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Michael R. Line

Publications and source records attributed to Michael R. Line.

At least 109 records · Page 6Linked to original sources

The Transiting Exoplanet Community Early Release Science Program for JWST

The James Webb Space Telescope (JWST) presents the opportunity to transform our understanding of planets and the origins of life by revealing the atmospheric compositions, structures, and dynamics of transiting exoplanets in unprecedented detail. However, the high-precision, time-series observations required for such investigations have unique technical challenges, and prior experience with other facilities indicates that there will be a steep learning curve when JWST becomes operational. In this paper we describe the science objectives and detailed plans of the Transiting Exoplanet Community Early Release Science (ERS) Program, which is a recently approved program for JWST observations early in Cycle 1. The goal of this project, for which the obtained data will have no exclusive access period, is to accelerate the acquisition and diffusion of technical expertise for transiting exoplanet observations with JWST, while also providing a compelling set of representative datasets that will enable immediate scientific breakthroughs. The Transiting Exoplanet Community ERS Program will exercise the time-series modes of all four JWST instruments that have been identified as the consensus highest priorities, observe the full suite of transiting planet characterization geometries (transits, eclipses, and phase curves), and target planets with host stars that span an illustrative range of brightnesses. The observations in this program were defined through an inclusive and transparent process that had participation from JWST instrument experts and international leaders in transiting exoplanet studies. Community engagement in the project will be centered on a two-phase Data Challenge that culminates with the delivery of planetary spectra, time-series instrument performance reports, and open-source data analysis toolkits in time to inform the agenda for Cycle 2 of the JWST mission.

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Community targets for JWST's early release science program: evaluation of WASP-63b

We present observations of WASP-63b by the Hubble Space Telescope (HST) as part of "A Preparatory Program to Identify the Single Best Transiting Exoplanet for JWST Early Release Science". WASP-63b is one of the community targets under consideration for the James Webb Space Telescope (JWST) Early Release Science (ERS) program. We present a spectrum derived from a single observation by HST Wide Field Camera 3 in the near infrared. We engaged groups across the transiting exoplanet community to participate in the analysis of the data and present results from each. There is general agreement amongst all results that we find an H2O absorption feature with 3.5-4.0 sigma significance. However, the feature is muted in comparison to a clear atmosphere at solar composition. Although the detection of the water feature is robust, the reasons for the muting of this feature are ambiguous due to a degeneracy between clouds and composition. The data does not yield robust detections of any molecular species other than H2O. The group was motivated to perform an additional set of retrieval exercises to investigate an apparent bump in the spectrum at ~ 1.55 um. We explore possible disequilibrium chemistry and find this feature is consistent with super-solar HCN abundance but it is questionable if the required mixing ratio of HCN is chemically and physically plausible. The ultimate goal of this study is to vet WASP-63b as a potential community target to best demonstrate the capabilities and systematics of JWST instruments for transiting exoplanet science. In the case of WASP-63b, the presence of a detectable water feature indicates that WASP-63b remains a plausible target for ERS observations.

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Global Climate and Atmospheric Composition of the Ultra-Hot Jupiter WASP-103b from HST and Spitzer Phase Curve Observations

We present thermal phase curve measurements for the hot Jupiter WASP-103b observed with Hubble/WFC3 and Spitzer/IRAC. The phase curves have large amplitudes and negligible hotspot offsets, indicative of poor heat redistribution to the nightside. We fit the phase variation with a range of climate maps and find that a spherical harmonics model generally provides the best fit. The phase-resolved spectra are consistent with blackbodies in the WFC3 bandpass, with brightness temperatures ranging from $1880\pm40$ K on the nightside to $2930 \pm 40$ K on the dayside. The dayside spectrum has a significantly higher brightness temperature in the Spitzer bands, likely due to CO emission and a thermal inversion. The inversion is not present on the nightside. We retrieved the atmospheric composition and found the composition is moderately metal-enriched ($\mathrm{[M/H]} = 23^{+29}_{-13}\times$ solar) and the carbon-to-oxygen ratio is below 0.9 at $3\,σ$ confidence. In contrast to cooler hot Jupiters, we do not detect spectral features from water, which we attribute to partial H$_2$O dissociation. We compare the phase curves to 3D general circulation models and find magnetic drag effects are needed to match the data. We also compare the WASP-103b spectra to brown dwarfs and young directly imaged companions and find these objects have significantly larger water features, indicating that surface gravity and irradiation environment play an important role in shaping the spectra of hot Jupiters. These results highlight the 3D structure of exoplanet atmospheres and illustrate the importance of phase curve observations for understanding their complex chemistry and physics.

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A HST/WFC3 Thermal Emission Spectrum of the Hot Jupiter HAT-P-7b

Secondary eclipse observations of several of the hottest hot Jupiters show featureless, blackbody-like spectra or molecular emission features, which are consistent with thermal inversions being present in those atmospheres. Theory predicts a transition between warmer atmospheres with thermal inversions and cooler atmospheres without inversions, but the exact transition point is unknown. In order to further investigate this issue, we observed two secondary eclipses of the hot Jupiter HAT-P-7b with the Hubble Space Telescope (HST) WFC3 instrument and combined these data with previous Spitzer and Kepler secondary eclipse observations. The HST and Spitzer data can be well fit by a blackbody with $T=2692 \pm 14$ K, and the Kepler data point constrains the geometric albedo to $A_{g}=0.077 \pm 0.006$. We modeled these data with a 3D GCM and 1D self-consistent forward models. The 1D models indicate that the atmosphere has a thermal inversion, weak heat redistribution, and water dissociation that limits the range of pressures probed. This result suggests that WFC3 observations of HAT-P-7b and possibly some other ultra-hot Jupiters appear blackbody-like because they probe a region near the tropopause where the atmospheric temperature changes slowly with pressure. Additionally, the 1D models constrain the atmospheric metallicity ($[\text{M/H}]=-0.87^{+0.38}_{-0.34}$) and the carbon-to-oxygen ratio (C/O $<1$ at 99 % confidence). The solar composition 3D GCM matches the Spitzer data but generally underpredicts the flux in the WFC3 bandpass and cannot reproduce its featureless shape. This discrepancy could be explained by high atmospheric drag or nightside clouds, and may be better understood through further observation with the James Webb Space Telescope (JWST).

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Water, High-Altitude Condensates, and Possible Methane Depletion in the Atmosphere of the Warm Super-Neptune WASP-107b

The super-Neptune exoplanet WASP-107b is an exciting target for atmosphere characterization. It has an unusually large atmospheric scale height and a small, bright host star, raising the possibility of precise constraints on its current nature and formation history. We report the first atmospheric study of WASP-107b, a Hubble Space Telescope measurement of its near-infrared transmission spectrum. We determined the planet's composition with two techniques: atmospheric retrieval based on the transmission spectrum and interior structure modeling based on the observed mass and radius. The interior structure models set a $3\,σ$ upper limit on the atmospheric metallicity of $30\times$ solar. The transmission spectrum shows strong evidence for water absorption ($6.5\,σ$ confidence), and the retrieved water abundance is consistent with expectations for a solar abundance pattern. The inferred carbon-to-oxygen ratio is subsolar at $2.7\,σ$ confidence, which we attribute to possible methane depletion in the atmosphere. The spectral features are smaller than predicted for a cloud-free composition, crossing less than one scale height. A thick condensate layer at high altitudes (0.1 - 3 mbar) is needed to match the observations. We find that physically motivated cloud models with moderate sedimentation efficiency ($f_\mathrm{sed} = 0.3$) or hazes with a particle size of 0.3 $μ$m reproduce the observed spectral feature amplitude. Taken together, these findings serve as an illustration of the diversity and complexity of exoplanet atmospheres. The community can look forward to more such results with the high precision and wide spectral coverage afforded by future observing facilities.

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H- Opacity and Water Dissociation in the Dayside Atmosphere of the Very Hot Gas Giant WASP-18 b

We present one of the most precise emission spectra of an exoplanet observed so far. We combine five secondary eclipses of the hot Jupiter WASP-18 b (Tday=2900K) that we secured between 1.1 and 1.7 micron with the WFC3 instrument aboard the Hubble Space Telescope. Our extracted spectrum (S/N=50, R=40) does not exhibit clearly identifiable molecular features but is poorly matched by a blackbody spectrum. We complement this data with previously published Spitzer/IRAC observations of this target and interpret the combined spectrum by computing a grid of self-consistent, 1D forward models, varying the composition and energy budget. At these high temperatures, we find there are important contributions to the overall opacity from H- ions, as well as the removal of major molecules by thermal dissociation (including water), and thermal ionization of metals. These effects were omitted in previous spectral retrievals for very hot gas giants, and we argue that they must be included to properly interpret the spectra of these objects. We infer a new metallicity and C/O ratio for WASP-18 b, and find them well constrained to be solar ([M/H]=-0.01 (0.35), C/O<0.85 at 3 sigma confidence level), unlike previous work but in line with expectations for giant planets. The best fitting self-consistent temperature-pressure profiles are inverted, resulting in an emission feature at 4.5 micron seen in the Spitzer photometry. These results further strengthen the evidence that the family of very hot gas giant exoplanets commonly exhibit thermal inversions.

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Strategies for Constraining the Atmospheres of Temperate Terrestrial Planets with JWST

TESS is expected to discover dozens of temperate terrestrial planets orbiting M dwarfs whose atmospheres could be followed up with the James Webb Space Telescope (JWST). Currently, the TRAPPIST-1 system serves as a benchmark to determine the feasibility and resources required to yield atmospheric constraints. We assess these questions and leverage an information content analysis to determine observing strategies for yielding high precision spectroscopy in transmission and emission. Our goal is to guide observing strategies of temperate terrestrial planets in preparation for the early JWST cycles. First, we explore JWST's current capabilities and expected spectral precision for targets near the saturation limits of specific modes. In doing so, we highlight the enhanced capabilities of high efficiency readout patterns that are being considered for implementation in Cycle 2. We propose a partial saturation strategy to increase the achievable precision of JWST's NIRSpec Prism. We show that JWST has the potential to detect the dominant absorbing gas in the atmospheres of temperate terrestrial planets by the 10th transit using transmission spectroscopy techniques in the near-IR. We also show that stacking $\gtrapprox$10 transmission spectroscopy observations is unlikely to yield significant improvements in determining atmospheric composition. For emission spectroscopy, we show that the MIRI LRS is unlikely to provide robust constraints on the atmospheric composition of temperate terrestrial planets. Higher precision emission spectroscopy at wavelengths longward of those accessible to MIRI LRS, as proposed in the Origins Space Telescope concept, could help improve the constraints on molecular abundances of temperate terrestrial planets orbiting M-dwarfs.

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Additional Exoplanet Science Enabled by FINESSE

FINESSE, a NASA MIDEX mission in Step 2, would conduct a large, uniform survey of exoplanet atmospheres and create a statistically significant sample for comparative planetology. FINESSE's technical capabilities, driven by a scientific program to study planetary formation and climate mechanisms, enable additional exoplanet science presented here.

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Characterizing Earth Analogs in Reflected Light: Atmospheric Retrieval Studies for Future Space Telescopes

Space-based high contrast imaging mission concepts for studying rocky exoplanets in reflected light are currently under community study. We develop an inverse modeling framework to estimate the science return of such missions given different instrument design considerations. By combining an exoplanet albedo model, an instrument noise model, and an ensemble Markov chain Monte Carlo sampler, we explore retrievals of atmospheric and planetary properties for Earth twins as a function of signal-to-noise ratio (SNR) and resolution ($R$). Our forward model includes Rayleigh scattering, single-layer water clouds with patchy coverage, and pressure-dependent absorption due to water vapor, oxygen, and ozone. We simulate data at $R = 70$ and $R = 140$ from 0.4-1.0 $μ$m with SNR $ = 5, 10, 15, 20$ at 550 nm (i.e., for HabEx/LUVOIR-type instruments). At these same SNR, we simulate data for WFIRST paired with a starshade, which includes two photometric points between 0.48-0.6 $μ$m and $R = 50$ spectroscopy from 0.6-0.97 $μ$m. Given our noise model for WFIRST-type detectors, we find that weak detections of water vapor, ozone, and oxygen can be achieved with observations with at least $R = 70$ / SNR$\ = 15$, or $R = 140$ / SNR$\ = 10$ for improved detections. Meaningful constraints are only achieved with $R = 140$ / SNR$\ = 20$ data. The WFIRST data offer limited diagnostic information, needing at least SNR = 20 to weakly detect gases. Most scenarios place limits on planetary radius, but cannot constrain surface gravity and, thus, planetary mass.

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A comparative study of WASP-67b and HAT-P-38b from WFC3 data

Atmospheric temperature and planetary gravity are thought to be the main parameters affecting cloud formation in giant exoplanet atmospheres. Recent attempts to understand cloud formation have explored wide regions of the equilibrium temperature-gravity parameter space. In this study, we instead compare the case of two giant planets with nearly identical equilibrium temperature ($T_\mathrm{eq}$ $\sim 1050 \, \mathrm{K}$) and gravity ($g \sim 10 \, \mathrm{m \, s}^{-1})$. During $HST$ Cycle 23, we collected WFC3/G141 observations of the two planets, WASP-67 b and HAT-P-38 b. HAT-P-38 b, with mass 0.42 M$_\mathrm{J}$ and radius 1.4 $R_\mathrm{J}$, exhibits a relatively clear atmosphere with a clear detection of water. We refine the orbital period of this planet with new observations, obtaining $P = 4.6403294 \pm 0.0000055 \, \mathrm{d}$. WASP-67 b, with mass 0.27 M$_\mathrm{J}$ and radius 0.83 $R_\mathrm{J}$, shows a more muted water absorption feature than that of HAT-P-38 b, indicating either a higher cloud deck in the atmosphere or a more metal-rich composition. The difference in the spectra supports the hypothesis that giant exoplanet atmospheres carry traces of their formation history. Future observations in the visible and mid-infrared are needed to probe the aerosol properties and constrain the evolutionary scenario of these planets.

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Quantifying the Impact of Spectral Coverage on the Retrieval of Molecular Abundances from Exoplanet Transmission Spectra

Using forward models for representative exoplanet atmospheres and a radiometric instrument model, we have generated synthetic observational data to explore how well the major C- and O-bearing chemical species (CO, CO2, CH4, and H2O), important for determining atmospheric opacity and radiation balance, can be constrained by transit measurements as a function of spectral wavelength coverage. This work features simulations for a notional transit spectroscopy mission and compares two cases for instrument spectral coverage (wavelength coverage from 0.5-2.5 $μ$m and 0.5-5 $μ$m. The simulation is conducted on a grid with a range of stellar magnitudes and incorporates a full retrieval of atmospheric model parameters. We consider a range of planets from sub-Neptunes to hot Jupiters and include both low and high mean molecular weight atmospheres. We find that including the 2.5-5 $μ$m wavelength range provides a significant improvement in the degree of constraint on the retrieved molecular abundances: up to ~3 orders of magnitude for a low mean molecular weight atmosphere ($μ$=2.3) and up to a factor of ~6 for a high mean molecular weight atmosphere ($μ$=28). These decreased uncertainties imply that broad spectral coverage between the visible and the mid-infrared is an important tool for understanding the chemistry and composition of exoplanet atmospheres. This analysis suggests that the JWST/NIRSpec 0.6-5 $μ$m prism spectroscopy mode, or similar wavelength coverage with possible future missions, will be an important resource for exoplanet atmospheric characterization.

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Uniform Atmospheric Retrieval Analysis of Ultracool Dwarfs II: Properties of 11 T-dwarfs

Brown dwarf spectra are rich in information revealing of the chemical and physical processes operating in their atmospheres. We apply a recently developed atmospheric retrieval tool to an ensemble of late T-dwarf (600-800K) near infrared spectra. With these spectra we are able to place direct constraints the molecular abundances of H$_2$O, CH$_4$, CO, CO$_2$, NH$_3$, H$_2$S, and Na+K, gravity, thermal structure (and effective temperature), photometric radius, and cloud optical depths. We find that ammonia, water, methane, and the alkali metals are present and well constrained in all 11 objects. From the abundance constraints we find no significant trend in the water, methane, or ammonia abundances with temperature, but find a very strong ($>$25$σ$) increasing trend in the alkali metal abundances with effective temperature, indicative of alkali rainout. We also find little evidence for optically thick clouds. With the methane and water abundances, we derive the intrinsic atmospheric metallicity and carbon-to-oxygen ratios. We find in our sample, that metallicities are typically sub solar and carbon-to-oxygen ratios are somewhat super solar, different than expectations from the local stellar population. We also find that the retrieved vertical thermal profiles are consistent with radiative equilibrium over the photospheric regions. Finally, we find that our retrieved effective temperatures are lower than previous inferences for some objects and that our radii are larger than expectations from evolutionary models, possibly indicative of un-resolved binaries. This investigation and methodology represents a paradigm in linking spectra to the determination of the fundamental chemical and physical processes governing cool brown dwarf atmospheres.

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Forecasting the Impact of Stellar Activity on Transiting Exoplanet Spectra

Exoplanet host star activity, in the form of unocculted star spots or faculae, alters the observed transmission and emission spectra of the exoplanet. This effect can be exacerbated when combining data from different epochs if the stellar photosphere varies between observations due to activity. redHere we present a method to characterize and correct for relative changes due to stellar activity by exploiting multi-epoch ($\ge$2 visits/transits) observations to place them in a consistent reference frame. Using measurements from portions of the planet's orbit where negligible planet transmission or emission can be assumed, we determine changes to the stellar spectral amplitude. With the analytical methods described here, we predict the impact of stellar variability on transit observations. Supplementing these forecasts with Kepler-measured stellar variabilities for F-, G-, K-, and M-dwarfs, and predicted transit precisions by JWST's NIRISS, NIRCam, and MIRI, we conclude that stellar activity does not impact infrared transiting exoplanet observations of most presently-known or predicted TESS targets by current or near-future platforms, such as JWST.

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Retrieval of atmospheric properties of cloudy L dwarfs

We present the first results from applying the spectral inversion technique in the cloudy L dwarf regime. Our new framework provides a flexible approach to modelling cloud opacity which can be built incrementally as the data requires, and improves upon previous retrieval experiments in the brown dwarf regime by allowing for scattering in two stream radiative transfer. Our first application of the tool to two mid-L dwarfs is able to reproduce their near-infrared spectra far more closely than grid models. Our retrieved thermal, chemical, and cloud profiles allow us to estimate $T_{\rm eff} = 1796^{+23}_{-25}$ K and $\log g = 5.21^{+0.05}_{-0.08}$ for 2MASS J05002100+0330501 and for 2MASSW J2224438-015852 we find $T_{\rm eff} = 1723^{+18}_{-19}$ K and $\log g = 5.31^{+0.04}_{-0.08}$, in close agreement with previous empirical estimates. Our best model for both objects includes an optically thick cloud deck which passes $τ_{cloud} \geq 1$ (looking down) at a pressure of around 5 bar. The temperature at this pressure is too high for silicate species to condense, and we argue that corundum and/or iron clouds are responsible for this cloud opacity. Our retrieved profiles are cooler at depth, and warmer at altitude than the forward grid models that we compare, and we argue that some form of heating mechanism may be at work in the upper atmospheres of these L dwarfs. We also identify anomalously high CO abundance in both targets, which does not correlate with the warmth of our upper atmospheres or our choice of cloud model, and find similarly anomalous alkali abundance for one of our targets. These anomalies may reflect unrecognised shortcomings in our retrieval model, or inaccuracies in our gas phase opacities.

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Information Content Analysis for Selection of Optimal JWST Observing Modes for Transiting Exoplanet Atmospheres

The James Webb Space Telescope (JWST) is nearing its launch date of 2018, and will undoubtedly revolutionize our knowledge of exoplanet atmospheres. While several studies have explored what the limits of the telescope will be in terms of exoplanet characterization, less has been done to specifically identify which observing modes will be most useful for characterizing a diverse range of exoplanetary atmospheres. We use an information content based approach commonly used in the studies of Solar System atmospheres. We develop a system based upon these information content methods to trace the instrumental and atmospheric model phase space in order to identify which observing modes are best suited for particular classes of planets, focusing on transmission spectra. Specifically, the atmospheric parameter space we cover is T=600-1800 K, C/O=0.55-1, [M/H]=1-100$\times$Solar for a R=1.39 R$_J$, M=0.59 M$_J$ planet orbiting WASP-62-like star. We find that obtaining broader wavelength coverage over multiple modes is preferred over higher precision in a single mode given the same amount of observing time. Regardless of the planet temperature and composition, the best modes for constraining terminator temperatures, C/O ratios, and metalicity are NIRISS SOSS+NIRSpec G395. If the target's host star is dim enough such that the NIRSpec prism can be used, then it cam be used instead of NIRISS SOSS+NIRSpec G395. Lastly, observations that use more than two modes, should be carefully analyzed because sometimes the addition of a third mode results in no gain of information. In these cases, higher precision in the original two modes is favorable.

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Spitzer Phase Curve Constraints for WASP-43b at 3.6 and 4.5 microns

Previous measurements of heat redistribution efficiency (the ability to transport energy from a planet's highly irradiated dayside to its eternally dark nightside) show considerable variation between exoplanets. Theoretical models predict a positive correlation between heat redistribution efficiency and temperature for tidally locked planets; however, recent HST WASP-43b spectroscopic phase curve results are inconsistent with current predictions. Using the Spitzer Space Telescope, we obtained a total of three phase curve observations of WASP-43b (P=0.813 days) at 3.6 and 4.5 microns. The first 3.6 micron visit exhibits spurious nightside emission that requires invoking unphysical conditions in our cloud-free atmospheric retrievals. The two other visits exhibit strong day-night contrasts that are consistent with the HST data. To reconcile the departure from theoretical predictions, WASP-43b would need to have a high-altitude, nightside cloud/haze layer blocking its thermal emission. Clouds/hazes could be produced within the planet's cool, nearly retrograde mid-latitude flows before dispersing across its nightside at high altitudes. Since mid-latitude flows only materialize in fast-rotating ($\lesssim1$ day) planets, this may explain an observed trend connecting measured day-night contrast with planet rotation rate that matches all current Spitzer phase curve results. Combining independent planetary emission measurements from multiple phases, we obtain a precise dayside hemisphere H2O abundance ($2.5\times 10^{-5} - 1.1\times 10^{-4}$ at 1$σ$ confidence) and, assuming chemical equilibrium and a scaled solar abundance pattern, we derive a corresponding metallicity estimate that is consistent with being solar (0.4 -- 1.7). Using the retrieved global CO+CO2 abundance under the same assumptions, we estimate a comparable metallicity of 0.3 - 1.7$\times$ solar. (Abridged)

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The Impact of Non-Uniform Thermal Structure on the Interpretation of Exoplanet Emission Spectra

The determination of atmospheric structure and molecular abundances of planetary atmospheres via spectroscopy involves direct comparisons between models and data. While varying in sophistication, most model-spectra comparisons fundamentally assume "1D" model physics. However, knowledge from general circulation models and of solar system planets suggests that planetary atmospheres are inherently "3D" in their structure and composition. We explore the potential biases resulting from standard "1D" assumptions within a Bayesian atmospheric retrieval framework. Specifically, we show how the assumption of a single 1-dimensional thermal profile can bias our interpretation of the thermal emission spectrum of a hot Jupiter atmosphere that is composed of two thermal profiles. We retrieve upon spectra of unresolved model planets as observed with a combination of $HST$ WFC3+$Spitzer$ IRAC as well as $JWST$ under varying differences in the two thermal profiles. For WFC3+IRAC, there is a significantly biased estimate of CH$_4$ abundance using a 1D model when the contrast is 80%. For $JWST$, two thermal profiles are required to adequately interpret the data and estimate the abundances when contrast is greater than 40%. We also apply this preliminary concept to the recent WFC3+IRAC phase curve data of the hot Jupiter WASP-43b. We see similar behavior as present in our simulated data: while the H$_2$O abundance determination is robust, CH$_4$ is artificially well-constrained to incorrect values under the 1D assumption. Our work demonstrates the need to evaluate model assumptions in order to extract meaningful constraints from atmospheric spectra and motivates exploration of optimal observational setups.

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No Thermal Inversion and a Solar Water Abundance for the Hot Jupiter HD209458b from HST WFC3 Emission Spectroscopy

The nature of the vertical thermal structure of hot Jupiter atmospheres is one of the key questions raised by the characterization of transiting exoplanets over the last decade. There have been claims that many hot Jupiter's exhibit vertical profiles with increasing temperature with decreasing pressure in the infrared photosphere that leads to the reversal of molecular absorption bands into emission features (an inversion). However, these claims have been based on broadband photometry rather than the unambiguous identification of emission features with spectroscopy, and the chemical species that could cause the thermal inversions by absorbing stellar irradiation at high altitudes have not been identified despite extensive theoretical and observational effort. Here we present high precision HST WFC3 observations of the dayside emission spectrum of the hot Jupiter HD209458b; the first exoplanet suggested to have a thermal inversion. Our observations resolve a water band in absorption at 6.2 sigma confidence. When combined with Spitzer photometry the data are indicative of a monotonically decreasing temperature with pressure over the range 1-0.001 bar at 7.7 sigma confidence. We test the robustness of our results by exploring a variety of model assumptions including the temperature profile parameterization, presence of a cloud, and choice of Spitzer data reduction. We also introduce a new analysis method, "chemical retrieval-on-retrieval", to determine the elemental abundances from the spectrally retrieved mixing ratios with thermochemical self-consistency and find plausible abundances consistent with solar metallicity (0.06 - 10 x solar) and carbon-to-oxygen ratios less than unity. This work suggests that high-precision spectrophotometric results are required to robustly infer thermal structures and compositions of extra-solar planet atmospheres.

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