arXiv subjects

Munan Hao

Publications and source records attributed to Munan Hao.

3 recordsLinked to original sources

arXiv2024

Weakly Coupled Type-II Superconductivity in a Laves compound ZrRe2

We present a comprehensive investigation of the superconducting properties of ZrRe2, a Re-based hexagonal Laves compounds. ZrRe2 crystallizes in a C14-type structure (space group P63/mmc), with cell parameters a=b=5.2682(5) and c=8.63045 . Resistivity and magnetic susceptibility data both suggest that ZrRe2 exhibits a sharp superconducting transition above 6.1 K. The measured lower and upper critical fields are 6.27 mT and 12.77 T, respectively, with a large upper critical field that approached the Pauli limit.Measurements of the heat capacity confirm the presence of bulk superconductivity, with a normalized specific heat change of 1.24 and an electron-phonon strength of 0.69 . DFT calculations revealed that the band structure of ZrRe2 is intricate and without van-Hove singularity. The observed large specific heat jump, combined with the electron-phonon strength , suggests that ZrRe2 is a weakly coupled type II superconductor.

cond-mat.supr-con↗

arXiv2024

Evidence of a hydrated mineral enriched in water and ammonium molecules in the Chang'e-5 lunar sample

The presence and distribution of water on the Moon are fundamental to our understanding of the Earth-Moon system. Despite extensive research and remote detection, the origin and chemical form of lunar water (H2O) have remained elusive. In this study, we present the discovery of a hydrated mineral, (NH4)MgCl3*6H2O, in lunar soil samples returned by the Chang'e-5 mission, containing approximately 41 wt% H2O. The mineral's structure and composition closely resemble novograblenovite, a terrestrial fumarole mineral formed through the reaction of hot basalt with water-rich volcanic gases, and carnallite, an earth evaporite mineral. We rule out terrestrial contamination or rocket exhaust as the origin of this hydrate, based on its chemical and isotopic compositions and formation conditions. The presence of ammonium indicates a more complex lunar degassing history and highlights its potential as a resource for lunar habitation. Our findings also suggest that water molecules can persist in sunlit areas of the Moon as hydrated salt, providing crucial constraints to the fugacity of water and ammonia vapor in lunar volcanic gases.

astro-ph.EP↗

arXiv2019

Crystal structures and the sign reversal Hall resistivity in iron-based superconductors Lix(C3H10N2)0.32FeSe (0.15<x<0.4)

We report the crystal structure, superconductivity and normal state properties of two iron-based materials, Li0.15(C3H10N2)0.32FeSe(P-4) and Lix(C3H10N2)0.32FeSe(P4/nmm, 0.25<x<0.4) with superconducting transition temperature from 40~46K. The determined crystal structures revealed a coupling between Li concentration and the oritation of 1,2-Diaminopropane molecules within the hyper expanded FeSe layers. Further fitting on resistivity in terms of the Lawence-Doniach model suggests the two superconductors belong to the quasi-two dimonsional system. With increasing temperature, a differences in crystal structures and doping levels. First principle calculations revealed the increase in FeSe layer diatance will restruct the Fermi surface and generate a new hole pocket around Gamma point in the Brillouin Zone. Our findings support that the increase in two dimensionalities will leads to a temperature induced Lifshitz transition in electron doped FeSe superconductors.

cond-mat.supr-con↗