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Milena Milich

Publications and source records attributed to Milena Milich.

4 recordsLinked to original sources

Closing the ultrahigh temperature metrology gap: non-contact thermal conductivity ($\mathrm{k}$) and spectral emittance ($\mathrm{\varepsilon_{\lambda}}$) of molybdenum up to 3200 K

Advances in next-generation hypersonic hot structures, high heat-flux fusion or fission components, and laser based additive manufacturing depend on reliable solid state thermal conductivity data at high and ultrahigh temperatures, where conventional measurements become increasingly sensitive to contact resistances, uncertain boundary conditions, and nonlinear radiative losses. Building on our initial demonstration of ultrahigh temperature steady-state temperature differential radiometry (SSTDR), we present a substantially more robust platform aimed at making high temperature thermal and radiative property measurements more routine. The method integrates lock-in infrared thermography with a spatially localized, modulated perturbation laser to form a conduction dominant differential observable along with hyperspectral pyrometry and a validated 2D axisymmetric steady state heat transfer model. Using high purity molybdenum as a benchmark, we report solid state thermal conductivity k(T) from 1500 - 3000 K (to the onset of melting) with uncertainties of 7.9-11 % enabled by comprehensive uncertainty propagation, sensitivity analysis, and bounding studies. We additionally provide normal spectral emittance of molybdenum in both solid and liquid states over 500-1000 nm. These advances establish SSTDR as an accurate, non-contact route for closing the high temperature k(T) data gap while simultaneously producing much needed phase dependent radiative property data for melt adjacent and extreme heat-flux applications. Note: This is a shortened abstract; full version in manuscript.

cond-mat.mtrl-sci

Validation of the Wiedemann-Franz Law in solid and molten tungsten above 2000 K through thermal conductivity measurements via steady state temperature differential radiometry

We measure the thermal conductivity of solid and molten tungsten using Steady State Temperature Differential Radiometry. We demonstrate that the thermal conductivity can be well described by application of Wiedemann-Franz Law to electrical resistivity data, thus suggesting the validity of Wiedemann-Franz Law to capture the electronic thermal conductivity of metals in their molten phase. We further support this conclusion using ab initio molecular dynamics simulations with a machine-learned potential. Our results show that at these high temperatures, the vibrational contribution to thermal conductivity is negligible compared to the electronic component.

cond-mat.mtrl-sci

Ablation threshold and temperature dependent thermal conductivity of high entropy carbide thin films

High entropy carbides (HECs) are a promising new class of ultra-high temperature ceramics that could provide novel material solutions for leading edges of hypersonic vehicles, which can reach temperatures above 3500C and experience extreme thermal gradients. Although the mechanical and thermal properties of HECs have been studied extensively at room temperature, few works have examined HEC properties at high temperatures or considered these materials' responses to thermal shock. In this work, we measure the thermal conductivity of a five-cation HEC up to 1200C. We find that thermal conductivity increases with temperature, consistent with trends demonstrated in single-metal carbides. We also measure thermal conductivity of an HEC deposited with varying CH4 flow rate, and find that although thermal conductivity is reduced when carbon content surpasses stoichiometric concentrations, the films all exhibited the same temperature dependent trends regardless of carbon content. To compare the thermal shock resistance of HECs with a refractory carbide, we conduct pulsed laser ablation measurements to determine the fluence threshold the HECs can withstand before damaging. We find that this metric for the average bond strength trends with the theoretical hardness of the HECs as expected.

physics.app-ph

Orientation Controlled Anisotropy in Single Crystals of Quasi-1D BaTiS3

Low-dimensional materials with chain-like (one-dimensional) or layered (twodimensional) structures are of significant interest due to their anisotropic electrical, optical, thermal properties. One material with chain-like structure, BaTiS3 (BTS), was recently shown to possess giant in-plane optical anisotropy and glass-like thermal conductivity. To understand the origin of these effects, it is necessary to fully characterize the optical, thermal, and electronic anisotropy of BTS. To this end, BTS crystals with different orientations (aand c-axis orientations) were grown by chemical vapor transport. X-ray absorption spectroscopy (XAS) was used to characterize the local structure and electronic anisotropy of BTS. Fourier transform infrared (FTIR) reflection/transmission spectra show a large inplane optical anisotropy in the a-oriented crystals, while the c-axis oriented crystals were nearly isotropic in-plane. BTS platelet crystals are promising uniaxial materials for IR optics with their optic axis parallel to the c-axis. The thermal conductivity measurements revealed a thermal anisotropy of ~4.5 between the c- and a-axis. Time-domain Brillouin scattering showed that the longitudinal sound speed along the two axes is nearly the same suggesting that the thermal anisotropy is a result of different phonon scattering rates.

cond-mat.mtrl-sci