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Mikael Santonen

Publications and source records attributed to Mikael Santonen.

2 recordsLinked to original sources

Role of Local Structural Variation in X-ray Photoelectron Spectrum of Silicon Oxide Interfaces

We show that the broad X-ray photoelectron lines of silicon oxide on silicon arise from a continuous statistical distribution of core-level binding energies. Statistical simulations spanning compositions from Si to SiO$_2$ reproduce the full extent of this broadening, reaching 5 eV for SiO$_{1.0}$ , in quantitative agreement with 0.23 nm layer-resolved spectra reconstructed from Ar$^+$ sputtering data. This continuous distribution blurs distinct spectral fingerprints of local structural motifs, thereby challenging conventional chemical state assignment in oxide X-ray photoelectron spectra.

cond-mat.mtrl-sci

A detailed examination of polysilicon resistivity incorporating the grain size distribution

Current transport in polysilicon is a complicated process with many factors to consider. The inhomogeneous nature of polysilicon with its differently shaped and sized grains is one such consideration. We have developed a method that enhances existing resistivity models with a two-dimensional extension that incorporates the grain size distribution using a Voronoi-based resistor network. We obtain grain size distributions both from our growth simulations (700 K, 800 K, and 900 K) and experimental analysis. Applying our method, we investigate the effect that variation in grain size produces with cases of different average grain sizes (2 nm to 3 $μ$m). For example, the resistivity of polysilicon with an average grain size of 175 nm drops from 11 k$Ω$ $\cdot$ cm to 4.5 k$Ω$ $\cdot$ cm when compared to conventional one-dimensional modeling. Our study highlights the strong effect of grain size variation on resistivity, revealing that wider distributions result in significant resistivity reductions of up to more than 50%. Due to the larger grains present with a grain size distribution, current transport encounters fewer grain boundaries while the average grain size remains the same resulting in fewer barriers along the current transport path. Incorporating the grain structure into the resistivity modeling facilitates a more detailed and comprehensive characterization of the electrical properties of polysilicon.

cond-mat.mtrl-sci