arXiv subjects

Michiel R. Hogerheijde

Publications and source records attributed to Michiel R. Hogerheijde.

At least 19 recordsLinked to original sources

arXiv2026

The asymmetric carbon-rich chemistry of the planet-forming disk of HD 142527 triggered by late infall

The planet-forming disk of HD 142527 is known for its azimuthally asymmetric dust trap, shadows, and spiral arms. We use new ALMA observations to investigate the molecular composition and to determine the ongoing chemical processes and the origin of its asymmetric molecular emission. The observations cover a wide variety of molecular species, enlarging the known molecular inventory of this system. Strikingly, the emission of H$_2$CO, CN, and C$_2$H is dominated by spiral-like features peaking in the southern region of the disk, opposite to the large dust trap, while no relation is found between the observed asymmetries and the shadows seen in the scattered light. We attribute these features to low-density, late infalling, atomic carbon-rich material that locally enhances the C/O-ratio and, subsequently, facilitates the gas-phase formation of these species. The emission of C$^{17}$O and the HCO$^+$ $J$=1-0 transition is aligned with the large dust trap, likely due to an azimuthal enhancement in the surface density. Differences between the two observed C$^{17}$O transitions may be due to dust obscuration effects. This is not expected to affect molecular emission at 3 millimetres, given the lower optical depth of the dust trap. The four observed transitions of CS display different azimuthal extents and strengths, with the lines with lower upper level energies appearing more ring-like. An analysis of the $^{13}$CO brightness temperature yields no significant azimuthal temperature variations. Therefore, we propose that the observed CS transitions trace two different reservoirs: a cold reservoir that resides on a Keplerian orbit and a second, hotter reservoir of CS that is facilitated by the infalling material. A single weak transition of SO is observed, which may be explained by weak shocks induced by the spirals observed in the scattered light that liberate sulphur.

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arXiv2025

The ALMA Survey of Gas Evolution of PROtoplanetary Disks (AGE-PRO): I. Program Overview and Summary of First Results

We present the ALMA Survey of Gas Evolution of PROtoplanetary Disks (AGE-PRO), a Large Program of the Atacama Large Millimeter/submillimeter Array (ALMA). AGE-PRO aims to systematically trace the evolution of gas disk mass and size throughout the lifetime of protoplanetary disks. It uses a carefully selected sample of 30 disks around M3-K6 stars in three nearby star-forming regions: Ophiuchus (0.5-1 Myr), Lupus (1-3 Myr), and Upper Sco (2-6 Myr). Assuming the three regions had similar initial conditions and evolutionary paths, we find the median gas disk mass appears to decrease with age. Ophiuchus disks have the highest median gas mass (6 M$_{\rm Jup}$), while the Lupus and Upper Sco disks have significantly lower median masses (0.68 and 0.44 M$_{\rm Jup}$, respectively). Notably, the gas and dust disk masses appear to evolve on different timescales. This is evidenced by the median gas-to-dust mass ratio, which decreases from 122 in the youngest disks ($<$1 Myr) to 46 in Lupus disks, and then increases to 120 in the Upper Sco disks. The median gas disk sizes range between 74-110 au, suggesting that typical gas disks are much smaller than those of well-studied, massive disks. Population synthesis models suggest that magneto-hydrodynamic wind-driven accretion can reproduce median disk properties across all three regions, when assuming compact disks with a declining magnetic field over time. In contrast, turbulent-driven models overestimate gas masses of $>$1 Myr disks by an order of magnitude. Here we discuss the program's motivation, survey design, sample selection, observation and data calibration processes, and highlight the initial results.

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arXiv2025

The ALMA Survey of Gas Evolution of PROtoplanetary Disks (AGE-PRO): IV. Dust and Gas Disk Properties in the Upper Scorpius Star-forming Region

The Atacama Large Millimeter/submillimeter Array (ALMA) large program AGE-PRO explores protoplanetary disk evolution by studying gas and dust across various ages. This work focuses on ten evolved disks in Upper Scorpius, observed in dust continuum emission, CO and its isotopologues, and N$_2$H$^+$ with ALMA Bands 6 and 7. Disk radii, from the radial location enclosing 68% of the flux, are comparable to those in the younger Lupus region for both gas and dust tracers. However, solid masses are about an order of magnitude below those in Lupus and Ophiuchus, while the dust spectral index suggests some level of dust evolution. These empirical findings align with a combination of radial drift, dust trapping, and grain growth into larger bodies. A moderate correlation between CO and continuum fluxes suggests a link between gas and dust content, through the increased scatter compared to younger regions, possibly due to age variations, gas-to-dust ratio differences, or CO depletion. Additionally, the correlation between C$^{18}$O and N$_2$H$^+$ fluxes observed in Lupus persists in Upper Sco, indicating a relatively stable CO gas abundance over the Class II stage of disk evolution. In conclusion, the AGE-PRO survey of Upper Scorpius disks reveals intriguing trends in disk evolution. The findings point towards potential gas evolution and the presence of dust traps in these older disks. Future high-resolution observations are needed to confirm these possibilities and further refine our understanding of disk evolution and planet formation in older environments.

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arXiv2025

The ALMA Survey of Gas Evolution of PROtoplanetary Disks (AGE-PRO): III. Dust and Gas Disk Properties in the Lupus Star-forming Region

We present Band 6 and Band 7 observations of 10 Lupus disks around M3-K6 stars from the ALMA survey of Gas Evolution in PROtoplanetary disks (AGE-PRO) Large Program. In addition to continuum emission in both bands, our Band 6 setup covers the $\mathrm{{}^{12}CO}$, $\mathrm{{}^{13}CO}$ and $\mathrm{C^{18}O}\,J$=2-1 lines, while our Band 7 setup covers the $\mathrm{N_2H^+}\,J$=3-2 line. All of our sources are detected in $\mathrm{{}^{12}CO}$ and $\mathrm{{}^{13}CO}$, 7 out of 10 are detected in $\mathrm{C^{18}O}$, and 3 are detected in $\mathrm{N_2H^+}$. We find strong correlations between the CO isotopologue line fluxes and the continuum flux densities. With the exception of one disk, we also identify a strong correlation between the $\mathrm{C^{18}O}\,J$=2-1 and $\mathrm{N_2H^+}\,J$=3-2 fluxes, indicating similar CO abundances across this sample. For the two sources with well-resolved continuum and $\mathrm{{}^{12}CO}\,J$=2-1 images, we find that their gas-to-dust size ratio is consistent with the median value of $\sim 2$ inferred from a larger sample of Lupus disks. We derive dust disk masses from continuum flux densities. We estimate gas disk masses by comparing $\mathrm{C^{18}O}\,J$=2-1 line fluxes with those predicted by the limited grid of self-consistent disk models of Ruaud et al. (2022). A comparison of these mass estimates with those derived by Trapman et al. (2025), using a combination of CO isotopologue and $\mathrm{N_2H^+}$ line emission, shows that the masses are consistent with each other. Some discrepancies appear for small and faint disks, but they are still within the uncertainties. Both methods find gas disk masses increase with dust disk masses, and gas-to-dust mass ratios are between $10-100$ in the AGE-PRO Lupus sample.

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arXiv2025

The ALMA Survey of Gas Evolution of PROtoplanetary Disks (AGE-PRO): V. Protoplanetary gas disk masses

The evolution of the gas mass of planet-forming disks around young stars is crucial for our understanding of planet formation, yet it has proven hard to constrain observationally, due both to the difficulties of measuring gas masses and the lack of a homogeneous sample. Here we present a large grid of thermochemical models which we use to measure protoplanetary gas disk masses of AGE-PRO, the ALMA survey of Gas Evolution in PROtoplanetary disks. AGE-PRO covers a sample of 30 disks around similar spectral type (M3-K6) stars with ages between 0.1 and 10 Myr. Our approach is to simultaneously fit observations of CO isotopologues and N2H+, a complementary molecule produced when CO freezes out. We find that the median gas mass of the three regions decreases over time, from 7.0(+4.4,-2.6)x10^-3 Msun in Ophiuchus (<1 Myr) to 9.4(+5.4,-3.4)x10^-4 Msun for Lupus (~1-3 Myr) and 6.8(+5.1,-2.8)x10^-4 Msun for Upper Sco (~2-6 Myr), with ~1 dex scatter in gas mass in each region. We note that the gas mass distributions for Lupus and Upper Sco look very similar, which could be due to survivorship bias for the latter. The median bulk CO abundance in the CO emitting layer is found to be a factor ~10 lower than the ISM value but does not significantly change between Lupus and Upper Sco. From Lupus to Upper Sco the median gas-to-dust mass ratio increases by a factor ~3 from ~40 to ~120, suggesting efficient inward pebble drift and/or the formation of planetesimals.

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arXiv2025

The ALMA Survey of Gas Evolution of PROtoplanetary Disks (AGE-PRO): VII. Testing accretion mechanisms from disk population synthesis

The architecture of planetary systems depends on the evolution of the disks in which they form. In this work, we develop a population synthesis approach to interpret the AGE-PRO measurements of disk gas mass and size considering two scenarios: turbulence-driven evolution with photoevaporative winds and MHD disk-wind-driven evolution. A systematic method is proposed to constrain the distribution of disk parameters from the disk fractions, accretion rates, disk gas masses, and CO gas sizes. We find that turbulence-driven accretion with initially compact disks ($R_0 \simeq 5-20~$au), low mass-loss rates, and relatively long viscous timescales ($t_{ν,0} \simeq 0.4-3~$Myr or $α_{SS} \simeq 2-4 \times 10^{-4}$) can reproduce the disk fraction and gas sizes. However, the distribution of apparent disk lifetime defined as the $M_D/\dot{M}_*$ ratio is severely overestimated by turbulence-driven models. On the other hand, MHD wind-driven accretion can reproduce the bulk properties of the disk populations from Ophiuchus to Upper Sco assuming compact disks with an initial magnetization of about $β\simeq 10^5$ ($α_{DW} \simeq 0.5-1 \times 10^{-3}$) and a magnetic field that declines with time. More studies are needed to confirm the low masses found by AGE-PRO, notably for compact disks that question turbulence-driven accretion. The constrained synthetic disk populations can now be used for realistic planet population models to interpret the properties of planetary systems on a statistical basis.

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arXiv2024

Radial and vertical constraints on the icy origin of H$_{2}$CO in the HD 163296 Protoplanetary Disk

H$_2$CO is a small organic molecule widely detected in protoplanetary disks. As a precursor to grain-surface formation of CH$_3$OH, H$_2$CO is considered an important precursor of O-bearing organic molecules that are locked in ices. Still, since gas-phase reactions can also form H$_2$CO, there remains an open question on the channels by which organics form in disks, and how much the grain versus the gas pathways impact the overall organic reservoir. We present spectrally and spatially resolved Atacama Large Millimeter/submillimeter Array observations of several ortho- and para-H$_2$CO transitions toward the bright protoplanetary disk around the Herbig Ae star HD 163296. We derive column density, excitation temperature, and ortho-to-para ratio (OPR) radial profiles for H$_2$CO, as well as disk-averaged values of $N_{\mathrm{T}}\sim4\times 10^{12}$ cm$^{-2}$, $T_{\mathrm{ex}}\sim20$ K, and $\mathrm{OPR}\sim2.7$, respectively. We empirically determine the vertical structure of the emission, finding vertical heights of $z/r\sim0.1$. From the profiles, we find a relatively constant $\mathrm{OPR}\sim2.7$ with radius, but still consistent with $3.0$ among the uncertainties, a secondary increase of $N_{\mathrm{T}}$ in the outer disk, and low $T_{\mathrm{ex}}$ values that decrease with disk radius. Our resulting radial, vertical, and OPR constraints suggest an increased UV penetration beyond the dust millimeter edge, consistent with an icy origin but also with cold gas-phase chemistry. This Herbig disk contrasts previous results for the T Tauri disk, TW Hya, which had a larger contribution from cold gas-phase chemistry. More observations of other sources are needed to disentangle the dominant formation pathway of H$_2$CO in protoplanetary disks.

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arXiv2023

The $\dot{M}$--$M_{\rm{disk}}$ relationship for Herbig Ae/Be stars: a lifetime problem for disks with low masses?

The accretion of material from protoplanetary disks onto their central stars is a fundamental process in the evolution of these systems and a key diagnostic in constraining the disk lifetime. We analyze the relationship between the stellar accretion rate and the disk mass in 32 intermediate-mass Herbig Ae/Be systems and compare them to their lower-mass counterparts, T Tauri stars. We find that the $\dot{M}$--$M_{\rm{disk}}$ relationship for Herbig Ae/Be stars is largely flat at $\sim$10$^{-7}$ M$_{\odot}$ yr$^{-1}$ across over three orders of magnitude in dust mass. While most of the sample follows the T Tauri trend, a subset of objects with high accretion rates and low dust masses are identified. These outliers (12 out of 32 sources) have an inferred disk lifetime of less than 0.01 Myr and are dominated by objects with low infrared excess. This outlier sample is likely identified in part by the bias in classifying Herbig Ae/Be stars, which requires evidence of accretion that can only be reliably measured above a rate of $\sim$10$^{-9}$ M$_{\odot}$ yr$^{-1}$ for these spectral types. If the disk masses are not underestimated and the accretion rates are not overestimated, this implies that these disks may be on the verge of dispersal, which may be due to efficient radial drift of material or outer disk depletion by photoevaporation and/or truncation by companions. This outlier sample likely represents a small subset of the larger young, intermediate-mass stellar population, the majority of which would have already stopped accreting and cleared their disks.

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arXiv2023

Disk Evolution Study Through Imaging of Nearby Young Stars (DESTINYS): Diverse outcomes of binary-disk interactions

Circumstellar disks do not evolve in isolation, as about half of solar-type stars were born in binary or multiple systems. Resolving disks in binary systems provides the opportunity to examine the influence of stellar companions on the outcomes of planet formation. We aim to investigate and compare disks in stellar multiple systems with near-infrared scattered-light imaging as part of the Disk Evolution Study Through Imaging of Nearby Young Stars (DESTINYS) program. We used polarimetric differential imaging with SPHERE/IRDIS at the VLT to search for scattered light from the circumstellar disks in three multiple systems, CHX 22, S CrA, and HP Cha. We performed astrometric and orbit analyses for the stellar companions using archival HST, VLT/NACO, and SPHERE data. Combined with the age and orbital constraints, the observed disk structures provide insights into the evolutionary history and the impact of the stellar companions. The small grains in CHX 22 form a tail-like structure surrounding the close binary, which likely results from a close encounter and capture of a cloudlet. S CrA shows intricate structures (tentative ringed and spiral features) in the circumprimary disk as a possible consequence of perturbations by companions. The circumsecondary disk is truncated and connected to the primary disk via a streamer, suggesting tidal interactions. In HP Cha, the primary disk is less disturbed and features a tenuous streamer, through which the material flows towards the companions. The comparison of the three systems spans a wide range of binary separation (50 - 500 au) and illustrates the decreasing influence on disk structures with the distance of companions. This agrees with the statistical analysis of exoplanet population in binaries, that planet formation is likely obstructed around close binary systems, while it is not suppressed in wide binaries.

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arXiv2021

Which molecule traces what: chemical diagnostics of protostellar sources

The physical and chemical conditions in Class 0/I protostars are fundamental in unlocking the protostellar accretion process and its impact on planet formation. The aim is to determine which physical components are traced by different molecules at sub-arcsecond scales (100 - 400 au). We use a suite of Atacama Large Millimeter/submillimeter Array (ALMA) datasets in Band 6 (1 mm), Band 5 (1.8 mm) and Band 3 (3 mm) at spatial resolutions 0.5 - 3" for 16 protostellar sources. The protostellar envelope is well traced by C$^{18}$O, DCO$^+$ and N$_2$D$^+$, with the freeze-out of CO governing the chemistry at envelope scales. Molecular outflows are seen in classical shock tracers like SiO and SO, but ice-mantle products such as CH$_3$OH and HNCO released with the shock are also observed. The molecular jet is prominent not only in SiO and SO but also occasionally in H$_2$CO. The cavity walls show tracers of UV-irradiation such as C$_2$H c-C$_3$H$_2$ and CN. The hot inner envelope, apart from showing emission from complex organic molecules (COMs), also presents compact emission from small molecules like H$_2$S, SO, OCS and H$^{13}$CN, most likely related to ice sublimation and high-temperature chemistry. Sub-arcsecond millimeter-wave observations allow to identify those (simple) molecules that best trace each of the physical components of a protostellar system. COMs are found both in the hot inner envelope (high excitation lines) and in the outflows (lower-excitation lines) with comparable abundances. COMs can coexist with hydrocarbons in the same protostellar sources, but they trace different components. In the near future, mid-IR observations with JWST-MIRI will provide complementary information about the hottest gas and the ice mantle content, at unprecedented sensitivity and at resolutions comparable to ALMA for the same sources.

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arXiv2021

Infrared spectra of complex organic molecules in astronomically relevant ice matrices. III. Methyl formate and its tentative solid-state detection

Context. Infrared spectroscopy of star and planet forming regions is at the dawn of a new age with the upcoming James Webb Space Telescope. In support of these observations, laboratory spectra are required to identify complex organic molecules in the ices that cover the dust grains in these regions. Aims. This study aims to provide reference spectra to firmly detect icy methyl formate in the different stages of star and planet forming regions. Methyl formate is mixed in astronomically relevant matrices, and the peak positions, FWHMs, and relative band intensities are characterized for different temperatures to provide an analytical tool for astronomers. Methods. Methyl formate is deposited at 15 K under high-vacuum conditions. Specifically, methyl formate is deposited pure and mixed with CO, H$_2$CO, CH$_3$OH, H$_2$O, and CO:H$_2$CO:CH$_3$OH combined. Throughout the experiment infrared spectra are acquired with a FTIR spectrometer in the range from 4000-500 cm$^{-1}$ (2.5-20 $μ$m) at a spectral resolution of 0.5 cm$^{-1}$. Results. We present the characterization of five solid-state methyl formate vibrational modes in pure and astronomically relevant ice matrices. The five selected vibrational modes, namely the C=O stretch, C$-$O stretch, CH$_3$ rocking, O$-$CH$_3$ stretching, and OCO deformation, are best suited for a JWST identification of methyl formate. For each of these vibrational modes, and each of the mixtures the TvS heatmaps, peak position versus FWHM, and relative band intensities are given. Additionally, the acquired reference spectra of methyl formate are compared with Spitzer observations of HH 46. A tentative detection of methyl formate provides an upper limit to the column density of $1.7\times10^{17}$ cm$^{-2}$, corresponding to an upper limit relative to water of $\leq 2.2\%$ and $\leq 40\%$ with respect to methanol.

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arXiv2021

An inherited complex organic molecule reservoir in a warm planet-hosting disk

Quantifying the composition of the material in protoplanetary disks is paramount to determining the potential for exoplanetary systems to produce and support habitable environments. A key complex organic molecule (COM) to detect is methanol (CH3OH). CH3OH primarily forms at low temperatures via the hydrogenation of CO ice on the surface of icy dust grains and is a necessary basis for the formation of more complex species like amino acids and proteins. We report the detection of CH3OH in a disk around a young, luminous A-type star HD100546. This disk is warm and therefore does not host a significant CO ice reservoir. We argue that the CH3OH cannot form in situ, and hence, this disk has likely inherited COMs rich ice from an earlier cold dark cloud phase. This is strong evidence that at least some of the organic material survives the disk formation process and can then be incorporated into forming planets, moons and comets. Therefore, crucial pre-biotic chemical evolution already takes place in dark star-forming clouds.

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arXiv2021

CO isotopolog line fluxes of viscously evolving disks: cold CO conversion insufficient to explain observed low fluxes

Protoplanetary disks are thought to evolve viscously, where the disk mass - the reservoir available for planet formation - decreases over time as material is accreted onto the central star. Observations show a correlation between dust mass and the stellar accretion rate, as expected from viscous theory. However, the gas mass inferred from 13CO and C18O line fluxes, which should be a more direct measure, shows no such correlation. Using thermochemical DALI models, we investigate how 13CO and C18O J=3-2 line fluxes change over time in a viscously evolving disk. We also investigate if the chemical conversion of CO through grain-surface chemistry combined with viscous evolution can explain the observations of disks in Lupus. The 13CO and C18O 3-2 line fluxes increase over time due to their optically thick emitting regions growing in size as the disk expands viscously. The C18O 3-2 emission is optically thin throughout the disk for only a subset of our models (Mdisk (t = 1 Myr) < 1e-3 Msun). For these disks the integrated C18O flux decreases with time, similar to the disk mass. The C18O 3-2 fluxes for the bulk of the disks in Lupus (with Mdust < 5e-5 Msun) can be reproduced to within a factor of ~2 with viscously evolving disks in which CO is converted into other species through grain-surface chemistry driven by a cosmic-ray ionization rate zeta_cr ~ 5e-17 - 1e-16 s^-1. However, explaining the stacked C18O upper limits requires a lower average abundance than our models can produce and they cannot explain the observed 13CO fluxes, which, for most disks, are more than an order of magnitude fainter than what our models predict. Reconciling the 13CO fluxes of viscously evolving disks with the observations requires either a combination of efficient vertical mixing and a high zeta_cr or low mass disks (Mdust < 3e-5 Msun) being much thinner and/or smaller than their more massive counterparts.

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arXiv2021

The TW Hya Rosetta Stone Project IV: A hydrocarbon rich disk atmosphere

Connecting the composition of planet-forming disks with that of gas giant exoplanet atmospheres, in particular through C/O ratios, is one of the key goals of disk chemistry. Small hydrocarbons like $\rm C_2H$ and $\rm C_3H_2$ have been identified as tracers of C/O, as they form abundantly under high C/O conditions. We present resolved $\rm C_3H_2$ observations from the TW Hya Rosetta Stone Project, a program designed to map the chemistry of common molecules at $15-20$ au resolution in the TW Hya disk. Augmented by archival data, these observations comprise the most extensive multi-line set for disks of both ortho and para spin isomers spanning a wide range of energies, $E_u=29-97$ K. We find the ortho-to-para ratio of $\rm C_3H_2$ is consistent with 3 throughout extent of the emission, and the total abundance of both $\rm C_3H_2$ isomers is $(7.5-10)\times10^{-11}$ per H atom, or $1-10$% of the previously published $\rm C_2H$ abundance in the same source. We find $\rm C_3H_2$ comes from a layer near the surface that extends no deeper than $z/r=0.25$. Our observations are consistent with substantial radial variation in gas-phase C/O in TW Hya, with a sharp increase outside $\sim30$ au. Even if we are not directly tracing the midplane, if planets accrete from the surface via, e.g., meridonial flows, then such a change should be imprinted on forming planets. Perhaps interestingly, the HR 8799 planetary system also shows an increasing gradient in its giant planets' atmospheric C/O ratios. While these stars are quite different, hydrocarbon rings in disks are common, and therefore our results are consistent with the young planets of HR 8799 still bearing the imprint of their parent disk's volatile chemistry.

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arXiv2020

The TW Hya Rosetta Stone Project III: Resolving the Gaseous Thermal Profile of the Disk

The thermal structure of protoplanetary disks is a fundamental characteristic of the system that has wide reaching effects on disk evolution and planet formation. In this study, we constrain the 2D thermal structure of the protoplanetary disk TW Hya structure utilizing images of seven CO lines. This includes new ALMA observations of 12CO J=2-1 and C18O J=2-1 as well as archival ALMA observations of 12CO J=3-2, 13CO J=3-2, 6-5, C18O J= 3-2, 6-5. Additionally, we reproduce a Herschel observation of the HD J=1-0 line flux, the spectral energy distribution, and utilize a recent quantification of CO radial depletion in TW Hya. These observations were modeled using the thermochemical code RAC2D, and our best fit model reproduces all spatially resolved CO surface brightness profiles. The resulting thermal profile finds a disk mass of 0.025 Msun and a thin upper layer of gas depleted of small dust with a thickness of approx 1.2% of the corresponding radius. Using our final thermal structure, we find that CO alone is not a viable mass tracer as its abundance is degenerate with the total H2 surface density. Different mass models can readily match the spatially resolved CO line profiles with disparate abundance assumptions. Mass determination requires additional knowledge and, in this work, HD provides the additional constraint to derive the gas mass and supports the inference of CO depletion in the TW Hya disk. Our final thermal structure confirms the use of HD as a powerful probe of protoplanetary disk mass. Additionally, the method laid out in this paper is an employable strategy for extraction of disk temperatures and masses in the future.

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arXiv2020

The TW Hya Rosetta Stone Project I: Radial and vertical distributions of DCN and DCO+

Molecular D/H ratios are frequently used to probe the chemical past of Solar System volatiles. Yet it is unclear which parts of the Solar Nebula hosted an active deuterium fractionation chemistry. To address this question, we present 0".2-0".4 ALMA observations of DCO+ and DCN 2-1, 3-2 and 4-3 towards the nearby protoplanetary disk around TW Hya, taken as part of the TW Hya Rosetta Stone project, augmented with archival data. DCO+ is characterized by an excitation temperature of ~40 K across the 70 au radius pebble disk, indicative of emission from a warm, elevated molecular layer. Tentatively, DCN is present at even higher temperatures. Both DCO+ and DCN present substantial emission cavities in the inner disk, while in the outer disk the DCO+ and DCN morphologies diverge: most DCN emission originates from a narrow ring peaking around 30~au, with some additional diffuse DCN emission present at larger radii, while DCO+ is present in a broad structured ring that extends past the pebble disk. Based on parametric disk abundance models, these emission patterns can be explained by a near-constant DCN abundance exterior to the cavity, and an increasing DCO+ abundance with radius. There appears to be an active deuterium fractionation chemistry in multiple disk regions around TW Hya, but not in the cold planetesimal-forming midplane and in the inner disk. More observations are needed to explore whether deuterium fractionation is actually absent in these latter regions, and if its absence is a common feature, or something peculiar to the old TW Hya disk.

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arXiv2020

The TW Hya Rosetta Stone Project II: Spatially resolved emission of formaldehyde hints at low-temperature gas-phase formation

Formaldehyde (H$_2$CO) is an important precursor to organics like methanol (CH$_3$OH). It is important to understand the conditions that produce H$_2$CO and prebiotic molecules during star and planet formation. H$_2$CO possesses both gas-phase and solid-state formation pathways, involving either UV-produced radical precursors or CO ice and cold ($\lesssim 20$ K) dust grains. To understand which pathway dominates, gaseous H$_2$CO's ortho-to-para ratio (OPR) has been used as a probe, with a value of 3 indicating "warm" conditions and $<3$ linked to cold formation in the solid-state. We present spatially resolved ALMA observations of multiple ortho- and para-H$_2$CO transitions in the TW Hya protoplanetary disk to test H$_2$CO formation theories during planet formation. We find disk-averaged rotational temperatures and column densities of $33\pm2$ K, ($1.1\pm0.1)\times10^{12}$ cm$^{-2}$ and $25\pm2$ K, $(4.4\pm0.3)\times10^{11}$ cm$^{-2}$ for ortho- and para-H$_2$CO, respectively, and an OPR of $2.49\pm0.23$. A radially resolved analysis shows that the observed H$_2$CO emits mostly at rotational temperatures of 30-40 K, corresponding to a layer with $z/R\ge0.25$. The OPR is consistent with 3 within 60 au, the extent of the pebble disk, and decreases beyond 60 au to $2.0\pm0.5$. The latter corresponds to a spin temperature of 12 K, well below the rotational temperature. The combination of relatively uniform emitting conditions, a radial gradient in the OPR, and recent laboratory experiments and theory on OPR ratios after sublimation, lead us to speculate that gas-phase formation is responsible for the observed H$_2$CO across the TW Hya disk.

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arXiv2019

Molecular complexity on disk-scales uncovered by ALMA: The chemical composition of the high-mass protostar AFGL 4176

The chemical composition of high-mass protostars reflects the physical evolution associated with different stages of star formation. In this study, the molecular inventory of the forming high-mass star AFGL 4176 is studied in detail at high angular resolution (~0.35 arcsec) using ALMA. This high resolution makes it possible to separate the emission associated with the inner hot envelope and disk around the forming star from that of its cool outer envelope. In addition, the high sensitivity of ALMA makes it possible to identify weak and optically thin lines and allows for many isotopologues to be detected, providing a more complete and accurate inventory of the source. A total of 23 different molecular species and their isotopologues are detected in the spectrum towards AFGL 4176. The most abundant species is methanol (CH3OH), remaining species are present at levels between 0.003 % and 15 % with respect to CH3OH. Hints that N-bearing species peak slightly closer to the location of the peak continuum emission than the O-bearing species are seen. AFGL 4176 comprises a rich chemical inventory including many complex species present on disk-scales. On average, the derived column density ratios with respect to methanol of O-bearing species are higher than those derived for N-bearing species by a factor of three. This may indicate that AFGL 4176 is a relatively young source since nitrogen chemistry generally takes longer to evolve in the gas-phase. Taking methanol as a reference, the composition of AFGL 4176 more closely resembles that of the low-mass protostar IRAS 16293-2422B than that of high-mass star-forming regions located near the Galactic centre. This similarity hints that the chemical composition of complex species is already set in the cold cloud stage and implies that AFGL 4176 is a young source whose chemical composition has not yet been strongly processed by the central protostar.

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