arXiv subjects

Minho Choi

Publications and source records attributed to Minho Choi.

At least 55 records · Page 3Linked to original sources

arXiv2020

The JCMT BISTRO Survey: Magnetic Fields Associated with a Network of Filaments in NGC 1333

We present new observations of the active star-formation region NGC 1333 in the Perseus molecular cloud complex from the James Clerk Maxwell Telescope B-Fields In Star-forming Region Observations (BISTRO) survey with the POL-2 instrument. The BISTRO data cover the entire NGC 1333 complex (~1.5 pc x 2 pc) at 0.02 pc resolution and spatially resolve the polarized emission from individual filamentary structures for the first time. The inferred magnetic field structure is complex as a whole, with each individual filament aligned at different position angles relative to the local field orientation. We combine the BISTRO data with low- and high- resolution data derived from Planck and interferometers to study the multiscale magnetic field structure in this region. The magnetic field morphology drastically changes below a scale of ~1 pc and remains continuous from the scales of filaments (~0.1 pc) to that of protostellar envelopes (~0.005 pc or ~1000 au). Finally, we construct simple models in which we assume that the magnetic field is always perpendicular to the long axis of the filaments. We demonstrate that the observed variation of the relative orientation between the filament axes and the magnetic field angles are well reproduced by this model, taking into account the projection effects of the magnetic field and filaments relative to the plane of the sky. These projection effects may explain the apparent complexity of the magnetic field structure observed at the resolution of BISTRO data toward the filament network.

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arXiv2020

ALMA ACA and Nobeyama observations of two Orion cores in deuterated molecular lines

We mapped two molecular cloud cores in the Orion A cloud with the ALMA ACA 7-m Array and with the Nobeyama 45-m radio telescope. These cores have bright N$_2$D$^+$ emission in single-pointing observations with the Nobeyama 45-m radio telescope, have relatively high deuterium fraction, and are thought to be close to the onset of star formation. One is a star-forming core, and the other is starless. These cores are located along filaments observed in N$_2$H$^+$, and show narrow linewidths of 0.41 km s$^{-1}$ and 0.45 km s$^{-1}$ in N$_2$D$^+$, respectively, with the Nobeyama 45-m telescope. Both cores were detected with the ALMA ACA 7m Array in the continuum and molecular lines at Band 6. The starless core G211 shows clumpy structure with several sub-cores, which in turn show chemical differences. Also, the sub-cores in G211 have internal motions that are almost purely thermal. The starless sub-core G211D, in particular, shows a hint of the inverse P Cygni profile, suggesting infall motion. The star-forming core G210 shows an interesting spatial feature of two N$_2$D$^+$ peaks of similar intensity and radial velocity located symmetrically with respect to the single dust continuum peak. One interpretation is that the two N$_2$D$^+$ peaks represent an edge-on pseudo-disk. The CO outflow lobes, however, are not directed perpendicular to the line connecting both N$_2$D$^+$ peaks.

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arXiv2019

Submillimeter continuum variability in Planck Galactic cold clumps

In the early stages of star formation, a protostar is deeply embedded in an optically thick envelope such that it is not directly observable. Variations in the protostellar accretion rate, however, will cause luminosity changes that are reprocessed by the surrounding envelope and are observable at submillimeter wavelengths. We searched for submillimeter flux variability toward 12 Planck Galactic Cold Clumps detected by the James Clerk Maxwell Telescope (JCMT)-SCUBA-2 Continuum Observations of Pre-protostellar Evolution (SCOPE) survey. These observations were conducted at 850 um using the JCMT/SCUBA-2. Each field was observed three times over about 14 months between 2016 April and 2017 June. We applied a relative flux calibration and achieved a calibration uncertainty of ~ 3.6% on average. We identified 136 clumps across 12 fields and detected four sources with flux variations of ~ 30%. For three of these sources, the variations appear to be primarily due to large-scale contamination, leaving one plausible candidate. The flux change of the candidate may be associated with low- or intermediate-mass star formation assuming a distance of 1.5 kpc, although we cannot completely rule out the possibility that it is a random deviation. Further studies with dedicated monitoring would provide a better understanding of the detailed relationship between submillimeter flux and accretion rate variabilities while enhancing the search for variability in star-forming clumps farther away than the Gould Belt.

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arXiv2019

The organic chemistry in the innermost, infalling envelope of the Class 0 protostar L483

Context: The protostellar envelopes, outflow and large-scale chemistry of Class~0 and Class~I objects have been well-studied, but while previous works have hinted at or found a few Keplerian disks at the Class~0 stage, it remains to be seen if their presence in this early stage is the norm. Likewise, while complex organics have been detected toward some Class~0 objects, their distribution is unknown as they could reside in the hottest parts of the envelope, in the emerging disk itself or in other components of the protostellar system, such as shocked regions related to outflows. Aims: In this work, we aim to address two related issues regarding protostars: when rotationally supported disks form around deeply embedded protostars and where complex organic molecules reside in such objects. Methods: We observed the deeply embedded protostar, L483, using Atacama Large Millimeter/submillimeter Array (ALMA) Band~7 data from Cycles~1 and 3 with a high angular resolution down to $\sim$~0.1$^{\prime\prime}$ (20~au) scales. Results: We find that the kinematics of CS~$J=7$--$6$ and H$^{13}$CN~$J=4$--$3$ are best fitted by the velocity profile from infall under conservation of angular momentum and not by a Keplerian profile. The spatial extents of the observed complex organics are consistent with an estimated ice sublimation radius of the envelope at $\sim$~50~au, suggesting that the complex organics exist in the hot corino of L483. Conclusions: We find that L483 does not harbor a Keplerian disk down to at least $15$~au in radius. Instead, the innermost regions of L483 are undergoing a rotating collapse. This result highlights that some Class~0 objects contain only very small disks, or none at all, with the complex organic chemistry taking place on scales inside the hot corino of the envelope, in a region larger than the emerging disk.

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arXiv2019

The JCMT BISTRO Survey: The Magnetic Field of the Barnard 1 Star-Forming Region

We present the POL-2 850 $μ$m linear polarization map of the Barnard 1 clump in the Perseus molecular cloud complex from the B-fields In STar-forming Region Observations (BISTRO) survey at the James Clerk Maxwell Telescope. We find a trend of decreasing polarization fraction as a function of total intensity, which we link to depolarization effects towards higher density regions of the cloud. We then use the polarization data at 850 $μ$m to infer the plane-of-sky orientation of the large-scale magnetic field in Barnard 1. This magnetic field runs North-South across most of the cloud, with the exception of B1-c where it turns more East-West. From the dispersion of polarization angles, we calculate a turbulence correlation length of $5.0 \pm 2.5$ arcsec ($1500$ au), and a turbulent-to-total magnetic energy ratio of $0.5 \pm 0.3$ inside the cloud. We combine this turbulent-to-total magnetic energy ratio with observations of NH$_3$ molecular lines from the Green Bank Ammonia Survey (GAS) to estimate the strength of the plane-of-sky component of the magnetic field through the Davis-Chandrasekhar-Fermi method. With a plane-of-sky amplitude of $120 \pm 60$ $μ$G and a criticality criterion $λ_c = 3.0 \pm 1.5$, we find that Barnard 1 is a supercritical molecular cloud with a magnetic field nearly dominated by its turbulent component.

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arXiv2019

High-Resolution Observations of the Molecular Clouds Associated with the Huge HII Region CTB 102

We report the first high-resolution (sub-arcminute) large-scale mapping $^{12}$CO and $^{13}$CO observations of the molecular clouds associated with the giant outer Galaxy HII region CTB~102 (KR 1). These observations were made using a newly commissioned receiver system on the 13.7-m radio telescope at the Taeduk Radio Astronomy Observatory. Our observations show that the molecular clouds have a spatial extent of $60 \times 35$ pc and a total mass of $10^{4.8} - 10^{5.0}$ M$_\odot$. Infrared data from WISE and 2MASS were used to identify and classify the YSO population associated with ongoing star formation activity within the molecular clouds. We directly detect 18 class I/class II YSOs and six transition disk objects. Moving away from the HII region, there is an age/class gradient consistent with sequential star formation. The infrared and molecular-line data were combined to estimate the star formation efficiency (SFE) of the entire cloud as well as the SFE for various sub-regions of the cloud. We find that the overall SFE is between $\sim5 - 10$%, consistent with previous observations of giant molecular clouds. One of the sub-regions, region 1a, is a clear outlier, with a SFE of 17 $-$ 35% on a 5 pc spatial scale. This high SFE is more typical for much smaller (sub-pc scale) star-forming cores, and we think region 1a is likely an embedded massive protocluster.

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arXiv2019

JCMT BISTRO survey: Magnetic Fields within the Hub-Filament Structure in IC 5146

We present the 850 $μ$m polarization observations toward the IC5146 filamentary cloud taken using the Submillimetre Common-User Bolometer Array 2 (SCUBA-2) and its associated polarimeter (POL-2), mounted on the James Clerk Maxwell Telescope (JCMT), as part of the B-fields In STar forming Regions Observations (BISTRO). This work is aimed at revealing the magnetic field morphology within a core-scale ($\lesssim 1.0$ pc) hub-filament structure (HFS) located at the end of a parsec-scale filament. To investigate whether or not the observed polarization traces the magnetic field in the HFS, we analyze the dependence between the observed polarization fraction and total intensity using a Bayesian approach with the polarization fraction described by the Rice likelihood function, which can correctly describe the probability density function (PDF) of the observed polarization fraction for low signal-to-noise ratio (SNR) data. We find a power-law dependence between the polarization fraction and total intensity with an index of 0.56 in $A_V\sim$ 20--300 mag regions, suggesting that the dust grains in these dense regions can still be aligned with magnetic fields in the IC5146 regions. Our polarization maps reveal a curved magnetic field, possibly dragged by the contraction along the parsec-scale filament. We further obtain a magnetic field strength of 0.5$\pm$0.2 mG toward the central hub using the Davis-Chandrasekhar-Fermi method, corresponding to a mass-to-flux criticality of $\sim$ $1.3\pm0.4$ and an Alfvénic Mach number of $<$0.6. These results suggest that gravity and magnetic field is currently of comparable importance in the HFS, and turbulence is less important.

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arXiv2019

SCOPE: SCUBA-2 Continuum Observations of Pre-protostellar Evolution - Survey Description and Compact Source Catalogue

We present the first release of the data and compact-source catalogue for the JCMT Large Program SCUBA-2 Continuum Observations of Pre-protostellar Evolution (SCOPE). SCOPE consists of 850-um continuum observations of 1235 Planck Galactic Cold Clumps (PGCCs) made with the Submillimetre Common-User Bolometer Array 2 on the James Clerk Maxwell Telescope. These data are at an angular resolution of 14.4 arcsec, significantly improving upon the 353-GHz resolution of Planck at 5 arcmin, and allowing for a catalogue of 3528 compact sources in 558 PGCCs. We find that the detected PGCCs have significant sub-structure, with 61 per cent of detected PGCCs having 3 or more compact sources, with filamentary structure also prevalent within the sample. A detection rate of 45 per cent is found across the survey, which is 95 per cent complete to Planck column densities of $N_{H_{2}}$ $>$ 5 $\times$ 10$^{21}$ cm$^{-2}$. By positionally associating the SCOPE compact sources with YSOs, the star formation efficiency, as measured by the ratio of luminosity to mass, in nearby clouds is found to be similar to that in the more distant Galactic Plane, with the column density distributions also indistinguishable from each other.

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arXiv2019

The JCMT BISTRO Survey: The Magnetic Field In The Starless Core $ρ$ Ophiuchus C

We report 850~$μ$m dust polarization observations of a low-mass ($\sim$12 $M_{\odot}$) starless core in the $ρ$ Ophiuchus cloud, Ophiuchus C, made with the POL-2 instrument on the James Clerk Maxwell Telescope (JCMT) as part of the JCMT B-fields In STar-forming Region Observations (BISTRO) survey. We detect an ordered magnetic field projected on the plane of sky in the starless core. The magnetic field across the $\sim$0.1~pc core shows a predominant northeast-southwest orientation centering between $\sim$40$^\circ$ to $\sim$100$^\circ$, indicating that the field in the core is well aligned with the magnetic field in lower-density regions of the cloud probed by near-infrared observations and also the cloud-scale magnetic field traced by Planck observations. The polarization percentage ($P$) decreases with an increasing total intensity ($I$) with a power-law index of $-$1.03 $\pm$ 0.05. We estimate the plane-of-sky field strength ($B_{\mathrm{pos}}$) using modified Davis-Chandrasekhar-Fermi (DCF) methods based on structure function (SF), auto-correlation (ACF), and unsharp masking (UM) analyses. We find that the estimates from the SF, ACF, and UM methods yield strengths of 103 $\pm$ 46 $μ$G, 136 $\pm$ 69 $μ$G, and 213 $\pm$ 115 $μ$G, respectively. Our calculations suggest that the Ophiuchus C core is near magnetically critical or slightly magnetically supercritical (i.e. unstable to collapse). The total magnetic energy calculated from the SF method is comparable to the turbulent energy in Ophiuchus C, while the ACF method and the UM method only set upper limits for the total magnetic energy because of large uncertainties.

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arXiv2018

Magnetic fields towards Ophiuchus-B derived from SCUBA-2 polarization measurements

We present the results of dust emission polarization measurements of Ophiuchus-B (Oph-B) carried out using the Submillimetre Common-User Bolometer Array 2 (SCUBA-2) camera with its associated polarimeter (POL-2) on the James Clerk Maxwell Telescope (JCMT) in Hawaii. This work is part of the B-fields In Star-forming Region Observations (BISTRO) survey initiated to understand the role of magnetic fields in star formation for nearby star-forming molecular clouds. We present a first look at the geometry and strength of magnetic fields in Oph-B. The field geometry is traced over $\sim$0.2 pc, with clear detection of both of the sub-clumps of Oph-B. The field pattern appears significantly disordered in sub-clump Oph-B1. The field geometry in Oph-B2 is more ordered, with a tendency to be along the major axis of the clump, parallel to the filamentary structure within which it lies. The degree of polarization decreases systematically towards the dense core material in the two sub-clumps. The field lines in the lower density material along the periphery are smoothly joined to the large scale magnetic fields probed by NIR polarization observations. We estimated a magnetic field strength of 630$\pm$410 $μ$G in the Oph-B2 sub-clump using a Davis-Chandeasekhar-Fermi analysis. With this magnetic field strength, we find a mass-to-flux ratio $λ$= 1.6$\pm$1.1, which suggests that the Oph-B2 clump is slightly magnetically supercritical.

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arXiv2018

Inflow Motions associated with High-mass Protostellar Objects

We performed a molecular line survey of 82 high-mass protostellar objects in search for inflow signatures associated with high-mass star formation. Using the H$^{13}$CO$^+$ (1$-$0) line as an optically thin tracer, we detected a statistically significant excess of blue asymmetric line profiles in the HCO$^+$ (1$-$0) transition, but nonsignificant excesses in the HCO$^+$ (3$-$2) and H$_2$CO (2$_{12}$$-$1$_{11}$) transitions. The negative blue excess for the HCN (3$-$2) transition suggests that the line profiles are affected by dynamics other than inflow motion. The HCO$^+$ (1$-$0) transition thus seems to be the suitable tracer of inflow motions in high-mass star-forming regions, as previously suggested. We found 27 inflow candidates that have at least one blue asymmetric profile and no red asymmetric profile, and derived the inflow velocities to be 0.23$-$2.00 km s$^{-1}$ for 20 of them using a simple two-layer radiative transfer model. Our sample is divided into two groups in different evolutionary stages. The blue excess of the group in relatively earlier evolutionary stages was estimated to be slightly higher than that of the other in the HCO$^+$ (1$-$0) transition.

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arXiv2018

Planck Cold Clumps in the $λ$ Orionis complex. II. Environmental effects on core formation

Based on the 850 $μ$m dust continuum data from SCUBA-2 at James Clerk Maxwell Telescope (JCMT), we compare overall properties of Planck Galactic Cold Clumps (PGCCs) in the $λ$ Orionis cloud to those of PGCCs in the Orion A and B clouds. The Orion A and B clouds are well known active star-forming regions, while the $λ$ Orionis cloud has a different environment as a consequence of the interaction with a prominent OB association and a giant Hii region. PGCCs in the $λ$ Orionis cloud have higher dust temperatures ($Td=16.13\pm0.15$ K) and lower values of dust emissivity spectral index ($ β=1.65\pm0.02$) than PGCCs in the Orion A (Td=13.79$\pm 0.21$K, $β=2.07\pm0.03$) and Orion B ($Td=13.82\pm0.19$K, $β=1.96\pm0.02$) clouds. We find 119 sub-structures within the 40 detected PGCCs and identify them as cores. Of total 119 cores, 15 cores are discovered in the $λ$ Orionis cloud, while 74 and 30 cores are found in the Orion A and B clouds, respectively. The cores in the $λ$ Orionis cloud show much lower mean values of size R=0.08 pc, column density N(H2)=$(9.5\pm1.2) \times 10^{22}$ cm$^{-2}$, number density n(H2)=$(2.9 \pm 0.4)\times10^{5}$ cm$^{-3}$, and mass $M_{core}$=$1.0\pm0.3$ M$_{\odot}$ compared to the cores in the Orion A (R=0.11pc, $N(H2)=(2.3\pm0.3) \times 10^{23}$ cm$^{-2}$, n(H2)=$(3.8\pm0.5) \times 10^{5}$cm$^{-3}$, and $M_{core}$=$2.4 \pm 0.3$ M$_{\odot}$) and Orion B (R=0.16pc, N(H2)=$(3.8 \pm 0.4) \times 10^{23}$cm$^{-2}$, n(H2)=$(15.6\pm1.8)\times10^{5}$ cm$^{-3}$, and $M_{core}$= $2.7\pm0.3$ M$_{\odot}$) clouds. These core properties in the $λ$ Orionis cloud can be attributed to the photodissociation and external heating by the nearby Hii region, which may prevent the PGCCs from forming gravitationally bound structures and eventually disperse them. These results support the idea of negative stellar feedback on core formation.

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arXiv2018

A First Look at BISTRO Observations of The $ρ$ Oph-A core

We present 850 $μ$m imaging polarimetry data of the $ρ$ Oph-A core taken with the Submillimeter Common-User Bolometer Array-2 (SCUBA-2) and its polarimeter (POL-2), as part of our ongoing survey project, BISTRO (B-fields In STar forming RegiOns). The polarization vectors are used to identify the orientation of the magnetic field projected on the plane of the sky at a resolution of 0.01 pc. We identify 10 subregions with distinct polarization fractions and angles in the 0.2 pc $ρ$ Oph A core; some of them can be part of a coherent magnetic field structure in the $ρ$ Oph region. The results are consistent with previous observations of the brightest regions of $ρ$ Oph-A, where the degrees of polarization are at a level of a few percents, but our data reveal for the first time the magnetic field structures in the fainter regions surrounding the core where the degree of polarization is much higher ($> 5 \%$). A comparison with previous near-infrared polarimetric data shows that there are several magnetic field components which are consistent at near-infrared and submillimeter wavelengths. Using the Davis-Chandrasekhar-Fermi method, we also derive magnetic field strengths in several sub-core regions, which range from approximately 0.2 to 5 mG. We also find a correlation between the magnetic field orientations projected on the sky with the core centroid velocity components.

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arXiv2018

Gravitationally unstable condensations revealed by ALMA in the TUKH122 prestellar core in the Orion A cloud

We have investigated the TUKH122 prestellar core in the Orion A cloud using ALMA 3 mm dust continuum, N$_2$H$^+$ ($J=1-0$), and CH$_3$OH ($J_K=2_K-1_K$) molecular line observations. Previous studies showed that TUKH122 is likely on the verge of star formation because the turbulence is almost dissipated and chemically evolved among other starless cores in the Orion A cloud. By combining ALMA 12-m and ACA data, we recover extended emission with a resolution of $\sim5"$ corresponding to 0.01 pc and identify 6 condensations with a mass range of $0.1-0.4$ $M_\odot$ and a radius of $\lesssim0.01$ pc. These condensations are gravitationally bound following a virial analysis and are embedded in the filament including the elongated core with a mass of $\sim29$ $M_\odot$ and a radial density profile of $r^{-1.6}$ derived by {\it Herschel}. The separation of these condensations is $\sim0.035$ pc, consistent with the thermal jeans length at a density of $4.4\times10^5$ cm$^{-3}$. This density is similar to the central part of the core. We also find a tendency that the N$_2$H$^+$ molecule seems to deplete at the dust peak condensation. This condensation may be beginning to collapse because the linewidth becomes broader. Therefore, the fragmentation still occurs in the prestellar core by thermal Jeans instability and multiple stars are formed within the TUKH122 prestellar core. The CH$_3$OH emission shows a large shell-like distribution and surrounds these condensations, suggesting that the CH$_3$OH molecule formed on dust grains is released into gas phase by non-thermal desorption such as photoevaporation caused by cosmic-ray induced UV radiation.

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arXiv2017

Precessing Jet and Large Dust Grains in the V380 Ori NE Star-forming Region

The V380 Ori NE bipolar outflow was imaged in the SiO and CO J = 1 - 0 lines, and dense cores in L1641 were observed in the 2.0-0.89 mm continuum. The highly collimated SiO jet shows point-symmetric oscillation patterns in both position and velocity, which suggests that the jet axis is precessing and the driving source may belong to a non-coplanar binary system. By considering the position and velocity variabilities together, accurate jet parameters were derived. The protostellar system is viewed nearly edge-on, and the jet has a flow speed of 35 km/s and a precession period of 1600 years. The CO outflow length gives a dynamical timescale of 6300 years, and the protostar must be extremely young. The inferred binary separation of 6-70 au implies that this protobinary system may have been formed through the disk instability process. The continuum spectra of L1641 dense cores indicate that the emission comes from dust, and the fits with modified blackbody functions give emissivity power indices of beta = 0.3-2.2. The emissivity index shows a positive correlation with the molecular line width, but no strong correlation with bolometric luminosity or temperature. V380 Ori NE has a particularly low value of beta = 0.3, which tentatively suggests the presence of millimeter-sized dust grains. Because the dust growth takes millions of years, much longer than the protostellar age, this core may have produced large grains in the starless core stage. HH 34 MMS and HH 147 MMS also have low emissivity indices.

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arXiv2017

Formation of Wide Binaries by Turbulent Fragmentation

Understanding the formation of wide binary systems of very low mass stars (M $\le$ 0.1 Msun) is challenging. The most obvious route is via widely separated low-mass collapsing fragments produced through turbulent fragmentation of a molecular core. However, close binaries/multiples from disk fragmentation can also evolve to wide binaries over a few initial crossing times of the stellar cluster through tidal evolution. Finding an isolated low mass wide binary system in the earliest stage of formation, before tidal evolution could occur, would prove that turbulent fragmentation is a viable mechanism for (very) low mass wide binaries. Here we report high resolution ALMA observations of a known wide-separation protostellar binary, showing that each component has a circumstellar disk. The system is too young to have evolved from a close binary and the disk axes are misaligned, providing strong support for the turbulent fragmentation model. Masses of both stars are derived from the Keplerian rotation of the disks; both are very low mass stars.

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arXiv2017

First results from BISTRO -- a SCUBA-2 polarimeter survey of the Gould Belt

We present the first results from the B-fields In STar-forming Region Observations (BISTRO) survey, using the Sub-millimetre Common-User Bolometer Array 2 (SCUBA-2) camera, with its associated polarimeter (POL-2), on the James Clerk Maxwell Telescope (JCMT) in Hawaii. We discuss the survey's aims and objectives. We describe the rationale behind the survey, and the questions which the survey will aim to answer. The most important of these is the role of magnetic fields in the star formation process on the scale of individual filaments and cores in dense regions. We describe the data acquisition and reduction processes for POL-2, demonstrating both repeatability and consistency with previous data. We present a first-look analysis of the first results from the BISTRO survey in the OMC 1 region. We see that the magnetic field lies approximately perpendicular to the famous 'integral filament' in the densest regions of that filament. Furthermore, we see an 'hour-glass' magnetic field morphology extending beyond the densest region of the integral filament into the less-dense surrounding material, and discuss possible causes for this. We also discuss the more complex morphology seen along the Orion Bar region. We examine the morphology of the field along the lower-density north-eastern filament. We find consistency with previous theoretical models that predict magnetic fields lying parallel to low-density, non-self-gravitating filaments, and perpendicular to higher-density, self-gravitating filaments.

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arXiv2016

Astrochemical Properties of Planck Cold Clumps

We observed thirteen Planck cold clumps with the James Clerk Maxwell Telescope/SCUBA-2 and with the Nobeyama 45 m radio telescope. The N$_2$H$^+$ distribution obtained with the Nobeyama telescope is quite similar to SCUBA-2 dust distribution. The 82 GHz HC$_3$N, 82 GHz CCS, and 94 GHz CCS emission are often distributed differently with respect to the N$_2$H$^+$ emission. The CCS emission, which is known to be abundant in starless molecular cloud cores, is often very clumpy in the observed targets. We made deep single-pointing observations in DNC, HN$^{13}$C, N$_2$D$^+$, cyclic-C$_3$H$_2$ toward nine clumps. The detection rate of N$_2$D$^+$ is 50\%. Furthermore, we observed the NH$_3$ emission toward 15 Planck cold clumps to estimate the kinetic temperature, and confirmed that most of targets are cold ($\lesssim$ 20 K). In two of the starless clumps observe, the CCS emission is distributed as it surrounds the N$_2$H$^+$ core (chemically evolved gas), which resembles the case of L1544, a prestellar core showing collapse. In addition, we detected both DNC and N$_2$D$^+$. These two clumps are most likely on the verge of star formation. We introduce the Chemical Evolution Factor (CEF) for starless cores to describe the chemical evolutionary stage, and analyze the observed Planck cold clumps.

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