arXiv subjects

Ming-Qiang Ren

Publications and source records attributed to Ming-Qiang Ren.

12 recordsLinked to original sources

arXiv2026

Intertwined Charge Stripes and Majorana Zero Modes in An Iron-Based Superconductor

In type-II superconductors, magnetic fields modulate the amplitude and phase of the superconducting order parameter, forming quantized vortices where superconductivity is locally suppressed and exotic bound states or competing electronic orders emerge. Using spectroscopic-imaging scanning tunneling microscopy on epitaxial Ba(Fe$_{0.94}Co$_{0.06})$_2$As$_2$ films, we discover an incommensurate charge-stripe order aligned with the Fe-Fe bond direction. These charge modulations become strongly enhanced at the vortex core and extend far into the vortex halo. Strikingly, the charge order modulates Andreev bound states of vortices at non-zero energies, producing abelian vortices with half-odd-integer level quantization and non-abelian vortices with integer-quantized core states that host a Majorana zero mode. The distinct vortex types are distinguished by the registry of their centers relative to the charge-stripe pattern and remain robust in ultrathin (2.5-unit-cell) films. Our findings reveal a density-wave-textured vortex matter and provide fresh insights into intertwined phenomena in iron-based superconductors.

cond-mat.supr-con↗

arXiv2026

Topological Semimetal Transport Modulated by Interstitial Fe in Ba(Fe$_{1-x}$Co$_x$)$_{2+\delta}As$_2$ Superconductors

Topological semimetals are renowned for exhibiting large, unsaturated magnetoresistance arising from ultrahigh carrier mobility and electron-hole compensation. However, such behaviors remain poorly understood in iron-based superconductors that have been recently recognized to harbor rich nontrivial topology. Here, we combine angle-resolved magneto-transport measurements with first principles calculations to reveal the emergence and tunability of topological semimetals in ferropnictide Ba(Fe$_{1-x}$Co$_x$)$_{2+\delta}As$_2$ epitaxial films, modulated by interstitial Fe. These states exhibit ultralow residual resistivity, coexisting high-mobility electron and hole carriers, and linear positive magnetoresistance below 110 K. Remarkably, the magnetoresistance becomes more pronounced when the magnetic field is applied parallel to the film plane, reaching an unsaturated 1206% at 56 T. Furthermore, superconductivity persists in these ferropnictide films, establishing them as a tunable platform for investigating the interplay among electron correlation, topology, and superconductivity.

cond-mat.supr-con↗

arXiv2025

Atomic-scale imaging of electronic nematicity in ferropnictides

Electronic nematicity, a correlated state characterized by broken rotational symmetry, has been recognized as a ubiquitous feature intertwined with unconventional electron pairing in various iron-based superconductors. Here we employ spectroscopic-imaging scanning tunneling microscopy to visualize atomic-scale electronic nematicity directly on FeAs planes of a prototypical ferropnictide BaFe$_2$As$_2$. Spatially, the nematic order appears as 4$a_{\textrm{Fe}}$-spaced stripes ($a_{\textrm{Fe}} \sim $ 0.28 nm is the in-plane Fe-Fe distance) within homogeneously and orthogonally oriented nano-domains. The energy-resolved conductance maps reveal a pronounced energy-dependence of the nematic order parameter that experiences a sign change at approximately 30 meV. This characteristic behavior coincides with energy-dependent orbital splitting previously identified in momentum space, but is remarkably visualized in real space for the first time in our study. Moreover, the electronic nematicity exhibits pronounced sensitivity to single impurities and is notably suppressed by cobalt substitution for Fe atoms, promoting optimal superconductivity when nematic fluctuations are strongest. Our results provide pivotal experimental insights for developing a microscopic model of nematic order, thus paving the way to study its complex relationship with unconventional superconductivity.

cond-mat.supr-con↗

arXiv2025

Full-Gap Superconductivity in BaAs/Ferropnictide Heterostructures

Interfacial interactions often promote the emergence of unusual phenomena in two-dimensional systems, including high-temperature superconductivity. Here, we report the observation of full-gap superconductivity with a maximal spectroscopic temperature up to 26 K in a BaAs monolayer grown on ferropnictide Ba(Fe$_{1-x}$Co$_x$)$_2$As$_2$ (abbreviated as BFCA) epitaxial films. The superconducting gap remains robust even when the thickness of underlying BFCA is reduced to the monolayer limit, in contrast to the rapid suppression of $T_\textrm{c}$ in standalone BFCA thin films. We reveal that the exceptional crystallinity of the BaAs/BFCA heterostructures, featured by their remarkable electronic and geometric uniformities, is crucial for the emergent full-gap superconductivity with mean-field temperature dependence and pronounced bound states within magnetic vortices. Our findings open up new avenues to unravel the mysteries of unconventional superconductivity in ferropnictides and advance the development of FeAs-based heterostructures.

cond-mat.supr-con↗

arXiv2022

Anomalous superconducting proximity effect of planar Pb-RhPb2 heterojunctions in the clean limit

Interest in superconducting proximity effect has been revived by the exploitation of Andreev states and by the possible emergence of Majorana bound states at the interface. Spectroscopy of these states has been so far restricted to just a handful of superconductor-metal systems in the diffusion regime, whereas reports in otherwise clean superconductor-superconductor heterojunctions are scarce. Here, we realize molecular beam epitaxy growth of atomically sharp planar heterojunctions between Pb and a topological superconductor candidate RhPb2 that allows us to spectroscopically image the proximity effect in the clean limit. The measured energy spectra of RhPb2 vary with the spatial separation from proximal Pb, and exhibit unusual modifications in the pairing gap structure and size that extend over a distance far beyond the coherence length. This anomalously long-range proximity (LRP) effect breaks the rotational symmetry of Cooper pair potential in real space and largely deforms the Abrikosov vortex cores. Our work opens promising avenues for fundamental studies of the Andreev physics and extraordinary states in clean superconducting heterojunctions.

cond-mat.supr-con↗

arXiv2022

Tuning the electronic states and superconductivity in alkali fulleride films

The successful preparation of superconducting alkali fulleride (A$_x$C$_{60}$, A = K, Rb, Cs) films using state-of-the-art molecular beam epitaxy overcomes the disadvantages of the air-sensitivity and phase separation in bulk A$_x$C$_{60}$, enabling for the first time a direct investigation of the superconductivity in alkali fullerides on the molecular scale. In this paper, we briefly review recent cryogenic scanning tunneling microscopy results of the structural, electronic, and superconducting properties of the fcc A$_x$C$_{60}$ films grown on graphitized SiC substrates. Robust $s$-wave superconductivity is revealed against the pseudogap, electronic correlation, non-magnetic impurities, and merohedral disorder. By controlling the alkali metal species, film thickness, and electron doping, we systematically tune the C$_{60}^{x-}$ orientational orderings and superconductivity in A$_x$C$_{60}$ films and then complete a unified phase diagram of superconducting gap size vs electronic correlation and doping. These investigations are conclusive and elucidated that the $s$-wave superconductivity retains in alkali fullerides despite of the electronic correlation and presence of pseudogap.

cond-mat.supr-con↗

arXiv2022

Semiconductor-metal phase transition and emergent charge density waves in 1T-ZrX$_2$ (X = Se, Te) at the two-dimensional limit

Charge density wave (CDW) is a collective quantum phenomenon in metals and features a wave-like modulation of the conduction electron density. A microscopic understanding and experimental control of this many-body electronic state in atomically thin materials remain hot topics in materials physics. By means of material engineering, we realized a dimensionality and Zr intercalation induced semiconductor-metal phase transition in 1T-ZrX$_2$ (X = Se, Te) ultra-thin films, accompanied by a commensurate 2 $\times$ 2 CDW order. Furthermore, we observed a CDW energy gap up to 22 meV around the Fermi level. Fourier-transformed scanning tunneling microscopy and angle-resolved photoemission spectroscopy reveal that 1T-ZrX$_2$ films exhibit the simplest Fermi surface among the known CDW materials in TMDCs, consisting only of Zr 4d-derived elliptical electron conduction band at the corners of the Brillouin zone.

cond-mat.mtrl-sci↗

arXiv2021

Merohedral disorder and impurity impacts on superconductivity of fullerenes

Local quasiparticle states around impurities provide essential insight into the mechanism of unconventional superconductivity, especially when the candidate materials are proximate to an antiferromagnetic Mott-insulating phase. While such states have been reported in atom-based cuprates and iron-based compounds, they are unexplored in organic superconductors which feature tunable molecular orientation. Here we employ scanning tunneling microscopy and spectroscopy to reveal multiple forms of robustness of an exotic $s$-wave superconductivity in epitaxial Rb$_3$C$_{60}$ films against merohedral disorder, non-magnetic single impurities and step edges at the atomic scale. Also observed have been Yu-Shiba-Rusinov (YSR) states induced by deliberately incurred Fe adatoms that act as magnetic scatters. The bound states display abrupt spatial decay and vary in energy with the Fe adatom registry. Our results and the universal optimal superconductivity at half-filling point towards local electron pairing in which the multiorbital electronic correlations and intramolecular phonons together drive the high-temperature superconductivity of doped fullerenes.

cond-mat.supr-con↗

arXiv2021

Charge density waves and Fermi level pinning in monolayer and bilayer SnSe$_2$

Materials with reduced dimensionality often exhibit exceptional properties that are different from their bulk counterparts. Here we report the emergence of a commensurate 2 $\times$ 2 charge density wave (CDW) in monolayer and bilayer SnSe$_2$ films by scanning tunneling microscope. The visualized spatial modulation of CDW phase becomes prominent near the Fermi level, which is pinned inside the semiconductor band gap of SnSe$_2$. We show that both CDW and Fermi level pinning are intimately correlated with band bending and virtual induced gap states at the semiconductor heterointerface. Through interface engineering, the electron-density-dependent phase diagram is established in SnSe$_2$. Fermi surface nesting between symmetry inequivalent electron pockets is revealed to drive the CDW formation and to provide an alternative CDW mechanism that might work in other compounds.

cond-mat.mtrl-sci↗

arXiv2020

Stoichiometry and defect superstructures in epitaxial FeSe films on SrTiO3

Cryogenic scanning tunneling microscopy is employed to investigate the stoichiometry and defects of epitaxial FeSe thin films on SrTiO3(001) substrates under various post-growth annealing conditions. Low-temperature annealing with an excess supply of Se leads to formation of Fe vacancies and superstructures, accompanied by a superconductivity (metal)-to-insulator transition in FeSe films. By contrast, high-temperature annealing could eliminate the Fe vacancies and superstructures, and thus recover the high-temperature superconducting phase of monolayer FeSe films. We also observe multilayer FeSe during low-temperature annealing, which is revealed to link with Fe vacancy formation and adatom migration. Our results document very special roles of film stoichiometry and help unravel several controversies in the properties of monolayer FeSe films.

cond-mat.supr-con↗

arXiv2019

Visualizing molecular orientational ordering and electronic structure in CsnC60 fulleride films

Alkali-doped fullerides exhibit a wealth of unusual phases that remain controversial by nature. Here we report a cryogenic scanning tunneling microscopy study of the sub-molecular structural and electronic properties of expanded fullerene C60 films with various cesium (Cs) doping. By varying the discrete charge states and film thicknesses, we reveal a large tunability of orientational ordering of C60 anions, yet the tunneling conductance spectra are all robustly characteristic of energy gaps, hallmarks of Jahn-Teller instability and electronic correlations. The Fermi level lies halfway within the insulating gap for stoichiometric Cs doping level of n = 1, 2, 3 and 4, apart from which it moves toward band edges with concomitant electronic states within the energy gap. Our findings establish the universality of Jahn-Teller instability, and clarify the relationship among the doping, structural and electronic structures in CsnC60 fullerides.

cond-mat.supr-con↗

arXiv2019

Coexistence of full-gap superconductivity and pseudogap in two-dimensional fullerides

Alkali-fulleride superconductors with a maximum critical temperature Tc of 40 K exhibit similar electronic phase diagram with unconventional high-Tc superconductors where the superconductivity resides proximate to a magnetic Mott-insulating state. However, distinct from cuprate compounds, which superconduct through two-dimensional (2D) CuO2 planes, alkali fullerides are attributed to the three-dimensional (3D) members of high-Tc family. Here, we employ scanning tunneling microscopy to show that trilayer K3C60 displays fully gapped strong coupling s-wave superconductivity that coexists spatially with a cuprate-like pseudogap state above Tc = 22 K and within vortices. A precise control of electronic correlations and doping reveals that superconductivity occurs near a superconductor-Mott insulator transition and reaches maximum at half-filling. The s-wave symmetry retains over the entire phase diagram, which, in conjunction with an abrupt decline of superconductivity below half-filling, demonstrates that alkali fullerides are predominantly phonon-mediated superconductors, although the multiorbital electronic correlations also come into play.

cond-mat.supr-con↗