arXiv subjects

Mohamad Numan

Publications and source records attributed to Mohamad Numan.

8 recordsLinked to original sources

arXiv2025

Interplay of Orbital Degeneracy and Vacancies in Stabilizing Collinear Magnetic Order in Cr$_{1+δ}$Te$_2$

Cr$_{1+δ}$Te$_2$, a two-dimensional van der Waals ferromagnet, displays a contested magnetic structure, poised between collinear and non-collinear spin configurations. In this work, we investigate the magnetic structure of Cr$_{1.33}$Te$_2$ at the microscopic level by combining single-crystal neutron diffraction, X-ray absorption spectroscopy, and first-principles calculations. Neutron diffraction measurements reveal a distinct collinear spin alignment, whereas spectroscopic analyses reveal inherent structural vacancies at both Cr and Te sites. These vacancies lead to local symmetry breaking that elevates the orbital degeneracy of the Cr 3$d$ states, as demonstrated by our first-principles analysis. The resulting modification of magnetocrystalline anisotropy emerges as the key mechanism stabilising the collinear magnetic ground state over the non-collinear one in the presence of vacancies. Our findings uncover a vacancy-driven route to control spin anisotropy and magnetic ordering in layered ferromagnets, offering new insights into the design of tunable 2D magnetic materials.

cond-mat.str-el↗

arXiv2025

Atypical Ferrimagnetism in Ni$_4$Nb$_2$O$_9$

Ferrimagnetism typically emerges from chemically distinct magnetic ions or the same element at two inequivalent crystallographic sites, rendering unequal moments. In contrast, Ni4Nb2O9 has been recently discovered to show a different mechanism, where identical Ni2 ions with the same ligand coordination develop unequal magnetic moments purely due to differences in local environments. Here, we investigate the microscopic origin of this emergent mechanism through a synergy of powder neutron diffraction, inelastic neutron scattering, and first principle based calculations. We demonstrate that the NiA and NiB sublattices, while sharing the same nominal valence, differ in their magnetic dimensionality NiA forms quasi one dimensional chains with enhanced p d hybridization and a reduced magnetic moment, whereas NiB retains a nearly two-dimensional geometry and a full S 1 moment. Our results underscore the pivotal role of spin dimensionality and local structural distortions in stabilizing ferrimagnetism in systems with electronically equivalent magnetic ions.

cond-mat.mtrl-sci↗

arXiv2025

Weak Itinerant Ferromagnetism (WIFM) in MAX phase compound Cr$_{1.9}$Fe$_{0.1}$GeC

Magnetic MAX phase compounds are important materials for studying the two-dimensional magnetism because of their layered crystallographic structure. The hexagonal MAX phase compound Cr$_2$GeC is a Pauli paramagnet, and here we report the induction of an ordered magnetic state by doping Fe at the Cr site. Induced magnetism for small doping concentrations (indicated as 5% and 2.5%) is found to have a weak itinerant ferromagnetic character. The Rhodes-Wolhfarth ratio is found to be 13.29, while the coefficient of electronic heat capacity ($Γ$) is 27 mJ-mol$^{-1}$K$^{-2}$ for Cr$_{1.9}$Fe$_{0.1}$GeC. Our x-ray magnetic circular dichorism measurement confirms that the magnetic moment arises from the Fe atom only, and Cr has negligible contribution towards the ordered moment. Our critical analysis indicates that the magnetic phase transition in Cr$_{1.9}$Fe$_{0.1}$GeC follows mean field theory.

cond-mat.str-el↗

arXiv2025

Magnetic Metastability driven Anomalous Hall Effect in Fe$_{x}$TaS$_2$

We report here the observation of robust thermoremanent magnetization (TRM) in Fe-intercalated TaS$_2$ single crystal Fe$_{x}$TaS$_2$, which develops upon cooling under a moderate magnetic field of 500 Oe or higher. The thermoremanence is found to exist in a zero magnetic field up to a temperature as high as 160 K, which is well above the ferromagnetic Curie point ($T_C =$ 90 K) of the sample. The TRM in this compound can be traced back to the strong Ising character and the quasi-two-dimensional nature of the spins. The analysis of the magnetization data indicates the presence of short-range magnetic correlation in the form of a Griffiths singularity above $T_C$ to a temperature as high as 2$T_C$. The TRM is further manifested in the form of a large anomalous Hall effect (AHE) in zero magnetic field. In contrast to TRM, which exists well above $T_C$, the thermoremanent Hall effect vanishes as soon as the sample is heated above $T_C$. This may be an indication that a long-range ordered phase is essential for the emergence of AHE.

cond-mat.str-el↗

arXiv2024

Magnetic field induced arrested state and observation of spontaneous anomalous Hall effect in TbMn$_6$Sn$_6$

The quasi two-dimensional kagome ferrimagnet TbMn$_6$Sn$_6$ is investigated for thermo-remanent magnetization and Hall effects. On cooling under a moderate magnetic field, the sample attains a magnetization value close to the saturation magnetization. Upon heating in a very small magnetic field, the sample continues to maintain the large value of magnetization, which eventually diminishes distinctly at around 200 K manifesting an ultrasharp jump. A similar feature is also observed in the Hall resistivity, which holds its saturation value when heated back in zero field after being field-cooled. The ultrasharp jump in magnetization is also get reflected in our Hall data. The observed data is exotic and can be rooted to the large anisotropy and the strong exchange interaction.

cond-mat.mtrl-sci↗

arXiv2024

Suppression of Intrinsic Hall Effect through Competing Berry Curvature in Cr$_{1+δ}$Te$_2$

We conducted a comprehensive analysis of the magnetic and electronic transport properties of the layered chalcogenide Cr$_{1+δ}$Te$_2$ in its single crystalline form. This material exhibits a ferromagnetic transition at a critical temperature of $T_C = 191$ K, characterized by significant thermal hysteresis in the magnetization data below this temperature. Measurements of isothermal magnetization, magnetocaloric effect, and magnetoresistance indicate that the system exhibits strong magnetocrystalline anisotropy, with the $c$-axis serving as the easy axis of magnetization. The Cr$_{1+δ}$Te$_2$ compound shows pronounced anomalous Hall effect (AHE); however, existing experimental and theoretical data do not provide a clear understanding of the nature and origin of this phenomenon. Our experimental findings suggest that the skew scattering mechanism primarily accounts for the observed AHE. In contrast, our theoretical study reveals the presence of gapped nodal points accompanied by non-zero Berry Curvature, which are expected to contribute towards intrinsic AHE. A detailed analysis of the electronic band structure, obtained through density functional theory calculations, reveals that the Berry Curvature at different nodal points exhibit both positive and negative signs. These opposing contributions largely cancel each other out, thereby significantly diminishing the intrinsic contribution to the AHE.

cond-mat.mtrl-sci↗

arXiv2024

Does carrier localization affect the anomalous Hall effect?

The effect of carrier localization due to electron-electron interaction in anomalous Hall effect is elusive and there are contradictory results in the literature. To address the issue, we report here the detailed transport study including the Hall measurements on $β$-Mn type cubic compound Co$_7$Zn$_7$Mn$_6$ with chiral crystal structure, which lacks global mirror symmetry. The alloy orders magnetically below $T_c$ = 204 K, and reported to show spin glass state at low temperature. The longitudinal resistivity ($ρ_{xx}$) shows a pronounced upturn below $T_{min}$ = 75 K, which is found to be associated with carrier localization due to quantum interference effect. The upturn in $ρ_{xx}$ shows a $T^{1/2}$ dependence and it is practically insensitive to the externally applied magnetic field, which indicate that electron-electron interaction is primarily responsible for the low-$T$ upturn. The studied sample shows considerable value of anomalous Hall effect below $T_c$. We found that the localization effect is present in the ordinary Hall coefficient ($R_0$), but we failed to observe any signature of localization in the anomalous Hall resistivity or conductivity. The absence of localization effect in the anomalous Hall effect in Co$_7$Zn$_7$Mn$_6$ may be due to large carrier density, and it warrants further theoretical investigations, particularly with systems having broken mirror symmetry.

cond-mat.str-el↗

arXiv2022

Evidence of exchange-striction and charge disproportionation in the magneto-electric material Ni3TeO6

The chiral magneto-electric compound Ni3TeO6 is investigated through temperature-dependent synchrotron-based powder x-ray diffraction and x-ray absorption spectroscopy between 15 to 300 K. Our work provides direct evidence for the exchange-striction in the material around the concomitant onset point of collinear antiferromagnetic and magneto-electric phases. The x-ray absorption near edge spectra and x-ray photoelectron spectra show that the sample consists of both Ni2+ and Ni3+ ions in the lattice. The ionic state of Ni is found to be quite robust, and it is largely independent of the preparation route. Additionally, the minority Te4+ state is found to coexist with the majority Te6+ state, which may arise from the charge disproportionation between Ni and Te ions (Ni2+ + Te6+ --> Ni3+ + Te4+). The observed mixed valency of Ni is also confirmed by the total paramagnetic moment per Ni atom in the system. This mixed valency in the metal ions and the exchange-striction may be attributed to the observed magneto-electric effect in the system.

cond-mat.str-el↗