arXiv subjects

Michel Latroche

Publications and source records attributed to Michel Latroche.

16 recordsLinked to original sources

arXiv2022

In-situ neutron diffraction during reversible deuterium loading in Ti-rich and Mn-substituted Ti(Fe,Mn)0.90 alloys

Hydrogen is an efficient energy carrier that can be produced from renewable sources, enabling the transition towards CO2-free energy. Hydrogen can be stored for a long period in the solid-state, with suitable alloys. Ti-rich TiFe0.90 compound exhibits a mild activation process for the first hydrogenation, and Ti(Fe,Mn)0.90 substituted alloys can lead to the fine tuning of equilibrium pressure as a function of the final application. In this study, the crystal structure of TiFe(0.90-x)Mnx alloys (x = 0, 0.05 and 0.10) and their deuterides has been determined by in-situ neutron diffraction, while recording Pressure-Composition Isotherms at room temperature. The investigation aims at analysing the influence of Mn for Fe substitution in Ti-rich Ti(Fe,Mn)0.90 alloys on structural properties during reversible deuterium loading, which is still unsolved and seldom explored. After activation, samples have been transferred into custom-made stainless-steel and aluminium alloy cells used for in-situ neutron diffraction experiments during deuterium loading at ILL and ISIS neutron facilities, respectively. The study enables remarkable understanding on hydrogen storage, basic structural knowledge, and support to the industrial application of TiFe-type alloys for integrated hydrogen tank in energy storage systems by determining the volume expansion during deuteration. Furthermore, the study demonstrates that different contents of Mn do not significantly change the volumetric expansion during phase transitions, affecting only the deuterium content for the γ phase and the cell evolution for the \b{eta} phase. The study confirms that the deuterated structures of the γ phase upon absorption, \b{eta} and α phase upon desorption, correspond to S.G. Cmmm, P2221 and Pm-3m, respectively.

cond-mat.mtrl-sci↗

arXiv2022

Mechanochemical synthesis of pseudobinary Ti-V hydrides and their conversion reaction with Li and Na

Lithium-ion batteries (LiBs) based on insertion electrodes reach intrinsic capacity limits. Performance improvements and cost reduction require alternative reaction mechanisms and novel battery chemistries such as conversion reactions and sodium-ion batteries (NaBs), respectively. We here study the formation of Ti1-xVxH2 hydrides (0 < x < 1) and their electrochemical properties as anodes in LiBs and NaBs half-cells. Hydrides were synthesized by mechanochemistry of the metal powders under hydrogen atmosphere (PH2~ 8 MPa). For V contents below 80 at.% (x < 0.8), single-phase pseudobinary dihydride compounds Ti1-xVxH2 are formed. They crystallize in the fluorite-type structure and are highly nanostructured (crystallite size < 10 nm). Their lattice parameter decreases linearly with the V content leading to hydride destabilization. Electrochemical studies were first carried out in Li-ion half cells with full conversion between Ti1-xVxH2 hydrides and lithium. The potential of the conversion reaction can be gradually tuned with the vanadium content due to its destabilization effect. Furthermore, different paths for the conversion reaction are observed for Ti-rich (x < 0.25) and V-rich (x > 0.7) alloys. Na-ion half-cell measurements prove the reactivity between (V,Ti)H2 hydrides and sodium, albeit with significant kinetic limitations

cond-mat.mtrl-sci↗

arXiv2021

Investigation of the phase occurrence and H sorption properties in the Y33.33Ni66.67-xAlx (0 <= x <= 33.33) system

The Y33.33Ni66.67-xAlx system has been investigated in the region 0 <= x <= 33.3. The alloys were synthesized by induction melting. Phase occurrence and structural properties were studied by X-Ray powder Diffraction (XRD). The Al solubility in each phase has been investigated by XRD and Electron Probe Micro-Analysis (EPMA). The hydrogenation properties were characterized by pressure-composition isotherm measurements and kinetic curves at 473 K. For x = 0, the binary Y33.33Ni66.67 alloy crystallizes in the cubic superstructure with F4-3m space group and ordered Y vacancies. For 1.67 <= x <= 8.33, the alloys contain mainly Y(Ni, Al)2 and Y(Ni, Al)3 pseudobinary phases; while for 16.67 <= x <= 33.33 they are mainly formed by ternary line compounds Y3Ni6Al2, Y2Ni2Al and YNiAl. Contrary to the binary Y33.33Ni66.67, Y(Ni, Al)2 pseudo-binary compounds crystalize in C15 phase (space group Fd-3m ) with disordered Y vacancies. The solubility limit of Al in the C15 YNi2-yAly phase is y = 0.11 (i.e., x = 3.67). The Y(Ni, Al)3 phase changes from rhombohedral (PuNi3-type, R-3m) to hexagonal (CeNi3-type, P63/mmc) structure for x increasing from 5.00 to 6.67. Upon hydrogenation, the disproportion of C15 Y(Ni, Al)2 and losses of crystallinity of YNi and Y2Ni2Al are the main reasons causing capacity decay of Y33.33Ni66.67-xAlx (0 <= x <= 33.33) alloys upon cycling.

cond-mat.mtrl-sci↗

arXiv2021

Fundamental hydrogen storage properties of TiFe-alloy with partial substitution of Fe by Ti and Mn

TiFe intermetallic compound has been extensively studied, owing to its low cost, good volumetric hydrogen density, and easy tailoring of hydrogenation thermodynamics by elemental substitution. All these positive aspects make this material promising for large-scale applications of solid-state hydrogen storage. On the other hand, activation and kinetic issues should be amended and the role of elemental substitution should be further understood. This work investigates the thermodynamic changes induced by the variation of Ti content along the homogeneity range of the TiFe phase (Ti:Fe ratio from 1:1 to 1:0.9) and of the substitution of Mn for Fe between 0 and 5 at.%. In all considered alloys, the major phase is TiFe-type together with minor amounts of TiFe2 or \b{eta}-Ti-type and Ti4Fe2O-type at the Ti-poor and rich side of the TiFe phase domain, respectively. Thermodynamic data agree with the available literature but offer here a comprehensive picture of hydrogenation properties over an extended Ti and Mn compositional range. Moreover, it is demonstrated that Ti-rich alloys display enhanced storage capacities, as long as a limited amount of \b{eta}-Ti is formed. Both Mn and Ti substitutions increase the cell parameter by possibly substituting Fe, lowering the plateau pressures and decreasing the hysteresis of the isotherms. A full picture of the dependence of hydrogen storage properties as a function of the composition will be discussed, together with some observed correlations.

cond-mat.mtrl-sci↗

arXiv2021

Substitutional effects in TiFe for hydrogen storage: a comprehensive review

The search for suitable materials for solid-state stationary storage of green hydrogen is pushing the implementation of efficient renewable energy systems. This involves rational design and modification of cheap alloys for effective storage in mild conditions of temperature and pressure. Among many intermetallic compounds described in the literature, TiFe-based systems have recently regained vivid interest as materials for practical applications since they are low-cost and they can be tuned to match required pressure and operation conditions. This work aims to provide a comprehensive review of publications involving chemical substitution in TiFe-based compounds for guiding compound design and materials selection in current and future hydrogen storage applications. Mono- and multi-substituted compounds modify TiFe thermodynamics and are beneficial for many hydrogenation properties. They will be reviewed and deeply discussed, with a focus on manganese substitution.

cond-mat.mtrl-sci↗

arXiv2021

Improvement of reversible H storage capacity by fine tuning of the composition in the pseudo-binary systems A2-xLaxNi7 (A = Gd, Sm, Y, Mg)

A2B7 compounds (A = rare earth or Mg, B = transition metal) are widely studied as active materials for negative electrode in Ni-MH batteries. By playing on the substitution rate of both A and B elements, it is possible to prepare various compositions. This strategy will help to improve the properties, for example get a higher reversible hydrogen capacity and a well-adapted hydrogen sorption pressure. Indeed, A can be almost all light rare earths (La to Gd), yttrium and alkaline earth metals (Mg or Ca), whereas B can contain various late transition metals (Mn to Ni). To understand the effects of composition on the physicochemical properties of La2Ni7-based compound, various pseudo-binary systems have been investigated: Gd2 xLaxNi7 (x = 0, 0.6, 1, 1.5), Sm2-xLaxNi7 (x = 0, 0.5, 1, 1.5), Y2-xLaxNi7 (x = 0, 0.4, 0.5, 0.6, 0.8, 1, 1.5, 1.75) and A0.5La1.1Mg0.4Ni7 (A = Sm, Gd and Y). To determine their crystallographic properties, X-ray diffraction analysis was performed followed by Rietveld refinement. Thermodynamic properties regarding reversible hydrogen sorption were investigated at room temperature. Quaternary compounds present drastically improved sorption properties in the frame of practical energy storage applications with reversible capacity equivalent to 400 mAh/g for the compound La1.1Sm0.5Mg0.4Ni7.

cond-mat.mtrl-sci↗

arXiv2021

Impact of Surface Chemistry of Silicon Nanoparticles on the Structural and Electrochemical Properties of Si/Ni3.4Sn4 Com-posite Anode for Li-Ion Batteries

Embedding silicon nanoparticles in an intermetallic matrix is a promising strategy to produce remarkable bulk anode materials for lithium-ion (Li-ion) batteries with low potential, high electrochemical capacity and good cycling stability. These composite materials can be synthetized at a large scale using mechanical milling. However, for Si-Ni3Sn4 composites, milling also induces a chemical reaction between the two components leading to the formation of free Sn and NiSi2, which is detrimental to the performance of the electrode. To prevent this reaction, a modification of the surface chemistry of the silicon has been undertaken. Si nanoparticles coated with a surface layer of either carbon or oxide were used instead of pure silicon. The influence of the coating on the composition, (micro)structure and electrochemical properties of Si-Ni3Sn4 composites is studied and compared with that of pure Si. Si coating strongly reduces the reaction between Si and Ni3Sn4 during milling. Moreover, contrary to pure silicon, Si-coated composites have a plate-like mor-phology in which the surface-modified silicon particles are surrounded by a nanostructured, Ni3Sn4-based matrix leading to smooth potential profiles during electrochemical cycling. The chemical homogeneity of the matrix is more uniform for carbon-coated than for oxygen-coated silicon. As a consequence, different electrochemical behaviors are obtained depending on the surface chemistry, with better lithiation properties for the carbon-covered silicon able to deliver over 500 mAh/g for at least 400 cycles.

cond-mat.mtrl-sci↗

arXiv2020

Hydrogen storage properties of Mn and Cu for Fe substitution in TiFe0.9 intermetallic compound

The present study investigates the partial substitutions of Mn and Cu for Fe in the TiFe-system to gain better understanding of the role of elemental substitution on its hydrogen storage properties. The TiFe0.88-xMn0.02Cux (x = 0, 0.02, 0.04) compositions were studied. From X-Ray Diffraction (XRD) and Electron Probe Micro-Analysis (EPMA), it was found that all alloys are multi-phase, with TiFe as a major phase, together with \b{eta}-Ti and Ti4Fe2O-type as secondary precipitates, of all them containing also Mn and Cu. Increasing the Cu content augments the secondary phase amounts. Low quantity of secondary phases helps the activation of the main TiFe phase for the first hydrogen absorption, but on increasing their amounts, harsher activation occurs. Both Mn and Cu substitutions increase the cell parameter of TiFe, thus decreasing the first plateau pressure. However, Cu substitution rises the second plateau pressure revealing the predominancy of electronic effects associated to this substitution. All samples have fast kinetics and high hydrogen capacity making these substituted compounds promising for large scale stationary applications.

cond-mat.mtrl-sci↗

arXiv2020

Ni-Sn intermetallics as efficient buffering matrix of Si anodes in Li-ion batteries

For a successful integration of silicon in high-capacity anodes of Li-ion batteries, its intrinsic capacity decay on cycling due to severe volume swelling should be minimized. In this work, Ni-Sn intermetallics are studied as buffering matrix during reversible lithiation of Si-based anodes. Si/Ni-Sn composites have been synthetized by mechanical milling using C and Al as process control agents. Ni3Sn4, Ni3Sn2 intermetallics and their bi-phasic mixture were used as constituents of the buffering matrix. The structure, composition and morphology of the composites have been analyzed by X-ray diffraction (XRD), 119Sn Transmission Mössbauer Spectroscopy (TMS) and scanning electron microscopy (SEM). They consist of ~ 150 nm Si nanoparticles embedded in a multi-phase matrix, the nanostructuration of which improves on increasing the Ni3Sn4 amount. The electrochemical properties of the composites were analyzed by galvanostatic cycling in half-cells. Best results for practical applications are found for the bi-phasic matrix Ni3Sn4-Ni3Sn2 in which Ni3Sn4 is electrochemically active while Ni3Sn2 is inactive. Low capacity loss, 0.04 %/cycle, and high coulombic efficiency, 99.6%, were obtained over 200 cycles while maintaining a high reversible capacity above 500 mAh/g at moderate regime C/5

cond-mat.mtrl-sci↗

arXiv2020

Solid-state Li-ion batteries operating at room temperature using new borohydride argyrodite electrolytes

Using a new class of (BH4)- substituted argyrodite Li6PS5Z0.83(BH4)0.17, (Z = Cl, I) solid electrolyte, Li-metal solid-state batteries operating at room temperature have been developed. The cells were made by combining the modified argyrodite with an In-Li anode and two types of cathode: an oxide, LixMO2 (M = 1/3Ni, 1/3Mn, 1/3Co; so called NMC) and a titanium disulfide, TiS2. The performance of the cells was evaluated through galvanostatic cycling and Alternating Current AC electrochemical impedance measurements. Reversible capacities were observed for both cathodes for at least tens of cycles. However, the high-voltage oxide cathode cell shows lower reversible capacity and larger fading upon cycling than the sulfide one. The AC impedance measurements revealed an increasing interfacial resistance at the cathode side for the oxide cathode inducing the capacity fading. This resistance was attributed to the intrinsic poor conductivity of NMC and interfacial reactions between the oxide material and the argyrodite electrolyte. On the contrary, the low interfacial resistance of the TiS2 cell during cycling evidences a better chemical compatibility between this active material and substituted argyrodites, allowing full cycling of the cathode material, 240 mAhg-1, for at least 35 cycles with a coulombic efficiency above 97%.

physics.app-ph↗

arXiv2020

Thermodynamic and corrosion study of Sm$_{1-x}$Mg$_x$Ni$_y$ (y = 3.5 or 3.8) compounds forming reversible hydrides

AB5 compounds (A = rare earth, B = transition metal) have been widely studied as anodes for Ni-MH applications. However, they have reached their technical limitations and the search for new promising materials with high capacity is foreseen. ABy compounds (2 < y < 5) are good candidates. They are made by stacking [AB5] and [A2B4] units along the c crystallographic axis. The latter unit allows a large increase in capacity, while the [AB5] unit provides good cycling stability. Consequently, the AB3.8 composition (i.e. A5B19 with three [AB5] for one [A2B4]) is expected to exhibit better cycling stability than the AB3.5 (i.e. A2B7 with two [AB5] for one [A2B4]). Furthermore, substitution of rare earth by light magnesium improves both the capacity and cycling stability. In this paper, we compare the hydrogenation and corrosion properties of two binary compounds SmNi$_{3.5}$ and SmNi$_{3.8}$ and two pseudo-binary ones (Sm,Mg)Ni$_{3.5}$ and (Sm,Mg)Ni$_{3.8}$. A better solid-gas cycling stability is highlighted for the binary SmNi$_{3.8}$. The pseudo-binary compounds also exhibit higher cycling stability than the binary ones. Furthermore, their resistance to corrosion was investigated.

cond-mat.mtrl-sci↗

arXiv2020

Correlations between stacked structures and weak itinerant magnetic properties of La$_{2-x}$ Y$_x $ Ni$_7$ compounds

Hexagonal La$_2$Ni$_7$ and rhombohedral Y$_2$Ni$_7$ are weak itinerant antiferromagnet (wAFM) and ferromagnet (wFM), respectively. The crystal structure and magnetic properties of $A_2B_7$ intermetallic compounds ($A$ = La, Y, $B$ = Ni) have been investigated combining X-ray powder diffraction and magnetic measurements. The La$_{2-x}$Y$_x$Ni$_7$ intermetallic compounds with $0 \leq x \leq 1$ crystallize in the Ce$_{2}$Ni$_7$-type hexagonal structure with Y preferentially located in the [$AB_2$] units. The compounds with larger Y content ($1.2 \leq x < 2$) crystallize in both hexagonal and rhombohedral (Gd$_2$Co$_7$-type) structures with a progressive substitution of Y for La in the $A$ sites belonging to the [$AB_5$] units. Y$_2$Ni$_7$ crystallizes in the rhombohedral structure only. The average cell volume decreases linearly versus Y content, whereas the c/a ratio presents a minimum at $x = 1$ due to geometric constrains. The magnetic properties are strongly dependent on the structure type and the Y content. La$_{2}$Ni$_7$ displays a complex metamagnetic behavior with split AFM peaks. Compounds with x = 0.25 and 0.5 display a wAFM ground state and two metamagnetic transitions, the first one towards an intermediate wAFM state and the second one towards a FM state.T$_N$ and the second critical field increase with the Y content, indicating a stabilization of the AFM state. LaYNi$_7$, which is as the boundary between the two structure types, presents a very wFM state at low field and an AFM state as the applied field increases. All the compounds with $x > 1$ and containing a rhombohedral phase are wFM with $T_C$ = 53(2) K. In addition to the experimental studies, first principles calculations using spin polarization have been performed to interpret the evolution of both structural phase stability and magnetic ordering for $0 \leq x < 2$.

cond-mat.mtrl-sci↗

arXiv2020

Investigation of H Sorption and Corrosion Properties of Sm2MnxNi7-x (0<x<0.5) Intermetallic Compounds Forming Reversible Hydrides

Intermetallic compounds are key materials for energy transition as they form reversible hydrides that can be used for solid state hydrogen storage or as anodes in batteries. ABy compounds (A = Rare Earth (RE); B = transition metal; 2 < y < 5) are good candidates to fulfill the required properties for practical applications. They can be described as stacking of AB5 and AB2 sub-units along the c crystallographic axis. The latter sub-unit brings a larger capacity, while the former one provides a better cycling stability. However, ABy binaries do not show good enough properties for applications. Upon hydrogenation, they exhibit multiplateau behavior and poor reversibility, attributed to H induced amorphization. These drawbacks can be overcome by chemical substitutions on the A and/or the B sites leading to stabilized reversible hydrides. The present work focuses on the pseudo-binary Sm2MnxNi7-x system (0 <= x < 0.5). The structural, thermodynamic and corrosion properties are analyzed and interpreted by means of X-ray diffraction, chemical analysis, scanning electron microscopy, thermogravimetric analysis and magnetic measurements. Unexpected cell parameter variations are reported and interpreted regarding possible formation of structural defects and uneven Mn distribution within the Ni sublattice. Reversible capacity is improved for x > 0.3 leading to larger and flatter isotherm curves, allowing for reversible capacity >1.4 wt %. Regarding corrosion, the binary compound corrodes in alkaline medium to form rare earth hydroxide and nanoporous nickel. As for the Mn-substituted compounds, a new corrosion product is formed in addition to those above mentioned, as manganese initiates a sacrificial anode mechanism taking place at the early corrosion stage.

cond-mat.mtrl-sci↗

arXiv2020

Pseudo-ternary LiBH4-LiCl-P2S5 system as structurally disordered bulk electrolyte for all-solid-state lithium batteries

The properties of the mixed system LiBH4 LiCl P2S5 are studied with respect to all-solid-state batteries. The studied material undergoes an amorphization upon heating above 601C, accompanied with increased Li+ conductivity beneficial for battery electrolyte applications. The measured ionic conductivity is 10-3 Scm-1 at room temperature with an activation energy of 0.40(2) eV after amorphization. Structural analysis and characterization of the material suggest that BH4 groups and PS4 may belong to the same molecular structure, where Cl ions interplay to accommodate the structural unit. Thanks to its conductivity, ductility and electrochemical stability (up to 5 V, Au vs. Li+/Li), this new electrolyte is successfully tested in battery cells operated with a cathode material (layered TiS2, theo. capacity 239 mAh g-1) and Li anode resulting in 93% capacity retention (10 cycles) and notable cycling stability under the current density 12 mA g-1 (0.05C-rate) at 501C. Further advanced characterisation by means of operando synchrotron X-ray diffraction in transmission mode contributes explicitly to a better understanding of the (de)lithiation processes of solid-state battery electrodes operated at moderate temperatures.

cond-mat.mtrl-sci↗

arXiv2020

Role of silicon and carbon on the structural and electrochemical properties of Si-Ni$_{3.4}$Sn$_4$-Al-C anodes for Li-ion batteries

Varying the amounts of silicon and carbon, different composites have been prepared by ball milling of Si, Ni$_{3.4}$Sn$_4$, Al and C. Silicon and carbon contents are varied from 10 to 30 wt.% Si, and 0 to 20 wt.% C. The microstructural and electrochemical properties of the composites have been investigated by X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and electrochemical galvanostatic cycling up to 1000 cycles. Impact of silicon and carbon contents on the phase occurrence, electrochemical capacity and cycle-life are compared and discussed. For C-content comprised between 9 and 13 wt.% and Si-content >= 20 wt.%, Si nanoparticles are embedded in a Ni$_{3.4}$Sn$_4$-Al-C matrix which is chemically homogeneous at the micrometric scale. For other carbon contents and low Si-amount (10 wt.%), no homogeneous matrix is formed around Si nanoparticles. When homogenous matrix is formed, both Ni$_3$Sn$_4$ and Si participate to the reversible lithiation mechanism, whereas no reaction between Ni$_3$Sn$_4$ and Li is observed for no homogenous matrix. Moreover, best cycle-life performances are obtained when Si nanoparticles are embedded in a homogenous matrix and Si-content is moderate (<= 20 wt.%). Composites with carbon in the 9-13 wt.% range and 20 wt.% silicon lead to the best balance between capacity and life duration upon cycling. This work experimentally demonstrates that embedding Si in an intermetallic/carbon matrix allows to efficiently accommodate Si volume changes on cycling to ensure long cycle-life.

physics.chem-ph↗

arXiv2020

Materials for hydrogen-based energy storage: Past, recent progress and future outlook

Magnesium hydride owns the largest share of publications on solid materials for hydrogen storage. The Magnesium group of international experts contributing to IEA Task 32 Hydrogen Based Energy Storage recently published two review papers presenting the activities of the group focused on magnesium hydride based materials and on Mg based compounds for hydrogen and energy storage. This review article not only overviews the latest activities on both fundamental aspects of Mg-based hydrides and their applications, but also presents a historic overview on the topic and outlines projected future developments. Particular attention is paid to the theoretical and experimental studies of Mg-H system at extreme pressures, kinetics and thermodynamics of the systems based on MgH2,nanostructuring, new Mg-based compounds and novel composites, and catalysis in the Mg based H storage systems. Finally, thermal energy storage and upscaled H storage systems accommodating MgH2 are presented.

cond-mat.mtrl-sci↗