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Mohammed Guendouz

Publications and source records attributed to Mohammed Guendouz.

12 recordsLinked to original sources

Yellow stimulated emission from Dy$^{3+}$-doped silica glass microspheres

Dy$^{3+}$-doped silica glass whispering gallery mode microspheres are fabricated by fiber fusion splicing. They present an almost ideal spherical morphology with a radius ranging from 60 to 67 $μ$m as determined by confocal laser microscopy. The host composition of the microsphere is close to that of the fiber core. The dopant Dy$^{3+}$ ions are uniformly distributed across the microsphere as evidenced by $μ$-luminescence studies and present a luminescence lifetime. The Dy$^{3+}$-doped glass microspheres were excited via evanescent field coupling using a half-tapered fiber and a blue 450-nm GaN laser diode (direct pumping scheme). The yellow fluorescence of Dy$^{3+}$ ions is filtered by the whispering gallery modes (free spectral range: 0.5 nm for 67-$μ$m radius microsphere). The onset of stimulated emission is further observed highlighting the potential of such microresonators for narrow-linewidth light sources directly emitting visible light.

physics.optics

Criticality of an isotropic-to-smectic transition induced by anisotropic quenched disorder

We report combined optical birefringence and neutron scattering measurements on the liquid crystal 12CB nanoconfined in mesoporous silicon layers. This liquid crystal exhibits strong nematic-smectic coupling responsible for a discontinuous isotropic-to-smectic phase transition in the bulk state. Confined in porous silicon, 12CB is subjected to strong anisotropic quenched disorder: a short-ranged smectic state evolves out of a paranematic phase. This transformation appears continuous, losing its bulk first order character. This contrasts with previously reported observations on liquid crystals under isotropic quenched disorder. In the low temperature phase, both orientational and translational order parameters obey the same power-law.

cond-mat.mes-hall

Relation between static short-range order and dynamic heterogeneities in a nanoconfined liquid crystal

We analyze the molecular dynamics heterogeneity of the liquid crystal 4-n-octyl-4'-cyanobiphenyl nanoconfined in porous silicon. We show that the temperature dependence of the dynamic correlation length ?wall, which measures the distance over which a memory of the interfacial slowing down of the molecular dynamics persists, is closely related to the growth of the short-range static order arising from quenched random fields. More generally, this result may also shed some light on the connection between static and dynamic heterogeneities in a wide class of condensed and soft matter systems.

physics.chem-ph

Bioprotectant glassforming solutions confined in porous silicon nanocapillaries

Glycerol and trehalose-glycerol binary solutions are glass-forming liquids with remarkable bioprotectant properties. In this paper, we address the effects of confining of these solutions in straight channels of diameter D=8 nm formed by porous silicon. Neutron diffraction and incoherent quasielastic neutron scattering are used to reveal the different effects of nanoconfinement and addition of trehalose on the intermolecular structure and molecular dynamics of the liquid and glassy phases, on a nanosecond timescale.

cond-mat.soft

Molecular dynamics of glycerol and glycerol-trehalose bioprotectant solutions nanoconfined in porous silicon

Glycerol and trehalose-glycerol binary solutions are glass-forming liquids with remarkable bioprotectant properties. Incoherent quasielastic neutron scattering (QENS) is used to reveal the different effects of nanoconfinement and addition of trehalose on the molecular dynamics in the normal liquid and supercooled liquid phases, on a nanosecond timescale. Confinement has been realized in straight channels of diameter D=8 nm formed by porous silicon. It leads to a faster and more inhomogeneous relaxation dynamics deep in the liquid phase. This confinement effect remains at lower temperature where it affects the glassy dynamics. The glass transitions of the confined systems are shifted to low temperature with respect to the bulk ones. Adding trehalose tends to slow down the overall glassy dynamics and increases the non-exponential character of the structural relaxation. Unprecedented results are obtained for the binary bioprotectant solution, which exhibits an extremely non-Debye relaxation dynamics as a result of the combination of the effects of confinement and mixing of two constituents.

cond-mat.soft

Incoherent Quasielastic Neutron Scattering Study of Molecular dynamics of 4-n-cyano-4'-octylbiphenyl

We report incoherent quasielastic neutron scattering experiments on the thermotropic liquid crystal 4-n-cyano-4'-octylbiphenyl. The combination of time-of-flight and backscattering data allows analyzing the intermediate scattering function over about three decades of relaxation times. Translational diffusion and uniaxial molecular rotations are clearly identified as the major relaxation processes in respectively the nanosecond and picosecond time scales. The comparison with literature data obtained by other techniques is discussed.

physics.chem-ph

Rich polymorphism of a rod-like liquid crystal (8CB) confined in two types of unidirectional nanopores

We present a neutron and X-rays scattering study of the phase transitions of 4-n-octyl-4'-cyanobiphenyl (8CB) confined in unidirectional nanopores of porous alumina and porous silicon (PSi) membranes with an average diameter of 30 nm. Spatial confinement reveals a rich polymorphism, with at least four different low temperature phases in addition to the smectic A phase. The structural study as a function of thermal treatments and conditions of spatial confinement allows us to get insights into the formation of these phases and their relative stability. It gives the first description of the complete phase behavior of 8CB confined in PSi and provides a direct comparison with results obtained in bulk conditions and in similar geometric conditions of confinement but with reduced quenched disorder effects using alumina anopore membranes

cond-mat.soft

Sliding and translational diffusion of molecular phases confined into nanotubes

The remaining dynamical degrees of freedom of molecular fluids confined into capillaries of nano to sub-nanometer diameter are of fundamental relevance for future developments in the field of nanofluidics. These properties cannot be simply deduced from the bulk one since the derivation of macroscopic hydrodynamics most usually breaks down in nanoporous channels and additional effects have to be considered. In the present contribution, we review some general phenomena, which are expected to occur when manipulating fluids under confinement and ultraconfinement conditions.

cond-mat.soft

Molecular dynamics of a short range ordered smectic phase nanoconfined into porous silicon

4-n-octyl-4-cyanobiphenyl (8CB) has been recently shown to display an unusual sequence of phases when confined into porous silicon (PSi). The gradual increase of oriented short-range smectic (SRS) correlations in place of a phase transition has been interpreted as a consequence of the anisotropic quenched disorder induced by confinement in PSi. Combining two quasielastic neutron scattering experiments with complementary energy resolutions, we present the first investigation of the individual molecular dynamics of this system. A large reduction of the molecular dynamics is observed in the confined liquid phase, as a direct consequence of the dynamical boundary conditions imposed by the confinement. Temperature fixed window scans (FWS) reveal a continuous 'glass-like' reduction of the molecular dynamics of the confined liquid and SRS phases on cooling down to 250 K, where a solid-like behavior is finally reached by a two steps crystallization process.

cond-mat.mtrl-sci

Structure and relaxation processes of an anisotropic molecular fluid confined into 1D nanochannels

Structural order parameters of a smectic liquid crystal confined into the columnar form of porous silicon are studied using neutron scattering and optical spectroscopic techniques. It is shown that both the translational and orientational anisotropic properties of the confined phase strongly couple to the one-dimensional character of the porous silicon matrix. The influence of this confinement induced anisotropic local structure on the molecular reorientations occuring in the picosecond timescale is discussed.

cond-mat.soft

Dynamics of 8CB confined into porous silicon probed by incoherent neutron backscattering experiments

Confinement in the nanochannels of porous silicon strongly affects the phase behavior of the archetype liquid-crystal 4-n-octyl-4-cyanobiphenyl (8CB). A very striking phenom- enon is the development of a short-range smectic order, which occurs on a very broad temperature range. It suggests in this case that quenched disorder effects add to usual finite size and surface interaction effects. We have monitored the temperature variation of the molecular dynamics of the confined fluid by incoherent quasielastic neutron scat- tering. A strongly reduced mobility is observed at the highest temperatures in the liquid phase, which suggests that the interfacial molecular dynamics is strongly hindered. A continuously increasing slowdown appears on cooling together with a progressive growth of the static correlation length

cond-mat.soft

First evidence of anisotropic quenched disorder effects on a smectic liquid crystal confined in porous silicon

We present a neutron scattering analysis of the structure of the smectic liquid crystal octylcyanobiphenyl (8CB) confined in one-dimensional nanopores of porous silicon films (PS). The smectic transition is completely suppressed, leading to the extension of a short-range ordered smectic phase aligned along the pore axis. It evolves reversibly over an extended temperature range, down to 50 K below the \textit{N-SmA} transition in pure 8CB. This behavior strongly differs from previous observations of smectics in different one-dimensional porous materials. A coherent picture of this striking behavior requires that quenched disorder effects are invoked. The strongly disordered nature of the inner surface of PS acts as random fields coupling to the smectic order. The one-dimensionality of PS nano-channels offers new perspectives on quenched disorder effects, which observation has been restricted to homogeneous random porous materials so far.

cond-mat.soft