arXiv subjects

Michele Re Fiorentin

Publications and source records attributed to Michele Re Fiorentin.

At least 19 recordsLinked to original sources

arXiv2026

Students using GenAI lag behind in problem-solving competence: an agent-based study of classroom networks

The development of problem-solving competence (PSC) among high school students is foundational for preparing resilient and adaptive citizens. Generative artificial intelligence (GenAI) can support this process, but it may also encourage students to offload part of the cognitive work that is necessary for deep learning. While the individual effects of GenAI use are increasingly studied, its collective consequences for competence development within classroom environments remain underexplored. In this study, we use an agent-based model to simulate the evolution of PSC in a high school physics classroom, where students complete tasks individually, in collaboration with peers, or with the support of GenAI. By comparing classrooms with and without access to GenAI across different peer-network structures, we show that GenAI use can diminish competence development and increase the share of students remaining in lower competence tiers. These results suggest that the educational impact of GenAI should be assessed not only through individual learning outcomes but also through its effects on collective competence dynamics.

physics.soc-ph↗

arXiv2026

Exciton radiative lifetimes in hexagonal diamond Ge and Si$_x$Ge$_{1-x}$ alloys

Recent reports of strong room-temperature photoluminescence in hexagonal diamond (2H) germanium stand in marked contrast to theoretical predictions of very weak band-edge optical transitions. Here we address radiative emission in 2H-Ge and related materials through a comprehensive investigation of their excitonic properties and radiative lifetimes, performing Bethe-Salpeter calculations on pristine and uniaxially strained 2H-Ge, 2H-Si$_x$Ge$_{1-x}$ alloys with $x=\frac{1}{6},\,\frac{1}{4},\,\frac{1}{2}$, and wurtzite GaN as a reference. Pristine 2H-Ge features sizable exciton binding energies ($\sim\!30$ meV) but extremely small dipole moments, yielding radiative lifetimes above $10^{-4}$ s. Alloying with Si reduces the lifetime by nearly two orders of magnitude, whereas a 2% uniaxial strain along the $c$ axis induces a band crossover that strongly enhances the in-plane dipole moment of the lowest-energy exciton and drives the lifetime down to the nanosecond scale. Although strained 2H-Ge approaches the radiative efficiency of GaN, its much lower exciton energy prevents a full match. These results provide the missing excitonic description of 2H-Ge and 2H-Si$_x$Ge$_{1-x}$, demonstrating that, even when excitonic effects are fully accounted for, the strong photoluminescence reported experimentally cannot originate from the ideal crystal.

cond-mat.mtrl-sci↗

arXiv2025

Silver electrodes are highly selective for CO in CO$_2$ electroreduction due to interplay between voltage dependent kinetics and thermodynamics

Electrochemical reduction is a promising way to make use of CO$_2$ as feedstock for generating renewable fuel and valuable chemicals. Several metals can be used in the electrocatalyst to generate CO and formic acid but hydrogen formation is an unwanted side reaction that can even be dominant. The lack of selectivity is in general a significant problem, but silver-based electrocatalysts have been shown to be highly selective for CO with over over 90% faradaic efficiency when the applied voltage is below -1 V vs. RHE. Hydrogen formation is then insignificant and little formate is formed even though it is thermodynamically favored. We present calculations of the activation free energy for the various elementary steps as a function of applied voltage at the three low index facets, Ag(111), Ag(100) and Ag(110), as well as experimental measurements on polycrystalline electrodes, to identify the reason for this high selectivity. The formation of formic acid is suppressed because of the low coverage of adsorbed hydrogen and kinetic hindrance to the formation of the HCOO* intermediate, while *COOH, a key intermediate in CO formation, is thermodynamically unstable until the applied voltage reaches -1 V vs. RHE, at which point the kinetics for its formation are more favorable than for hydrogen. The calculated results are consistent with experimental measurements carried out for acidic conditions and provide an atomic scale insight into the high CO selectivity of silver-based electrocatalysts.

cond-mat.mtrl-sci↗

arXiv2025

Electrochemical Interfaces at Constant Potential: Data-Efficient Transfer Learning for Machine-Learning-Based Molecular Dynamics

Simulating electrified metal/water interfaces with explicit solvent under constant potential is essential for understanding electrochemical processes, yet remains prohibitively expensive with ab initio methods. We present TRECI, a data-efficient workflow for constructing machine learning force-fields (ML-FFs) that achieve ab initio-level accuracy in electronically grand-canonical molecular dynamics. By leveraging transfer learning from general-purpose and domain-specific models, TRECI enables stable and accurate simulations across a wide potential range using a reduced number of reference configurations. This efficiency allows the use of high-level meta-GGA functionals and rigorous surface-electrification schemes. Applied to Cu(111)/water, models trained on just one thousand configurations yield accurate molecular dynamics simulations, capturing bias-dependent solvent restructuring effects not previously reported. TRECI offers a general strategy for characterising diverse materials and interfacial chemistries, significantly lowering the cost of realistic constant-potential simulations and expanding access to quantitative electrochemical modelling.

physics.comp-ph↗

arXiv2025

Cosmological horizons

The recently unveiled deep-field images from the James Webb Space Telescope have renewed interest in what we can and cannot see of the universe. Answering these questions requires understanding the so-called "cosmological horizons" and the "Hubble sphere". Here we review the topic of cosmological horizons in a form that university physics teachers can use in their lessons, using the latest data about the so-called standard "Lambda Cold Dark Matter" ($Λ$CDM) model. Graphical representations are plotted in terms of both conformal and proper coordinates as an aid to understanding the propagation of light in the expanding universe at various epochs.

gr-qc↗

arXiv2025

The relationship between episcopal genealogy and ideology in the Roman Catholic Church

In this study we investigate how hierarchical structures within the Roman Catholic Church shape the ideological orientation of its leadership. The full episcopal genealogy dataset comprises over 35,000 bishops, each typically consecrated by one principal consecrator and two co-consecrators, forming a dense and historically continuous directed network of episcopal lineage. Within this broader structure, we focus on a dataset of 245 living cardinals to examine whether genealogical proximity correlates with doctrinal alignment on a broad set of theological and sociopolitical issues. We identify motifs that capture recurring patterns of lineage, such as shared consecrators or co-consecrators. In parallel, we apply natural language processing techniques to extract each cardinal's publicly stated positions on ten salient topics, including LGBTQIA+ rights, women's roles in the Church, liturgy, bioethics, priestly celibacy, and migration. Our results show that cardinals linked by specific genealogical motifs, particularly those who share the same principal consecrator, are significantly more likely to exhibit ideological similarity. We find that the influence of pope John Paul II persists through the bishops he consecrated, who demonstrate systematically more conservative views than their peers. These findings underscore the role of hierarchical mentorship in shaping ideological coherence within large-scale religious institutions. Our contribution offers quantitative evidence that institutional lineages, beyond individual background factors, may have an impact on the transmission and consolidation of doctrinal positions over time.

physics.soc-ph↗

arXiv2025

Optical absorption in hexagonal-diamond Si and Ge nanowires: insights from STEM-EELS experiments and ab initio theory

Hexagonal-diamond (2H) group IV nanowires are key for advancing group IV-based lasers, quantum electronics, and photonics. Understanding their dielectric response is crucial for performance optimization, but their optical absorption properties remain unexplored. We present the first comprehensive study of optical absorption in 2H-Si and 2H-Ge nanowires, combining high-resolution STEM, monochromated EELS, and ab initio simulations. The nanowires, grown in situ in a TEM as nanobranches on GaAs stems, show excellent structural quality: single crystalline, strain-free, minimal defects, no substrate contamination, enabling access to intrinsic dielectric response. 2H-Si exhibits enhanced absorption in the visible range compared to cubic Si, with a marked onset above 2.5 eV. 2H-Ge shows absorption near 1 eV but no clear features at the direct bandgap, as predicted by ab initio simulations. A peak around 2 eV in aloof-beam spectra is attributed to a thin 3C-Ge shell. These findings clarify structure-optical response relationships in 2H materials.

cond-mat.mes-hall↗

arXiv2025

Complex totopapa: predicting the successor to pope Francis

Following the death of Pope Francis, the College of Cardinals will convene in conclave to elect the new Pontiff of the Roman Catholic Church. In this report, we present a computational framework for analyzing the ideological landscape of the cardinal electors and estimating the likely outcomes of the upcoming papal election. We collected public textual data describing each cardinal's positions on a range of topics currently relevant to the Church, including sexuality, migration, poverty, governance and interreligious dialogue. These texts were embedded using a transformer-based language model to construct a semantic similarity matrix among cardinals. We then simulated conclave voting dynamics using this matrix as a proxy for ideological proximity. The model produced both topic-conditioned and aggregate probabilistic forecasts of election outcomes. We report the predicted leading candidates under various scenarios and discuss the structure of factional clustering revealed by the embeddings. The results highlight a polarized field with a small number of structurally central candidates, among whom Pietro Parolin, the former secretary of state, consistently emerges as the most broadly electable across thematic scenarios, followed by both high-profile and outsider names such as card. Brislin and Tagle. Post-election analysis added at the end of the document.

physics.soc-ph↗

arXiv2025

Estimates of the reproduction ratio from epidemic surveillance may be biased in spatially structured populations

Accurate estimates of the reproduction ratio are crucial to project infectious disease epidemic evolution and guide public health response. Here, we prove that estimates of the reproduction ratio based on inference from surveillance data can be inaccurate if the population comprises spatially distinct communities, as the space-mobility interplay may hide the true epidemic evolution from surveillance data. Consequently, surveillance may underestimate the reproduction ratio over long periods, even mistaking growing epidemics as subsiding. To address this, we use the spectral properties of the matrix describing the spatial epidemic spread to reweigh surveillance data. We propose a correction that removes the bias across all epidemic phases. We validate this correction against simulated epidemics and use COVID-19 as a case study. However, our results apply to any epidemic where mobility is a driver of circulation. Our findings will help improve epidemic monitoring and surveillance and inform strategies for public health response.

physics.soc-ph↗

arXiv2024

Giant light emission enhancement in strain-engineered InSe/MS$_2$ (M=Mo,W) van der Waals heterostructures

Two-dimensional crystals stack together through weak van der Waals (vdW) forces, offering unlimited possibilities to play with layer number, order and twist angle in vdW heterostructures (HSs). The realisation of high-performance optoelectronic devices, however, requires the achievement of specific band alignments, $k$-space matching between conduction band minima and valence band maxima, as well as efficient charge transfer between the constituent layers. Fine tuning mechanisms to design ideal HSs are lacking. Here, we show that layer-selective strain engineering can be exploited as an extra degree of freedom in vdW HSs to tailor their band alignment and optical properties. To that end, strain is selectively applied to MS$_2$ (M=Mo,W) monolayers in InSe/MS$_2$ HSs. This triggers a giant PL enhancement of the highly tuneable but weakly emitting InSe by one to three orders of magnitude. Resonant PL excitation measurements, supported by first-principle calculations, provide evidence of a strain-activated direct charge transfer from the MS$_2$ MLs toward InSe. This significant emission enhancement achieved for InSe widens its range of applications for optoelectronics.

cond-mat.mtrl-sci↗

arXiv2021

First-Principles Calculations of Exciton Radiative Lifetimes in Monolayer Graphitic Carbon Nitride Nanosheets: Implications for Photocatalysis

In this work, we report on the exciton radiative lifetimes of graphitic carbon nitride monolayers in the triazine- (gC$_3$N$_4$-t) and heptazine-based (gC$_3$N$_4$-h) forms, as obtained by means of ground- plus excited-state ab initio calculations. By analysing the exciton fine structure, we highlight the presence of dark states and show that the photo-generated electron-hole pairs in gC$_3$N$_4$-h are remarkably long-lived, with an effective radiative lifetime of 260 ns. This fosters the employment of gC$_3$N$_4$-h in photocatalysis and makes it attractive for the emerging field of exciton devices. Although very long intrinsic radiative lifetimes are an important prerequisite for several applications, pristine carbon nitride nanosheets show very low quantum photo-conversion efficiency, mainly due to the lack of an efficient e-h separation mechanism. We then focus on a vertical heterostructure made of gC$_3$N$_4$-t and gC$_3$N$_4$-h layers which shows a type-II band alignment and looks promising for achieving net charge separation.

cond-mat.mtrl-sci↗

arXiv2021

Spatially indirect excitons in black and blue phosphorene double layers

Monolayer black and blue phosphorenes possess electronic and optical properties that result in unique features when the two materials are stacked. We devise a low-strain van-der-Waals double layer and investigate its properties with ab initio many-body perturbation theory techniques. A type-II band alignment and optical absorption in the visible range are found. The study demonstrates that spatially indirect excitons with full charge separation can be obtained between two layers with the same elemental composition but different crystalline structure, proving the system interesting for further studies where dipolar excitons are important and for future opto-electronic applications.

cond-mat.mtrl-sci↗

arXiv2019

A full analytic solution of $SO(10)$-inspired leptogenesis

Recent encouraging experimental results on neutrino mixing parameters prompt further investigation on $SO(10)$-inspired leptogenesis and on the associated strong thermal solution that has correctly predicted a non-vanishing reactor mixing angle, it further predicts $\sinδ\lesssim 0$, now supported by recent results at $\sim 95\%$ C.L., normally ordered neutrino masses and atmospheric mixing angle in the first octant, best fit results in latest global analyses. Extending a recent analytical procedure, we account for the mismatch between the Yukawa basis and the weak basis, that in $SO(10)$-inspired models is described by a CKM-like unitary transformation $V_L$, obtaining a full analytical solution that provides useful insight and reproduces accurately all numerical results, paving the way for future inclusion of different sources of theoretical uncertainties and for a statistical analysis of the constraints. We show how muon-dominated solutions appear for large values of the lightest neutrino mass in the range $(0.01$--$1)\,{\rm eV}$ but also how they necessarily require a mild fine tuning in the seesaw relation. For the dominant (and untuned) tauon-dominated solutions we show how, turning on $V_L \simeq V_{CKM}$, some of the constraints on the low energy neutrino parameters get significantly relaxed. In particular we show how the upper bound on the atmospheric neutrino mixing angle in the strong thermal solution gets relaxed from $θ_{23} \lesssim 41^{\circ}$ to $θ_{23} \lesssim 44^{\circ}$, an important effect in the light of the most recent NO$ν$A, T2K and IceCube results.

hep-ph↗

arXiv2019

Representing seesaw neutrino models and their motion in lepton flavour space

We discuss how seesaw neutrino models can be graphically represented in lepton flavour space. We examine various popular models and show how this representation helps understanding their properties and connection with experimental data showing in particular how certain texture zero models are ruled out. We also introduce a new matrix, the bridging matrix, that brings from the light to the heavy neutrino mass flavour basis, showing how this is related to the orthogonal matrix and how different quantities are easily expressed through it. We then show how one can randomly generate orthogonal and leptonic mixing matrices uniformly covering all flavour space in an unbiased way (Haar-distributed matrices). Using the isomorphism between the group of complex rotations and the Lorentz group, we also introduce the conceptof Lorentz boost in flavour space for a seesaw model and how this has an insightful physical interpretation. Finally, as a significant application, we consider $N_2$-leptogenesis. Using current experimental values of low energy neutrino parameters, we show that the probability that at least one flavoured decay parameter of the lightest right-handed neutrino is smaller than unity is about $49\%$ (to be compared with the tiny probability that the total decay parameter is smaller than unity, $P(K_{\rm I}< 1)\sim 0.1 \%$, confirming the crucial role played by flavour effects). On the other hand when $m_1 \gtrsim 0.1\,{\rm eV}$ this probability reduces to less than $5\%$, showing how also $N_2$-leptogenesis disfavours degenerate light neutrinos.

hep-ph↗

arXiv2018

Epidemic Threshold in Continuous-Time Evolving Networks

Current understanding of the critical outbreak condition on temporal networks relies on approximations (time scale separation, discretization) that may bias the results. We propose a theoretical framework to compute the epidemic threshold in continuous time through the infection propagator approach. We introduce the {\em weak commutation} condition allowing the interpretation of annealed networks, activity-driven networks, and time scale separation into one formalism. Our work provides a coherent connection between discrete and continuous time representations applicable to realistic scenarios.

physics.soc-ph↗

arXiv2016

Supersymmetric $SO(10)$-inspired leptogenesis and a new $N_2$-dominated scenario

We study the supersymmetric extension of $SO(10)$-inspired thermal leptogenesis showing the constraints on neutrino parameters and on the reheat temperature $T_{\rm RH}$ that derive from the condition of successful leptogenesis from next-to-lightest right handed (RH) neutrinos ($N_2$) decays and the more stringent ones when independence of the initial conditions (strong thermal leptogenesis) is superimposed. In the latter case, the increase of the lightest right-handed neutrino ($N_1$) decay parameters helps the wash-out of a pre-existing asymmetry and constraints relax compared to the non-supersymmetric case. We find significant changes especially in the case of large $\tanβ$ values $(\gtrsim 15)$. In particular, for normal ordering, the atmospheric mixing angle can now be also maximal. The lightest (ordinary) neutrino mass is still constrained within the range $10 \lesssim m_1/{\rm meV} \lesssim 30$ (corresponding to $75\lesssim \sum_i m_i/{\rm meV} \lesssim 120$). Inverted ordering is still disfavoured, but an allowed region satisfying strong thermal leptogenesis opens up at large $\tanβ$ values. We also study in detail the lower bound on $T_{\rm RH}$ finding $T_{\rm RH}\gtrsim 1 \times 10^{10}\,{\rm GeV}$ independently of the initial $N_2$ abundance. Finally, we propose a new $N_2$-dominated scenario where the $N_1$ mass is lower than the sphaleron freeze-out temperature. In this case there is no $N_1$ wash-out and we find $T_{\rm RH} \gtrsim 1\times 10^{9}\,{\rm GeV}$. These results indicate that $SO(10)$-inspired thermal leptogenesis can be made compatible with the upper bound from the gravitino problem, an important result in light of the role often played by supersymmetry in the quest of a realistic model of fermion masses.

hep-ph↗

arXiv2015

FaRe: a Mathematica package for tensor reduction of Feynman integrals

We present FaRe, a package for Mathematica that implements the decomposition of a generic tensor Feynman integral, with arbitrary loop number, into scalar integrals in higher dimension. In order for FaRe to work, the package FeynCalc is needed, so that the tensor structure of the different contributions is preserved and the obtained scalar integrals are grouped accordingly. FaRe can prove particularly useful when it is preferable to handle Feynman integrals with free Lorentz indices and tensor reduction of high-order integrals is needed. This can then be achieved with several powerful existing tools.

hep-ph↗

arXiv2015

Decrypting $SO(10)$-inspired leptogenesis

Encouraged by the recent results from neutrino oscillation experiments, we perform an analytical study of $SO(10)$-inspired models and leptogenesis with hierarchical right-handed (RH) neutrino spectrum. Under the approximation of negligible misalignment between the neutrino Yukawa basis and the charged lepton basis, we find an analytical expression for the final asymmetry directly in terms of the low energy neutrino parameters that fully reproduces previous numerical results. This expression also shows that is possible to identify an effective leptogenesis phase for these models. When we also impose the wash-out of a large pre-existing asymmetry $N^{\rm p,i}_{B-L}$, the strong thermal (ST) condition, we derive analytically all those constraints on the low energy neutrino parameters that characterise the {\rm ST}-$SO(10)$-inspired leptogenesis solution, confirming previous numerical results. In particular we show why, though neutrino masses have to be necessarily normally ordered, the solution implies an analytical lower bound on the effective neutrino-less double beta decay neutrino mass, $m_{ee} \gtrsim 8\,{\rm meV}$, for $N^{\rm p,i}_{B-L}=10^{-3}$, testable with next generation experiments. This, in combination with an upper bound on the atmospheric mixing angle, necessarily in the first octant, forces the lightest neutrino mass within a narrow range $m_1 \simeq (10$-$30)\,{\rm meV}$ (corresponding to $\sum_i \, m_i \simeq (75$-$125)\,{\rm meV}$). We also show why the solution could correctly predict a non-vanishing reactor neutrino mixing angle and requires the Dirac phase to be in the fourth quadrant, implying $\sinδ$ (and $J_{CP}$) negative as hinted by current global analyses. Many of the analytical results presented (expressions for the orthogonal matrix, RH neutrino mixing matrix, masses and phases) can have applications beyond leptogenesis.

hep-ph↗