray clouds with inhomogeneous coverage of the planet's terminator.

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A strong H- opacity signal in the near-infrared emission spectrum of the ultra-hot Jupiter KELT-9b

We present the analysis of a spectroscopic secondary eclipse of the hottest transiting exoplanet detected to date, KELT-9b, obtained with the Wide Field Camera 3 aboard the Hubble Space Telescope. We complement these data with literature information on stellar pulsations and Spitzer/Infrared Array Camera and Transiting Exoplanet Survey Satellite eclipse depths of this target to obtain a broadband thermal emission spectrum. Our extracted spectrum exhibits a clear turnoff at 1.4$μ$m. This points to H$^{-}$ bound-free opacities shaping the spectrum. To interpret the spectrum, we perform grid retrievals of self-consistent 1D equilibrium chemistry forward models, varying the composition and energy budget. The model with solar metallicity and C/O ratio provides a poor fit because the H$^{-}$ signal is stronger than expected, requiring an excess of electrons. This pushes our retrievals toward high atmospheric metallicities ($[M/H]=1.98^{+0.19}_{-0.21}$) and a C/O ratio that is subsolar by 2.4$σ$. We question the viability of forming such a high-metallicity planet, and therefore provide other scenarios to increase the electron density in this atmosphere. We also look at an alternative model in which we quench TiO and VO. This fit results in an atmosphere with a slightly subsolar metallicity and subsolar C/O ratio ($[M/H]=-0.22^{+0.17}_{-0.13}$, log(C/O)$=-0.34^{+0.19}_{-0.34}$). However, the required TiO abundances are disputed by recent high-resolution measurements of the same planet.

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Unifying High- and Low-resolution Observations to Constrain the Dayside Atmosphere of KELT-20b/MASCARA-2b

We present high-resolution dayside thermal emission observations of the exoplanet KELT-20b/MASCARA-2b using the MAROON-X spectrograph. Applying the cross-correlation method with both empirical and theoretical masks and a retrieval analysis, we confirm previous detections of Fe\,\textsc{i} emission lines and we detect Ni\,\textsc{i} for the first time in the planet (at 4.7$σ$ confidence). We do not see evidence for additional species in the MAROON-X data, including notably predicted thermal inversion agents TiO and VO, their atomic constituents Ti\,\textsc{i} and V\,\textsc{i}, and previously claimed species Fe\,\textsc{ii} and Cr\,\textsc{i}. We also perform a joint retrieval with existing \textit{Hubble Space Telescope}/WFC3 spectroscopy and \textit{Spitzer}/IRAC photometry. This allows us to place bounded constraints on the abundances of Fe\,\textsc{i}, H$_2$O, and CO, and to place a stringent upper limit on the TiO abundance. The results are consistent with KELT-20b having a solar to slightly super-solar composition atmosphere in terms of the bulk metal enrichment, and the carbon-to-oxygen and iron-to-oxygen ratios. However, the TiO volume mixing ratio upper limit (10$^{-7.6}$ at 99\% confidence) is inconsistent with this picture, which, along with the non-detection of Ti\,\textsc{i}, points to sequestration of Ti species, possibly due to nightside condensation. The lack of TiO but the presence of a large H$_2$O emission feature in the WFC3 data is challenging to reconcile within the context of 1D self-consistent, radiative-convective models.

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The Roasting Marshmallows Program with IGRINS on Gemini South I: Composition and Climate of the Ultra Hot Jupiter WASP-18 b

We present high-resolution dayside thermal emission observations of the exoplanet WASP-18b using IGRINS on Gemini South. We remove stellar and telluric signatures using standard algorithms, and we extract the planet signal via cross correlation with model spectra. We detect the atmosphere of WASP-18b at a signal-to-noise ratio (SNR) of 5.9 using a full chemistry model, measure H2O (SNR=3.3), CO (SNR=4.0), and OH (SNR=4.8) individually, and confirm previous claims of a thermal inversion layer. The three species are confidently detected (>4$σ$) with a Bayesian inference framework, which we also use to retrieve abundance, temperature, and velocity information. For this ultra-hot Jupiter (UHJ), thermal dissociation processes likely play an important role. Retrieving abundances constant with altitude and allowing the temperature-pressure profile to freely adjust results in a moderately super-stellar carbon to oxygen ratio (C/O=0.75^{+0.14}_{-0.17}) and metallicity ([M/H]=1.03^{+0.65}_{-1.01}). Accounting for undetectable oxygen produced by thermal dissociation leads to C/O=0.45^{+0.08}_{-0.10} and [M/H]=1.17^{+0.66}_{-1.01}. A retrieval that assumes radiative-convective-thermochemical-equilibrium and naturally accounts for thermal dissociation constrains C/O<0.34 (2$σ$) and [M/H]=0.48^{+0.33}_{-0.29}, in line with the chemistry of the parent star. Looking at the velocity information, we see a tantalising signature of different Doppler shifts at the level of a few km/s for different molecules, which might probe dynamics as a function of altitude and location on the planet disk. Our results demonstrate that ground-based, high-resolution spectroscopy at infrared wavelengths can provide meaningful constraints on the compositions and climate of highly irradiated planets. This work also elucidates potential pitfalls with commonly employed retrieval assumptions when applied to UHJ spectra.

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Identification of carbon dioxide in an exoplanet atmosphere

Carbon dioxide (CO2) is a key chemical species that is found in a wide range of planetary atmospheres. In the context of exoplanets, CO2 is an indicator of the metal enrichment (i.e., elements heavier than helium, also called "metallicity"), and thus formation processes of the primary atmospheres of hot gas giants. It is also one of the most promising species to detect in the secondary atmospheres of terrestrial exoplanets. Previous photometric measurements of transiting planets with the Spitzer Space Telescope have given hints of the presence of CO2 but have not yielded definitive detections due to the lack of unambiguous spectroscopic identification. Here we present the detection of CO2 in the atmosphere of the gas giant exoplanet WASP-39b from transmission spectroscopy observations obtained with JWST as part of the Early Release Science Program (ERS). The data used in this study span 3.0 to 5.5 μm in wavelength and show a prominent CO2 absorption feature at 4.3 μm (26σ significance). The overall spectrum is well matched by one-dimensional, 10x solar metallicity models that assume radiative-convective-thermochemical equilibrium and have moderate cloud opacity. These models predict that the atmosphere should have water, carbon monoxide, and hydrogen sulfide in addition to CO2, but little methane. Furthermore, we also tentatively detect a small absorption feature near 4.0 μm that is not reproduced by these models.

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The SPHINX M-dwarf Spectral Grid. I. Benchmarking New Model Atmospheres to Derive Fundamental M-Dwarf Properties

About 70-80% of stars in our solar and galactic neighborhood are M dwarfs. They span a range of low masses and temperatures relative to solar-type stars, facilitating molecule formation throughout their atmospheres. Standard stellar atmosphere models primarily designed for FGK stars face challenges when characterizing broadband molecular features in spectra of cool stars. Here, we introduce SPHINX--a new 1-D self-consistent radiative-convective thermochemical equilibrium chemistry model grid of atmospheres and spectra for M dwarfs in low-resolution (R~250). We incorporate the latest pre-computed absorption cross-sections with pressure-broadening for key molecules dominant in late-K, early/main-sequence-M stars. We then validate our grid models by acquiring fundamental properties (Teff, log(g), [M/H], radius, and C/O) for 10 benchmark M+G binary stars with known host metallicities and 10 M dwarfs with interferometrically measured angular diameters. Incorporating a Gaussian-process inference tool Starfish, we account for correlated and systematic noise in low-resolution (spectral stitching of SpeX, SNIFS, and STIS) observations and derive robust estimates of fundamental M dwarf atmospheric parameters. Additionally, we assess the influence of photospheric heterogeneity on acquired [M/H] and find that it could explain some deviations from observations. We also probe whether the model-assumed convective mixing-length parameter influences inferred radii, effective temperature, and [M/H] and again find that may explain discrepancies between interferometry observations and model-derived stellar parameters for cooler M dwarfs. Mainly, we show the unique strength in leveraging broadband molecular absorption features occurring in low-resolution M dwarf spectra and demonstrate the ability to improve constraints on fundamental properties of exoplanet hosts and late brown dwarf companions.

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A Uniform Retrieval Analysis of Ultra-cool Dwarfs. IV. A Statistical Census from 50 Late-T Dwarfs

The spectra of brown dwarfs are key to exploring the chemistry and physics that take place in their atmospheres. Late-T dwarf spectra are particularly diagnostic due to their relatively cloud-free atmospheres and deep molecular bands. With the use of powerful atmospheric retrieval tools applied to the spectra of these objects, direct constraints on molecular/atomic abundances, gravity, and vertical thermal profiles can be obtained enabling a broad exploration of the chemical/physical mechanisms operating in their atmospheres. We present a uniform retrieval analysis on low-resolution IRTF SpeX near-IR spectra of a sample of 50 T dwarfs, including new observations as part of a recent volume-limited survey. This analysis more than quadruples the sample of T dwarfs with retrieved temperature profiles and abundances (H$_2$O, CH$_4$, NH$_3$, K and subsequent C/O and metallicities). We are generally able to constrain effective temperatures to within 50K, volume mixing ratios for major species to within 0.25dex, atmospheric metallicities [M/H] to within 0.2, and C/O ratios to within 0.2. We compare our retrieved constraints on the thermal structure, chemistry, and gravities of these objects with predictions from self-consistent radiative-convective equilibrium models and find, in general though with substantial scatter, consistency with solar composition chemistry and thermal profiles of the neighboring stellar FGK population. Objects with notable discrepancies between the two modeling techniques and potential mechanisms for their differences, be they related to modeling approach or physically motivated, are discussed more thoroughly in the text.

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