arXiv subjects

Misaki Mizumoto

Publications and source records attributed to Misaki Mizumoto.

At least 73 records · Page 4Linked to original sources

arXiv2020

Testing The Lamp-Post and Wind Reverberation Models with XMM-Newton Observations of NGC 5506

The lamp-post geometry is often used to model X-ray data of accreting black holes. Despite its simple assumptions, it has proven to be powerful in inferring fundamental black hole properties such as the spin. Early results of X-ray reverberations showed support for such a simple picture, though wind-reverberation models have also been shown to explain the observed delays. Here, we analyze new and old XMM-Newton observations of the variable Seyfert-1 galaxy NGC 5506 to test these models. The source shows an emission line feature around 6.7 keV that is delayed relative to harder and softer energy bands. The spectral feature can be modeled with either a weakly relativistic disk line or by scattering in distant material. By modeling both the spectral and timing signatures, we find that the reflection fraction needed to explain the lags is larger than observed in the time-averaged spectrum, ruling out both a static lamp-post and simple wind reverberation models.

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arXiv2019

Possible progression of mass flow processes around young intermediate-mass stars based on high-resolution near-infrared spectroscopy. I. Taurus

We used the WINERED spectrograph to perform near-infrared high-resolution spectroscopy (resolving power $R = 28$,000) of 13 young intermediate-mass stars in the Taurus star-forming region. Based on the presence of near- and mid-infrared continuum emission, young intermediate-mass stars can be classified into three different evolutionary stages: Phases I, II, and III in the order of evolution. Our obtained spectra ($λ= 0.91$--1.35\,$μ$m) depict \HeI $λ$10830 and P$β$ lines that are sensitive to magnetospheric accretion and winds. We also investigate five sources each for P$β$ and \ion{He}{1} lines that were obtained from previous studies along with our targets. We observe that the P$β$ profile morphologies in Phases I and II corresponded to an extensive variety of emission features; however, these features are not detected in Phase III. We also observe that the He I profile morphologies are mostly broad subcontinuum absorption lines in Phase I, narrow subcontinuum absorption lines in Phase II, and centered subcontinuum absorption features in Phase III. Our results indicate that the profile morphologies exhibit a progression of the dominant mass flow processes: stellar wind and probably magnetospheric accretion in the very early stage, magnetospheric accretion and disk wind in the subsequent stage, and no activities in the final stage. These interpretations further suggest that opacity in protoplanetary disks plays an important role in mass flow processes. Results also indicate that \ion{He}{1} absorption features in Phase III sources, associated with chromospheric activities even in such young phases, are characteristics of intermediate-mass stars.

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arXiv2019

Thermally driven wind as the origin of warm absorbers in AGN

Warm absorbers are present in many Active Galactic Nuclei (AGN), seen as mildly ionised gas outflowing with velocities of a few hundred to a few thousand kilometres per second. These slow velocities imply a large launch radius, pointing to the broad line region and/or torus as the origin of this material. Thermal driving was originally suggested as a plausible mechanism for launching this material but recent work has focused instead on magnetic winds, unifying these slow, mildly ionised winds with the more highly ionised ultra-fast outflows. Here we use the recently developed quantitative models for thermal winds in black hole binary systems to predict the column density, velocity and ionisation state from AGN. Thermal winds are sensitive to the spectral energy distribution (SED), so we use realistic models for SEDs which change as a function of mass and mass accretion rate, becoming X-ray weaker (and hence more disc dominated) at higher Eddington ratio. These models allow us to predict the launch radius, velocity, column density and ionisation state of thermal winds as well as the mass loss rate and energetics. While these match well to some of the observed properties of warm absorbers, the data point to the presence of additional wind material, most likely from dust driving.

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arXiv2019

First detection of $A$--$X$ (0,0) bands of interstellar C$_2$ and CN

We report the first detection of C$_2$ $A^1Π_u$--$X^1Σ_g^+$ (0,0) and CN $A^2Π_u$--$X^2Σ^+$ (0,0) absorption bands in the interstellar medium. The detection was made using the near-infrared (0.91--1.35 $μ$m) high-resolution ($R=20,000$ and 68,000) spectra of Cygnus OB2 No.\,12 collected with the WINERED spectrograph mounted on the 1.3 m Araki telescope. The $A$--$X$ (1,0) bands of C$_2$ and CN were detected simultaneously. These near-infrared bands have larger oscillator strengths, compared with the $A$--$X$ (2,0) bands of C$_2$ and CN in the optical. In the spectrum of the C$_2$ (0,0) band with $R=68,000$, three velocity components in the line of sight could be resolved and the lines were detected up to high rotational levels ($J''\sim20$). By analyzing the rotational distribution of C$_2$, we could estimate the kinetic temperature and gas density of the clouds with high accuracy. Furthermore, we marginally detected weak lines of $^{12}$C$^{13}$C for the first time in the interstellar medium. Assuming that the rotational distribution and the oscillator strengths of the relevant transitions of $^{12}$C$_2$ and $^{12}$C$^{13}$C are the same, the carbon isotope ratio was estimated to be $^{12}\text{C}/^{13}\text{C}=50$--100, which is consistent with the ratio in the local interstellar medium. We also calculated the oscillator strength ratio of the C$_2$ (0,0) and (1,0) bands from the observed band strengths. Unfortunately, our result could not discern theoretical and experimental results because of the uncertainties. High-resolution data to resolve the velocity components will be necessary for both bands in order to put stronger constraints on the oscillator strength ratios.

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arXiv2019

FeI lines in 0.91-1.33 ${\rm μ}$m spectra of red giants for measuring the microturbulence and metallicities

For a detailed analysis of stellar chemical abundances, high-resolution spectra in the optical have mainly been used, while the development of near-infrared (NIR) spectrograph has opened new wavelength windows. Red giants have a large number of resolved absorption lines in both the optical and NIR wavelengths, but the characteristics of the lines in different wave passbands are not necessarily the same. We present a selection of FeI lines in the $z^{\prime}$, $Y$, and $J$ bands (0.91-1.33 $μ$m). On the basis of two different lists of lines in this range, the Vienna Atomic Line Database (VALD) and the catalog published by Meléndez & Barbuy in 1999 (MB99), we selected sufficiently strong lines that are not severely blended and compiled lists with 107 FeI lines in total (97 and 75 lines from VALD and MB99, respectively). Combining our lists with high-resolution ($λ/Δλ= 28,000$) and high signal-to-noise ($>500$) spectra taken with a NIR spectrograph, WINERED, we present measurements of the iron abundances of two prototype red giants: Arcturus and $μ$ Leo. A bootstrap method for determining the microturbulence and abundance together with their errors is demonstrated. The standard deviations of $\logε_{\rm Fe}$ values from individual FeI lines are significantly smaller when we use the lines from MB99 instead of those from VALD. With the MB99 list, we obtained $ξ=1.20\pm0.11\ {\rm km~s^{-1}}$ and $\logε_{\rm Fe}=7.01\pm0.05$ dex for Arcturus, and $ξ=1.54\pm0.17\ {\rm km~s^{-1}}$ and $\logε_{\rm Fe}=7.73\pm0.07$ dex for $μ$ Leo. These final values show better agreements with previous values in the literature than the corresponding values we obtained with VALD.

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arXiv2018

Kinetic energy transfer from X-ray ultrafast outflows to mm/sub-mm cold molecular outflows in Seyfert galaxies

UltraFast Outflows (UFOs), seen as X-ray blueshifted absorption lines in active galactic nuclei (AGNs), are considered to be a key mechanism for AGN feedback. In this scenario, UFO kinetic energy is transferred into the cold and extended molecular outflow observed at the mm/sub-mm wavelength, which blows away the gas and suppresses star formation and accretion onto the central black hole (BH). However, the energy transfer between the inner UFO and the outer molecular outflow has not yet fully studied mainly due to the limited sample. In this paper, we performed comparison of their kinetic energy using the mm/sub-mm published data and the X-ray archival data. Among fourteen Seyfert galaxies whose molecular outflows are detected in the IRAM/PdBI data, eight targets are bright enough to perform spectral fitting in X-ray, and we have detected UFO absorption lines in six targets with 90% significance level, using XMM-Newton and Suzaku satellites. The time-averaged UFO kinetic energy was derived from the spectral fitting. As a result, we have found that the energy-transfer rate (kinetic energy ratio of the molecular outflow to the UFO) ranges from $\sim7\times10^{-3}$ to $\sim$1, and has a negative correlation with the BH mass, which shows that the AGN feedback is more efficient in the lower mass BHs. This tendency is consistent with the theoretical prediction that the cooling time scale of the outflowing gas becomes longer than the flow time scale when the BH mass is smaller.

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arXiv2018

X-ray reverberation lags of the Fe-K line due to AGN disc winds

Short X-ray reverberation lags are seen across a broad Fe-K energy band in more than twenty active galactic nuclei (AGNs). This broad iron line feature in the lag spectrum is most significant in super-Eddington sources such as Ark 564 ($L/L_{\rm Edd}\sim 1$) and 1H 0707--495 ($L/L_{\rm Edd}\gtrsim 10$). The observed lag timescales correspond to very short distances of several $R_g/c$, so that they have been used to argue for extremely small `lamp-post' coronae close to the event horizon of rapidly spinning black holes. Here we show for the first time that these Fe-K short lags are more likely to arise from scattering in a highly-ionised wind, launched at $\sim 50\,R_g$, rotating and outflowing with a typical velocity of $0.2c$. We show that this model can simultaneously fit the time-averaged energy spectra and the short-timescale lag-energy spectra of both 1H 0707--495 and Ark 564. The Fe-K line in 1H 0707--495 has a strong P-Cygni-like profile, which requires that the wind solid angle is large and that our line of sight intercepts the wind. By contrast the lack of an absorption line in the energy spectrum of Ark 564 requires rather face-on geometry, while the weaker broad Fe-K emission in the energy and lag-energy spectra argue for a smaller solid angle of the wind. This is consistent with theoretical predictions that the winds get stronger when the sources are more super-Eddington, supporting the idea of AGN feedback via radiation pressure driven winds.

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arXiv2018

A newly-identified emission-line region around P Cygni

We present a high-resolution ($R \simeq 20,000$) near-infrared (9,100-13,500 $Å$) long-slit spectrum of P Cygni obtained with the newly commissioned WINERED spectrograph in Japan. In the obtained spectrum, we have found that the velocity profiles of the [Fe II] emission lines are resolved into two peaks at a velocity of $\simeq220$ km s$^{-1}$ with a moderate dip in between and with additional sub-peaks at $\simeq\pm100$~km~s$^{-1}$. The sub-peak component is confirmed with the long-slit echellogram to originate in the known shell with a radius of $\simeq10^{\prime\prime}$, which was originally created by the outburst in 1600 AD. On the other hand, the $\simeq220$ km s$^{-1}$ component, which dominates the [Fe II] flux from P Cygni, is found to be concentrated closer to the central star with an apparent spatial extent of $\simeq3^{\prime\prime}$. The extent is much larger than the compact ($<0^{\prime\prime}.1$) regions traced with hydrogen, helium, and metal permitted lines. The velocity, estimated mass, and dynamical time of the extended emission-line region suggest that the region is an outer part of the stellar wind region. We suggest that the newly-identified emission-line region may trace a reverse shock due to the stellar wind overtaking the outburst shell.

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arXiv2018

Correction of near-infrared high-resolution spectra for telluric absorption at 0.90-1.35 microns

We report a method of correcting a near-infrared (0.90-1.35 $μ$m) high-resolution ($λ/Δλ\sim28,000$) spectrum for telluric absorption using the corresponding spectrum of a telluric standard star. The proposed method uses an A0\,V star or its analog as a standard star from which on the order of 100 intrinsic stellar lines are carefully removed with the help of a reference synthetic telluric spectrum. We find that this method can also be applied to feature-rich objects having spectra with heavily blended intrinsic stellar and telluric lines and present an application to a G-type giant using this approach. We also develop a new diagnostic method for evaluating the accuracy of telluric correction and use it to demonstrate that our method achieves an accuracy better than 2\% for spectral parts for which the atmospheric transmittance is as low as $\sim$20\% if telluric standard stars are observed under the following conditions: (1) the difference in airmass between the target and the standard is $\lesssim 0.05$; and (2) that in time is less than 1 h. In particular, the time variability of water vapor has a large impact on the accuracy of telluric correction and minimizing the difference in time from that of the telluric standard star is important especially in near-infrared high-resolution spectroscopic observation.

astro-ph.IM↗

arXiv2018

X-ray short-time lags in the Fe-K energy band produced by scattering clouds in active galactic nuclei

X-rays illuminating the accretion disc in active galactic nuclei give rise to an iron K line and its associated reflection spectrum which are lagged behind the continuum variability by the light-travel time from the source to the disc. The measured lag timescales in the iron band can be as short as $\sim R_g/c$, where $R_g$ is the gravitational radius, which is often interpreted as evidence for a very small continuum source close to the event horizon of a rapidly spinning black hole. However, the short lags can also be produced by reflection from more distant material, because the primary photons with no time-delay dilute the time-lags caused by the reprocessed photons. We perform a Monte-Carlo simulation to calculate the dilution effect in the X-ray reverberation lags from a half-shell of neutral material placed at $100\,R_g$ from the central source. This gives lags of $\sim2\,R_g/c$, but the iron line is a distinctly narrow feature in the lag-energy plot, whereas the data often show a broader line. We show that both the short lag and the line broadening can be reproduced if the scattering material is outflowing at $\sim0.1c$. The velocity structure in the wind can also give shifts in the line profile in the lag-energy plot calculated at different frequencies. Hence we propose that the observed broad iron reverberation lags and shifts in profile as a function of frequency of variability can arise from a disc wind at fairly large distances from the X-ray source.

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arXiv2018

Can the relativistic light bending model explain X-ray spectral variations of Seyfert galaxies?

Many Seyfert galaxies are known to exhibit Fe-K broad emission line features in their X-ray energy spectra. The observed lines have three distinct features; (1) the line profiles are skewed and show significant low-energy tails, (2) the Fe-K band have low variability, which produces a broad and deep dip in the root-mean-square (rms) spectra, and (3) photons in this band have time lags behind those in the adjacent energy bands with amplitudes of several $R_g/c$, where $R_g$ is the gravitational radius. The "relativistic light bending model" is proposed to explain these observed features, where a compact X-ray source (lamp post) above an extreme Kerr black hole illuminates the innermost area of the accretion disc. In this paper, we critically examine the relativistic light bending model by computing the rms spectra and the lag features using a ray-tracing technique, when a lamp post moves vertically on the black hole spin axis. As a result, we found that the observed deep rms dip requires that the iron is extremely overabundant ($\gtrsim10$ solar), whereas the observed lag amplitude is consistent with the normal iron abundance. Furthermore, disappearance of the lag in the high-flux state requires a source height as high as $\sim40\,R_g$, which contradicts the relativistically broad emission line feature. Our simulations agree with the data that the reverberation feature moves to lower frequencies with larger source height, however, if this scenario is correct, the simulations predict detection of a clear Fe-K lag at low frequencies, which is not constrained in the data. Therefore, we conclude that the relativistic light bending model may not explain the characteristic Fe-K spectral variations in Seyfert galaxies.

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arXiv2017

Nature of the Warm Absorber Outflow in NGC 4051

The Narrow-line Seyfert 1 galaxy NGC 4051 is known to exhibit significant X-ray spectral/flux variations and have a number of emission/absorption features. X-ray observations have revealed that these absorption features are blueshifted, which indicates that NGC 4051 has warm absorber outflow. In order to constrain physical parameters of the warm absorber outflow, we analyze the archival data with the longest exposure taken by XMM-Newton in 2009. We calculate the root-mean-square (RMS) spectra with the grating spectral resolution for the first time. The RMS spectra have a sharp peak and several dips, which can be explained by variable absorption features and non-variable emission lines; a lower-ionized warm absorber (WA1: $\logξ= 1.5,\, v=-650\,\mathrm{km\,s}^{-1}$) shows large variability, whereas higher-ionized warm absorbers (WA2: $\logξ= 2.5,\,v=-4100\,\mathrm{km\,s}^{-1}$, WA3: $\logξ= 3.4,\, v=-6100\,\mathrm{km\,s}^{-1}$) show little variability. WA1 shows the maximum variability at a timescale of $\sim10^4$~s, suggesting that the absorber locates at $\sim10^3$ times of the Schwarzschild radius. The depth of the absorption features due to WA1 and the observed soft X-ray flux are anti-correlated in several observational sequences, which can be explained by variation of partial covering fraction of the double-layer blobs that are composed of the Compton-thick core and the ionized layer ($=$WA1). WA2 and WA3 show little variability and presumably extend uniformly in the line of sight. The present result shows that NGC 4051 has two types of the warm absorber outflows; the static, high-ionized and extended line-driven disk winds, and the variable, low-ionized and clumpy double-layer blobs.

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arXiv2016

Origin of the Characteristic X-ray Spectral Variations of IRAS 13224$-$3809

The Narrow-line Seyfert 1 galaxy (NLS1) IRAS 13224$-$3809 is known to exhibit significant X-ray spectral variation, a sharp spectral drop at $\sim$ 7 keV, strong soft excess emission, and a hint of iron L-edge feature, which is very similar to the NLS1 1H 0707$-$495. We have proposed the "Variable Double Partial Covering (VDPC) model" to explain the energy spectra and spectral variability of 1H 0707$-$495 (Mizumoto, Ebisawa and Sameshima 2014, PASJ, 66, 122). In this model, the observed flux/spectral variations below 10 keV within a $\sim$day are primarily caused by change of the partial covering fraction of patchy clouds composed by double absorption layers in the line of sight. In this paper, we apply the VDPC model to IRAS 13224$-$3809. Consequently, we have found that the VDPC model can explain the observed spectral variations of IRAS 13224$-$3809 in the 0.5$-$10 keV band. In particular, we can explain the observed Root Mean Square (RMS) spectra (energy dependence of the fractional flux variation) in the entire 0.5$-$10 keV band. In addition to the well-known significant drop in the iron K-band, we have found intriguing iron L-peaks in the RMS spectra when the iron L-edge is particularly deep. This feature, which is also found in 1H 0707$-$495, is naturally explained with the VDPC model, such that the RMS variations increase at the energies where optical depths of the partial absorbers are large. The absorbers have a larger optical depth at the iron L-edge than in the adjacent energy bands, thus a characteristic iron L-peak appears. On the other hand, just below the iron K-edge, the optical depth is the lowest and the RMS spectrum has a broad dip.

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arXiv2016

Near infrared diffuse interstellar bands toward the Cygnus OB2 association

We obtained the near-infrared (NIR) high-resolution ($R\equivλ/Δλ\sim20,000$) spectra of the seven brightest early-type stars in the Cygnus OB2 association for investigating the environmental dependence of diffuse interstellar bands (DIBs). The WINERED spectrograph mounted on the Araki 1.3m telescope in Japan was used to collect data. All 20 of the known DIBs within the wavelength coverage of WINERED ($0.91<λ<1.36μ$m) were clearly detected along all lines of sight because of their high flux density in the NIR wavelength range and the large extinction. The equivalent widths (EWs) of DIBs were not correlated with the column densities of C$_2$ molecules, which trace the patchy dense component, suggesting that the NIR DIB carriers are distributed mainly in the diffuse component. On the basis of the correlations among the NIR DIBs both for stars in Cyg OB2 and stars observed previously, $λλ$10780, 10792, 11797, 12623, and 13175 are found to constitute a "family", in which the DIBs are correlated well over the wide EW range. In contrast, the EW of $λ$10504 is found to remain almost constant over the stars in Cyg OB2. The extinction estimated from the average EW of $λ$10504 ($A_V\sim3.6$mag) roughly corresponds to the lower limit of the extinction distribution of OB stars in Cyg OB2. This suggests that $λ$10504 is absorbed only by the foreground clouds, implying that the carrier of $λ$10504 is completely destroyed in Cyg OB2, probably by the strong UV radiation field. The different behaviors of the DIBs may be caused by different properties of the DIB carriers.

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arXiv2016

Origin of the Broad Iron Line Feature and the Soft X-ray Variation in Seyfert Galaxies

Many Seyfert galaxies are known to exhibit significant X-ray spectral variations and seemingly broad iron K-emission line features. In this paper, we show that the "variable partial covering model", which has been successfully proposed for MCG-6.30-15 (Miyakawa, Ebisawa & Inoue 2012) and 1H0707.495 (Mizumoto, Ebisawa & Sameshima 2014), can also explain the spectral variations in 2-10 keV as well as the broad iron line features in 20 other Seyfert galaxies observed with Suzaku. In this model, the absorbed spectral component through the optically-thick absorbing clouds has a significant iron K-edge, which primarily accounts for the observed seemingly broad iron line feature. Fluctuation of the absorbing clouds in the line of sight of the extended X-ray source results in variation of the partial covering fraction, which causes an anti-correlation between the direct (not covered) spectral component and the absorbed (covered) spectral component below ~10 keV. Observed spectral variation in 2-10 keV in a timescale of less than ~day is primarily explained by such variations of the partial covering fraction, while the intrinsic soft X-ray luminosity is hardly variable.

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arXiv2015

Origin of the X-ray Broad Iron Spectral Feature in GRS 1915+105

The X-ray spectrum of GRS 1915+105 is known to have a ``broad iron spectral feature'' in the spectral hard state. Similar spectral features are often observed in Active Galactic Nuclei (AGNs) and other black-hole binaries (BHBs), and several models have been proposed for explaining it. In order to distinguish spectral models, time variation provides an important key. In AGNs, variation amplitude has been found to drop significantly at the iron K-energy band at timescales of ~10 ks. If spectral variations of black-holes are normalized by their masses, the spectral variations of BHBs at timescales of sub-seconds should exhibit similar characteristics to those of AGNs. In this paper, we investigated spectral variations of GRS 1915+105 at timescales down to ~10 ms. This was made possible for the first time with the Suzaku XIS Parallel-sum clocking (P-sum) mode, which has the CCD energy-resolution as well as a time-resolution of 7.8 ms. Consequently, we found that the variation amplitude of GRS 1915+105 does not drop at the iron K-energy band at any timescales from 0.06 s to 63000 s, and that the entire X-ray flux and the iron feature are independently variable at timescales of hours. These are naturally understood in the framework of the ``partial covering'' model, in which variation timescales of the continuum flux and partial absorbers are independent. The difference of energy dependence of the variation amplitude between AGN and BHB is presumably due to different mechanisms of the outflow winds, i.e., the partial absorbers are due to UV-line driven winds (AGN) or thermally-driven winds (BHB).

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arXiv2015

Variability of the X-ray Broad Iron Spectral Features in Active Galactic Nuclei and Black-hole Binaries

The "broad iron spectral features" are often seen in X-ray spectra of Active Galactic Nuclei (AGN) and black-hole binaries (BHB). These features may be explained either by the "relativistic disc reflection" scenario or the "partial covering" scenario: It is hardly possible to determine which model is valid from time-averaged spectral analysis. Thus, X-ray spectral variability has been investigated to constrain spectral models. To that end, it is crucial to study iron structure of BHBs in detail at short time-scales, which is, for the first time, made possible with the Parallel-sum clocking (P-sum) mode of XIS detectors on board Suzaku. This observational mode has a time-resolution of 7.8~ms as well as a CCD energy-resolution. We have carried out systematic calibration of the P-sum mode, and investigated spectral variability of the BHB GRS 1915+105. Consequently, we found that the spectral variability of GRS 1915+105 does not show iron features at sub-seconds. This is totally different from variability of AGN such as 1H0707--495, where the variation amplitude significantly drops at the iron K-energy band. This difference can be naturally explained in the framework of the "partial covering" scenario.

astro-ph.HE↗

arXiv2015

Near-infrared diffuse interstellar bands in 0.91-1.32 micron

We present a comprehensive survey of diffuse interstellar bands (DIBs) in $0.91-1.32μ$m with a newly-developed near-infrared (NIR) spectrograph, WINERED, mounted on the Araki 1.3 m Telescope in Japan. We obtained high-resolution ($R=28,300$) spectra of 25 early-type stars with color excesses of $0.07<E(B-V)<3.4$. In addition to the five DIBs previously detected in this wavelength range, we identified 15 new DIBs, 7 of which were reported as DIB "candidates" by Cox. We analyze the correlations among NIR DIBs, strong optical DIBs, and the reddening of the stars. Consequently, we found that all NIR DIBs show weaker correlations with the reddening rather than the optical DIBs, suggesting that the equivalent widths of NIR DIBs depend on some physical conditions of the interstellar clouds, such as UV flux. Three NIR DIBs, $λλ$10780, 10792, and 11797, are found to be classifiable as a "family," in which the DIBs are well correlated with each other, suggesting that the carriers of these DIBs are connected with some chemical reactions and/or have similar physical properties such as ionization potential. We also found that three strongest NIR DIBs $λ\lambda10780, 11797, 13175$ are well correlated with the optical DIB $λ5780.5$, whose carrier is proposed to be a cation molecule with high ionization potential, indicating that the carriers of the NIR DIBs could be cation molecules.

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