arXiv subjects

Mihkel Kama

Publications and source records attributed to Mihkel Kama.

At least 19 recordsLinked to original sources

arXiv2026

The refractory fraction of phosphorus in planet-forming discs

Context. Phosphorus (P) is an essential element for life on Earth and a potential tracer of planet formation history. However, there has been no detection of P-bearing molecules in protoplanetary discs so far. Herbig Ae/Be stars constantly accrete matter from their pro- toplanetary disc, which alters the composition of the stellar photosphere due to their shallow convective, or fully radiative, envelope. The altered surface composition reflects the composition of the accreting matter, and thus that of the inner protoplanetary disc. This accretion contamination of stellar photosphere can persist after accretion has ended in young A and B-type stars (age < 50 Myr). Aims. We aim to quantify the fraction of P locked in dust (the refractory fraction of P) compared to gas in the inner protoplanetary disc around Herbig Ae/Be stars. Methods. We measure the stellar parameters and abundance of 5 Herbig Ae/Be stars using optical and UV spectra, to compare their P and Fe abundances. We also used a 20 Myrs old main sequence B-type star, which has P and Fe abundance estimated from optical spectrum. Fe is assumed to be completely locked in refractory reservoirs in the inner disc. A parameterised relationship between the stellar P and Fe abundance gives the fraction of P locked in refractory reservoirs. Results. We find the refractory fraction of P in the inner protoplanetary disc to be > 96 % within 95th percentile of the posterior distribution. Conclusions. Consistent with a previous finding in the HD 100546 system, we conclude most of the P in the inner protoplanetary disc is locked in dust, likely in refractory minerals like schreibersite or apatite. Our result, combined with the low cosmic abundance of P, is also consistent with the lack of infrared and mm-wavelength observations of P-bearing molecules in protoplanetary discs to date.

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arXiv2026

The Tartu Observatory Fiber-fed Echelle Spectrograph (TOFES) Data Reduction Pipeline

We introduce the data reduction pipeline for the Tartu Observatory Fiber-fed Echelle Spectrograph (TOFES). TOFES is installed in the Coud\'e room and will be connected to the 1.5 m Tartu Observatory AZT-12 telescope through a four-channel instrument adapter to be mounted at the Cassegrain focus of the telescope. The spectrograph has an average spectral resolution of 30,000 and covers the 390 to 900 nm wavelength band in a single exposure. The data reduction pipeline, based on the PyReduce package, was tested on spectra of the Sun. We also present the Spectroscopy-Toolbox package, which was developed to provide additional tools for diagnostics and spectral line identification for radial velocity measurements. The spectrograph will address a range of scientific questions, including the stellar characterisation of Herbig AeBe stars to measure accretion contamination from their protoplanetary disks, the stellar characterisation of exoplanet host-stars including the Ariel space mission targets, and radial velocity monitoring of large-scale atmospheric variability in massive stars.

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arXiv2026

Detectability of deuterium in spectra of early-type stars

Context: Deuterium is easily destroyed in stellar interiors through nuclear fusion. It is therefore usually not expected to be present in stellar photospheres. Early-type stars, with radiative envelopes that mix slowly, may provide a favourable environment for the survival of recently accreted deuterium. Aims: In this study, we explore the detectability of deuterium in B-, A-, and F-type stars, which possess radiative envelopes that can delay the mixing and destruction of recently accreted material. Methods: We used synthetic spectra to generate model observations including deuterium, focusing on Balmer line regions, for stars with effective temperatures between 7 500 K and 12 500 K and a surface gravity of log g = 4.0. To assess the detectability of deuterium, we employed a Markov Chain Monte Carlo framework over a range of signal-to-noise ratios between 100 and 1000. We then applied this method to observed spectra of the A9 star HD 32115 and the B9.5 star 21 Peg. Results: We show how detection limits of deuterium abundance depend on signal-to-noise ratio, effective temperature, and projected rotational velocity. For example, for a 10 000 K star, the detection limit decreases from D/H = -4.6 dex to -5.5 dex, as the signal-to-noise ratio increases from 100 to 1000. For HD 32115, we find an upper limit of D/H < -5.5 dex, and for 21 Peg < -4.9 dex. We conclude that the detection of deuterium on early-type stars may be possible in some heavily accretion-contaminated cases, providing a new diagnostic tool for the study of proto- or exo-planetary material.

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arXiv2026

sponchpop: Population synthesis to investigate volatile sulfur as a fingerprint of gas giant formation histories

Planet population synthesis is an integral tool for linking exoplanets to their formation environments. Most planet population synthesis studies have focused on the carbon-to-oxygen ratio (C/O) in gas or solids, yet more insight into planet formation may be afforded by considering a wider suite of elements. Sulfur is one such key element. It has been assumed to be entirely refractory in population synthesis models, restricting it to being a tracer of accreted rocky solids. However, sulfur also has a volatile reservoir dominant at the onset of star and planet formation, which is then converted into refractories. We investigate sulfur's wider potential as a formation history tracer by implementing a gas-grain chemical conversion, the first multi-phase treatment of S in a planet population synthesis model. We also present the planet formation module of SPONCHPOP and its first predicted planet growth tracks and populations. We apply these to explore the diversity of the planetary sulfur budget. We show that planets can inherit a wide range of core and envelope sulfur content, depending on their formation environment and accretion history including late-stage infall, demonstrating sulfur's new potential as a diagnostic tool for planet formation. Our models predict that some rocky planets are born sulfur-poor, which may have significant implications for their geochemistry and habitability. Enhanced sulfur abundances in gas-giant atmospheres, such as in our solar system, may result not only from accretion of rocky planetesimals, but also from formation beyond the H2S iceline.

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arXiv2025

Planet-induced Gas and Dust Substructure Feedbacks on Disk Thermal Structure

Protoplanets can interact with their natal disks and generate gas and dust substructures such as gaps and rings. However, how these planet-induced substructures affect the disk temperature, and how that in turn influences the substructures, remains unclear. We aim to study disk substructures and the thermal structure self-consistently and explore their impact on volatile distribution. To this end, we perform iterative multi-fluid hydrodynamical and radiative transfer simulations of planet-disk interactions. We find that the temperature in a structured disk deviates significantly from that of a smooth disk due to giant planet formation. In particular, midplane temperatures in gaps can increase by tens of Kelvin, leading to volatile sublimation as well as radial shifts and multiplication of icelines. Comparing our multi-dust models with previous gas-only models, we find that the former produces slightly shallower gaps and temperatures about 10 K ($\sim25\%$) higher. Furthermore, the temperature at dust rings formed by pressure bumps can drop by several Kelvin, creating volatile freeze-out regions. Nevertheless, the overall midplane ice distribution is not strongly sensitive to whether dust is included. We also investigate the effect of varying disk viscosity. Increasing $α$ viscosity from $10^{-4}$ to $10^{-2}$ leads to a roughly 10 K ($\sim25\%$) warmer midplane due to enhanced vertical dust mixing. However, higher viscosity suppresses gap opening and reduces the temperature enhancement within gaps. As a result, iceline locations do not follow a simple trend with viscosity. Finally, we propose an observational strategy using ALMA to test our predicted temperature changes within disk gaps.

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arXiv2025

Refractory phosphorus in the HD 100546 protoplanetary disk

The phosphorus budget of planets is intertwined with their formation history and is thought to influence their habitability. The chemical reservoirs and volatile \emph{vs} refractory budget of phosphorus in planet-forming environments have so far eluded empirical characterisation. We employ high-resolution spectra from HST/STIS in the ultraviolet and APEX in the sub-mm to constrain the phosphorus budget in the well-characterized HD\,100546 star and protoplanetary disk system. We measure $\log{(P/H)_{\star}}=-7.50^{+0.23}_{-0.28}$ on the stellar surface, which traces the total inventory of P in accreting gas \emph{and }dust from the inner disk. The inner disk gas, inside of the main dust trap, has $\log{(P/H)_{\rm in}}\lesssim-8.70$, and the outer disk gas $\log{(P/H)_{\rm out}}\lesssim-9.30$. Phosphorus in the disk is carried by a relatively refractory reservoir, consistent with minerals such as apatite or schreibersite, or with ammonium phosphate salts, in terms of sublimation temperature. We discuss the impact this might have on the two protoplanets around HD\,100546. Our results contribute to our understanding of the chemical habitability of planetary systems and lay a foundation for future explorations, especially in the context of JWST and \emph{Ariel} which can study phosphorus in exoplanet atmospheres.

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arXiv2025

Abundance analysis of stars hosting gas-rich debris disks

Accretion from protoplanetary or debris disks can contaminate the stellar photosphere, which is detectable in stars with radiative envelopes due to relatively slower photospheric mixing. The contaminated photosphere reflects ongoing disk processes, detectable through stellar spectroscopy. We investigate the composition of six gas-rich debris disk-hosting A-type stars to understand possible links with their debris disk or earlier accretion stages. We used archival spectra to estimate the stellar parameters and abundances of our sample. We also estimated the stellar photospheric accretion contamination parameter, fph which indicates the fraction of accreting material on the stellar photosphere. The oxygen abundance in intermediate-mass stars decreases with age until the debris disk stage (< 20 Myr). The downward trend could result from H2O ice accumulating in dust traps or the formation of hydrated asteroids in the protoplanetary disk, locking oxygen in solids and reducing its accretion onto the star. All stars have similar volatile abundances (C, O), but HD 110058 and HD 32297 show refractory depleted abundances. The near-zero fph values in the six stars suggest that any currently accreted gas would not overwhelm mixing in the photosphere and would not impact the observed composition. The refractory depleted abundances in HD 110058 and HD 32297 suggest residual, or even chronic, accretion contamination from their earlier protoplanetary stages when the accretion rates were about five orders of magnitude higher. For HD 110058, with the highest refractory depletion, we estimated a lower limit on its earlier protoplanetary accretion rate of 9 x 10^(-8) Msun/yr, similar to other Herbig stars and equal to the Herbig star - HD 100546. This supports our hypothesis that refractory depletion in HD 110058 originates from a prior phase of higher accretion of dust-poor material.

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arXiv2024

Volatile composition of the HD 169142 disk and its embedded planet

The composition of a planet's atmosphere is intricately linked to the chemical makeup of the protoplanetary disk in which it formed. Determining the elemental abundances from key volatiles within disks is therefore essential for establishing connections between the composition of disks and planets. The disk around the Herbig Ae star HD 169142 is a compelling target for such a study due to its molecule-rich nature and the presence of a newly-forming planet between two prominent dust rings. In this work, we probe the chemistry of the HD 169142 disk at small spatial scales, drawing links between the composition of the disk and the planet-accreted gas. Using thermochemical models and archival data, we constrain the elemental abundances of volatile carbon, oxygen, and sulfur. Carbon and oxygen are only moderately depleted from the gas phase relative to their interstellar abundances, with the inner 60 au appearing enriched in volatile oxygen. The C/O ratio is approximately solar within the inner disk and rises above this in the outer disk, as expected across the H2O snowline. The gas-phase sulfur abundance is depleted by a factor of 1000, consistent with a number of other protoplanetary disks. Interestingly, the observed SiS emission near the HD 169142 b protoplanet vastly exceeds chemical model predictions, supporting previous hypotheses suggesting its origin in shocked gas or a localised outflow. We contextualise our findings in terms of the potential atmospheric composition of the embedded planet, and highlight the utility of sulfur-bearing molecules as probes of protoplanetary disk chemistry.

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arXiv2024

An ALMA molecular inventory of warm Herbig Ae disks: I. Molecular rings, asymmetries and complexity in the HD 100546 disk

Observations of disks with the Atacama Large Millimeter/submillimeter Array (ALMA) allow us to map the chemical makeup of nearby protoplanetary disks with unprecedented spatial resolution and sensitivity. The typical outer Class II disk observed with ALMA is one with an elevated C/O ratio and a lack of oxygen-bearing complex organic molecules, but there are now some interesting exceptions: three transition disks around Herbig Ae stars all show oxygen-rich gas traced via the unique detections of the molecules SO and CH3OH. We present the first results of an ALMA line survey at 337 to 357 GHz of such disks and focus this paper on the first Herbig Ae disk to exhibit this chemical signature - HD 100546. In these data, we detect 19 different molecules including NO, SO and CH3OCHO (methyl formate). We also make the first tentative detections of H213CO and 34SO in protoplanetary disks. Multiple molecular species are detected in rings, which are, surprisingly, all peaking just beyond the underlying millimeter continuum ring at 200 au. This result demonstrates a clear connection between the large dust distribution and the chemistry in this flat outer disk. We discuss the physical and/or chemical origin of these sub-structures in relation to ongoing planet formation in the HD 100546 disk. We also investigate how similar and/or different the molecular make up of this disk is to other chemically well-characterised Herbig Ae disks. The line-rich data we present motivates the need for more ALMA line surveys to probe the observable chemistry in Herbig Ae systems which offer unique insight into the composition of disk ices, including complex organic molecules.

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arXiv2024

An ALMA molecular inventory of warm Herbig Ae disks: II. Abundant complex organics and volatile sulphur in the IRS 48 disk

The Atacama Large Millimeter/submillimeter Array (ALMA) can probe the molecular content of planet-forming disks with unprecedented sensitivity. These observations allow us to build up an inventory of the volatiles available for forming planets and comets. Herbig Ae transition disks are fruitful targets due to the thermal sublimation of complex organic molecule (COM) and likely H2O-rich ices in these disks. The IRS 48 disk shows a particularly rich chemistry that can be directly linked to its asymmetric dust trap. Here, we present ALMA observations of the IRS 48 disk where we detect 16 different molecules and make the first robust detections of H213CO, 34SO, 33SO and c-H2COCH2 (ethylene oxide) in a protoplanetary disk. All of the molecular emissions, aside from CO, are colocated with the dust trap and this includes newly detected simple molecules such as HCO+, HCN and CS. Interestingly, there are spatial offsets between different molecular families, including between the COMs and sulphur-bearing species, with the latter being more azimuthally extended and located radially further from the star. The abundances of the newly detected COMs relative to CH3OH are higher than the expected protostellar ratios, which implies some degree of chemical processing of the inherited ices during the disk lifetime. These data highlight IRS 48 as a unique astrochemical laboratory to unravel the full volatile reservoir at the epoch of planet and comet formation and the role of the disk in (re)setting chemical complexity.

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arXiv2023

Spatially resolving the volatile sulfur abundance in the HD 100546 protoplanetary disk

Volatile elements play a crucial role in the formation of planetary systems. Their abundance and distribution in protoplanetary disks provide vital insights into the connection between formation processes and the atmospheric composition of individual planets. Sulfur, being one of the most abundant elements in planet-forming environments, is of great significance, and now observable in exoplanets with JWST. However, planetary formation models currently lack vital knowledge regarding sulfur chemistry in protoplanetary disks. Developing a deeper understanding of the major volatile sulfur carriers in disks is essential to building models that can meaningfully predict planetary atmospheric composition, and reconstruct planetary formation pathways. In this work, we combine archival observations with new data from ALMA and APEX, covering a range of sulfur-bearing species/isotopologs. We interpret this data using the DALI thermo-chemical code, for which our model is highly refined and disk-specific. We find that volatile sulfur is heavily depleted from the cosmic value by a factor of 1000, with a disk-averaged abundance of S/H = 1e-8. We show that the gas-phase sulfur abundance varies radially by 3 orders of magnitude, with the highest abundances inside the inner dust ring and coincident with the outer dust ring at 150 to 230 au. Extracting chemical abundances from our models, we find OCS, H2CS, and CS to be the dominant molecular carriers in the gas phase. We also infer the presence of a substantial OCS ice reservoir. We relate our results to the potential atmospheric composition of planets in HD 100546, and the wider exoplanet population

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arXiv2023

Planet Gap-opening Feedback on Disk Thermal Structure and Composition

(Exo-)planets inherit their budget of chemical elements from a protoplanetary disk. The disk temperature determines the phase of each chemical species, which sets the composition of solids and gas available for planet formation. We investigate how gap structures, which are widely seen by recent disk observations, alter the thermal and chemical structure of a disk. Planet-disk interaction is a leading hypothesis of gap formation and so such changes could present a feedback that planets have on planet-forming material. Both the planet gap-opening process and the disk thermal structure are well studied individually, but how the gap-opening process affects disk thermal structure evolution remains an open question. We develop a new modelling method by iterating hydrodynamical and radiative transfer simulations to explore the gap-opening feedback on disk thermal structure. We carry out parameter studies by considering different planet locations rp and planet masses Mp. We find that for the same rp and Mp, our iteration method predicts a wider and deeper gap than the non-iteration method. We also find that the inner disk and gap temperature from the iteration method can vary strongly from the non-iteration or disk without planets, which can further influence dust-trap conditions, iceline locations, and distribution of various ices, such as H2O, CO2, and CO on large dust grains ("pebbles"). Through that, a gap-opening planet can complicate the canonical picture of the non-planet disk C/O ratio and influence the composition of the next generation of planetesimals and planets.

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arXiv2023

Iceline Variations Driven by Protoplanetary Disc Gaps

The composition of forming planets is strongly affected by the protoplanetary disc's thermal structure. This thermal structure is predominantly set by dust radiative transfer and viscous (accretional) heating and can be impacted by gaps - regions of low dust and gas density that can occur when planets form. The effect of variations in dust surface density on disc temperature has been poorly understood until now. In this work, we use the radiative transfer code MCMax to model the 2D dust thermal structure with individual gaps corresponding to planets with masses of 0.1 M$_J$ - 5 M$_J$ and orbital radii of 3, 5, and 10 AU. Low dust opacity in the gap allows radiation to penetrate deeper into the disc and warm the midplane by up to 16 K, but only for gaps located in the region of the disc where stellar irradiation is the dominant source of heat (here, a$\gtrsim$4 AU). In viscously-heated regions (a$\lesssim$4 AU), the midplane of the gap is relatively cooler by up to 100 K. Outside of the gap, broad radial oscillations in heating and cooling are present due to changes in disc flaring. These thermal features affect local segregation of volatile elements (H$_2$O, CH$_4$, CO2, CO) between the dust and gas. We find that icelines experience dramatic shifts relative to gapless models: up to 6.5 AU towards the star and 4.3 AU towards the midplane. While quantitative predictions of iceline deviations will require more sophisticated models which include transport and sublimation/condensation kinetics, our results provide evidence that planet-induced iceline variations represent a potential feedback from the planet onto the composition of material it is accreting.

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arXiv2023

Azimuthal C/O Variations in a Planet-Forming Disk

The elemental carbon-to-oxygen ratio (C/O) in the atmosphere of a giant planet is a promising diagnostic of that planet's formation history in a protoplanetary disk. Alongside efforts in the exoplanet community to measure C/O in planetary atmospheres, observational and theoretical studies of disks are increasingly focused on understanding how the gas-phase C/O varies both with radial location and between disks. This is mostly tied to the icelines of major volatile carriers such as CO and H2O. Using ALMA observations of CS and SO, we have unearthed evidence for an entirely novel type of C/O variation in the protoplanetary disk around HD 100546: an azimuthal variation from a typical, oxygen-dominated ratio (C/O=0.5) to a carbon-dominated ratio (C/O>1.0). We show that the spatial distribution and peculiar line kinematics of both CS and SO molecules can be well-explained by azimuthal variations in the C/O ratio. We propose a shadowing mechanism that could lead to such a chemical dichotomy. Our results imply that tracing the formation history of giant exoplanets using their atmospheric C/O ratios will need to take into account time-dependent azimuthal C/O variations in a planet's accretion zone.

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arXiv2022

KELT-9 and its ultra-hot Jupiter: stellar parameters, composition, and planetary pollution

KELT-9b is an ultra-hot Jupiter observed to be undergoing extreme mass loss. Its A0-type host star has a radiative envelope, which makes its surface layers prone to retaining recently accreted material. To search for potential signs of planetary material polluting the stellar surface, we carry out the most comprehensive chemical characterisation of KELT-9 to-date. New element detections include Na and Y, which had previously been detected in the ultra-hot Jupiter but not studied in the star; these detections complete the set of nine elements measured in both star and planet. In comparing KELT-9 with similar open cluster stars we find no strong anomalies. This finding is consistent with calculations of photospheric pollution accounting for stellar mixing and using observationally estimated KELT-9b mass loss rates. We also rule out recent, short-lived intensive mass transfer such as the stellar ingestion of an Earth-mass exomoon.

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arXiv2022

The first interferometric measurements of NH$_2$D/NH$_3$ ratio in hot corinos

The nitrogen chemical evolution during star and planet formation is still not fully understood. Ammonia (NH$_3$) is a key specie in the understanding of the molecular evolution in star-forming clouds and nitrogen isotope fractionation. In this paper, we present high spatial resolution observations of multiple emission lines of NH$_3$ toward the protobinary system NGC1333 IRAS4A with Karl G. Jansky Very Large Array (VLA). We spatially resolved the binary (hereafter 4A1 and 4A2) and detected compact emission of NH$_3$ transitions with high excitation energies ($\gtrsim$100 K) from the vicinity of the protostars, indicating the NH$_3$ ice has sublimated at the inner hot region. The NH$_3$ column density is estimated to be $\sim 10^{17}-10^{18}$ cm$^{-2}$. We also detected two NH$_2$D transitions, allowing us to constrain the deuterium fractionation of ammonia. The NH$_2$D/NH$_3$ ratios are as high as $\sim 0.3-1$ in both 4A1 and 4A2. From the comparisons with the astrochemical models in the literature, the high NH$_2$D/NH$_3$ ratios suggest that the formation of NH$_3$ ices mainly started in the prestellar phase after the formation of bulk water ice finished, and that the primary nitrogen reservoir in the star-forming cloud could be atomic nitrogen (or N atoms) rather than nitrogen-bearing species such as N$_2$ and NH$_3$. The implications on the physical properties of IRAS4A cores are discussed as well.

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arXiv2022

Sulphur monoxide emission tracing an embedded planet in the HD 100546 protoplanetary disk

Molecular line observations are powerful tracers of the physical and chemical conditions across the different evolutionary stages of star, disk and planet formation. Using the high angular resolution and unprecedented sensitivity of the Atacama Large Millimeter Array (ALMA) there is now a drive to detect small-scale gas structures in protoplanetary disks that can be attributed directly to forming planets. We report high angular resolution ALMA Band 7 observations of sulphur monoxide (SO) in the nearby planet-hosting disk around Herbig star HD 100546. SO is rarely detected in evolved protoplanetary disks but in other environments, it is most often utilised as a tracer of shocks. The SO emission from the HD 100546 disk is primarily originating from gas within the approx. 20 au mm-dust cavity and shows a clear azimuthal brightness asymmetry of a factor of 2. In addition, we see a significant difference in the line profile shape when comparing these new Cycle 7 data to Cycle 0 data of the same SO transitions. We discuss the different physical/chemical mechanisms that could be responsible for this asymmetry and time variability including disk winds, disk warps, and a shock triggered by a (forming) planet. We propose that the SO is enhanced in the cavity due to the presence of a giant planet. The SO asymmetry complements evidence for hot circumplanetary material around the giant planet HD 100546 c traced via CO ro-vibrational emission. This work sets the stage for further observational and modelling efforts to detect and understand the chemical imprint of a forming planet on its parent disk.

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arXiv2022

Inferring the Gas-to-Dust Ratio in the Main Planet-Forming Region of Disks

Measuring the amount of gas and dust in protoplanetary disks is a key challenge in planet formation studies. Here we provide a new set of dust depletion factors and relative mass surface densities of gas and dust for the innermost regions of a sample of protoplanetary disks. We do this by combining stellar theory with observed refractory element abundances in both disk hosts and open cluster stars. Our results are independent of, and complementary to, those obtained from spatially resolved disk observations.

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