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Monique A. van der Veen

Publications and source records attributed to Monique A. van der Veen.

2 recordsLinked to original sources

Capacitive Pixelated CMOS Electronic Nose

Although some of the human senses can nowadays be replaced by low-cost electronic sensors such as microphones and image sensors, a compact low-cost electronic nose (E-nose) remains elusive. In this work, an E-nose is presented that can capacitively detect volatile organic compounds (VOCs). The E-nose consists of an array of 1024 capacitive microelectrodes on a complementary metal-oxide-semiconductor (CMOS) chip, functionalized by inkjet printing. The pixels are coated with a UV-curable ink and metal-organic frameworks (MOFs: ZIF-8, MIL-101(Cr), MIL-140A) to create chemically diverse microdomains that generate gas-specific response patterns through adsorption-driven dielectric loading. ZIF-8 exhibits the highest response to 2-butanone, whereas the UV-curable layer responds most strongly to toluene; both show low cross-sensitivity to water vapor, enabling operation under humid conditions. After calibration in pure gases, reproducible responses to controlled binary mixtures of toluene and 2-butanone are observed. The device operates at low power, combines a large 1024-pixel array with CMOS integration, and offers application-specific functionalization by inkjet printing, providing both low cost and versatility. By further extending the range of functionalization materials, the E-nose can be applied to analyze a wide variety of gases, with potential applications in safety monitoring, health, agriculture, and robotics.

physics.app-ph↗

Amorphous to Crystalline Transformation: How Cluster Aggregation Drives the Multistep Nucleation of ZIF-8

Nucleation, the pivotal first step of crystallization, governs essential characteristics of crystallization products, including size distribution, morphology, and polymorphism. While understanding this process is paramount to the design of chemical, pharmaceutical and industrial production processes, major knowledge gaps remain, especially with respect to the crystallization of porous solids. Also for nanocrystalline ZIF-8, one of the most widely studied metal-organic frameworks, questions regarding the species involved in the nucleation pathway and their structural and chemical transformations remain unanswered. By combining harmonic light scattering, inherently sensitive to structural changes, with NMR spectroscopy, which reveals molecular exchanges between particles and solution, we were able to capture the crystallization mechanism of ZIF-8 in unprecedented detail. This dual approach provides concurrent structural and chemical insights, revealing key processes not previously observed in ZIF crystallization. Upon mixing small charged prenucleation clusters (PNCs) are formed, exhibiting an excess of ligands and net positive charge. We show that nucleation is initiated by aggregation of PNCs, through the release of ligands and associated protons to the liquid. This leads to the formation of charge neutral amorphous precursor particles (APPs) which incorporate neutral monomers from solution, and crystallize ZIF-8. Our work highlights chemical dynamics as a vital, yet often overlooked, dimension in the multi-stage structural evolution of MOFs. By establishing the critical role of PNCs in the nucleation of ZIF-8, new pathways open up for controlling crystallization of metal-organic frameworks through targeted chemical interactions with these species.

cond-mat.mtrl-sci↗