arXiv subjects

Mihael S. Grbić

Publications and source records attributed to Mihael S. Grbić.

8 recordsLinked to original sources

arXiv2024

Properties of an organic model $S=1$ Haldane chain system

We present the properties of a new organic $S=1$ antiferromagnetic chain system $m$-NO$_2$PhBNO (abbreviated BoNO). In this biradical system two unpaired electrons from aminoxyl groups are strongly ferromagnetically coupled ($|J_\text{FM}| /k_B \gtrsim 500$ K) which leads to the formation of an effective $S=1$ state for each molecule. The chains of BoNO biradicals propagate along the crystallographic $a$ axis. Temperature dependence of the $g$ factor and electron paramagnetic resonance (EPR) linewidth are consistent with a low-dimensional system with antiferromagnetic interactions. The EPR data further suggest that BoNO is the first known Haldane system with an almost isotropic $g$ factor ($2.0023 \pm 2 \unicode{x2030}$). The magnetization measurements in magnetic fields up to $40$ T and low-field susceptibility, together with $^1$H nuclear magnetic resonance (NMR) spectra, reveal a dominant intrachain antiferromagnetic exchange coupling of $J_\text{1D}/k_B = (11.3\pm0.1)$ K, and attainable critical magnetic fields of $μ_0 H_\text{c1} \approx 2$ T and $μ_0 H_\text{c2} \approx 33$ T. These measurements therefore suggest that BoNO is a unique Haldane system with extremely small magnetic anisotropy. Present results are crucial for a future in-depth NMR study of the low-temperature Tomonaga-Luttinger liquid (TLL) and magnetic field-induced phases, which can be performed in the entire phase space.

cond-mat.str-el↗

arXiv2023

Uniaxial stress study of spin and charge stripes in La$_{1.875}$Ba$_{0.125}$CuO$_{4}$ by $^{139}$La NMR and $^{63}$Cu NQR

We study the response of spin and charge order in single crystals of La$_{1.875}$Ba$_{0.125}$CuO$_{4}$ to uniaxial stress, through $^{139}$La nuclear magnetic resonance (NMR) and $^{63}$Cu nuclear quadrupole resonance (NQR), respectively. In unstressed La$_{1.875}$Ba$_{0.125}$CuO$_{4}$, the low-temperature tetragonal structure onsets below $T_{\text{LTT}} = 57$K, while the charge order and the spin order transition temperatures are $T_\text{CO} = 54$K and $T_\text{SO} = 37$K, respectively. We find that uniaxial stress along the [110] lattice direction strongly suppresses $T_\text{CO}$ and $T_{\text{SO}}$, but has little effect on $T_\text{LTT}$. In other words, under stress along [110] a large splitting ($\approx 21$K) opens between $T_\text{CO}$ and $T_{\text{LTT}}$, showing that these transitions are not tightly linked. On the other hand, stress along [100] causes a slight suppression of $T_\text{LTT}$ but has essentially no effect on $T_\text{CO}$ and $T_{\text{SO}}$. Magnetic field $H$ along [110] stabilizes the spin order: the suppression of $T_\text{SO}$ under stress along [110] is slower under $H \parallel [110]$ than $H \parallel [001]$. We develop a Landau free energy model and interpret our findings as an interplay of symmetry breaking terms driven by the orientation of spins.

cond-mat.str-el↗

arXiv2020

$^{105}$Pd NMR and NQR study of the cubic heavy fermion system Ce$_3$Pd$_{20}$Si$_6$

We report $^{105}$Pd NMR and NQR measurements on a single crystal of Ce$_3$Pd$_{20}$Si$_6$, where antiferroquadrupolar and antiferromagnetic orders develop at low temperature. From the analysis of NQR and NMR spectra, we have determined the electric field gradient (EFG) tensors and the anisotropic Knight shift ($K$) components for both inequivalent Pd sites - Pd($32f$) and Pd($48h$). The observed EFG values are in excellent agreement with our state-of-the-art DFT calculations. The principal values of the quadrupolar coupling are $(20.37 \pm 0.02)$ MHz and $(5.45 \pm 0.02)$ MHz, for the Pd($32f$) and Pd($48h$) site, respectively, which is large compared to the Larmor frequency defined by the gyromagnetic constant $γ= 1.94838$ MHz/T for $^{105}$Pd. Therefore, the complete knowledge of $K$ and the EFG tensors is crucial to establish the correspondence between NMR spectra and crystallographic sites, which is needed for a complete analysis of the magnetic structure, static spin susceptibility, and the spin-lattice relaxation rate data and a better understanding of the groundstate of Ce$_3$Pd$_{20}$Si$_6$.

cond-mat.str-el↗

arXiv2019

Quantum critical behaviour and Lifshitz transition in intermediate valence $α$-YbAlB$_4$

Intermetallic compounds containing $f$-electron elements have been prototypical materials for investigating strong electron correlations and quantum criticality (QC). Their heavy fermion ground state evoked by the magnetic $f$-electrons is susceptible to the onset of quantum phases, such as magnetism or superconductivity, due to the enhanced effective mass ($m^{*}$) and a corresponding decrease of the Fermi temperature. However, the presence of $f$-electron valence fluctuations to a non-magnetic state is regarded an anathema to QC, as it usually generates a paramagnetic Fermi-liquid state with quasiparticles of moderate $m^{*}$. Such systems are typically isotropic, with a characteristic energy scale $T_0$ of the order of hundreds of kelvins that require large magnetic fields or pressures to promote a valence or magnetic instability. Here we show that the intermediate valence compound $α$-YbAlB$_4$ surprisingly exhibits both quantum critical behaviour and a Lifshitz transition under low magnetic field, which is attributed to the anisotropy of the hybridization between the conduction and localized $f$-electrons. These findings suggest a new route to bypass the large valence energy scale in developing the QC.

cond-mat.str-el↗

arXiv2019

Modes of an elliptical cylindrical resonant cavity -- analytical solution

An analytical solution of the Helmholtz equation for electromagnetic field distribution in a resonant cavity with elliptic cross-section is found. We compare the frequencies of the eigenmodes with numerical and experimental values for a metallic cavity and find an excellent matching. We focus our analysis on the microwave frequency region, and show how the ellipticity of the cavity (ratio of the minor and major axes length $b/a$) influences several mode frequencies and also the $Q$-factor of the cavity. By doing so, we demonstrate how the elliptic geometry splits the degeneracy of certain modes of the circular cylindric cavity.

physics.class-ph↗

arXiv2018

Two-axis goniometer for single-crystal nuclear magnetic resonance measurements

We report the design and construction of a two-axis goniometer capable of any sample orientation with respect to the external magnetic field. The advantage of this design is that it allows free rotations around a single axis independent of the other which minimizes rotational error without reduction of angle range. Goniometer is capable of operating with high precision at both low and high temperatures and in high magnetic fields. It was mounted on the custom made nuclear magnetic resonance probe for use in Oxford Instruments wide-bore variable field superconducting magnet.

physics.ins-det↗

arXiv2018

Singlet state formation and its impact on magnetic structure in tetramer system SeCuO$_3$

We present an experimental investigation of the magnetic structure in a tetramer system SeCuO$_3$ using neutron diffraction and nuclear resonance techniques. We establish a non-collinear, commensurate antiferromagnetic ordering with a propagation vector $\textbf{k} = \left(0,0,1 \right)$. The order parameter follows a critical behavior near $T_N = 8$ K, with a critical exponent $β= 0.32$ in agreement with a 3D universality class. Evidence is presented that a singlet state starts to form on tetramers at temperatures as high as 200 K, and its signature is preserved within the ordered state through a strong renormalization of the ordered magnetic moment on two non-equivalent copper sites, $m_{Cu1} \approx 0.4 μ_B$ and $m_{Cu2} \approx 0.7 μ_B$ at 1.5 K.

cond-mat.str-el↗

arXiv2017

Nuclear magnetic resonance study of the magnetic-field-induced ordered phase in the NiCl2-4SC(NH2)2 compound

Nuclear magnetic resonance (NMR) study of the high magnetic field (H) part of the Bose-Einstein condensed (BEC) phase of the quasi-onedimensional (quasi-1D) antiferromagnetic quantum spin-chain compound NiCl2-4SC(NH2)2 (DTN) was performed. We precisely determined the phase boundary, Tc(H), down to 40 mK; the critical boson density, n_c(Tc); and the absolute value of the BEC order parameter S_perp at very low temperature (T = 0.12 K). All results are accurately reproduced by numerical quantum Monte Carlo simulations of a realistic three-dimensional (3D) model Hamiltonian. Approximate analytical predictions based on the 1D Tomonaga-Luttinger liquid description are found to be precise for Tc(H), but less so for S_perp(H), which is more sensitive to the strength of 3D couplings, in particular close to the critical field. A mean-field treatment, based on the Hartree-Fock-Popov description, is found to be valid only up to n_c = 4% (T < 0.3 K), while for higher n_c boson interactions appear to modify the density of states.

cond-mat.str-el↗