arXiv subjects

Michael R. Tarbutt

Publications and source records attributed to Michael R. Tarbutt.

9 recordsLinked to original sources

arXiv2026

Deterministic loading of molecular arrays by microwave-assisted collisions

Molecular tweezer arrays offer great prospects for quantum simulation, sensing, and computing, and would benefit from methods that enhance loading efficiency. Whereas light-assisted collisions underpin enhanced loading methods for atomic tweezer arrays, this approach cannot be directly extended to molecular arrays due to collisional loss. We show how this collisional loss can be suppressed by shelving molecules in rotationally or vibrationally excited states, so that a shelved molecule interacts with a newly loaded molecule through a repulsive van der Waals interaction. By introducing microwave assisted collisions, we show how to control the final states and the energy released in a collision between a pair of molecules. Following this controlled collision, one of the two molecules can be ejected, and we explore several strategies for ensuring deterministic ejection. Our schemes rely on currently available techniques for laser-coolable molecules, and we predict achievable filling fractions up to 96%, paving the way for scalable molecular arrays.

physics.atom-ph↗

arXiv2026

Tuning interactions between static-field-shielded polar molecules with microwaves

The ability to tune interparticle interactions is one of the main advantages of using ultracold quantum gases for quantum simulation of many-body physics. Current experiments with ultracold polar molecules employ shielding with microwave or static electric fields to prevent destructive collisional losses. The interaction potential of microwave-shielded molecules can be tuned by using microwaves of two different polarisations, while for static-field-shielded molecules the tunability of interactions is more limited and depends on the particular species. In this work, we propose a general method to tune the interactions between static-field-shielded molecules by applying a microwave field. We carry out coupled-channel scattering calculations in a field-dressed basis set to determine loss rate coefficients and scattering lengths. We find that both the s-wave scattering length and the dipole length can be widely tuned by changing the parameters of the microwave field, while maintaining strong suppression of lossy collisions.

cond-mat.quant-gas↗

arXiv2026

A Penning trap single-photon counter for axion detection

Discovering the microscopic composition of dark matter is one of the most important open problems in physics today. Axions are a leading candidate to be dark matter; however, a search of the full range of all likely axion masses is hampered by the standard quantum noise limit. This makes haloscope searches for axions with masses above 0.1 meV unfeasible with current technologies. To overcome this limitation, we propose a new photon counting technique designed to operate at 30-60 GHz for detecting axions with masses between 0.124 meV and 0.248 meV, based on a single electron in a Penning trap. The electron cyclotron mode absorbs microwave photons, and, via the continuous Stern-Gerlach effect, this absorption imparts a measurable phase shift onto the axial motion. In this paper, we comprehensively analyze this photon detection method. We introduce a new type of fast, phase-sensitive axial detection technique, using axial-magnetron parametric amplification to overcome detector Johnson noise and cancel associated frequency shifts. This method may find other applications in precision Penning trap frequency measurements. We compare the efficiency of the electron single-photon counter with an ideal device, and find that our proposed photon counter has sufficient performance to search for high mass axions.

hep-ph↗

arXiv2024

Scheme for Deterministic Loading of Laser-Cooled Molecules into Optical Tweezers

We propose to repeatedly load laser-cooled molecules into optical tweezers, and transfer them to storage states that are rotationally excited by two additional quanta. Collisional loss of molecules in these storage states is suppressed, and a dipolar blockade prevents the accumulation of more than one molecule. Applying three cycles loads tweezers with single molecules at an 80% success rate, limited by residual collisional loss. This improved loading efficiency reduces the time needed for rearrangement of tweezer arrays, which would otherwise limit the scalability of neutral molecule quantum computers.

physics.atom-ph↗

arXiv2024

Quantum Computation and Quantum Simulation with Ultracold Molecules

Ultracold molecules confined in optical lattices or tweezer traps can be used to process quantum information and simulate the behaviour of many-body quantum systems. Molecules offer several advantages for these applications. They have a large set of stable states with strong transitions between them and long coherence times. They can be prepared in a chosen state with high fidelity, and the state populations can be measured efficiently. They have controllable long-range dipole-dipole interactions that can be used to entangle pairs of molecules and generate interesting many-body states. We review the advances that have been made and the challenges still to overcome, and describe the new ideas that will unlock the full potential of the field.

cond-mat.quant-gas↗

arXiv2023

Shielding collisions of ultracold CaF molecules with static electric fields

We study collisions of ultracold CaF molecules in strong static electric fields. These fields allow the creation of long-range barriers in the interaction potential, effectively preventing the molecules from reaching the short-range region where inelastic and other loss processes are likely to occur. We carry out coupled-channel calculations of rate coefficients for elastic scattering and loss. We develop an efficient procedure for including energetically well-separated rotor functions in the basis set via a Van Vleck transformation. We show that shielding is particularly efficient for CaF and allows the rate of two-body loss processes to be reduced by a factor of $10^7$ or more at a field of 23 kV/cm. The loss rates remain low over a substantial range of fields. Electron and nuclear spins cause strong additional loss in some small ranges of field, but have little effect elsewhere. These results pave the way for evaporative cooling of CaF towards quantum degeneracy.

quant-ph↗

arXiv2023

Tunable Feshbach resonances in collisions of ultracold molecules in $^2Σ$ states with alkali-metal atoms

We consider the magnetically tunable Feshbach resonances that may exist in ultracold mixtures of molecules in $^2Σ$ states and alkali-metal atoms. We focus on Rb+CaF as a prototype system. There are likely to be Feshbach resonances analogous to those between pairs of alkali-metal atoms. We investigate the patterns of near-threshold states and the resonances that they cause, using coupled-channel calculations of the bound states and low-energy scattering on model interaction potentials. We explore the dependence of the properties on as-yet-unknown potential parameters. There is a high probability that resonances will exist at magnetic fields below 1000 G, and that these will be broad enough to control collisions and form triatomic molecules by magnetoassociation. We consider the effect of CaF rotation and potential anisotropy, and conclude that they may produce additional resonances but should not affect the existence of rotation-free resonances.

physics.atom-ph↗

arXiv2022

Inner-shell excitation in the YbF molecule and its impact on laser cooling

The YbF molecule is a sensitive system for measuring the electron's electric dipole moment. The precision of this measurement can be improved by direct laser cooling of the molecules to ultracold temperature. However, low-lying electronic states arising from excitation of a 4f electron may hinder laser cooling. One set of these "4f hole" states lies below the $A^2Π_{1/2}$ excited state used for laser cooling, and radiative decay to these intermediate levels, even with branching ratios as small as $10^{-5}$, can be a hindrance. Other 4f hole states lie very close to the $A^2Π_{1/2}$ state, and a perturbation results in states of mixed character that are involved in the laser cooling cycle. This perturbation may enhance the loss of molecules to states outside of the laser cooling cycle. We model the perturbation of the $A^2Π_{1/2}$ state to determine the strength of the coupling between the states, the de-perturbed potential energy curves, and the radiative branching ratios to various vibrational levels of the ground state, $X ^{2}Σ^+$. We use electronic structure calculations to characterise the 4f hole states and the strengths of transitions between these states and the $A^2Π_{1/2}$ and $X ^{2}Σ^+$ states. We identify a leak out of the cooling cycle with a branching ratio of roughly $5 \times 10^{-4}$, dominated by the contribution of the ground state configuration in a 4f hole state. Finally, we assess the impact of these results for laser cooling of YbF and molecules with similar structure.

physics.atom-ph↗

arXiv2019

Characterising molecules for fundamental physics: an accurate spectroscopic model of methyltrioxorhenium derived from new infrared and millimetre-wave measurements

Precise spectroscopic analysis of polyatomic molecules enables many striking advances in physical chemistry and fundamental physics. We use several new high-resolution spectroscopic devices to improve our understanding of the rotational and rovibrational structure of methyltrioxorhenium (MTO), the achiral parent of a family of large oxorhenium compounds that are ideal candidate species for a planned measurement of parity violation in chiral molecules. Using millimetre-wave and infrared spectroscopy in a pulsed supersonic jet, a cryogenic buffer gas cell, and room temperature absorption cells, we probe the ground state and the Re=O antisymmetric and symmetric stretching excited states of both CH3 187 ReO3 and CH3 185 ReO3 isotopologues in the gas phase with unprecedented precision. By extending the rotational spectra to the 150-300 GHz range, we characterize the ground state rotational and hyperfine structure up to J = 43 and K = 41, resulting in refinements to the rotational, quartic and hyperfine parameters, and the determination of sextic parameters and a centrifugal distortion correction to the quadrupolar hyperfine constant. We obtain rovibrational data for temperatures between 6 and 300 K in the 970-1015 cm-1 range, at resolutions down to 8 MHz and accuracies of 30 MHz. We use these data to determine more precise excited-state rotational, Coriolis and quartic parameters, as well as the ground-state centrifugal distortion parameter D K of the 187 Re isotopologue. We also account for hyperfine structure in the rovibrational transitions and hence determine the upper state rhenium atom quadrupole coupling constant eQq' .

physics.atom-ph↗