arXiv subjects

Ming Yi

Publications and source records attributed to Ming Yi.

At least 37 records · Page 2Linked to original sources

arXiv2025

Thermoelectric evidence of the electronic structure changes from the charge-density-wave transition in FeGe

Kagome metals provide a material platform for probing new correlated quantum phenomena due to the naturally incorporated linear dispersions, flat bands, and Van Hove singularities in their electronic structures. Among these quantum phenomena is the charge density wave (CDW), or the distortion of the lattice structure due to the motion of correlated electrons through the material. CDWs lower the energy of the compound, creating an energy gap that facilitates behaviors akin to superconductivity, nonlinear transport, or other quantum correlated phenomena. The kagome metal FeGe has been shown to host a CDW transition at approximately 100 K, and its occurrence is strongly influenced by the sample annealing conditions. However, a notable gap in the literature is the lack of clear thermoelectric transport evidence for electronic structure changes associated with this CDW transition. Here we present evidence of electron behavior modification due to annealing disorder via thermoelectric measurements on FeGe crystals presenting a CDW transition and those without a CDW. The observed Nernst effect and Seebeck effect under sufficient annealing demonstrate modified electrical transport properties resulting from induced disorder, including a change in carrier sign and an enhancement of the Nernst effect due to the CDW. Our results provide evidence of multiple phase transitions, which confirms the influence of CDW on the thermal properties of FeGe and demonstrates the suppression of CDW with sufficient disordering.

cond-mat.str-el↗

arXiv2025

Dichotomy of flat bands in the van der Waals ferromagnet Fe$_5$GeTe$_2$

Quantum materials with bands of narrow bandwidth near the Fermi level represent a promising platform for exploring a diverse range of fascinating physical phenomena, as the high density of states within the small energy window often enables the emergence of many-body physics. On one hand, flat bands can arise from strong Coulomb interactions that localize atomic orbitals. On the other hand, quantum destructive interference can quench the electronic kinetic energy. Although both have a narrow bandwidth, the two types of flat bands should exhibit very distinct spectral properties arising from their distinctive origins. So far, the two types of flat bands have only been realized in very different material settings and chemical environments, preventing a direct comparison. Here, we report the observation of the two types of flat bands within the same material system--an above-room-temperature van der Waals ferromagnet, Fe$_{5-x}$GeTe$_2$, distinguishable by a switchable iron site order. The contrasting nature of the flat bands is also identified by the remarkably distinctive temperature-evolution of the spectral features, indicating that one arises from electron correlations in the Fe(1) site-disordered phase, while the other geometrical frustration in the Fe(1) site-ordered phase. Our results therefore provide a direct juxtaposition of the distinct formation mechanism of flat bands in quantum materials, and an avenue for understanding the distinctive roles flat bands play in the presence of magnetism, topology, and lattice geometrical frustration, utilizing sublattice ordering as a key control parameter.

cond-mat.str-el↗

arXiv2025

Kramers nodal lines in intercalated TaS$_2$ superconductors

Kramers degeneracy is one fundamental embodiment of the quantum mechanical nature of particles with half-integer spin under time reversal symmetry. Under the chiral and noncentrosymmetric achiral crystalline symmetries, Kramers degeneracy emerges respectively as topological quasiparticles of Weyl fermions and Kramers nodal lines (KNLs), anchoring the Berry phase-related physics of electrons. However, an experimental demonstration for ideal KNLs well isolated at the Fermi level is lacking. Here, we establish a class of noncentrosymmetric achiral intercalated transition metal dichalcogenide superconductors with large Ising-type spin-orbit coupling, represented by In$_x$TaS$_2$, to host an ideal KNL phase. We provide evidence from angle-resolved photoemission spectroscopy with spin resolution, angle-dependent quantum oscillation measurements, and ab-initio calculations. Our work not only provides a realistic platform for realizing and tuning KNLs in layered materials, but also paves the way for exploring the interplay between KNLs and superconductivity, as well as applications pertaining to spintronics, valleytronics, and nonlinear transport.

cond-mat.supr-con↗

arXiv2025

A Decision-Focused Predict-then-Bid Framework for Strategic Energy Storage

This paper introduces a novel decision-focused framework for energy storage arbitrage bidding. Inspired by the bidding process for energy storage in electricity markets, we propose a predict-then-bid end-to-end method incorporating the storage arbitrage optimization and market clearing models. This is achieved through a tri-layer framework that combines a price prediction layer with a two-stage optimization problem: an energy storage optimization layer and a market-clearing optimization layer. We leverage the implicit function theorem for gradient computation in the first optimization layer and incorporate a perturbation-based approach into the decision-focused loss function to ensure differentiability in the market-clearing layer. Numerical experiments using electricity market data from New York demonstrate that our bidding design substantially outperforms existing methods, achieving the highest profits and showcasing the effectiveness of the proposed approach.

eess.SY↗

arXiv2024

Conformal Uncertainty Quantification of Electricity Price Predictions for Risk-Averse Storage Arbitrage

This paper proposes a risk-averse approach to energy storage price arbitrage, leveraging conformal uncertainty quantification for electricity price predictions. The method addresses the significant challenges posed by the inherent volatility and uncertainty of real-time electricity prices, which create substantial risks of financial losses for energy storage participants relying on future price forecasts to plan their operations. The framework comprises a two-layer prediction model to quantify real-time price uncertainty confidence intervals with high coverage. The framework is distribution-free and can work with any underlying point prediction model. We evaluate the quantification effectiveness through storage price arbitrage application by managing the risk of participating in the real-time market. We design a risk-averse policy for profit-maximization of energy storage arbitrage to find the safest storage schedule with very minimal losses. Using historical data from New York State and synthetic price predictions, our evaluations demonstrate that this framework can achieve good profit margins with less than $35\%$ purchases.

math.OC↗

arXiv2024

Perturbed Decision-Focused Learning for Modeling Strategic Energy Storage

This paper presents a novel decision-focused framework integrating the physical energy storage model into machine learning pipelines. Motivated by the model predictive control for energy storage, our end-to-end method incorporates the prior knowledge of the storage model and infers the hidden reward that incentivizes energy storage decisions. This is achieved through a dual-layer framework, combining a prediction layer with an optimization layer. We introduce the perturbation idea into the designed decision-focused loss function to ensure the differentiability over linear storage models, supported by a theoretical analysis of the perturbed loss function. We also develop a hybrid loss function for effective model training. We provide two challenging applications for our proposed framework: energy storage arbitrage, and energy storage behavior prediction. The numerical experiments on real price data demonstrate that our arbitrage approach achieves the highest profit against existing methods. The numerical experiments on synthetic and real-world energy storage data show that our approach achieves the best behavior prediction performance against existing benchmark methods, which shows the effectiveness of our method.

eess.SY↗

arXiv2024

Vacancy-induced suppression of CDW order and its impact on magnetic order in kagome antiferromagnet FeGe

Two-dimensional (2D) kagome lattice metals are interesting because they display flat electronic bands, Dirac points, Van Hove singularities, and can have interplay between charge density wave (CDW), magnetic order, and superconductivity. In kagome lattice antiferromagnet FeGe, a short-range CDW order was found deep within an antiferromagnetically ordered state, interacting with the magnetic order. Surprisingly, post-growth annealing of FeGe at 560$^{\circ}$C can suppress the CDW order while annealing at 320$^{\circ}$C induces a long-range CDW order, with the ability to cycle between the states repeatedly by annealing. Here we perform transport, neutron scattering, scanning transmission electron microscopy (STEM), and muon spin rotation ($μ$SR) experiments to unveil the microscopic mechanism of the annealing process and its impact on magneto-transport, CDW, and magnetic properties of FeGe. We find that 560$^{\circ}$C annealing creates germanium vacancies uniformly distributed throughout the FeGe kagome lattice, which prevent the formation of Ge-Ge dimers necessary for the CDW order. Upon annealing at 320$^{\circ}$C, the system segregates into stoichiometric FeGe regions with long-range CDW order and regions with stacking faults that act as nucleation sites for the CDW. The presence or absence of CDW order greatly affects the anomalous Hall effect, incommensurate magnetic order, and spin-lattice coupling in FeGe, thus placing FeGe as the only known kagome lattice material with a tunable CDW and magnetic order, potentially useful for sensing and information transmission.

cond-mat.str-el↗

arXiv2024

Persistent flat band splitting and strong selective band renormalization in a kagome magnet thin film

Magnetic kagome materials provide a fascinating playground for exploring the interplay of magnetism, correlation and topology. Many magnetic kagome systems have been reported including the binary FemXn (X=Sn, Ge; m:n = 3:1, 3:2, 1:1) family and the rare earth RMn6Sn6 (R = rare earth) family, where their kagome flat bands are calculated to be near the Fermi level in the paramagnetic phase. While partially filling a kagome flat band is predicted to give rise to a Stoner-type ferromagnetism, experimental visualization of the magnetic splitting across the ordering temperature has not been reported for any of these systems due to the high ordering temperatures, hence leaving the nature of magnetism in kagome magnets an open question. Here, we probe the electronic structure with angle-resolved photoemission spectroscopy in a kagome magnet thin film FeSn synthesized using molecular beam epitaxy. We identify the exchange-split kagome flat bands, whose splitting persists above the magnetic ordering temperature, indicative of a local moment picture. Such local moments in the presence of the topological flat band are consistent with the compact molecular orbitals predicted in theory. We further observe a large spin-orbital selective band renormalization in the Fe d_xy+d_(x^2-y^2 ) spin majority channel reminiscent of the orbital selective correlation effects in the iron-based superconductors. Our discovery of the coexistence of local moments with topological flat bands in a kagome system echoes similar findings in magic-angle twisted bilayer graphene, and provides a basis for theoretical effort towards modeling correlation effects in magnetic flat band systems.

cond-mat.mes-hall↗

arXiv2024

Topological Surface State Evolution in Bi$_2$Se$_3$ via Surface Etching

Topological insulators are materials with an insulating bulk interior while maintaining gapless boundary states against back scattering. Bi$_2$Se$_3$ is a prototypical topological insulator with a Dirac-cone surface state around $Γ$. Here, we present a controlled methodology to gradually remove Se atoms from the surface Se-Bi-Se-Bi-Se quintuple layers, eventually forming bilayer-Bi on top of the quintuple bulk. Our method allows us to track the topological surface state and confirm its robustness throughout the surface modification. Importantly, we report a relocation of the topological Dirac cone in both real space and momentum space, as the top surface layer transitions from quintuple Se-Bi-Se-Bi-Se to bilayer-Bi. Additionally, charge transfer among different surface layers is identified. Our study provides a precise method to manipulate surface configurations, allowing for the fine-tuning of the topological surface states in Bi$_2$Se$_3$, which represents a significant advancement towards nano-engineering of topological states.

cond-mat.mtrl-sci↗

arXiv2024

INK: Inheritable Natural Backdoor Attack Against Model Distillation

Deep learning models are vulnerable to backdoor attacks, where attackers inject malicious behavior through data poisoning and later exploit triggers to manipulate deployed models. To improve the stealth and effectiveness of backdoors, prior studies have introduced various imperceptible attack methods targeting both defense mechanisms and manual inspection. However, all poisoning-based attacks still rely on privileged access to the training dataset. Consequently, model distillation using a trusted dataset has emerged as an effective defense against these attacks. To bridge this gap, we introduce INK, an inheritable natural backdoor attack that targets model distillation. The key insight behind INK is the use of naturally occurring statistical features in all datasets, allowing attackers to leverage them as backdoor triggers without direct access to the training data. Specifically, INK employs image variance as a backdoor trigger and enables both clean-image and clean-label attacks by manipulating the labels and image variance in an unauthenticated dataset. Once the backdoor is embedded, it transfers from the teacher model to the student model, even when defenders use a trusted dataset for distillation. Theoretical analysis and experimental results demonstrate the robustness of INK against transformation-based, search-based, and distillation-based defenses. For instance, INK maintains an attack success rate of over 98\% post-distillation, compared to an average success rate of 1.4\% for existing methods.

cs.CR↗

arXiv2024

Anomalous Hall effect in the antiferromagnetic Weyl semimetal SmAlSi

The intrinsic anomalous Hall effect (AHE) has been reported in numerous ferromagnetic (FM) Weyl semimetals. However, AHE in the antiferromagnetic (AFM) or paramagnetic (PM) state of Weyl semimetals has been rarely observed experimentally, and only in centrosymmetric materials. Different mechanisms have been proposed to establish the connection between the AHE and the type of magnetic order. In this paper, we report AHE in both the AFM and PM states of non-centrosymmetric compound SmAlSi. To account for the AHE in non-centrosymmetric Weyl semimetals without FM, we introduce a new mechanism based on magnetic field-induced Weyl nodes evolution. Angle-dependent quantum oscillations in SmAlSi provide evidence for the Weyl points and large AHE in both the PM and the AFM states. The proposed mechanism qualitatively explains the temperature dependence of the anomalous Hall conductivity (AHC), which displays unconventional power law behavior of the AHC in both AFM and PM states of SmAlSi.

cond-mat.mtrl-sci↗

arXiv2024

Angle-resolved photoemission spectroscopy with an $\textit{in situ}$ tunable magnetic field

Angle-resolved photoemission spectroscopy (ARPES) is a powerful tool for probing the momentum-resolved single-particle spectral function of materials. Historically, $\textit{in situ}$ magnetic fields have been carefully avoided as they are detrimental to the control of photoelectron trajectory during the photoelectron detection process. However, magnetic field is an important experimental knob for both probing and tuning symmetry-breaking phases and electronic topology in quantum materials. In this paper, we introduce an easily implementable method for realizing an $\textit{in situ}$ tunable magnetic field at the sample position in an ARPES experiment and analyze magnetic field induced artifacts in ARPES data. Specifically, we identified and quantified three distinct extrinsic effects of a magnetic field: Fermi surface rotation, momentum shrinking, and momentum broadening. We examined these effects in three prototypical quantum materials, i.e., a topological insulator (Bi$_2$Se$_3$), an iron-based superconductor (LiFeAs), and a cuprate superconductor (Bi$_2$Sr$_2$CaCu$_2$O$_{8+x}$), and demonstrate the feasibility of ARPES measurements in the presence of a controllable magnetic field. Our studies lay the foundation for the future development of the technique and interpretation of ARPES measurements of field-tunable quantum phases.

cond-mat.str-el↗

arXiv2024

Energy Storage Arbitrage in Two-settlement Markets: A Transformer-Based Approach

This paper presents an integrated model for bidding energy storage in day-ahead and real-time markets to maximize profits. We show that in integrated two-stage bidding, the real-time bids are independent of day-ahead settlements, while the day-ahead bids should be based on predicted real-time prices. We utilize a transformer-based model for real-time price prediction, which captures complex dynamical patterns of real-time prices, and use the result for day-ahead bidding design. For real-time bidding, we utilize a long short-term memory-dynamic programming hybrid real-time bidding model. We train and test our model with historical data from New York State, and our results showed that the integrated system achieved promising results of almost a 20\% increase in profit compared to only bidding in real-time markets, and at the same time reducing the risk in terms of the number of days with negative profits.

math.OC↗

arXiv2024

Spin-charge-lattice coupling across the charge density wave transition in a Kagome lattice antiferromagnet

Understanding spin and lattice excitations in a metallic magnetic ordered system form the basis to unveil the magnetic and lattice exchange couplings and their interactions with itinerant electrons. Kagome lattice antiferromagnet FeGe is interesting because it displays rare charge density wave (CDW) deep inside the antiferromagnetic ordered phase that interacts with the magnetic order. We use neutron scattering to study the evolution of spin and lattice excitations across the CDW transition $T_{\rm CDW}$ in FeGe. While spin excitations below $\sim$100 meV can be well described by spin waves of a spin-1 Heisenberg Hamiltonian, spin excitations at higher energies are centered around the Brillouin zone boundary and extend up to $\sim180$ meV consistent with quasiparticle excitations across spin-polarized electron-hole Fermi surfaces. Furthermore, $c$-axis spin wave dispersion and Fe-Ge optical phonon modes show a clear hardening below $T_{\rm CDW}$ due to spin-charge-lattice coupling but with no evidence for a phonon Kohn anomaly. By comparing our experimental results with density functional theory calculations in absolute units, we conclude that FeGe is a Hund's metal in the intermediate correlated regime where magnetism has contributions from both itinerant and localized electrons arising from spin polarized electronic bands near the Fermi level.

cond-mat.str-el↗

arXiv2024

Tunability of charge density wave in a magnetic kagome metal

The discovery of the charge density wave order (CDW) within a magnetically ordered phase in the kagome lattice FeGe has provided a promising platform to investigate intertwined degrees of freedom in kagome lattices. Recently, a method based on post-annealing has been suggested to manipulate the CDW order in kagome FeGe towards either long-range or suppressed orders. Here, we provide a comprehensive comparison of the experimentally measured electronic structures of FeGe crystals that have undergone different post-annealing procedures and demonstrate the remarkable effectiveness on tuning the CDW gap without strong perturbation on the underlying electronic structure. Moreover, we observe an additional low temperature transition that only appears in crystals with a long-range CDW order, which we associate with a lattice-spin coupled order. Our work indicates a likely strong sensitivity of the CDW order to disorder in FeGe, and provides evidence for strong coupling between the electronic, lattice, and spin degrees of freedom in this kagome magnet.

cond-mat.str-el↗

arXiv2024

Charge order induced Dirac pockets in the nonsymmorphic crystal TaTe$_4$

The interplay between charge order (CO) and nontrivial band topology has spurred tremendous interest in understanding topological excitations beyond the single-particle description. In a quasi-one-dimensional nonsymmorphic crystal TaTe$_4$, the (2a$\times$2b$\times$3c) charge ordered ground state drives the system into a space group where the symmetry indicator features the emergence of Dirac fermions and unconventional double Dirac fermions. Using angle-resolved photoemission spectroscopy and first-principles calculations, we provide evidence of the CO induced Dirac fermion-related bands near the Fermi level. Furthermore, the band folding at the Fermi level is compatible with the new periodicity dictated by the CO, indicating that the electrons near the Fermi level follow the crystalline symmetries needed to host double Dirac fermions in this system.

cond-mat.str-el↗

arXiv2024

Tailoring Physical Properties of Crystals through Synthetic Temperature Control: A Case Study for new Polymorphic NbFeTe2 phases

Growth parameters play a significant role in the crystal quality and physical properties of layered materials. Here we present a case study on a van der Waals magnetic NbFeTe2 material. Two different types of polymorphic NbFeTe2 phases, synthesized at different temperatures, display significantly different behaviors in crystal symmetry, electronic structure, electrical transport, and magnetism. While the phase synthesized at low temperature showing behavior consistent with previous reports, the new phase synthesized at high temperature, has completely different physical properties, such as metallic resistivity, long-range ferromagnetic order, anomalous Hall effect, negative magnetoresistance, and distinct electronic structures. Neutron diffraction reveals out-of-plane ferromagnetism below 70K, consistent with the electrical transport and magnetic susceptibility studies. Our work suggests that simply tuning synthetic parameters in a controlled manner could be an effective route to alter the physical properties of existing materials potentially unlocking new states of matter, or even discovering new materials.

cond-mat.str-el↗

arXiv2024

Symmetry breaking and ascending in the magnetic kagome metal FeGe

Spontaneous symmetry breaking-the phenomenon where an infinitesimal perturbation can cause the system to break the underlying symmetry-is a cornerstone concept in the understanding of interacting solid-state systems. In a typical series of temperature-driven phase transitions, higher temperature phases are more symmetric due to the stabilizing effect of entropy that becomes dominant as the temperature is increased. However, the opposite is rare but possible when there are multiple degrees of freedom in the system. Here, we present such an example of a symmetry-ascending phenomenon in a magnetic kagome metal FeGe by utilizing neutron Larmor diffraction and Raman spectroscopy. In the paramagnetic state at 460K, we confirm that the crystal structure is indeed hexagonal kagome lattice. On cooling to TN, the crystal structure changes from hexagonal to monoclinic with in-plane lattice distortions on the order of 10^(-4) and the associated splitting of the double degenerate phonon mode of the pristine kagome lattice. Upon further cooling to TCDW, the kagome lattice shows a small negative thermal expansion, and the crystal structure becomes more symmetric gradually upon further cooling. Increasing the crystalline symmetry upon cooling is unusual, it originates from an extremely weak structural instability that coexists and competes with the CDW and magnetic orders. These observations are against the expectations for a simple model with a single order parameter, hence can only be explained by a Landau free energy expansion that takes into account multiple lattice, charge, and spin degrees of freedom. Thus, the determination of the crystalline lattice symmetry as well as the unusual spin-lattice coupling is a first step towards understanding the rich electronic and magnetic properties of the system and sheds new light on intertwined orders where the lattice degree of freedom is no longer dominant.

cond-mat.str-el↗